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By N. S. Dalal, Xianglin Shi

Metal ions, such as chromium (Cr) and vanadium (V) are found as trace impurities in mineral dust. Since metal ion mediated free radical generation has been implicated in many disease processes, we carried out a detailed investigation of the metabolism of these metal ions by biological redox systems and the possible oxygenated radical generation therefrom. We found that highly reactive Cr(5+) species are generated in the reduction of Cr(6+) by NADPH-dependent glutathione reductase, lipoyl dehydrogenase, and ferredoxin-NADP+ oxidoreductase. The reduced metal ion species react with hydrogen peroxide, to generate hydroxyl (•OH) radicals in a continuous cycle. The enzymatic catalysis processes also involves the reduction of molecular oxygen to the superoxide [(0-1 2)] radical. Thus only a trace amount of metal ions chemisorbed on mineral dusts, such as quartz, can catalyze the generation of the highly toxic oxygenated radical species from cellular hydrogen peroxide, suggesting a new biochemical mechanism for mineral dust induced chronic lung injury.

Jan 1, 1991

By George Aul, Richard Ray

Short-hole horizontal degasification systems have been utilized in Island Creek's Virginia Division mines since 1986. These systems remove methane from the coal seam in advance of longwall mining. Without an in-seam methane drainage program, methane liberation rates from the longwall faces may exceed 0.47 cu m/s (1,000 cfrn), requiring 47 cu m/s (100,000 cfm) of air for adequate dilution capability. Optimization of the degas systems has enabled methane liberation levels and the associated ventilation requirements on the longwall faces to be reduced by 50 to 80 percent. Since the inception of the first degas system at the Virginia Pocahontas No. 6 Mine, Island Creek has developed an overall methane drainage program designed to maximize gas production and minimize ventilation requirements for methane dilution. Gas production from the degas systems is affected by four main design criteria: (1) hole location, (2) hole length and spacing, (3) collection system capacity, and (4) time available for drainage. Drilling equipment and materials for the gas collection system are selected to meet the necessary criteria while minimizing manpower requirements. Benefits gained from reducing methane liberation rates from the longwall faces are fourfold: (1) improved safety due to lower methane concentrations in the face area, (2) fewer production delays caused by excessive methane concentrations, (3) lower fan operating costs resulting from reduced air requirements, and (4) enhanced worker comfort resulting from lower air velocities and less dust generation.

Jan 1, 1991

By Yu A. B

An experimental study of the packing of a coal heap has been carried out. The bulk density of a coal heap is considered as a function of a number of variables, viz flow rate, conveyor belt speed, the height of the disengagement point of the conveyor belt, coal particle density, moisture content, the size of the heap and coal particle size distribution. The effects of the dimensionless numbers resulting from dimensional analysis on the packing density of a coal heap have been experimentally examined and analysed. Based on the experimental results, equations have been formulated for the estimation of the bulk density of a coal stockpile. The validity of these equations are checked by comparing the predictions with measurements of real industrial Stockpiles.

Jan 1, 1991

By Michael J. Cruickshank

The State of Hawaii has expressed concern over deterioration of the tourist beaches at Waikiki, which are becoming seriously depleted of sand. In this report the options for acquisition, transportation and placement .of sand on the beach are examined with respect to feasibility and cost. Ten sources of sand were compared, including commercial, from Australia, Maui, and Barbers Point (3), deposits offshore of the Reef Runway (3), offshore of Waikiki (3), and offshore of Molokai from the Penguin Bank (1).

Jan 1, 1991

Traditionally mill operators have been employed with varying educational backgrounds with little if any formal training in aspects of mineral processing. Pasminco Mining-Rosebery, in line with other organisations, saw the need for a prerequisite entry level for operators to enter the industry. After initial discussions between various West Coast Mines personnel, union and government representatives, an industry working group was formed in 1989 with the aim of developing a traineeship suitable for the mineral processing industry. Training and technical representatives from four of the West Coast Mines and TAFE were commissioned with the curriculum development. The resultant course, which is recognised under the Australian Traineeship system, involved an integrated on and off-the-job training program, including 13 weeks of formal off-the-job instruction.

Jan 1, 1991

Revised throughput rates, as a result of current mining methods and tight controls on mine dilution, have dictated a change in metallurgical philosophy at Renison Limited. Emphasis on throughput capacity increases has altered to a reduction in circuit complexity and operating costs. Extensive surveys of the gravity and cassiterite flotation circuits led to several plant modifications between August 1989 and March 1990. The coarse and fine gravity retreatment roughing tables were by-passed, the coarse gravity retreatment roughing tables were re-commissioned, the cassiterite flotation rougher capacity expanded and the gravity regrind cyclones re-configured.

