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By Gale F. Hoffnagle

INTRODUCTION On November 15, 1990, President Bush signed the Clean Air Act Amendments of 1990. These Amendments cover many aspects of air pollution control. The provisions which seek to control emissions of "air toxics" may, however, be the most far-reaching and will potentially have the greatest effect on American industry. The Administration has estimated that by the year 2005 industry will be spending $6.7 billion per year on air toxics control. Meanwhile, the Business Round Table has estimated that the price will be far higher, up to $62 billion per year, depending on how EPA and the States implement the program. BASIC REQUIREMENTS Any "major" source of emissions of 189 air toxics will be required to install "MACT." The translation of this statement requires some definitions: •MAJOR SOURCE - A facility (a contiguous property under single ownership and control) which has actual emissions of 10 tons or more per year of any single one of the air toxics or 25 tons per year of any combination of air toxics. •AIR TOXICS - Congress has provided a list of the 189 chemicals on this list. Those that may be important to the mining industry are shown on Table 1. This list can be changed by petition or by EPA. •MACT - Maximum Achievable Control Technology is to be defined by EPA for each industrial source category. EPA says there are about 400 categories. The Act defines MACT as: "the average emission limit achieved by the best performing 12% of the existing sources ... for categories with 30 sources or more" or, "the average emission limitation achieved by the best performing 5 sources in the category." TABLE 1 SELECTED AIR TOXICS FROM CLEAN AIR ACT LIST IMPORTANT TO MINING INDUSTRY Antimony Compounds Arsenic compounds (inorganic including arsenic)' Beryllium Compounds' Cadmium Compounds Chromium Compounds Colbalt Compounds Cyanide Compounds (dissociation compounds) Lead Compounds' Manganese Compounds Mercury Compounds' Fine Mineral Fibers Nickel Compounds Radionuclides (including radon)1 Selenium Compounds 1Previously listed under NESHAP 2The Administration may not list elemental lead as a hazardous air pollutant.

Jan 1, 1991

By L. G. Stolarczyk, R. C. Fry

In coal-bearing formations, seams are often bounded by sedimentary layers of mudstone, claystone or shale. When the electrical conductivity of the surrounding sediment layers is greater than the conductivity of the seam, a natural parallel plate waveguide forms in the strata. For frequencies below the AM broadcast band, the waveguide can be used for the transmission of electromagnetic (EM) waves. In a uniform seam, the primary wave travels in the coal layer along paths between a radiating antenna and a distant receiving antenna. The travel distance increases with seam height and the conductivity of the surrounding sediment layers. The distance decreases with increased coal conductivity. In Cretaceous western bituminous coal, the distance may exceed 549 m (1800 ft). Anomalous geologic disturbance zones such as faults, shear zones, paleochannels, sills and dikes significantly alter the values of EM wave propagation constants (attenuation and phase) expected in a uniform seam. In the neighborhood of an anomaly, EM wave energy is scattered (reflected and diffracted). Scattering creates secondary waves in the seam wave guide. A receiving antenna at a remote location in the coal seam can be used to measure the magnitude and phase of the EM wave at the end of the path. The measured data can be processed to determine the average value of the propagation constants along each path. Paths with anomalous propagation constants are used to locate and image geologic disturbance zones. Radio Imaging Method (RIM) instrumentation, survey procedures and data processing (tomography) algorithms have been developed to image geologic structure in advance of mining. The survey is conducted between gate roads of a longwall panel. Data processing constructs contours of constant attenuation rate (phase constant) across the plan view of the panel. In anomalous zones, the contours rapidly change with distance. The shape of the contour lines generates a visual image of the anomaly and suggests the type of anomalous condition to be expected in the coal seam. This paper briefly discusses the depositional environment and the formation of the imperfect waveguide in coal-bearing strata. The linkage between sedimentary geology and EM wave theory establishes an understanding of how the propagation constants depend on the anomalous geologic conditions. A case study compares in-mine geologic mapping with the tomographic image of a longwall panel.

