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By Robert M. Hopkins, Craig C. Monahan

A corrosion survey was performed on ten selected H-piles which support a reinforced concrete wharf located at Trepassey, Newfoundland. Approximately 900 thickness measurements were taken at twelve different locations in each off our zones on the steel piles: the splash (atmospheric) zone, the intertidal zone, the low tide zone and the submerged zone. Results show that over the 2o-year life of the wharf, corrosion has been most severe in the splash, low tide and submerged zones with average corrosion rates for the flanges of 6.95, 9.45 and 6.86 mils per year (mpy}, respectively, and average corrosion rates for the webs of 5.13, 4.12 and 3.45 mpy, respectively. Minimal attack was found in the intertidal zone where the average corrosion rate was only 1.66 mpy on the flanges and 1.37 mpy on the webs. Such a pattern of attack is frequently observed f or steel piles partly submerged in seawater. The abnormally low corrosion rate associated with the intertidal zone is generally explained as being due to cathodic protection induced by the high corrosion rate in the adjacent low tide zone. Analysis of the corrosion data obtained for the Trepassey wharf would suggest that this explanation might be incorrect. An alternate hypothesis has been brought forward which better accounts for the extremely low corrosion rate observed in the intertidal zones of these piles.

Jan 1, 1990

The mechanisms of fragmentation in homogeneous materials and structured rock mass are reviewed. A method previously used to predict vibration damage to the remaining rock is extended and shown to be valid for the prediction of fragmentation in the rock mass removed by blasting. The effectiveness of different explosives in different types of rock blasting is discussed.

Jan 1, 1990

The Woodlawn base metal sulphide deposit, located 50km S of Goulbum, New South Wales, was mined as an open pit operation for 10 years from 1977, producing 8 million tonnes of ore. Underground development began in 1985 and reached full production of 500,000t/yr as open pit mining ceased in mid 1987. Underground development highlighted the extensive deformation and intense alteration associated with the deposit and the host rocks.The deposit occurs above an acid volcanic pile in a sequence of interbedded and interfingering shales, cherts, volcanogenic sediments and pyroclastics of mid to late Silurian age intruded by dolerite sills.

Jan 1, 1990

By Townsend MG, Evans RB

In Northland, New Zealand, localised large deposits of halloysite clay have been produced by in-situ alteration of rhyolite volcanics of Pliocene or Pleistocene age, which were erupted through pre- Pliocene sedimentary strata and locally through Pleistocene basalt; and which were subsequently onlapped by further basalt flows. Alteration to clay has been a result of both hydrothermal and of meteoric processes, and decreases in intensity of alteration with increasing depth.The raw material is crushed and fractionated to produce a product of less than 2 micron particle size, which is of exceptional whiteness and brightness. The unique properties of the clays render them highly desirable for specialised ceramic purposes.

Jan 1, 1990

By D. C. Martin

Stability analysis and design of open pit slopes is generally based on an assessment of rock cores and rock exposures on surface or in underground workings. Until recently, core for such assessments has been readily available from exploration drilling programs. In recent years, many exploration programs have reduced the amount of coring and rely more heavily on less expensive rotary or percussion drilling programs where drill cut-tings are sampled for geological evaluation and assay. This paper describes a technique whereby costs of the geotechnical investigation are reduced by using rotary percussion drilling information to assess geotechnical properties of the rock mass. A limited number of core holes are required to establish basic relationships between the mechanical properties of core and the characteristics of the percussion chips. These properties are used as a basis to extrapolate the coring information to encompass the entire area of the rock mass for which percussion drilling information is available.

Jan 1, 1990

The Northland Peninsula of northern North Island, New Zealand contains a complex and diverse record of volcanism which reflects rapid tectonic changes during the late Cenozoic. The main volcanic associations observed on the peninsula are late Cretaceous- early oceanic crust obducted onto Northland at the end of the Oligocene, Miocene arc-type rocks and Pliocene-Quaternary intraplate basalts. This sucession of volcanic successions can be related to tectonic convergence developing into subduction and followed by a an environment of tectonic tension. While the volcanic activity is ultimately linked to specific tectonic regimes, because of rapid change magmatism was decoupled from the specific tectonic event. This decoupling of magmatism and tectonism appears to be a feature of the zones of plate interaction in the southwest Pacific region.

