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By M. B. Cortie, J. H. Potgieter

An account is given of the production of three types of experimental high-chromium duplex stainless steel. The alloys had chromium contents of 22, 29, and 35 per cent. The partitioning of the main alloying elements between the austenite and ferite phases was determined, and the effect of the alloying elements chromium, nickel, and molybdenum on the mechanical properties and corrosion resistance of the duplex stainless steels is summarized. The phase compositions of the different duplex stainless steels were measured by different techniques, and the values obtained were correlated. The cracking occasionally observed during the thermo mechanical processing of these alloys was studied, and is explained as being the result of known embritlement processes.

Jan 1, 1990

By P. A. Mingione

"AEROPHINE@ 3418A is a unique sulfide mineral promoter produced by Cyanamid, based on phosphine (PH3) chemistry. It has proven effective as a collector for the sulfide minerals of copper and particularly lead (galena), as well as for secondary gold and silver values. AEROPHINE 3418A has widest application as a Cu and/or Pb collector for complex ores of Cu-Zn and Pb-Zn, which frequently have significant quantities of associated precious metal values. Advantages shown in the use of AEROPHINE 3418A are improved selectivities against Zn- and Fe-sulfides, increased precious metals recoveries, reduced total collector consumptions for Cu and/or Pb flotation, and increased flotation kinetics leading to higher recoveries of these values. Operating plant, pilot plant and laboratory test data from treating different ores are presented, demonstrating the advantages in use and preferred application of AEROPHINE 3418A.INTRODUCTIONCyanamid operates the only phosphine and phosphine derivatives plant in North America, located in Niagara Falls, Ontario. Specialty chemicals manufactured at this facility are used in many diverse applications, including solvent extraction reagents and textile flame retardants. A unique phosphine-based sulfide mineral promoter, AEROPHINE 3418A, is also produced. The origins of AEROPHINE 3418A promoter date back to the 1960's, when it was established that sulfide mineral collectors based on phosphine chemistry demonstrated efficacy. This new collector chemistry was found to provide flotation performance differing significantly from those of more traditional thiol collector chemistries such as xanthates, dithiophosphates, mercaptobenzothiazoles, thionocarbamates and those with xanthogen groups. Some of the advantages ultimately demonstrated by AEROPHINE 3418A promoter compared to these traditional collectors include:"

Jan 1, 1990

By J. F. Peterman, M. C. Roberts

The success of any industrial mineral project requires an accurate forecast of the demand fir the material as well as accurate projections of costs and prices. This paper develops a general method of predicting mineral requirements and applies it to the case of graphite. The basic method is to explain graphite consumption in each of its major uses by the output and manufacturing technology of the using industry. Once these underlying factors are determined, they can he projected to establish future requirements. This forecast is critical to the evaluation of a new source of supply, such as the graphite resources of Upper Michigan.

Jan 1, 1990

Mineral resource and ore reserve estimation is a challenging and demanding field, requiring application of professional knowledge, skill and experience of the highest order. If the many potential hazards and pitfalls are to be avoided however, there are two other requirements which are of equal, if not greater importance:

Jan 1, 1990

By Draper J. J, Lang S. C

Regional geological mapping and facies analysis of the Late Devonian to Early Carboniferous Keelbottom Group of the Burdekin Basin have resulted in a depositional model representing six siliciclastic-carbonate facies. The six facies represent alluvial fan, braidplain delta, siliciclastic shoreline, siliciclastic shallow marine, restricted siliciclastic/carbonate shelf, and carbonate shoal depositional environments. These facies are identified in the Star beds which are equated with and included in the Keelbottom Group in this paper. Facies are repeated throughout the Group, as a result of two transgressive-regressive cycles.The first transgression recognised in the Keelbottom Group began in the mid-Famennian, and followed deposition of the Late Devonian Dotswood Group. It was marked by the deposition of Siliciclastic Shoreline facies in the basal Myrtlevale Formation, which was succeeded by Siliciclastic Shallow Marine facies at the peak of the transgression. The return of Siliciclastic Shoreline facies in the upper part of the Myrtlevale Formation marked the onset of the first regression, which resulted in the progradation of Braidplain Delta facies from the northwest of the basin. During the peak of this regression, deposition in the western part of the basin was dominated by Alluvial Fan facies.