Jan 1, 1991

The incidence of colliery disasters has highlighted the need for more centralised and directed coal mining safety research in Queensland, with particular impetus from explosions at Box Flat in 1972, Kianga in 1975 and Moura No 4 in 1986. Inquiries which identified the likely causes recommended measures and, research and two outcomes have been the present Mines Safety Research Advisory Committee and The Safety in Mines Testing and Research Station at Redbank, near Brisbane, dealing with all mining problems, coal and metalliferous. Already, important research into ignition and explosion and other health and safety matters has been accomplished; the Station has become an accredited testing laboratory; and international recognition has been achieved. Now the advisory, testing and research arms are soundly in place to pursue preventive investigations and be ready to provide assistance in any emergencies.

Jan 1, 1991

By Z. Yang

The flotation behavior of the. green algae Chlorella vulgaris and a wild Chlamydomonas spp. was studied in the presence of Zn(II) using dodecylammonium chloride as collector. At about pH 6. both organisms readily float as amine concentration approaches lx10-3 kmol/m3. In addition, electrokinetic measurements were made on the organisms as a function of pH in both the presence and absence of Zn(II). It was found that the Zn(II) has a considerably greater effect on the zeta potential of C. vulgaris than on Chlamydomonas. Zn(II) adsorption studies also indicated that C. vulgaris is able to accumulate more Zn from solution than the Chlamydomonas.

Jan 1, 1991

By Hayward P. G

Complex ores, characterised by intimate intergrowths between minerals, have previously been treated by flotation with limited success. The most common problem has been that the liberation size is often finer than the lower size limit for selection flotation. A technique has been developed in which the problem is overcome by the use of a selective agglomeration procedure in which the values are coalesced with oil to a size suitable for flotation prior to introduction into the flotation machine. A complex lead ore was characterised by QEM*SEM mineralogy as having a mean galena liberation size of 15 ¦m. The best recovery of lead at 50 per cent Pb grade by standard flotation was 53 per cent. After application of the procedure, 86 per cent recovery was obtained after a single cleaner step. The oil functions as a bridging liquid in the presence of conventional collectors which render the mineral oleophillic.

Jan 1, 1991

By J. A. Finch, G. Labonté

The behavior of four different redox sensing electrodes (gold spiral, black platinum, chalcopyrite, and galena) during roughing and cleaning flotation is examined and related to the flotation response. The results indicate that the solution potential (as sensed by the black platinum electrode) is different from that of the pulp potential (gold spiral) and is only weakly related to the flotation response. On the other hand, the potentials exhibited by the gold spiral and the two mineral electrodes are related to the flotation response. The transient responses of the gold and mineral electrodes during the addition of flotation modifiers could indicate the conditioning time required to achieve flotation or depression of selected minerals.

Jan 1, 1991

By J. L. Fuller, N. A. Abdel-Khalek

This paper contains a brief summary of design descriptions and generally accepted designations for longwall ventilation systems. Various ventilation systems for longwalls developed using single-entry and multiple- entry systems are discussed. Design considerations specific to longwall mining are included.

Jan 1, 1991

By L. Rainey, W. E. Wallace, B. L. Razzaboni, P. Bolsaitis, V. Vallyathan

The hemolytic activity of milligram-sized mineral dust samples from coal mines collected in personal dust samplers were measured by a modified Harington assay method which increases the sensitivity of the technique. Measurements were conducted on a large number of samples from different mines characterized for gravimetric quartz content and the relative bulk concentration of common contaminants (Al,Ca,Fe). The results of these measurements were compared to the hemolytic activity of pure quartz and of mineral samples obtained from roof-bolter dust boxes of two coal mines. No correlation could be established between hemolytic activity and the compositional variables tested. The results suggest that the distribution of minerals among individual particles and the surface characteristics of particles, rather than the bulk concentration, determine the hemolytic activity of respirable mine dusts.