Jan 1, 1991

By Q. Xu

Adsorption of nonionic/anionic surfactant mixtures on kaolinite has been studied with sodium dodecylsulfate as the anionic surfactant and octaethyleneglycol mono-n-dodecylether as the nonionic surfactant. Synergistic interaction between these surfactant was found to cause adsorption of the nonionic surfactant with its hydrophilic chains protruding into the bulk, leading to substantial changes in wettability and dispersion characteristics of kaolinite. Similarly, hydrophobicity changes are observed also for silica particles upon adsorption of nonionic ethoxylated alcohols owing to possible changes in the orientation of the adsorbed surfactant molecules at the interface.

Jan 1, 1991

By Annan Cook

J.R. Atkinson, office engineer to Kennecott Copper Corp., summarized data on the Mineral Park area [Wallapai (Chloride) Mining District, Mohave County, Arizona, Fig. 1] and submitted it to the New York office in 1950. He recommended an examination. Weston Bourret, a Kennecott geologist, accompanied by B.S. Butler, the well known former US Geological Survey geologist, examined the larger of two hydrothermally altered areas in Mineral Park that same year. Bourret recommended that the property be optioned and mapped. Georges Ordonez, Kennecott's chief geologist, after a field examination, agreed with Bourret's conclusions At the end of the summer of 1951, Annan Cook (another Kennecott geologist) accompanied Ordonez to the property prior to starting a mapping program. At Ithaca Peak, the structure, alteration, and reddish-brown coloring in leached cavities-hematite, jarosite, and goethite with minor copper staining - made an interesting target. The Peak, which has since been mined, was a Laramide quartz monzonite porphyry grading into quartz porphyry, penetrating Precambrian rocks. Turquoise had been mined from several workings on the Peak. Surrounding the central area of alteration, but mainly to the northwest, there were many long-abandoned underground workings mined for zinc, lead, gold, silver, and copper. To the west of Ithaca Peak within the main area of alteration, surface evidence of a chum drill hole suggested interest in the disseminated mineralization probably prior to World War II. A topographic and geologic survey of the altered Ithaca Peak area was initiated by Cook in September 1951. He was assisted by Richard Vosburgh, field engineer, and by four geologists: Charles Goddard, III, Donlon LoBionda, Keith Martin, and A.T. Stone. When Cook returned to New York, Vosburgh was left in charge. Mapping continued and diamond drilling took place during the winter of 1951-1952. Drill sites were selected entirely on the basis of surface geology. Five drill holes, including a flat hole, located around the flanks of Ithaca Peak, averaged about 183 m (600 ft) in length. A sixth hole caved at less than 60 m (200 ft). The best values obtained were in the first hole (-45°): 90 m (300 ft) averaged 0.62% copper and 103 m (337 ft) averaged 0.041% molybdenum. In another hole, 43 m (142 ft) averaged 1.09% copper and 0:023% molybdenum. The values of copper and molybdenum in these two holes were generally higher than in the remaining holes, although molybdenum values were always around 0.024% or better. The New York office decided, however, to abandon the project even though the remaining field crew of three had recommended more drilling.

Jan 1, 1991

By Orville L. Lantto, Bruce K. Cantrell, Keith S. Olson

Approximately 10 to 20 pct of exhaust aerosol mass from diesel equipped vehicles operating without exhaust controls is attributable to particles in the 1.0-10 µm size range. Recent in-mine measurements suggest that, in addition to reducing overall exhaust aerosol mass concentrations, the use of waterbath exhaust conditioners (water scrubbers) may significantly reduce the concentration of diesel exhaust particles larger than approximately 0.5 µm aerodynamic diameter. This implies that a measurement system that discriminates between diesel and mineral dust aerosols on the basis of aerosol size would have different accuracies depending on use of a water scrubber. To test this hypothesis, laboratory measurements were made by the Bureau of Mines to determine diesel exhaust aerosol penetration efficiency through a water scrubber as a function of size and engine operating conditions. Size distributions were determined using a Micro-Orifice, Uniform Deposit Impactor. Concentrations of CO, CO2, NO x, O2 and gas-phase hydrocarbon concentrations were also measured. No significant effect was found for these gases other than a slight decrease in NOx emissions. The water scrubber served as a moderate aerosol control with reductions in mass concentrations of about 29±9 pct under most conditions. This reduction occurred for particles less than 0.2 µm and greater than 0.6 µm aerodynamic diameter. Coal dust aerosols are mostly larger than 0.8 µm aerodynamic diameter. With use of a water scrubber, separating the aerosol into two parts, greater and less than about 0.8 µm aerodynamic diameter during sampling, results in collection of diesel and coal dust aerosol accurate to within 10 pct. Without a water scrubber in operation, such a sampling protocol would only be accurate to approximately 15 pct.