Jan 1, 1990

By Orid A

A fast, non-contact technique for measuring sizes of rock fragments on a conveyor belt is presented. An image processing technique called active stereopsis is used which makes use of a light stripe projected on to the surface of the fragments on the conveyor belt. A CCD TV camera is used to capture the shape of the distorted light stripe. the video image of this shape is then processed by a computer program so that the 3D profile of the surface can be obtained by triangulation. The sizes of the rock fragments are then calculated from this profile. The speed of the technique is improved by calibrating the light stripe system before measurement begins so that the profile of the fragment surface can then be measured using simple geometry. The technique is fast and highly parallel so that it is able to operate in real time.

Jan 1, 1990

By Daniel B. Conn, John L. Floyd

PhotoSeis™ is a blast analysis method that combines the advanced technologies of high speed motion picture photography and digital seismology. When fracturing rock with the use of explosive energy, the human eye cannot detect the details of the process due to its short duration. An extended time base is required to accurately quantify the response of the rock mass to the detonation process. This time base is provided by the use of high speed motion picture cameras. The control of ground vibrations and airblast is an important consideration when developing efficient blast designs. High vibration and airblast levels can be an indication of improper design, inaccurate detonators, or adverse geology. Since many factors can elevate airblast and ground vibration, a greater understanding of the site specific response to the blast design is needed that is beyond the scope of simple seismographic recordings. By synchronizing the photographic record provided by the high speed motion picture cameras with the airblast and vibration information from digital seismological monitoring, the Photoseis™ technique can be of great assistance in controlling airblast and vibration and optimizing the use of explosive energy for rock fragmentation.

Jan 1, 1990

Gold mineralization like other low concentration high value commodities has gained the notoriety of being difficult to sample. This adversely affects the confidence that can be placed in resource estimates and ore reserves. As an example, it is not uncommon to find differences of the order of 30% between duplicates of a single sample sent to two different commercial laborartories. Two halves of drill core generally show marked differences in grade. Again differences of 50% are not uncommon in halved core. In the context of this type of "error" within the base data used for the resource estimate, many of the subtleties of computation methods and expert judgement of resource categories, are almost a case of shutting the gate after the horse has bolted. Managers, financiers and consultants must question the quality of the base data upon which resource estimates are made. They must insist that standard and duplicate samples are used to measure the accuracy and precision of commercial analytical laboratories, that sampling practices have been checked for possible bias and give tolerable repeatability. Further they must ensure there can be a realistic confidence in the estimates by correctly using these measures of data quality to quantify risk.

Jan 1, 1990

By Tim Q. Haldane

The ability to efficiently process low grade gold ores has allowed the Gold Fields Mesquite Mine in Imperial County, California to expand from a 2.1 million tonne per year rate in 1986 to its present 7.3 million tonne per year processing rate. Increased tonnage demands led to the 1989 construction and start-up of a dump leach pad to supplement the existing heap leach operation, resulting in an excellent opportunity to compare the two processes at the same operation. Additional operating costs associated with the crushed ore heaps are justified through enhanced recoveries, even at very low ore grades. An overview of current operating practices at Mesquite is presented along with metallurgical and economic comparisons between the crushed and run-of-mine ore heaps.

Jan 1, 1990

By Richard C. Repsher

The U.S. Bureau of Mines has developed a method and device designed to detect lose rock material in underground mines. The technology is designed to be an aid to mine workers in detecting hazardous roof conditions in underground mines which can complement or replace the traditional roof sounding techniques where the miner relies on experience to determine whether rock conditions are sound. The leading cause of accidents and fatalities in underground mines is falls of lose rock pieces or rock slabs from the mine roof. The device is an electronic roof sounding device that acoustically determines the integrity of mine rock. In previous research the Bureau of Mines found that loose rock, when impacted, vibrates at a much lower frequency than intact rock material. A major problem in determining rock stability using this technique has been the repeatability of the matt signal. This difficulty baa been greatly reduced in the current design by measuring the power spectra contained in two separate frequency bands of the signal produced by striking the rock in question. The ratio of the energy contained in each band is computed. This process minimizes any striking force differences, producing accurate, repeatable results for solid rock as well as loose, drummy material. The prototype has been successfully- tested in a variety of underground environments including coal, uranium, molybdenum, silver and salt. The technology has been investigated by the U.S. Mine Health and Safety Administration and the Department of Energy for use in detecting detached tunnel lining areas in nuclear repositories. The paper will discuss the technique, applicable results, and future applications.