Jan 1, 1991

By Paul G. Schmidt

Exxon Minerals Co. was exploring for mineral deposits in Precambrian terranes of the US portion of the Lake Superior region in the late 1960s. Exploration drilling and other activities had been concentrated on massive sulfide prospects in northeastern Minnesota, but general exploration studies and competitor scouting were conducted in other areas of the region. These activities drew attention to Wisconsin in 1969 when it became apparent that Bear Creek Mining Co. had made a discovery near Ladysmith in the northwestern part of the state. Observation of their drill hole pattern suggested that a massive sulfide deposit, since named the Flambeau deposit (Schwenk, 1977), had been found. With this background, Exxon initiated an exploration program for Precambrian massive sulfide deposits in northern Wisconsin in 1970 (Figs. 1 and 2). Northern Wisconsin is extensively mantled by Pleistocene glacial drift and bedrock outcrop is sparse. Other than iron mines in the extensive iron formations along the Wisconsin-Michigan border and Jackson County, no significant mineral deposits were known in the Wisconsin portion of the Precambrian Shield until the discovery of the Flambeau deposit. Until the mid-1970s, the only specific published literature on the Wisconsin Precambrian consisted of old outcrop locations and descriptions in journals of the Wisconsin Geological and Natural History Survey (Chamberlain, 1882; [ ] Weidman, 1907; Hotchkiss, 1915) and the summary maps of Dutton and Bradley (1970).

Jan 1, 1991

By Yiyin Ma, Yuqi Chen

Based on two in-situ measurements and mathematical analysis, the micro-climate in a large central underground pump and power station has been discussed in this paper. It is found from the research that the "semi- infinite" body model in the general heat transfer can closely represent the heat exchange process in the air flow-surrounding rock-adiabatic intermittent heat source complex in the station. Finally, computer simulations were made to calculate the micro-climate in a similar pump and power station where power machines operate intermittently. The simulation results are quite satisfactory. It can provide useful information for decision- making in the air conditioning of such stations.

Jan 1, 1991

Epithermal gold mineralisation was discovered at the Muyup prospect during regional reconnaissance exploration in 1986. Further exploration utilising routine techniques of stream sediment, panconcentrate, rockchip sampling and geological mapping resulted in the discovery of five auriferous vein systems located along northwest-trending fault zones. Scout diamond drilling was conducted on two of the vein systems. Mineralisation is hosted by a poorly exposed, mid-Tertiary volcanic inlier composed of intermediate and minor felsic volcanic rocks intruded by intermediate hypabyssal por- phyries. Gold is wholly contained in narrow steep-dipping hydrothermal breccias and quartz vein stockworks in which chalcedonic silica and fine grained quartz is the predominant gangue with minor adularia, carbonate, and sulphides. Alteration zoning is manifested as intense fracture-controlled silicification mantled by narrow clay-rich envelopes which in tam grade outward and downward into propylitic alteration or unaltered host rocks. Late advanced argillic alteration is superimposed on the vein-related altera- tion assemblages. Alteration assemblages and fluid inclusion data suggest that gold mineralisation occurred in response to episodic hydraulic fractur- ing and boiling of low to moderate temperature, dilute alkali-chloride fluids. The Muyup prospect represents the shallow eroded remnants of an epither- mal gold deposit enriched in Au, Ag, As, Sb and Hg. Low sulphur fugacities reflected by vein and alteration assemblages support an adularia-sericite classification (Heald et al, 1987) for this epithennal gold deposit.

Jan 1, 1991

By J. Hanna

The University of Alabama Mineral Resources Institute (MRI) has developed a unique process for selective fatty acid flotation of carbonate gangue from sedimentary apatites (francolite) in the pH range of 4-6 without collector conditioning of the pulp. The process, which does not require an apatite depressant, was modified to benepciate a high- MgO siliceous phosphate matrix from south Florida. The modified process includes two flotation stages, one for car- bonate removal and the other for phosphate recovery from the siliceous gangue. The selective flotation separation of the carbonate and phosphate from siliceous constituents of the matrix at various pH levels and collector dosages are discussed. In the carbonate flotation stage, about 70% of the MgO was rejected in the froth. The phosphate flotation stage produced concentrates analyzing about 31% P2O5 0.7% ? 5 MgO, and 4% insol. The overall P2O5 recovery In the two stages was about 85%

