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By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) spin trapping methodology has been used to study the reactions of manganese dusts with glutathione, employing a-{4-pyridyl-1-oxide)·N-tert-butyl-nitrone (PBN) and 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as spin traps. The results show evidence for the glutathionyl radical formation in the reactions of both MnO2 and manganese (Ill) acetate with glutathione. Based on these experimental observations, we hypothesise that the mechanism of neurotoxic effects of manganese might be due to the fact that the generation of glutathionyl radicals depletes the glutathione pool and reduces the glutathione shield against free radical products of dopamine metabolism and manganese induced reactive oxygenated species. IntroductionExposure to manganese compounds often occurs as the result of foundries and mining operations (1. 2). Other significant sources of environmental manganese include coal-fired power plants and burning of residual and crude oil (3, 4). Lately gasoline combustion has also started to contribute since manganese (methyl cyclopentadienyl manganese tricarbonyl. 0. 125 g/gallon) is being used instead of lead as an antiknock ingredient in automobile fuels (5. 6). Although manganese is an essential element in certain biological processes it is toxic in excessive amounts. The manganese toxicity is mainly associated with the nervous system (7-9). Symptoms frequently observed in manganese poisoning or manganism are disorientation, memory loss, anxiety, compulsive laughing and crying, mask-like faces, akincsia rigidity and tremor (10). In spite of numerous investigations to understand the mechanism of manganese induced injury. it has not been possible to localize the initial chemical lesion responsible for altered physiology and ultimate cell death. This may perhaps he the reason for failure in developing a successful therapy for manganese intoxication."

Jan 1, 1990

"INTRODUCTIONThe information compiled in this volume initially formed the response by the Generic Mineral Technology Center for -Respirable Dust (GTCRD) to a review of its research and technology transfer programs performed in 1990 by the Advisory Committee on Mining and Mineral Resources Research. This review for each mineral technology research center is accomplished, as required of the Bureau of Mines by the House/Senate Joint Conference Committee, through site visitation to the research institutions of the GTCRD and an in-depth questionnaire. The information provided by that questionnaire becomes an important factor in their recommendations concerning future directions of the program.The site visitations took place during January and February 1991 at the Milton S. Hershey Medical Center~ The Pennsylvania State University, West Virginia University, University of Minnesota, and Michigan Technological University, in addition to an in-mine visit conducted at the Loveridge Mine in West Virginia. The questionnaire was prepared and made available to the Advisory Committee and the Research Council for their review at the GTCRD annual project review meeting in Hershey, Pennsylvania, in April 1991.The comprehensive nature of the questionnaire and the scope of the information contained therein make it an excellent retrospective of the Center. Having a clear vision of where the Center has been and knowing where it is now helps to guide it into the future. It is believed that such a detailed view of the Center's facilities and research program will be of value to Center personnel and Advisory Committee members. Each aspect of the questionnaire was examined, answered in detail and documented thoroughly. With the completed questionnaire as a guide, this review of the Center's activities provides an update to Respirable Dust Center Research Program Review 1988, published in 1989 as the seventh of the Generic Mineral Technology Center for Respirable Dust volumes. As does that volume, this review presents the complete General Mineral Technology Center questionnaire, with the GTCRD's expanded responses and supporting documentation appended. An examination of the research program, Center personnel currently active on GMTC projects, the number of graduate degrees granted with GMTC supports GMTC publications, the degree of individual interaction, technology transfer activities, the reference center, GMTC equipment and facilities, and envisioned plans for future research directions provides updated information in these areas. In addition, this year, information has been included to demonstrate the interaction between the Center's goals and its research projects, with thorough consideration of actual research needs as specified by the National Academy of Sciences. This volume serves as a review of the years 1989 through 1990, the sixth and seventh years of the Center's operation."