Jan 1, 1990

By D. A. Stanley, B. J. Scheiner, P. M. Brown

The Bureau of Mines (USBM), US Department of the Interior, has developed a method of dewatering clay slurries based on flocculation by high-molecular-weight polymers and water removal from the formed flocs using a trommel or hydrosieve. The exchange ion on the clays affects their dewaterability. Metal ions in solution and on the exchange sites of smectite clays are known to act as Lewis acids. Recent work has determined that these ions can be titrated with high-molecular-weight polymers. The relative acidity of the exchange ion and the basicity of the polymer determined by the new method give insight into the dewatering mechanism.

Jan 1, 1990

By John C. Stankus

Jennmar Corporation. in an effort to improve mine roof control, has conducted extensive study and research comparing tensioned point anchor resin systems versus the use of non-tensioned fully grouted rehar. Preliminary indications are showing that in thinly laminated, weak strata, tensioned point anchor resin systems are providing more effective roof control than the non-tensioned fully grouted rehar. In this paper two case studies are presented in which tensioned point anchor resin systems were utilized to stabilize and control the mine roof in two different mines. Both mines are alike in many ways, but yet very different in other aspects. However, the mines do share one main common factor. and that being the non-effectiveness of the non-tensioned fully grouted rebar in controlling the thinly lamininated strata in each respective mine.

Jan 1, 1990

By Hamid Maleki

A new failure criteria is proposed for assessment of roof stability in underground sedimentary rocks. Unlike other stability assessment techniques, this method is simple and practical, having improved mine safety and productivity in several mines. It is shown that roof movements accelerate to a critical rate prior to actual roof collapse. Critical rates vary between 0.025 inches per day to 0.2 inches per minute depending on rock mass - pillar mechanical properties. Specific critical rates are determined for three rock mass - pillar categories which are common to mining in sedimentary rocks. Time-to-caving varies from one minute to ten days on rock structural controls and type of primary support utilized.

Jan 1, 1990

By R. L. Grayson

Compliance standards for respirable dust which are reduced because of high quartz concentrations have become an industry-wide problem. Research on the physical and chemical character of quartz-classified particles in respirable coal mine dusts indicates that they may exist in intermixed layers or may be coated by clay or coal material. The relative amount of intermixing varies with the coal seam being mined. If most of the quartz particles of a mine dust are "pure," then the dust may have a high fibrogenic risk potential because of truly free silica and the compliance standard should be lowered. If, however, the quartz is locked inside another material matrix, or coated, a reduced compliance standard may not be appropriate.

Jan 1, 1990

By Boyack DJ

DEFINING AN ECONOMIC TARGETExploration usually begins with the corporate goal of finding a minimum tonnage and grade of a selected mineral. Sometimes this is expressed more simply as a minimum quantity of contained metal without any indication of the desired grade or implied profitability. Such a goal is useful in the selection of exploration areas and the planning of initial drilling programs. However, it should be reviewed as soon as significant mineralisation has been identified. To make rational decisions about exploration expenditure, the potential return from a deposit must be estimated from the outset and re-esti-mated frequently.The potential return will depend on:1. The proportion of mineral which can be economically recovered from the deposit by mining (the mining recovery).2. The quantity of valuable constituent that can be recovered after dilution with waste rock during mining and losses due to incomplete metallurgical recovery.3. Expectations of price and markets.4. Capital and operating costs applying to the selected mining and processing methods, and to transportation and marketing. Increasingly, environmental costs and constraints must also be considered.

Jan 1, 1990

By L G. B Wadley

The Australian gold industry has made large steps forward in the last few years. This progress has been driven by improvements in mining and processing technology, the high price of gold and by a favourable legislative, political and taxation environment. This paper concentrates on improvements in gold project development, process engineering and technology as seen by BHP Engineering, Perth, Australia. The paper describes technical aspects of successful gold project development including metallurgical test work, feasibility studies, choice of process flow sheet (gravity, heap leach, carbon in pulp (CIP), carbon in leach (CIL) or other routes). It sets out our views on plant design, plant construction, procurement and project management. A case study for a small plant recently completed in the Philippines is presented as a solution to the problems often encountered in treating quartz vein gold deposits.

