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By K. M. Parida

The kinetics of dissolution of manganese dioxide in dilute sulphuric acid solution have been investigated using iron pyrites as a reductant. The dissolution rate of manganese is independent of the speed stirring but depends upon temperature, particle size, specific surface area of manganese ore, acid concentration, Fe(II) concentration and amount of pyrite. The activation energy is 43.6 KJ/mol and the linear relationship between the rate of dissolution and lido indicates that the reaction is chemically-controlled. The redox reactions of MnO2 with iron pyrites and Fe(II) are the rate-controlling reactions.

Jan 1, 1990

By Jr. Raleigh

Three run-of-mine bituminous coals, which ranged in rank from low volatile to high volatile A, were floated at nominal -28 mesh (590 µ m), -100 mesh (150 µ m), and -400 mesh (37 µ m) feed particle sizes with selected pyrite depressants and a dispersant. For the coals tested, pyrite and ash-forming minerals were usually rejected best at a -100 mesh feed particle size. Depressant additions tended to improve flotation selectivity between pyrite and coal. When joint dispersant-depressant systems were used at -100 mesh (150 µ m) feed particle sizes, the total sulfur content of the clean coal decreased further. For a comparable coal yield, less fuel oil collector was required for the flotation of -100 mesh coal than was required for the flotation of either -28 or -400 mesh feed.

Jan 1, 1990

By R. C. Bryce

"Selbaie is located northwest of Joutel, in what is known as the fourth east-west volcanic sediment group in northwestern Quebec. The main metals produced are copper and zinc, with important contents of both silver and gold. Production comes from an open pit mine on the A-I zone and from two underground mines on the B zone and the A-2 zone. Each mine gave rise to important capital investment programs for construction and mine development, all of which were managed and staffed with company-hired, non-union personnel. Production from all sources now exceeds 7000 tonnes per day, with a workforce of540 regular employees. Of particular interest technically is the high recovery of B zone reserves underneath 40 m of overburden cover, the low-cost capital development of the A-2 zone, the computerized control of open pit mining, and the successful copper-zinc separation of the A-1 zone ore. Due to the low grades of the mineral deposits, efficiency in all aspects of the production process, is essential to the success of the operation.LocationThe Selbaie Mine is located 82 km northwest of the locality of Joutel in northwestern Quebec (Fig. 1). Access to the mine is by an all-weather road, 32 km of which is paved. A second road access to the site is via La Sarre, 134km to the southwest. Employee access, materials transport and haulage of copper and zinc concentrates take place over both of these roads."

Jan 1, 1990

By L. Xiao, P. Somasundaran

Using potassium oleate as a collector and alizarin red S as a modifying agent, selective depression of dolomite from francolite was achieved in an alkaline medium (pH > 9.0). Adsorption of alizarin reds alone on dolomite was found to be higher than that on francolite. Complimentary adsorption experiments of alizarin red S and oleate showed that oleate adsorprion was increased in the presence of alizaring red S. The results are explained in terms of comparative adsorption for the active sites on francolite and dolomite by oleate and alizarin red S and their interactions with dissolved mineral species in solution.

Jan 1, 1990

By I Hustwick

New Zealand Steel Mining Limited operates two independent sand mining operations on the West Coast of the North Island of New Zealand. Waikato North Head 30 km south of Auckland supplies ironsand concentrate as the raw feed for New Zealand Steel's works at Glenbrook and Taharoa 70 km further south, exports ironsand concentrate to Japan.   Taharoa uses two sets of six low pressure Warman centrifugal pumps in series to load bulk ore carriers 3 km off shore through two underwater pipelines. Waikato North Head delivers the ironsand to Glenbrook 18 km through a 200 mm ID buried pipeline using two stages of high pressure positive displacement (HPPD) pumping.   A high level of operating and maintenance expertise has been developed since commissioning the two systems which are proving to be reliable, efficient and of minimal impact environmentally.

