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By Lary L. Speakman

Typical heavy metal removal system generate a great deal of waste that must then be discharged somewhere. Using Bio-Fix Beads developed by the Bureau of Mines in combination with other waste stream minimization processes, Harrison Western Environmental Services has developed a "zero" discharge operation. Data from current on-site operations will demonstrate the effectiveness of the Harrison Western approach. For 1992 Annual TMS meeting,: "Future Trends and Innovations" Material category Key words: Residues and Effluents Technical category Key words: Extraction and Processing.

Jan 1, 1992

By Emil B. Milosavljevic

The photochemical reactions of cyanide ion induced by light were investigated in the presence or absence of a titanium(IV) oxide semiconductor photocatalyst. The light sources employed were the sun and arrays of either mercury or fluorescent (cool white) lamps. The results obtained verify that cyanide decomposes much faster when TiO2 is present in the solution and that it is first oxidized to cyanate. However, contrary to the previous studies, it is established that cyanide is subsequently further oxidized via nitrite all the way to nitrate irrespective of the light source. As expected, the rates of the oxidation processes decrease with the illumination source utilized in the following order: Hg-lamps > sunlight > fluorescent lamps. As nitrate is a significantly less hazardous contaminant than cyanide, complete photocatalytic oxidation of cyanide to nitrate may be a viable method for decontamination of cyanide wastes. Contrary to previous claims, we find that cyanide is slowly photochemically decomposed even in the absence of TiO2. For example, with the mercury lamps as the light source, in two hours, cyanide concentration decreases to essentially zero; up to 7% was converted to cyanate and the remainder to unidentified products.

Jan 1, 1992

By Elaine Ellingham, Francis T. Manns

"The Orostar and Scadding were two small gold mines owned and operated by Orofino Resources Limited. Conventional statistical treatment indicates an identical arithmetic mean grade of 0.22 oz/T Au for both mineable reserves. Further, the deposits are both shown to have cut weighted average reserve grade of 0.21 oz/T. Orostar mined out at 0.206 oz/T and Scadding at 0.156 oz/T Au. The combined exploration and development database contained 1394 fire assays, more than enough for statistical confidence in a normal distribution. Therefore this study was initiated to determine, if possible, why the mill head grades were lower than the averages and to experiment with several methods to determine whether a reliable statistical mill head grade estimation method would emerge. Despite the identical reserve grades, distinct differences in the grade distribution histograms are present. By studying the arithmetic and log-normal grade distributions, with some attention to South African practices, this paper reports on those differences which may account for the considerable divergence in the mill head grades. Furthermore, this study casts considerable doubt on the industry standard method of cut weighted averages.The global mill head grades of the two deposits have been derived from the arithmetic average grades by graphic means. This precise method of mill head grade prediction, if applied to complex orebodies, could permit selective grade control and result in direct cost savings by allowing the operator to detect false value stopes, benches or levels and emphasize reliable regions of not only gold mines, but also uranium or base metal deposits."

Jan 1, 1992

By B. Jena, M. Rigaud, S. C. Panigrahy

"The influence of flux addition on the structure and properties of pellets produced from low silica specularite with peat moss and bentonite as binders was investigated. Specific pellets basicities in the range of 0.4 to 3.2 were obtained by the addition of limestone or a combination of dolomite and limestone as flux. A t basicities < 1.6, the bonding in the pellets was provided by a glassy silicate phase. At basicities =1.6, calcium ferrites were the predominant bonding phase. When dolomite was added as a flux, presence of magnesia-ferrite was noted. The reduction behaviour of pellets at different basicities was found to be influenced by the type of flux and binder. The pellet compression strength and swelling characteristics were improved with increased basicity.IntroductionThe properties of iron ore pellets are influenced by the type and nature of the ore or concentrate, additives and their subsequent treatment to produce pellets. The interaction between various constituents of the concentrate and additives, i.e. iron oxides, gangue and fluxes etc. result in the formation of various mineralogical phases which affect the degree and nature of bonding achieved in the pellet and the structure and distribution of pores. The pellet properties such as pellet strength and reducibility are influenced by the extent and type of bonding achieved between the ore particles. In view of the present emphasis on the production of high quality pellets to meet progressively stringent quality control requirements, it is essential to investigate the effect of additives on the bonding mechanism and properties of the pellets.In the past, the effects of additives on the bonding mechanism of pellets have been investigated. It is important to note that the conditions and parameters to be controlled are typical of a given concentrate/ore. In this paper, the results of the investigation on characterization of fluxed pellets produced from a low silica specularite concentrate are reported.This investigation was also aimed at assessing the suitability of peat moss for use as a binder for the production of low silica fluxed pellets. Peat moss is abundantly available in the vicinity of iron ore mines in Quebec and encouraging results have been obtained du ring the production of high silica acid and fluxed pellets."