Jan 1, 1990

Dealing with Aboriginals and various others purporting to represent them has become part and parcel of exploration and mining in Australia, whereas 20 years ago it was not. The author has been involved in dealings with Aboriginal groups over this period. The following paper is a summary of the social background to such dealings and a compendium of rules for the newcomer to this aspect of the resource industry.

Jan 1, 1990

By Dan A. Mackie

Continuous leaching of precious metals ores in a vat is possible using a jigging technique. This patented method promises to be competitive with heap leaching, particularly in northern climates, difficult terrain, high precipiptation regions, and environmentally sensitive areas. The paper discusses test work to date, plans for pilot plant testing and basic economics

Jan 1, 1990

By B. L. Razzaboni, P. Bolsaitis

"The formation of reactive oxygen species resulting from the interaction of silica dust particles with red blood cell membranes was investigated; particularly, the effect of surface hydroxyl (silanol) group concentration on the rate of formation of such reactive oxygen species was investigated. The rate of formation was measured indirectly through the effect of catalase, a hemoprotein peroxidase, on silica-induced hemolysis. It was found that the addition of exogenous catalase to erythrocytes markedly reduces the hemolysis caused by silica particles. Furthermore, the amount of catalase required for deactivation of silica per unit area of particle surface is lower for fumed silica particles and calcined crystalline particles than for uncalcined, crystalline silica, suggesting a correlation between the concentration of OH groups at the silica particle surface and its potential for generation of H2O 2• The addition of albumin, a copper chelator, also decreases hemolysis. These results suggest that the hemolysis caused by silica particles is at least partly related to the formation of H2O2 at the particle surface and its subsequent reaction with Cu+ ions. The relationship between the concentration of surface silanol groups on the silica surface and the amount of catalase required to decrease hemolysis may also provide a method for testing potential fibrogenicity of respirable dusts. IntroductionReactive hydroxyl groups on silica surfaces are known to be cytotoxic and are believed to play a major role in silicosis (1-9). It has been proposed that this cytotoxicity results from hydrogen bonding to cell membranes and a resulting increase in membrane fluidity and permeability (4). Surface hydroxyl groups on silica surfaces have also been shown to interact with carbonyl oxygens in cell membranes (1,5). An extensive study by Nolan et al. (6) of the relationship between the negative surface charge resulting from ionized silanol groups and the hemolytic activity of crystalline a-quartz (Min-U-Sil) has shown a positive correlation between hemolytic activity and the surface concentration of silanol groups. These authors demonstrated that the hydrogen bonding of polyvinyl-N-oxide (PVPNO) with silanol groups, as well as the bonding of metal cations to the ionized sm- groups, results in significant decreases in hemolytic activity. Furthermore, it has been found that the complete removal of surface hydroxyl groups from the surface of respirable silica particles nearly eliminates the hemolytic potential of silica (7), suggesting that hydroxyl groups might be involved in other cytotoxic processes associated with silica-induced lung injury. Reactive oxygen species have been .implicated in cellular damage caused by respirable silica particles. Evidence for the presence .of oxygen radical species (02, OH°, H2O2) generated by silica, especially on freshly formed surfaces, has been produced by various investigators. Kalbanev et al. (8) detected H2O 2 in aqueous suspensions of quartz. Electron spin resonance and spin trapping by Shi et al. (9) confirmed the presence of OH"" radicals in aqueous suspensions of quartz, and Gulumian and van Wyk (10) suggested that both glass and quartz produce hydroxyl radicals in the presence of H2O 2 • Gabor et al. (11) detected the presence of malondialdehydereactive lipid peroxides (i.e., lipid-0°) in cultures of macrophages and respirable silica particles using the thiobarbituric acid (TBA) reaction test. Will (12), however, reported that iron enhances the TBA value of peroxidized lipids, and Scheulen and Kappus (19) found that catalase augmented malondialdehyde formation, thereby increasing the TBA values."

Jan 1, 1990

By Gunther L. M, Rich N

Remapping of the Burdekin Basin has resulted in the subdivision of the three formations (megafacies) previously recognised in the Late Devonian Dotswood Group. Nine dominantly volcaniclastic facies are now identified within the three megafacies, representing coastal plain, floodplain lake, alluvial plain, ephemeral lake and alluvial fan depositional environments. The Dotswood Group was deposited during a major regressive phase that began at the end of the Givetian, continued throughout the Frasnian and ended in the early Famennian.The proposed depositional model completes a southeasterly progradation of coastal plain facies over shoreline and nearshore marine facies established in the underlying Fanning River Group. Uplift and associated acid-intermediate volcanism to the south of the Burdekin Basin, resulted in the deposition of a volcanogenic alluvial fan facies locally preserved along the southwestern margin of the basin. Tuffs and ?ignimbrite were deposited in widespread floodplain lakes which lay behind the coastal plain. An alluvial plain traversed by southward flowing rivers, formed the northern margin of the basin.