Jan 1, 1991

By Zhu Mingshan, Wu Jiang, Xu Yingqin

A mathematical model to simulate spontaneous combustion of coal in goaf was developed. Under the condition of two-dimensional flaw of air through a bed of uniform mixture of coal, gob, stone etc., the model simulates the temperature rise in the air-and-particle system associated with Arrhenius particle surface reaction. The model is developed as a set of coupled non-linear partial differential equations, which include (1)mass conservation equation for oxygen, (2)energy conservation equation for gas, (3)energy conservation for solid, and (4)velocity equation for gas, that are solved numerically. An elaborate parametric analysis is made of effect of leakage air flux and position of source and sink, parameters relating to the coal accumulating character and the kinetic properties of coal on the tendency to spontaneously combust. In addition, the dynamic process of temperature rise within goaf under several conditions is displayed with picture drawn by computer.

Jan 1, 1991

By J. W. Stevenson

At this 5th U.S. Mine Ventilation Symposium I would like to focus your attention on safety and the contribution of the ventilation engineer over the past 50 years. This conference affords us the opportunity to express, to listen, and to learn. As ventilation engineers it is indeed an exciting time--a time that not only stimulates our imagination but also pin points our aims in our quest to obtain zero fatalities by the year 2000, the goal expressed by William J. Tattersall, Assistant Secretary of Labor, Mine Safety and Health Administration. In the past, coal mine ventilation has often been unfortunately synonymous with explosions and resulting fires. Those not familiar with us do not recognize the painful evolution of the coal mining industry and particularly the evolution of mine ventilation. To put my presentation into perspective, I recently reviewed a U.S. Bureau of Mines Bulletin No. 586 - "Historical Summary of Coal-Mine Explosions in the United States 1810 - 1958 prepared by H. B. Humphrey Mining Health and Safety Engineer. This bulletin was published in 1960. Mr. Humphrey stated "In 1946, factors contributing to the explosions occurring from 1941 to 1945 were: (1) The rapid increase in the use of electrical equipment at face regions where gas and dust are most likely to be found; (2) the increased demand for coal with the desire to obtain maximum tonnage per machine at minimum cost, which in many mines has resulted in neglect of even rudimentary precautionary measures; (3) multiple-shift operation without provision of time for adequate maintenance of equipment, effective rock dusting, and testing for gas; (4) decrease in supervision owing to demands on supervisors for maximum tonnage and loss of competent supervisors to other employment; (5) lack of effective supervision, owing to numerous new conditions, some of them war-connected; (6) inability to obtain adequate equipment repair and replacement parts; (7) shortage of labor and inadequate training of coal-mine workers; and (8) failure of both miners and mining officials to show regard for safety in changing from hand-loading to mechanized methods". Most of the eight factors listed by Mr. Humphrey continue to affect our work lives as mining engineers. The increased demand for coal with the desire to obtain maximum tonnage per machine at minimum cost has never changed. The local and regionalized coal industry of the 40's is today competing against the world coal market. Our mines work or shut down based on cost. This has always been the case. During the five year time-frame Mr. Humphrey was documenting, 345 miners were killed in major explosions. A major explosion was one in which five or more miners were killed in a single accident. In addition, 105 more miners were killed in minor explosions for a total of 450. What a wanton waste of life. What fears, anxieties, miseries, and sufferings were created by these accidents. However, we must remember and keep in mind that the coal mining company officials, engineers, and foremen, the governmental agencies- federal, state, and local - were using the technical tools and knowledge available to operate the mines as safely as they could. Obviously mine ventilation engineering technology was woefully inadequate.