Jan 1, 1992

By Veena Sahajwalla

The cupola furnace is a coke-fueled shaft furnace used as a primary melting unit in iron foundries. Control of chemical composition of the iron tapped from the cupola is a key factor in productivity and quality control. In an effort to develop a control model for the cupola, a fundamental approach based on physical and chemical principles has been taken to describe the melting process. The behavior of oxidation of the solid charge in the stack of the cupola has been studied. Sulfidation of the charge materials by sulfur-bearing components released to the furnace gases from the coke has been described. Carburization of metal droplets of iron and of steel in separate molten streams has been characterized. Finally, reactions with alloying elements in the hearth (well) of the furnace have been defined. These reactions have been described in a computer-implemented model developed to predict the composition of the iron tapped from the cupola. The model has utilized the thermodynamics and kinetics of the oxidation, sulfidation, and carburization reactions, including temperature and physical aspects, in the various zones of the melting unit. The model predictions have been compared favorably with operating results.

Jan 1, 1992

By W. M. Ma, Daniel W. H. Su, K. Centofanti, Yi Luo, W. L. Zhong, Syd S. Peng

3.1 INTRODUCTION The final subsidence basin discussed so far is that developed long after mining has stopped. In a supercritical final subsidence basin, the central portion subsides uniformly. Thus any structures located there are not subjected to any final permanent surface deformation. But this statement is only true for the final subsidence basin. When the face is moving, the structures are subjected to dynamic deformations associated with the dynamic subsidence basin. For instance the house in front of a moving face (location 1 in Fig. 3.1) is subjected to the maximum tensile strain and the maximum positive curvahue. When it falls behind the face in location 2, it is subjected to the maximum compressive strain and the maximum negative curvature. When the house is far behind the face in location 3, it returns to its original condition with only uniform subsidence. However, the magnitude of the dynamic deformations may be sufficiently large to damage a structure in locations 1 and 2 before it reaches location 3. Therefore it is very important to study the characteristics of the dynamic subsidence basin. Under normal conditions, when the face has advanced for a distance approximately one-sixth to one-third of the seam depth from the setup entry, depending on the seam depth and the physical properties of the overburden strata, the movement of the over- burden strata reaches the surface, whereupon the surface also be- gins to deform. Thereafter, the surface point where the movement initiates is always located at a fixed distance ahead of the face. The angle between the vertical line at the faceline and the line connecting the movement initiation point on the surface and the face- line is the angle of advance influence, w. The angle of advance influence can be used to determine the distance, [ 1], which is the influence zone ahead of the face. w is approximately 20O to 35 O for the northern Appalachian coalfield (Peng and Geng, 1984). The movement of each surface point is a relatively complicated process both in time and in space, because the relative position between the faceline and each surface point varies continuously, so that the direction and rate of movement for each surface point differ. In the following sections, the movements of each surface point on the major cross section are illustrated. 3.2 DYNAMIC SURFACE MOVEMENTS Dynamic surface movements include dynamic subsidence and displacement. The movement of each point on the subsidence basin is different as the face advances from 1 to 6 (Fig. 3.2). Surface points A and B, being far in front of the moving face, subside and displace toward the face (i.e., from A to A&apos; and from B to B&apos;). Point C, which is quite near but in front of the moving face, subsides continuously but displaces initially toward the face and then turns to pure subsidence ending up at C&apos;. Point D, which is behind the face above the gob, subsides continuously, but displaces initially toward the face when it is in front of the face and reverses to follow the moving face when it is behind the face, with the amount of displacement toward the face being larger than that following the face. As a result the net displacement is toward the center of the gob (i.e., from point D to D&apos;). The same statement is true for point E. For point F, the net displacement is zero, i.e it appears to have dropped down vertically to F&apos;. For points G to I, the net displacements are in the direction of face advance except the magnitudes are increasing in sequential order. Point 1, has reached the final dynamic position of 1&apos;. In other words, the face has passed sufficiently away such that it does not affect the movement at point I. All other points (A to H) are still within the face influenced area. 3.3 DEVELOPMENT OF DYNAMIC SUBSIDENCE PROFILES When the face has moved for a distance of h/6-h/3 from the setup entry, surface subsidence reaches the surface. At this time the surface subsidence basin is very mild (S, in Fig. 3.3), and it is symmetrical about the center. As the face continues to advance, the maximum subsidence continues to increase, and its location moves with, but falls farther behind the face. When the face has advanced a sufficient distance, e.g., (0.9-2.2)h, away from the setup entry, the maximum subsidence reaches the maximum possible value (curve S,). At this time, the dynamic subsidence profile is fully developed. Thereafter both sides of the dynamic subsidence profile become stabilized. The subsidence profile on the face side moves with the advancing face in an orderly manner (curves S, and S,). When the face stops, the face side of the profile continues to subside and becomes stabilized (curves;) sometime after. Curve S; is the final subsidence profile (see Fig. 2.22). 3.4 DEVELOPMENT OF DYNAMIC DISPLACEMENT AND SLOPE PROFILES The dynamic displacement profile moves with the advancing face (Fig. 3.4), but changes according to some specific rules. When the face has advanced to A, the surface begins to move and its dynamic displacement profile has two maximum values (curve Ua): one positive near the setup entry moving toward the face advancing direction and the other negative on the face side also moving toward the face advancing direction. As the face continues to advance, the positive maximum displacement on the setup entry side increases and moves toward the face continuously. The same statement is true for the negative maximum displacement on the face side. When the opening increases to the critical size, both the maximum positive and negative displacements reach the peak values and remain constant thereafter. Notice that when the opening becomes critical in size, the point of zero displacement no longer moves with the advancing face. Rather it spreads into an area of zero displacement (curve Ue) and expands as the face advances. When the face stops, the displacement on the face side continues until it becomes stabilized (curve Úe). Curve Úe is the final displacement profile. The ratio of maximum dynamic to final displacement ranges from 60 to 75%. The dynamic slope profile follows the same patterns of change. The ratio of maximum dynamic to maximum final slope ranges from 50 to 80%. The maximum slope decreases with in- creasing rate of face advance (Peng and Geng, 1984). It must be pointed out that except for those near both sides of the profiles, each point on the displacement and slope profiles is subjected to a cycle of positive and negative displacements and slopes depending on its relative position with respect to the face.