Jan 1, 1991

Increase the productivity of domestic mining operations by improving the performance of rock drilling systems. Approach Investigate the use of chemical solutions at zero surface charge concentrations as drilling fluid additives to enhance penetration rates and extend bit life. Background Bureau researchers have investigated the use of chemical additives to enhance drilling performance and have found that the most efficient drilling occurred when the drilling fluid was able to maintain a zero surface charge (ZSC) on the rock surface. Laboratory drilling studies using 5/8-inch diameter diamond-impregnated coring bits on rock types such as quartzite, granite, taconite, and marble. Cationic compounds were used as the surface charge neutralizing additives during these tests. The drilling studies demonstrated enhanced drilling performance, however, only at the singular additive concentration that produced the ZSC condition. Bureau researchers made a breakthrough when they found that polyethylene oxide, although a nonionic polymer, was able to maintain the ZSC condition over a wide range of concentrations. Success using polyethylene oxide as the drilling fluid additive during subsequent laboratory tests prompted testing under field conditions.

Jan 1, 1991

By V. M. Troughton

Further pile load testing has been carried out at Canary Wharf to compare the performance of base grouted and ungrouted bored piles founded in the Thanet Sand. The testing regime included three preliminary test piles and two working test piles. The results of these tests are summarised in Table 1 below. Two of the preliminary test piles were located only 14m apart to compare the performance of a base grouted and ungrouted pile in similar ground conditions. The load/settlement behaviour of these two preliminary test piles are compared on Figure 1. All the piles were drilled under bentonite with a drilling bucket. In the base grouted piles four grouting tubes were placed with the reinforcement cage to within 500mm of the pile toe. After the pile had been concreted these grouting tubes were then extended to the pile base by drilling and packers were installed. Grout was then injected into the four tubes simultaneously.

Jan 1, 1991

By Franklin M. Grynkewicz

The subject of bearing pile performance installed by vibratory hammers has been a matter of increasing study and continued controversy. A recent case study from a major bridge replacement project is discussed which provides encouraging data on the use of vibratory pile hammers as a primary means of pile installation and also presents the problems associated with its general acceptance. The bridge project case study foundations consisted of HP 14 x 89 pile sections, designed to develop capacity primarily in friction. Preliminary tip elevations were determined by traditional static analyses. Production pile installation was performed using an IHC S-70 Hydro-Hammer. Driving criteria and final production pile tip elevations were determined after preliminary indicator pile drive tests and static load test results at bridge pier cofferdam locations. Based on impact driven production pile performance, the Contractor wished to investigate vibratory driven piles as a means to accelerate construction schedule. Dynamic pile testing procedures were used as the primary measurement tool and test results were compared to the production pile drive records and prior static load tests. Field testing consisted of driving and monitoring with the PDA impact driven piles to the design tip elevation. Three vibratory driven piles were installed to the same tip elevation and immediately subjected to impact driving and dynamic testing to compare dynamic pile resistance. The results indicated that the site soil conditions were favorable for vibratory pile hammer installation. Recommendations and procedures for proceeding with vibratory hammer pile installation were presented to the Owner. These procedures included quality control in conformance with latest AASHTO recommendations. The Owner, in spite of the site specific data base and QA/QC procedures, would not accept vibratory pile hammer installation, due to the absence of precedence. It is concluded that for vibratory methods to become accepted a rational method of analysis, design and field QA/QC procedures requires development. In addition, the engineering community and Owners/Agencies must be more open to alternate methods of foundation construction. The continued development of dynamic methods of monitoring vibratory pile installation is considered to be key to the general acceptance of this installation procedure.

Jan 1, 1991

The Mineral Resources Act 1989-90 came into force on 1 Septem- ber 1990 and the Second Schedule of this Act set out the Savings, Transitional and Validation Clauses to this legislation. The Second Schedule gave rise to a number of interesting situa- tions however due to the fact that the time set aside to attend to these matters (the prescribed period) has now expired, with the exception of the points raised below, most of these situations are now history and are of no relevance. The Transitional provisions of the Second Schedule provided for a three month "prescribed period" in which certain actions were required to be undertaken to ensure tenements granted or applied for under the repealed legislation transitioned into the framework provided by the Mineral Resources Act. This Second Schedule of the Mineral Resources Act highlighted a number of anomalies which are still worthy of mention and are listed below.