Jan 1, 1990

By J. A. Mielczarski

An infrared external reflection spectroscopy (ERS) technique has been developed to study the structure of the adsorbed layer of ethyl xanthate formed on copper and natural chalcocite (Cu2S) electrodes. The infrared technique provides information concerning the identity and the orientation of the adsorbed species at monolayer and submonolayer coverages. X-ray photoelectron spectroscopy (XPS) studies have also been conducted to monitor changes at the surface. The results show that the first oxidation peak on the voltammograms for copper and the first and second oxidation peaks on the voltammograms for chalcocite electrodes are not characteristic of a chemisorbed xanthate species, which is contrary to what has been reported by other investigators previously. As evidenced by the XPS spectra, there was an increase in sulfur relative to copper on the copper and chalcocite surfaces over the potential region where these oxidation processes occur. The spectroscopic results (ERS, XPS) indicate that the second and third (on copper) and the third and fourth (on chalcocite) oxidation processes recorded on the voltammograms are due to cuprous ethyl xanthate adsorption. The orientation of the adsorbed molecules of xanthate was observed to change with increasing surface coverage. Therefore, it has been concluded that xanthate can modify the copper and chalcocite surface in two different ways. At lower potentials, xanthate is a source of sulfur for the formation of a sulfur-rich surface. At higher potentials, an adsorption layer of cuprous ethyl xanthate is formed. Contact angle measurements show that both of these processes of xanthate surface modification lead to an increase in the hydrophobicity of the substrates.

Jan 1, 1990

By Richard Curtis

Optimum Colliery is presently experiencing a shortfall of stripping capacity in order to meet its production requirements. Due to the long dragline procurement times, several alternative stripping methods were evaluated in order to alleviate this shortfall in the interim period. Based on the experience gained at the mine. The writer will discuss some of the important factors which influence dragline performance and show how these factors may by used in a theoretical approach to analyse various dragline applications.

Jan 1, 1990

By J. F. Jackson, R. W. Mau

"The first commercial installation in the mineral industry of the ""Verti-Press"" pressure filter was made by Falconbridge Limited at the Strathcona Concentrator to filter copper concentrate. The filtercake produced contains 6 - 7% H2O, an improvement from the 12 - 13% H2O produced by an internal drum filter, at rates of up to 20 t/hr. A novel slurry feed system incorporates a hose pump and a pressurized slurry accumulator.INTRODUCTIONIncreased copper production from Falconbridge Limited operational mines in the Sudbury Area has exceeded the current refinery capacity. A copper concentrate has been produced to overcome this constraint and has been shipped to custom smelters either as a slurry or as a 12 - 13% moisture filtercake utilizing an internal drum filter.With the treatment of the new Deep Copper Zone from the Strathcona Mine, copper concentrate production was forecast in excess of the installed dewatering capacity. The filtercake was too wet to transport by truck and the custom smelter refused to handle this product at the truck unloading site. The filtercake had to be trucked to a rail spur and transloaded into gondola cars. This system was expensive, incurred unaccountable losses and the concentrate was assessed a moisture penalty.To reduce the concentrate moisture content to permit direct shipment by truck, two basic systems were available; vacuum filter followed by a thermal dryer or a pressure filter. Past experience with the high capital and operating costs of dryers led Falconbridge to closely examine the pressure filter alternative.COPPER CONCENTRATE PRODUCTIONThere are two separate circuits at the Strathcona Mill; one treating nickel ore and the other treating copper ore.The rougher concentrates produced by both circuits are conditioned with lime and cyanide before the copper-nickel separation in a flotation columns. The concentrate consisting of cha lcopyrite with mi nor cubanite is very clean as shown in Table I. Currently 50% of the copper in the plant feed reports as copper concentrate, in the past, this has been as high as 70%."

Jan 1, 1990

By Y. Ye

Typically, rougher molybdenite flotation and recovery from bulk copper/ molybdenum concentrates involves the use of alkalisulfides, Nokes reagents, cyanides, oxidants, and/or thermal treatment for the depression of copper sulfide minerals. The bulk copper/molybdenum feed generally varies from 0.2% Mo to 1.0% Mo, and with traditional reagents the single-stage rougher flotation recovery of molybdenite varies between 40 and 90% at a concentrate grade of 5 to 10% Mo. With ozone conditioning for copper depression, however, improved separations appear to be possible, as demonstrated by tests with Cu/Me concentrates from both the Phelps Dodge Morenci Operations and the Kennecott Copperton Operations. Single-stage rougher flotation after ozone conditioning can provide a molybdenum concentrate at a recovery of more than 90% and a rougher concentrate grade higher than 20% Mo in some cases. Subsequent cleaner flotation with additional ozone conditioning results in relatively copper-free molybdenum concentrates containing as much as 52% Mo. Preliminary analysis indicates that, with a multistage ozone conditioning/flotation strategy, the process is technically and economically viable and should be suitable for industrial application.