Jan 1, 1990

By C. Tan, A. Putz, P. Lacombe, R. Kemp, M. Kaya, B. J. Huls, A. R. Laplante

"This paper concentrates on the four recent plant trials/ applications of froth washing. Results showed that improved metallurgical performance can be achieved with wash water. Increased froth cleaning yielded better upgrading, and some cases slightly improved recovery. Froth sampling and salt tracer tests supported the findings of froth washing tests.At Falconbridge, Ni grade increased from l.47% to 2.15% and recovery from 85% to 87%. At Eastmaque, final Au grade increased from 2.3 to 2.7 oz/st at a slightly higher recovery. At Les Mines Selbaie, Cu grade increased from 24.5% to 25.S% and Zn grade from 54.5% to 56.l%. At Zinc Corp. of America, average Zn grade increased from 55% to 56. 8% at the same recovery for a 45-day period. A number of plants in Canada and the United States have evaluated and/or now practicing froth washing. Wash water has now proved itself in some plants over several months of operation.INTRODUCTIONFroth washing in mechanical flotation cells offers a number of metallurgical (i. e. increased grades and/or recoveries) and economical (i.e. decreased transportation and smelting & refining costs) benefits. Fundamental development work in laboratory and pilot scales performed at McGill yielded encouraging results. (Kaya and Laplante, 1988a and 1989a). Since laboratory and pilot flotation performance can differ from full-scale due to differences in hydrodynamics, kinetics, and froth characteristics (e.g. stability, loading etc.), plant trials were essential to prove the viability of this technology."

Jan 1, 1990

Disastrous earthquakes are a reality on the Australiancontinent. Unfortunately it has taken the fatal 1989 New-castle earthquake to demonstrate to all Australians that we do not reside on a "stable continent". While the world accepts the potential of plate tectonics and its associated plate margin earthquakes, particularly around the active Pacific Rim, the realisation of devastating intra-plate, or continental, earthquakes is only now beginning to take effect. The 1989 Newcastle earthquake provides many lessons on which to further fundamental earthquake research and the applications to the future welfare of human civilisation. To mitigate the earthquake hazard in relation to the devastation to life, property and industry, research must be undertaken with the resulting informa-tion to be included in the nation's disaster management programs. The earthquake hazard is everpresent in east-ern Australia and the major step in its quantification is a more realistic determination of earthquake risk estimates through an integrated study of seismology, engineering, insurance and sociology.

Jan 1, 1990

By C. Richard Tinsley

Investment activity in the Pacific Rim of Fire has seen a phenomenal surge from epithermal gold exploration. Individual countries are attractive because of lower up-front minerals lease costs (United States, Canada), better geological prospects (Chile, Indonesia), or cheaper equities (Australia). Since the October 1987 stock market crash, large companies are shedding minority joint venture interests to focus on core businesses. Some vertical integration is evident in Japanese coal investments in the Pacific Rim. This article does not cover the aluminum industry oligopoly, which is multinational in character. Nor does it cover the many Canada to US minerals investments. It will be interesting to see if the new US-Canadian free trade treaty will reverse that investment flow. Cross-border investments The following examples should dispel any doubts about the significance of cross-border investment in the Pacific Rim. BHP, Australia's largest public company, has invested $US 4.5 billion in the JS for the following transactions 1984 $2 billion Utah Minerals 1984 $500 million Energy Resources 1985 $745 million Monsanto Oil 1987 $400 million 50.7% Hamilton Oil 1989 $378 million Pacific Resources Placer Dome, mainly through 76% owned Placer Pacific, has the following gold mine developments in hand including the date the project began, Placer Dome's ownership, project name, its location, and capital expenditures: • 1985, 53.1 %, Kidston, Queensland, $A 139 million; • 1989, 37.9%, Big Bell, Western Australia, $A135 million; • 1989, 60.6%, Misima, Papua New Guinea, $C252 million; • 1990,45.5%, Granny Smith, Western Australia, $A95 million; • 1991, 50%, La Coipa, Chile, $US276 million; and • 1991, 25.3%, Porgera, Papua New Guinea, $C1.1 billion. Australia's Western Mining Corp. (WMC), through a foray of off-market acquisitions in late 1987, acquired con¬trol of five Canadian gold companies for a $A488-million outlay ($C452 million) as follows:

Jan 1, 1990

By Bluck R. G

The Murray Basin is known to contain major deposits of heavy mineral sands and intensive exploration for new deposits is being conducted in Victoria, South Australia and New South Wales. The western Basin was well served in the Pliocene and Early Pleistocene by a variety of appropriate sediment sources, and potential coastal traps. Immature, fluvially-sourced sediments forming the Pliocene coastal complex of the Marmon-Jabuk Range in South Australia are part of a marginal marine assemblage containing a suite of economically important heavy minerals that include ihnenite, zircon, rutile and tourmaline. From a consideration of Pliocene palaeogeography and coastal dynamics, specific targets where concentrating processes are likely to have operated are identified in the South Australian portion of the Murray Basin. Such palaeo-environments include the down-drift, littoral zone of discrete foredunes or coastal barriers, the source area for transgressive dune complexes, tombolo facies, and intertidal shoals and sandbanks. Similar coastal processes are recognised for a preserved Early Pleistocene barrier complex.

Jan 1, 1990

By Susanne Pignolet-Brandom

This paper examines the viability of using the QEM*SEM automated scanning electron microscope for the determination iron sulfide and calcite volumetric percentages. The analytical reliability was verified by comparing elemental abundances calculated for fourteen samples using the QEM*SEM volumetric percentages and appropriate mineral compositions and elemental abundances determined by standard laboratory procedures. The abundances were comparable, thus demonstrating suitability of this technique for evaluation of the acid neutralization and generation potentials of mining wastes.

Jan 1, 1990

By L. J. Blatnica

Throughout the 1980's the tem Mine-Wide Monitoring System has had various meanings for manufacturers of these systems and underground mine operators alike. System suppliers had visions of grandeur in the early 80's as they envisioned each mine, that has more than a single section, installing a computer based monitoring system to provide surveillance, control and documentation of the entire mining operation, including everything from a single heat detector to the weekly payroll. In a few cases this may have become reality but the truth is these systems have quietly become a steady but unspectacular workbase for the modern mining industry of the 1990's. As it exists today the total market for underground monitoring systems may not exceed $10 million annually. Suppliers have lowered their expectations of the dollar value of this particular market. Some were entering a new market because of experience with computer based data acquisition systems. Others had been active in the mining industry for years with more traditional equipment (communication systems, methane monitors, safety equipment, etc.) and decided to become involved with Mine-Wide Monitoring Systems.

Jan 1, 1990

By R. Amelunxen

"The molybdenite associated with copper porphyry ores is generally treated in a flotation circuit consisting of a separation and a cleaning section. In the last few years column flotation cells have replaced the numerous counter-current stages that were previously used in the cleaning section. Despite this, little has been published regarding the number of column cleaning stages required. Therefore a Moly flotation database is assembled with the objective of verifying the existence of a common upgrading profile. This can then be used as a guide in the prediction of the number of stages required to achieve a given concentrate grade.INTRODUCTIONAlthough the first use of Column Flotation was on copper flotation products, the popularity and understanding of their operation was not really achieved until they were widely implemented in Moly circuits in early 1983. The use of columns in Moly plants has since left a legacy of information, both published and unpublished. The data collected since that time has been used primarily used to establish column operating parameters and to determine upgrading potential within the circuit.Byproduct Moly generally occurs with porphyritic copper ores in concentrations less than 0.1% MoS2. As such, piloting a new moly ore to produce, say 5 Kg/Hr MoS2, in a slurry approximately 1 Lt/min (at 10% solids), requires a moly plant feed of about 570 Kg/Hr, which translates to a mill feed rate of 200 to 800 Tonnes per day (depending whether you deal with Chilean or Canadian ores). Piloting Moly for any lower tonnage would reduce the accuracy of the testwork.Thus a need exists to collect operating data in order to establish the existence of process relationships that could be used for feasibility and design purposes.The object of this paper is to expose a preliminary relationship that could be used for the purposes described above and to apply the findings to a preliminary design of a moly cleaning circuit flowsheet."