Jan 1, 1991

By Sun Jiale

This paper presents a brief description of information construction technology for supported excavation to assure satisfactory performance of engineered system. As a successful example of application of the technique, quite a few troublesome problems, such as high groundwater level in soft ground and crowded buildings around the excavation, were solved satisfactorily in the construction of the new tower of Guangzhou Overseas Chinese Manison.

Jan 1, 1991

By W. D. Delahaut

Sampling tests performed at the Paradise Peak Mine compared various blasthole samplers and reverse circulation sampling methods. Statistical analysis of the data indicates that be-low-the-deck bag sampling produced a 24 to 29 percent error when compared to bulk sampling methods. Use of a chip pile wedge sampler reduced error to 17 percent. Reverse circulation sampling upgraded over bulk blasthole sampling by 7 percent for gold and 11 percent for silver. These results indicate that bias sampling conditions exist when small volume bag sampling is employed in production blasthole drilling.

Jan 1, 1991

By E. Cameron

Yeelirrie lies toward the center of Western Australia, 650 km (404 miles) northeast of Perth (Fig. 1). The ore reserves have been estimated as 52.5 kt (57,871 tons) of contained U3O8, at an average grade of 0.15%, of which almost two-thirds average 0.24% U3O8. the ore body is a thin, elliptical, more or less horizontal sheet measuring approximately 9 km (5.6 miles) in length, between 0.5 and 1.5 km (0.3 and 0.9 miles) in width, and up to 7 m (23 ft) in thickness, extending from the surface to a depth of 8 m (26 ft). In spite of its near surface position, there is only one small outcrop of significant mineralization. Carnotite is the only uranium mineral recognized so far, dispersed through a calcrete horizon, and deposited from circulating ground water which was also responsible for the carbonation of the clays completely filling an Early Tertiary drainage system. Calcrete, as seen at Yeelirrie, is quite distinct from the widespread, thin pedogenic horizons, as it often forms bodies many kilometers in length and up to 20 m (65.6 ft) in thickness, elongated parallel to the drainage lines. It is variously referred to as "valley calcrete" or "ground water calcrete" to emphasize the occurrence and mode of origin. The discovery of Yeelirrie in mid-1971 was the successful culmination of a grass-roots exploration program initiated in 1968 as part of Western Mining Cop's program of diversification from its historical position as a major gold producer. The object was simply to find an economic uranium deposit - with no constaints other than those normally taken as applying in the mineral search. There was, therefore, complete freedom in the selection of the exploration model, or models, to be applied and the areas to be considered, though the choice was inevitably influenced by both the nature of world occurrences and the local geology. One of the options avail- able was the sandstone environment. Yeelirrie was the direct result of pursuing this line of investigation through three sequential, but quite distinct, stages: first, a regional study; second, establishing a case for exploring the inland drainage systems of Western Australia; and finally, an evaluation of the calcrete environment. An assessment of the potential for sandstone-type deposits in Australia necessitated going back to first principles, since there were no known precedents in this country for guiding exploration and, as a consequence, the search need not be influenced by established prejudices. Previous uranium exploration during the 1950s had been preoccupied with vein-type deposits, and, although the sandstone environment was undoubtedly being examined in 1968, no discoveries had been announced to that time. When considering the necessary ingredients -a source of leachable uranium, a circulating ground water system, and a suitable reducing environment - it could be argued that considerable areas in the eastern part of the continent were theoretically prospective, but basin depth and the extensive superficial cover of Mesozoic and Cainozoic sediments presented considerable practical difficulties.