Jan 1, 1990

By M. A. Cristovici

The possibility of using surfactants as wetting agents for the suppression of sulphide ore dust has been investigated. Numerous surfactants were examined to determine their characteristics and to investigate their ability to improve the wetting of the sulphide ore dust. However, the surfactants selected as suitable dust suppressors proved to have a negative effect on the flotation of the ore contaminated with such reagents. A method was developed to eliminate the detrimental influence of dust-suppressing surfactants. It consisted of surfactants adsorption on activated carbon and separation of loaded carbon prior to flotation. The technique is simple and requires minimal changes in the plant flowsheet.

Jan 1, 1990

By Joan Stoupa

The expansion of the West Point wastewater treatment plant located in Seattle, Washington, will require a permanent tieback retaining wall to enlarge the plant site for the new treatment plant facili­ties. The retaining wall will extend approximately 3,000 feet along the property boundary between the treatment plant and the neighboring Discovery Park. Wall heights will range from 35 to as high as 65 feet. The purpose of the retaining wall is to provide a more uniform grade on the plant site and to resist lateral pressures exerted by the upslope, unstable hillside. During preliminary design of the retaining wall, various wall systems were evaluated based on assumed subsurface soil conditions. Results of preliminary studies indicated that expected subsurface conditions and wall heights made a permanent tieback retaining wall feasible. However, uncertain loads on the wall and the capacity of anchors in the native soils were significant. As a result, a detailed geotechnical program was conducted. The scope of the program included conventional drilling, sampling, analyses, and a field test program to determine site-specific anchor capacities. This paper describes the anchor test program and results.

Jan 1, 1990

By R. D. Doepker

The dissolution of metals from various metal-mine tailings has been studied through a series of submerged tailings batch tests at U.S. Bureau of Mines laboratories. Tailings selected for this study included both reactive (as determined by column leaching studies) and benign tailings. Metal mobilization in aerated (97 pct saturated with oxygen) samples appeared to be consistently greater than metal dissolution from stagnant (79 pct or 70 pct saturated with oxygen) waters. In the early weeks of the study, sulfate concentrations increased with solid-liquid contact time, while calcium dissolution remained nearly constant. Metal concentrations varied in relation to solid-liquid contact time and aeration. Leachate pH appeared to be nearly independent of solid-liquid contact time for basic tailings. Reactive tailings having both a submerged and a surface component demonstrated increased metal mobility.

Jan 1, 1990

The Australian bulk explosives industry has matured significantly over the last five years and it would appear that the rest of the world is following suit. This maturity is characterised by the technical sophistication of modem bulk explosives, an increase in the technical competence of the explosives consumer and a greater openness in the debate on the quality and performance of explosives. The principal mechanism by which these advances have been made is undoubtedly commercial competition in the market place although a new element, technical competition between manufacturers and independent professionals, has and will continue to play an important role in the development of the industry. The relationship between the explosives manufacturer and consumer is necessarily both complementary and competitive. This paper identifies the need for the consumer to take a more prominent role in the critical analysis of the performance of explosives and to use his commercial influence to direct explosives manufacturers at least in the direction required for the future technical development of the industry.

Jan 1, 1990

By Ashraf A. M. A. Wali

Many of the economic resources of Egypt have been recognized and exploited for thousands of years (e.g. gold and copper). Most of these minerals, particularly those from hard-rock sited deposits, are found in complex form along with other components while those present in sedimentary sequences are largely in simple compounds or as native elements. Recognition of their characteristic settings (structure, basin development, environment of formation etc.) is the main clue in predicting and locating their presence. The main economic minerals exploited in Egypt today come from sedimentary sequences and include sodium and potassium chlorides, gypsum, sulfur, and sedimentary iron ores. Large amounts of low grade sedimentary phosphates are known but are not of economic value at today's prices. Recent intensive investigation in the north-eastern Sinai (EI Arish) and along the southern coasts of the Gulf of Suez has revealed new and extensive sulfur and chloride deposits, and considerable oil and gas are now being exploited from closely related sediments. Tin is the only mineral that is produced from hard-rock sources, and gold and copper deposits are present but not of high enough grade to be economically viable. However, a significant part of Egypt has not yet been studied in enough detail to close the door on future discoveries. Another point of considerable geological interest is the presence of diverse, modern evaporitic settings, from which we may draw the analogs for many of the older gypsum, anhydrite, chloride and sulfur de-posits. In fact these analogs are so well displayed that both the Sinai and Gulf of Suez-Red Sea evaporites (Middle and Upper Miocene) can be readily compared with these modern deposits.