Jan 1, 1990

By A. Venkatachalam

Spinel ferrites, like NiFe2-2x Znx Ti4 O4 Fe CO1.5 Ge0.5 Tix O4, Ga1-x Fex Ni CO O4, Nil-x Fex Mn2 O4 have been prepared using the respective metal oxides in Stoichiometric quantities, by the ceramic method. The oxides were homogenized in acetone medium, pelletifed by using poly vinyl acetate as the binder. They were fired at 1000°C for 100 hours for compound formation. Chalcogenide spinels such as Zn1-x Cux Cr2 Se4 where 0=x=l and Cu1-x Fex Cr2 Se4 where 0=x=0.3 have been prepared by using 99.99% pure elements and then fired at 1000°C in quartz ampoules under vacuum conditions. X-ray diffraction studies of these compounds indicated a single cubic spinel phase. DC resistivity studies of the compounds were taken between 300-700K using LCR bridge by two probe technique. Thermo-electric power measurements were taken between 300-500K for all the compounds. Initial susceptibility studies have been carried out using a low field (0.506) and from which the nature of magnetic dimains and Curie temperatures were determined. Magnetic hysteresis measurements were carried out at 300K and at 80K, using alternating current hysteresis loop tracer, at 2K02 field. Mossbauer spectral measurements were carried out using Co57 source embedded in a copper matrix and an absorber containing 0.3 mg/cm2 of the sample. The spectra has been fitted by Mossfit Program. The catalytic effect of the spinel ferrites NiFe2-2x Znx Tix O4 where 0=x=1 has been studied by using the model reaction of decomposition of H2O2 at temperatures from 40°C to 70°C. It was found that the spinel oxides were found to possess poor catalytic activity.

Jan 1, 1990

By Anders Sellgren, K. Hansson, A. Jedborn

In the mining industry, conversion of fine particles into a slurry is often part of the normal processing of the ore. Therefore. from a system's point of view, slurry transportation would be considered as a natural alternative, all the way from the working face to the final processing. In underground mines, there is sometimes a considerable inflow of ground water that has to be pumped out. When the mine dewatering installations are integrated with a hydraulic hoisting system, the cost of power needed to pump out the ground water can be excluded from the cost of hoisting, compared with other modes of transporting the solids to the surface. The chief advantage of hydraulic hoisting is that the hoisting capacity can be increased at comparatively low total cost without necessitating the sinking of new shafts. Alternative examples include deepening of the existing mechanical hoisting system, truck, or conveyor belts transport in ramps to the present level. These often become very expensive. The economic effectiveness of hydraulic hoisting and hydraulic design considerations have been discussed by Kostuik (1965) and Sellgren (1985, 1986) for both small shallow mines and large deep underground mines. Objective and scope The objective of this study was to demonstrate the feasibiliy of hydraulic hoisting in hypothetical examples of mine deepening. Underground grinding to a maximum particle size of about 700 um (about 25 mesh) is considered. The pumping of ground ore products with positive displacement plunger or membrane type of pumps at working pressures of up to 15 MPa (2200 psi) is a thoroughly tested technique (Venton, 1986). Hydraulic hoisting system A hydraulic hoisting system is described schematically in Fig. 1. The ore is mined, handled, and crushed conventionally. It is then ground wet underground. The slurry is then temporarily stored in an agitated tank and pumped to an agitated receiving tank on the surface. The ore is then further processed in the concentrator. The capacity of a pipeline is very high. For example, an annual production of 500 Kt (550,000 st) of ore can be handled in a 100-mm-diam (4-in.-diam) pipeline. Systems layout - economic effectiveness Schematic mine layouts are presented that represent situations where hydraulic hoisting often is the most economical alternative. A situation where the ore is trucked to the level of the existing hoisting system is shown in Fig. 2 (following page). With hydraulic hoisting, only a shaft for ventilation, pipe- line, and personnel are needed. In a first phase (Fig. 2). a hydraulic hoisting installation with crushing and grinding units, storage facilities, and pumps has been located at a level of about 400 to 600 m (1310 to 1970 ft) below the surface. With further development of the mine, the hydraulic hoisting

Jan 1, 1990

The Permo-Triassic Bowen Basin developed during the final stages of the Tasman Orogenic Phase in eastern Australia. The basin has considerable economic value as a source of coal, natural gas and precious metals. The basin, which is of controversial origin, is preserved as a north-south trending, asymmetrical syncline bounded in places by faults. It is here interpreted as a retroarc foreland basin which developed on the landward (west) side of a continental arc associated with continent-ocean plate convergence. Initiation of the basin occurred via back-arc extension in Early Permian times, coincident with a phase of talc-alkaline arc volcanism. Early Permian, mostly marine sedimentation gave away to extensive coastal and alluvial plain depositional systems in Late Permian times, coincident with a resurgence of arc volcanism. Triassic sedimentation was almost entirely alluvial and coeval with westward propagation of thrust sheets from the eastern basin margin. Compressive tectonics climaxed in Middle to Late Triassic times, terminating sediment accumulation and uplifting the entire area.