Jan 1, 1991

By Michael L. Free

Bacterial oxidation of an arsenopyritic gold-ore .concentrate was carried out with continuous-flow .operation in 14-liter, mechanically agitated reactors. Samples from the slurry reactors were separated into solid and liquid fractions and analyzed separately to determine the electrochemical rates of sulfide conversion by the bacteria and the rates of direct bacterial oxidation of sulfide. The rates of the individual mechanisms are compared to the overall rates of biooxidation in the continuous-flow slurry reactors. The results show that the commonly hypothesize4 direct and indirect mechanisms of biooxidation both play a significant role in the bacterial oxidation of sulfide ores.

Jan 1, 1991

By S. K. Bhatt

This paper reviews major developments in continuous haulage technology for underground coal mines. Haulage systems in use and development are investigated through a comprehensive literature search and visits to mines and manufacturers. The systems include flexible conveyor train, mobile conveyor, multiple- unit continuous haulage, extensible and belt turning systems. Strengths and weaknesses of the systems are assessed in light of their operating under remote control and their application to the computer-assisted continuous mining machine being developed by the US Bureau of Mines. Through mining scenarios, candidate haulage systems are conceptualized to be consistent with the capabilities of the mining machine.

Jan 1, 1991

By Jiang G

The Chinese Central Government attaches great importance to the development of its coal industry. Besides carrying out the policy of simultaneous development of large, medium and small coalmines,the main strategy is to gradually modernize coal mining areas and coalmines and to increase the output from individual coalfaces. There are particular implications, processes and main experiences of coalmine modernisation in China.Ensuring a coal output of over one M tonne/yr from one coalface is a very complicated system-engineering project which deals with a wide range of problems. The most important measure used for achieving an output of over one M tonne/yr from a single coalface is the analysis of affecting factors on coalface production by means of the theory c reliability. Thus, as far as possible , the production stoppages caused by mechanical equipment failures and other factors are avoided, the equipment recovery rate is increased and the working hours of shearers are extended so as to ensure a high output and high efficiency.

Jan 1, 1991

By Henry L. Ehrlich

This survey compares bioleaching and biobeneficiation by autotrophic bacteria with that by heterotrophic bacteria and fungi Some physiological principles are reviewed. Advantages and disadvantages of autotrophic and heterotrophic leaching are discussed. Principles of anaerobic leaching by autotrophs and heterotrophs are introduced. and the advantages? over aerobic heterotrophic leaching are discussed. Examples of useful organisms in the autotrophic and heterotrophic categories are cited.

Jan 1, 1991

By P. L. Claessens, S. Belisle, C. Bowen

"Use of zinc shot feed is a well-established procedure among North American electro-galvanizers. This form of zinc is easy to handle and relatively inexpensive when compared with zinc oxide. This paper reports results on the kinetics of zinc shot dissolution in traditional pure zinc solutions and in electrolytes used for the plating of nickel/zinc alloys. Despite the cementation of minor amounts of nickel in the latter solution, acceptable dissolution rates of the zinc shot can be achieved through proper adjustment of the solution velocity. Under these conditions, the nickel shell produced by cementation is continuously abraded, exposing the underlying zinc.IntroductionThe use of insoluble, noble metal-containing anodes rather than soluble zinc anodes for the operation of high current density electro-galvanizing lines has gained almost universal acceptance. Two major reasons for this trend are:• improved control of the process by virtue of constant inter-electrode distance; and• increased productivity because the operation of the lines does not require the relatively frequent interruptions for replacement of consumed anodes .The results of the principal anode and cathode reactions are, respectively, depletion of the zinc content of the electrolyte and the increase on its acidity;"

Jan 1, 1991

By V. Rajaram

The Metropolitan Water Reclamation District of Greater Chicago (MWRD) imposed a no-blasting specification (blasting is restricted to the construction shaft and shaft bottom or boot) on the Deep Tunnel project in 1988. This was prompted by numerous complaints from the residents in the vicinity of the project, and controversies experienced on previous projects from blasting the rock overlying the tunnel. This paper will describe the methods utilized by two major contractors who are driving 20 km (12.5 of tunnel along with drilling over 36 shafts under this restrictive specification. The impacts on design, construction, schedule, cost, and the environment are detailed.

Jan 1, 1991