Jan 1, 1990

By M. Dattilo

The U.S. Bureau of Mines has been conducting research on the use of waste-derived zinc as a partial replacement for pure zinc in the electrogalvanizing process. The end product of this process is automotive sheet, which has enhanced cosmetic protection over previously used cold-rolled (CR) steel. In this study, primer-coated specimens of CR and electrogalvanized (EG) steel were subjected to the on-vehicle environment and monitored periodically by electrochemical impedance spectroscopy (EIS) during immersion in 1M NaCI solution. The results of these tests were compared with immersion-only conditions. Scanning electron microscope (SEM) and energy-dispersive X-ray (EDX) techniques were also used to evaluate the corrosion processes and compare them with atmospheric exposure specimens. EIS was found to measure the corrosion associated with on-vehicle exposure, thus providing an excellent screening technique for evaluation of the performance of EG automotive sheet steel.

Jan 1, 1990

By Gary J. Goldberg

Through the early 1980s, surveying at Bingham Canyon required a great deal of repetitive and manual work. The advent of total station surveying equipment provided an opportunity to improve the speed and accuracy of surveying work while reducing manpower needs. An evaluation was made of total station systems and their ability to meet the surveying requirements of Bingham Canyon. This culminated in the purchase of a total station system as the mine reopened in 1986. The surveying department at Bingham Canyon during the early 1980s consisted of three, four-man crews using theodolites and self-leveling levels to perform the majority of the field work. Office work involved data reduction and hand plotting. Although hand-held programmable calculators were used, a great deal of time was spent manually transferring field notes to final calculations. After shutting down in early 1985, plans for start-up of mining operations in 1986 included a review of all aspects of the operation for cost and productivity improvement. Applying total station survey capabilities offered the potential to improve surveying accuracy and speed while reducing manpower needs.

Jan 1, 1990

Conservation and environmental issues are raising their profile with respect to both demand restraint and electricity supply options. In New Zealand, conservation pressures and energy efficiency need to be seen in relation to the supply system currently in place which has capacity for economic supply of electricity in quantities substantially in excess of the current market. Consequently, energy efficiency and conservation need to be interpreted in relation to the supply system as well as in relation to end use. The relationship between the environment and conservation is strongest when new generation is required. New Zealand's electricity supply system consists of a large proportion of hydro production and this has significant environmental benefits when considered in relation to concerns of global wanning and the greenhouse effect. However, environmental trade-offs in supply options need to take account of both the efficiency of electricity end use, the trade-off between hydro and thermal generation and the inter-regional effects of shifting development options from one region to another. The Electricity Corporation has a high level of consciousness with respect to environmental and conservation issues and this paper demonstrates its own moves to maximise energy efficiency and illustrate the environmental trade-offs for supply.

Jan 1, 1990

By Miles M. J, Sandy D. A

It has long been known that drilling and blasting operations have a direct influence over productivity and costs of subsequent operations. If mine management is to effectively optimise blasting operations, good information is required on the operating costs of each of the affected operations, together with knowledge of how they are influenced by blasting. In practice it is not possible to do enough repeats of a full scale production blasting experiment to make a statistically significant analysis of the results. By monitoring each blast and subsequent operations in as much detail as possible, enough data will be available to effectively measure the effect of blasting on costs. This gives management an insight into the blast performance and is the first step towards optimisation. An Integrated Blast-related Cost Reporting System has been developed at the Rossing Mine Open Pit, which calculates the total mining cost for each blast. In assessing the total mining cost for each blast, use was made of an.integrated planning and management information system to collect relevant production variables, current operating costs and survey data. An automatic image analysis system was employed to measure the fragmentation of the blasted material in the back of haul trucks. A shovel monitoring system is also under development for use in assessing the muckpile diggability and, in conjunction with an appraisal of shovel component reliability, to estimate the maintenance cost under various digging conditions.