Jan 1, 1990

By Richard A. Andre, R. Larry Grayson, Thomas Simonyi

"INTRODCICTIONThe search for the cause(s) of coal workers' Pneunoconiosis continues despite the vast amount of research that has been undertaken over the past forty to fifty years. Good correlation between the mass of dust inhaled over workers' lifetimes and the incidence of the disease has led to the development of effective environmental standards and implementation of good procedures for the control of dust generation and dispersion in the working place. Research has only begun, however, to uncover the biochemical mechanisms involved in initiating the disease.Correlation between the rank of the coal seam in which miners worked and disease incidence and severity is acknowledged worldwide, but the agents in the higher rank coal seams which cause CWP arc still not defined. The basic components of the coal seams, i.e., the elements and minerals, are generally known, but the way in which they interact with human pulmonary cells is largely still a mystery.The process of disease development is a biochemical one which depends on the characteristics of the pulmonary cells within their immediate biochemical environment and the characteristics of invading respirable coal mine dust particles, probably both chemical and physical ones. The cell-particle relationship, therefore, must be defined, and both cells and particles must be characterized according to properties which potentially are involved in the disease process.Following such characterization, specific respirable dusts from different coal seams, which appear to have different effects on coal workers, must be obtained or constructed and then used in experiments designed to determine dust toxicity or the response of animals exposed to the dusts.The results presented here focus on characterizing properties of respirable coal mine dust particles collected from operating longwalls in West Virginia and Virginia Longwall panels were selected for analysis because the respirable dust in the coal face areas is largely uncontaminated by rock dust and analysis of the dust yields results unconfounded by rock dust."

Jan 1, 1990

By J. B. Hiskey, X. H. Jiang

The extraction of gold from chloride solutions by ion exchange is examined. It is shown that at initial gold concentrations between 1 - 5 ppm, 20 g/l C1- and pH 5, the kinetics of loading on weak base resins are slightly slower than those observed with activated charcoal. Equilibrium loading of auric chloride varies considerably as a function of pH from one resin to another. For all of the resins studied, nearly complete gold extraction was achieved between pH 2 and pH 6.5. Sodium hypochlorite was found to exhibit a slight effect on the equilibrium loading of gold chloride.

Jan 1, 1990

By F. Villanueva Araya

Compania Minera Disputada de las Condes (CMD), an Exxon Affiliate stewarded by Exxon Coal and Minerals Company, operates two' copper mines and concentrators in Chile. Pilot plant studies were initiated in 1984 using a 0.46 meter and a 0.91 meter diameter column for the cleaning of copper concentrate. This eventually resulted in the design and operation of a rectangular column with an area of 6.8 m2, increasing the final copper concentrate grade from about 30% to almost 32'1. Cu without any loss in copper recovery. Evaluation studies of a commercial bubble generator as against the previously used filter cloth air sparger are now in progress.

Jan 1, 1990

By M. K. Alam

Chemical Vapor Deposition (CVD) processes are currently attracting special attention in materials processing. CVD processes are now used to produce special materials in the form of thin films, coatings, composites, and optical fibers. This process produces material of high purity, in complex shapes, and in a variety of microstructures. It is a capital intensive process, involving use of high cost raw materials. Modeling simulations have the potential of reducing the time for CVD . process design, and the need for experimentation. Modeling would, therefore, appear to be an attractive option for producing a product of acceptable quality. At Ohio University, progress has been made in modeling of CVD processes, specially in the areas of optical fiber preform fabrication, and fiber coating.

Jan 1, 1990

The international scientific and engineer-ing community is being challenged to take advantage of the opportunity offered by the U.N. International Decade for Natural Disaster Reduction (IDNDR) program to reduce rapid onset geological hazards along the Pacific Rim. Natural disasters observe no national boundaries; international cooperation offers the best opportunity to reduce the losses these catastrophic events create.