Jan 1, 1991

By Kenneth K. Humphreys

INTRODUCTION At the time the 4th edition of this book was published in 1979, the coal industry had experienced a sharp upturn in prices for its product. From 1950 throgh 1969, steam coal prices had held almost flat at about $5 US per st (about $5.50/t). Thus, when considering the effects of inflation, the price of coal had actually been declining for two decades. The passage of the Coal Mine Health and Safety Act in 1969 and its cost effects started an upward trend in coal prices which was rapidly accelerated by the effects of the Mid-East oil embargo in 1972. Prices of steam coal on the spot market eventually climbed to over $30 US per st ($33/t) and higher in some cases. Metallurgical coal prices skyrocketed in a similar manner and the industry at long last appeared assured of an adequate return on investment. Many companies did expend large sums of money to upgrade and expand their mining and preparation facilities. Unfortunately the bubble eventually burst, in great measure due to the downturn in the US domestic steel industry and the resultant decline in metallurgical coal demand, loss of export markets to other nations and even imports of large amounts of foreign coal to the United States, and more stringent environmental regulations which made many high sulfur coal measures uneconomical to mine. Compounding the problem was the rapid world decline in oil prices in the mid-1980s which encouraged many consumers to utilize oil rather than coal. During the 1980s, metallurgical coal dropped over 20% in price, which, when considering inflation, actually amounted to about a 40% decrease in value. Export coal decreased a similar amount in price. Steam coal prices held nearly constant, thus also losing considerable value when inflation is considered. All of these factors make it even more imperative than ever that the industry do everything in its power to make wise economic decisions and to examine carefully all existing operations and planned future expenditures to be certain that their full cost implications are understood and that they can be justified on the basis of an adequate return on investment. It cannot be assumed that the price of coal will increase. To the contrary, as indicated previously, when considering inflation, coal decreased in value in the 1980s, just as it also did in the 1950s and 1960s. The price surges in the 1970s merely were a catchup game, and in truth the true market value of coal is in reality even lower than it was in 1950. CAPITAL AND OPERATING COST ESTIMATION Prior to constructing a new plant or expanding existing facilities, a detailed preliminary cost estimate is necessary to determine the capital investment

Jan 1, 1991

By D. L. Petersen, C. R. Nelson, B. K. Nelson, B. D. Wagener

The Lafayette Bluff tunnel, currently under construction for the Minnesota Department of Transportation (MnDOT), will be among the widest highway tunnels in the United States. The 199-meter tunnel is being constructed in a closely jointed, variably weathered diabase rock mass. Cover above the tunnel crown ranges from 4 meters to 27 meters, and is less than the tunnel excavated width of 18.3 meters for about 60 percent of its length. These factors dictated special support and lining design, limitations on excavation sizes and required sequences for support installation. Tunnel excavation is by controlled blasting, with multiple top headings and bench. Rock support and lining consists of external portal beams, rockbolts and reinforced shotcrete. A final concrete lining provides structural support for the rock mass and the membrane waterproofing system.

Jan 1, 1991

By Fathi Habashi, Michel Pagé, Farouk T. Awadalla

"Chrysotile asbestos can be dyed with certain dyestuffs to form stable coloured products whose hemolytic and cytotoxicity are greatly reduced. Examples of these dyes are Thiazol Yellow G (a monazo dye) and Trypan Blue (a diazo dye). Other dye stuffs, for example, basic dyes with triphenyl methane structure, Brilliant Yellow (a diazo dye), and Methylene Blue (a thiazine dye) colour asbestos but do not reduce its toxicity. Similarly alizarin, 8-hydroxyquinoline, and representative members of the phthalein group Bromocresol Purple and Phenolphthalein.IntroductionThere is, at present, a controversy regarding the dangers of asbestos fibres, and attempts are being made to render it less toxic. One of these attempts consisted of treating chrysotile asbestos with gaseous phosphorus oxychloride, POCI], at ambient temperature and in absence of moisture. The product had to be heated at 300°C to 500°C to expel exess entrained reagent to get a material containing 0.5070 to 5% phosphate groups and known as Chrysophosphate (Lalancette and Dunnigan, 1982). This product showed decreased toxicity as measured by its hemolytic effect on red blood cells (fable 1). In another approach, Flowers (1983) showed that when chrysotile asbestos was thoroughly mixed with a solution of ferric ammonium sulphate and the slurry was then filtered and dried, the product showed a marked decrease in cytotoxicity.In the present investigation the problem of toxicity was considered from a different point-of-view. Chrysotile asbestos is a hydrated magnesium silicate that can be represented by the structural model shown in Figure 1 from which it can be seen that magnesium hydroxide groups, Mg(OH)2, form a part of the silicate structure. Certain organic reagents that are known to react with magnesium ion in solution to form chelates were reacted with asbestos to find out whether a chelate was also formed on the fibres, and if so , what will be the hemolytic action and cytotoxicity of the product."

Jan 1, 1991

By Kenneth L. Driggs

The 1988 shift in primary smelting facilities from low grade matte (35%) reverberatory furnaces to high grade matte (63%) flash smelting heavily impacted a very stable and successful converter operation. Low matte grade converter campaigns averaged 36,000 short tons of copper and revert production/consumption was in balance. The conversion to high matte grades necessitated oxygen enrichment of converter blast and revisions in operating practices. After two years of operational development, campaign life has risen to over 40,000 short tons and revert production/consumption is again in balance.

Jan 1, 1991