Jan 1, 1990

By William D. Gallant

This paper describes a joint cooperative project between the CANMET Cape Breton Coal Research Laboratory and the Cape Breton Development Corporation to conduct a trial of split set cable slings for remedial support in longwall gateroads. Slings were installed in two test sections of the 2 West panel, Phalen Mine which exhibited deformation and the potential for excessive deterioration when subjected to the front abutment of the wallface. Roadway support behaviour was monitored at the trial sites, including lengths of roadway with the standard support of steel sets without remedial support. Observations were made on convergence, loading of the steel supports, loading of the slings, and wallface performance. Comparisons are made of the results obtained from the areas with remedial support to that without, which demonstrates that the slings provided effective remedial support limiting further deterioration of the roof. Improved face end conditions have contributed to increases in safety and productivity of the longwall panel.

Jan 1, 1990

By F. H. Mertens

The costs of an open-pit operation can be classified according to the following hierarchy : -overall cost of production (per ton of ore) -costs of basic operations and functions -costs of auxiliary operations -costs of machines and equipment -maintenance costs. Production cost is a measure of the open-pit mine performance and should be the final target of the management control. It is also a measure of the share of the mine in the processing stages.

Jan 1, 1990

By Moxon N. T

A series of low shock energy water resistant emlulsion based explosives have been developed by combining inert materials, such as Perlite P500, into the formulation. The material handling, water resistance and explosive properties of these mixtures were determined as a function of inert additive type, density, charge diameter and emulsion base. Of the emulsion bases tested Emulite produced the best and most stable low density mixtures ranging in density from 0.8 to 1.35 g/cm3 producing velocity of detonations (unconfined) ranging from 3000 to 5500 nits. The mixtures could be detonated successfully at these densities at diameters as low as 25mm. Low shock mixtures formed by combining Emulite with Perlite P500 were successfully trailed at the Cadjebut zinc mine in Western Australia. The performance of the explosive, at three densities, was monitored using both continuous and point to point VOD techniques. The fragmentation produced by the blasts were compared by photographic analysis. During this trial the low shock emulsion mixtures were shown to be as effective as the currently used explosives (packaged emulsion) at a significantly reduced cost.

Jan 1, 1990

By John McEwen, Ian R. Jonasson, David H. Watkinson

"Mine Gallen is a zinc-rich pyritic volcanogenic massive sulphide deposit that occurs in a fault-bounded block of intermediate volcanic rocks. The block is completely surrounded at the present erosion level by the eastern part of the Lac Dufault granodiorite. The volcanic succession includes a massive feldspar porphyry that is probably a subvolcanic intrusion, an andesitic flow unit and lapilli tuffs. The latter are variably sericitized and pyritic, especially in the vicinity of the massive sulphide into which they grade.The ore body is predominantly pyritewith local sphalerite contents as high as 20%; minor chalcopyrite and trace galena are disseminated, but are found mainly along late cleavage. Most ore is a breccia of massive to banded pyrite-sphalerite, veined by massive and complexly banded sulphides. These structures formed by repeated blocky jointing, cracking, sealing, healing and annealing as hydrothermal fluid repeatedly passed through a developing sulphide mound. The deposit is interpreted to have grown on the seafloor in a manner similar to active mounds in the Galapagos rift.RESUME La Mine Gallen exploite un gisement de sulfures massifs volcan géniques comprenant essentiellement de la pyrite riche en zinc. Ce gisement se trouve a /'intérieur d’un bloc de roches volcaniques de caractère dacitique a andésitique, limite par failles et entoure de tout cote par la granodiorite du Lac Dufault. La séquence volcanique comprend des coulées andésitiques et des tufs à lapilli ainsi qu'un porphyre feldspathique massif sub-volcanique. Les tufs sont sericitises et pyritises, tout particulièrement au voisinage des sulfures massifs."

Jan 1, 1990