Jan 1, 1990

By R. P. King, L. C. Woollacott

To date developments in the simulation of carbon-in-pulp (CIP) adsorption circuits have focused primarily on the modeling of adsorption. This series of three papers describes a development in a direction that has received less attention, i.e. the need for a detailed description of the movement of carbon and slurry in continuous CIP and carbon-in-leach (CIL) plants. A new simulator has been developed based on the population-balance approach for modeling the movement of carbon and slurry. Existing adsorption and leaching models are evaluated in this paper in order to establish which are appropriate for use in the new simulator. The details of the simulator are given in Part 2 of this series.

Jan 1, 1990

By James J. Scott

Research and development has been carried out on the patented Dynamic Rock Anchor, tradenamed DYNA-ROK and DYNA-ROK PLUS Anchors, which are manufactured and marketed by Ingersoll-Rand Company. This paper will present the results of field testing of this revolutionary new concept in ground control. Geologic conditions will be described where the plastic sleeve of the DYWA-ROK anchor alone is sufficient to provide anchorage and also, where in softer ground conditions, the DYWA-ROK PLUS is applied. The rationale for making the decision as to the type of fixture to be employed, the length of plastic tube to be used and the quantity of resin are explained. Pull test data will be shown from eight different coal seams in the Eastern United States where the product has been installed.

Jan 1, 1990

By R W. Givens

Comparison tests were performed on 6 emulsion concentrates, 3 microballoon sensitized emulsion concentrates, and 2 water gel concentrates from 8 different sources with ANFO used as a control standard. Variables measured include density, detonation, velocity, detonation pressure, calculated borehole pressure, viscosity, and lead cylinder deformation for blends of 15%, 30%, and 45% concentrate and AN/ANFO blends. Comparative results are presented for detonation velocity vs. deformation, and percentage of inherent air vs. deformation for these blends. It was hoped that these tests would serve as a tool to facilitate the comparison of different manufacturer's concentrates in AN/ANFO blends for equivalent performance characteristics and to help evaluate these products on an equal basis for bid solicitation purposes.

Jan 1, 1990

By J. A. Herbst, Z. Rogovin

In order to develop more accurate procedures for scale-up and design of semi-autogenous grinding mills through detailed mathematical models, a better understanding of the charge motion and rocklball segregation is needed. To achieve this a 0.61 m (2.0 ft) diam by 0.305m (1 .0ft) length plexiglas mill was constructed as a scale model of a commercial SAG mill. Rock motion in the rotating mill was simulated using various sizes of ceramic balls. Quantitative measurements of dynamic angle of repose, water and slurry motion, holdup and size segregation of the charge were taken. In addition, a video presentation (available to the public) was prepared to elucidate charge and water motion at various mill speeds, charge volumes, rocksize distribution, and flow rates.

Jan 1, 1990

Maps of mineral grade used to assess mineral reserves are most commonly generated using one of the many estimation methods available such as inverse distance weighting or ordinary kriging. Most such maps incorporate a degree of spatial smoothing which is an integral part of the averaging process. In deposits with highly variable grade which include many gold deposits, this smoothing can mask the detailed geometry of the mineralization at the economic cutoff grades being considered. In underground mining, a knowledge of this geometry is important in the choice of mining method and thus in the assessment of the minable reserves.The method of conditional simulation in geostatistics can be used to generate maps of grade which reflect the actual spatial variability of grade as measured through the variograms of the drill hole data. Simulated maps can provide a number of equiprobable images of the mineralization geometry from which a more appropriate mining model of the mineralization can be developed. Multiple simulations can also be used to assess the uncertainty existing in the current knowledge of the reserves.

Jan 1, 1990

By C. A. Carroll

In February of 1989 the Mission Complex of ASARCO Incorporated completed an expansion of its concentrator, raising the base mining rate from 25,900 TPO (28,500 STPD) to 37,200 TPO (41,000 STPD). The expansion was accomplished by extending the twelve existing Mission ball mills in length, by installing the grinding circuit from Asarco's idled Sacaton Concentrator along with various auxiliary equipment, and by modifications to the flotation circuit and water systems. This paper will give a brief history of the consolidation of the ore body which made the expansion possible and explain the various parts of the expansion.

Jan 1, 1990

The seemingly insatiable world demand for mineral and energy products is continuously pushing out the frontiers of exploration and development in countries around the Pacific Rim.

Jan 1, 1990