Jan 1, 1990

By Frank F. Aplan, Edward C. Dowling, Richard R. Klimpel

Several series of time-instantaneous samples were taken on a cell-by-cell basis in the flotation circuits of the Pinto Valley, AZ copper concentrator. These samples were used to calculate mass flow rates throughout the circuit using standard, deterministic metallurgical formulae and also a variety of more statistically oriented techniques. Because of the magnitude of the errors associated with the individual cell samples, the standard metallurgical formulae are not sufficient. Consequently, it is necessary to utilize some type of statistical technique capable of distributing the individual cell sample errors in such a way so as to provide a physically useful mass balance for the entire circuit. This paper explores the use of linear and least squares programming as one technique to providing credible mass balance calculations. For linear programming this was done by distributing the error using two different criteria involving specific linear programming formulations: least absolute sum minimization (which assumes an underlying double exponential distribution error structure) and minimax (which minimizes the maximum absolute deviation and assumes an underlying rectangular distribution error structure). These results were then compared to the more standard formulation of minimization of the sum of least squares which assumes an underlying normal distribution error structure. The least absolute sum approach was particularly attractive due to its simplicity of use and the ease in which repetitive calculations can be done with no user intervention.

Jan 1, 1990

By M. Z. Rashad

The purpose of this paper was to compare the covariance and multiquadric functions in same mining and geological applications. The basic principals of the two techniques are covered briefly. Similarities and dissimilarities of the covariance and multiquadric functions are discussed geometrically, mathematically and practically. A 14 by 16 kilometer square area in Baharia Oasis, Western Desert of Egypt, was selected for a detailed comparative test. The gravity anomalies of forty-eight test stations were computed by using the data of sixty-three control stations. The results indicated that the covariance function is quite better than the multiquadric one. On the other hand, the multiquadric function more simple in computation than the other one, which needs to precalculations such as semivariogram and covariogram. Moreover, multiquadric equations are based on geometrical and physical considerations rather than covariance functions.

Jan 1, 1990

By N. S. Dalal, X. Shi

"This study reports a new property of the important NAD(P)H-dependent flavoenzymes, glutathione reductase, lipoyl dehydrogenase and ferredoxin- NADP oxidoreductase, that can catalyze a one electron reduction of metal ions such as chromium(VI) and vanadium(V). During the enzymatic reduction process, molecular oxygen is reduced to H2O 2 , which reacts with the reduced metal complexes to generate hydroxyl radicals. Since the hydroxyl radicals have been suggested to play an important role in Cr(VI) toxicity, this study provides a basis for a recent observation that Cr(VI) mutagenesis is strongly oxygen dependent. These results also point to an enzymatic pathway for the metabolism of some metal ions and concomitant generation of hydroxyl radicals. l. INTRODUCTIONThe purpose of this communication is to report that some important NAD(P)H-dependent flavoenzymes (glutathione reductase, lipoyl dehydrogenase and ferredoxin-NADP+ oxidoreductase) can catalyze one electron reduction of metal ions such as chromium(VI) and vanadium(V) and simultaneously reduce molecular oxygen to generate Hi02 and, eventually, the ""OH radical. This finding is significant because (i) the known substrates for the flavoenzymes are organic species and not metal ions, and (ii) the report on the enzymatic formation of the ""OH radical provides a new pathway for understanding the mechanism of genotoxicity of some non-ferrous metal ions. For example, it has been suggested that OH radical is likely to be the major species responsible for Cr(VI) genotoxicity [1-5). The 'OH radical is generated through the reaction of Cr(V) complexes with cellular Hi02 [4,5]. Cr(V) itself is known to be generated from Cr(VI) in various biological systems, in particular, microsomes [ 6), mitochondria [7] and mitochondrial electron transfer chain complexes [8]. However, no specific enzyme responsible for the Cr(V) generation has been identified except possibly glutathione reductase [4]. In this study we have used ESR and spin trapping techniques to show that the flavoenzymes can generate Cr(V) and provide a catalytic redox cycle for 'OH formation in such reactions. Herein we present our results on Cr(VI) and summarize those on other systems. Correspondence address: N.S."

Jan 1, 1990