Jan 1, 1990

By J. M. King

A crucial step in the acquisition by one company of the assets of another, the acquisition of the stock of another company, or the merger of two com-ponies, is the legal due diligence which needs to be performed in order for the acquirer to ascertain or confirm the obligations, liabilities and exposures to risk that are being assumed along with the assets or corporate stock being acquired. Where the obligations, liabilities, or exposures to risk arise from existing contracts, or from pending lawsuits, administrative proceedings, or threats of these actions, those matters are relatively straightforward to discover by careful review of the files of the party whose assets or stock is being acquired. However, where a company is engaged in ongoing mining or processing operations and has operated or owned mining proper-. ties, there are many sources of liability and exposure to risk which could have major adverse economic consequences to the acquiring party and which are not revealed, or at least are not clearly delineated, by the records of the company whose stock or assets are being acquired.

Jan 1, 1990

By F. H. Seymour

Central to Newmont Gold's Mine planning system is the ability to interactively perform cut and fill operations on topographic contours and to accurately evaluate grades and tonnages within contour outlines using polygon set manipulation routines. This paper develops the applied geometry concepts that underlie these routines. Included are representation of volumes with contours, point in polygon test, block proportion in polygon calculation, polygon area and centroid calculation, and intersection, union, and complement between polygon sets.

Jan 1, 1990

By Friedel. Michael J.

The U.S. Bureau of Mines investigated acoustic emission (AE) and the Kaiser effect in six types of rock: St. Cloud gray granodiorite, Barre granite, Dresser basalt, Salem limestone, Berea sandstone, and a volcanic tuff. AE signatures were used for interpreting the rock deformation stage and for indicating mechanisms of failure in uniaxial compression. The research demonstrated the advantages of using the volumetric stress-strain curve, as opposed to the more conventional uniaxial curve, for correlating AE response signatures with deformation stages and fracture processes in the rock. Standardized experimental procedures were used for the AE monitoring. The Kaiser effect was shown to be capable of determining prestress levels to within a few percentage points in uniaxial compression tests. Also, prestress memory was shown to be retained in the rock for periods of up to at least. 5 months, the maximum period of testing. The Kaiser effect AE technology holds promise for providing a comparatively inexpensive and less complex method for examihing stress history in rock. However, since the conftning stress has a pronounced influence on the Kaiser effect, it must be considered in developing technology for determining peak fteld stresses based on the Kaiser effect.

Jan 1, 1990

By A. Dale Wunderlich

In the past, most people have associated gold scams with the sale of non-existent gold mines, an undivided interest in unmined ore or the sale of gold-plated lead bars. These scams are still available to those who want to speculate. Now, though, the mining industry is plagued with a new type of con artist. Many of the new scams involve large, well established mining companies being victimized. Nearly all legitimate mining companies are in search of good mining prospects. This makes them susceptible to modern day con artists. Many professionals from the mining and petrochemical industries are out of work. Some of them have gotten involved with scams or activities that border on the criminal. Mining companies are losing millions of dollars each year to scams. Some of these scams involve venture-capital fraud. Some involve fraudulent mining proposals. And some involve unqualified individuals who are providing services by the precious metals industry. The author estimates that mining scams may be costing precious metals companies as much in dollar losses annually as employee theft. Employee theft is at an all time high, but so are gold scams. Since January of 1990, the au¬thor has been involved in gold theft investigations in which more than $1 million in gold product has been stolen by employees. In the past, most of the gold mine scam operators have concentrated on the general public, which is generally ignorant of basic mining procedures and practices. A scam artist would tell someone from your neighborhood that they have a wonderful underground mine. It produces 62.2 kg/t (2000 oz per st) of gold ore. Your neighbor might think that sounds like a very good investment. Those involved in the mining industry know better.

Jan 1, 1990

By Robert M. Carland, Horace Gene Biggs, David Holland

At a North Carolina feldspar surface mine, the orebody contains intrusions of waste material occurring at various angles from horizontal to dipping, and varying considerably in thickness. In order to obtain optimum feed for the mill, it is desirable to obtain maximum separation of ore from waste during blasting and digging.

Jan 1, 1990