Jan 1, 1992

Highwall mining commenced in the Appalachian region 50 years ago. With innovative equipment design introduced in more recent times, penetration distances over 300 m are now commonplace. It is only in the last three years that highwall mining has become part of the Australian coal industry. Geotechnical evaluation is an integral part of the Australian procedures, and although still being refined, has already proven its worth. Statutory guidelines have also been prepared for operations in Queensland. This paper explores trends in equipment design, geotechnical prediction, operating techniques and statutory requirements with regard to highwall mining Australia&apos;s coal deposits. A quick assessment guide to assist in the evaluation of potential sites is included.

Jan 1, 1992

By R. L. Nyirenda

One of the problems with ammoniacal-ammonium carbonate leaching of EAF carbon steelmaking flue dust is that zinc present in spinel phases is not leached. This paper presents results of test work in which prior to leaching, EAF dust was reduced with CO containing gas to decompose the spinels into zinc oxide and iron bearing phases, mainly metallic iron and wustite. From such reduction products, the amount of zinc leached increases but the iron co-leached becomes extensive. The effect of various leaching parameters such as liquor concentration and redox potential on zinc and iron dissolution has been investigated. Supplementary experiments utilizing pure zinc oxide and pure iron phases were also carried out. Results show that the co-dissolution of iron from severely reduced EAF dust cannot be prevented. This is because the wustite phase contains zinc which can only be leached when iron also dissolves. Further, the zinc bearing wustite phase is not totally soluble so that the residue cannot be made zinc free. In the absence of air, dissolution of metallic iron hardly occurred, though in leaching experiments of a long duration its transformation to a spinel structure was observed.

Jan 1, 1992

By Arthur J. Hudson, Lawrence W. Scott

The performance of RETIMET metal foam as a flame arrester on explosion-proof enclosures was investigated by the U.S. Bureau of Mines both in laboratory tests and at the U.S. Mine Safety and Health Administration&apos;s (MSHA&apos;s) Approval and Certification Center, Triadelphia, WV. The objective of this research was to develop a permissible pressure vent for use on lightweight, vented, explosion- proof enclosures. In laboratory tests, four grades of RETIMET, a stainless steel foam material, were evaluated: (1) 45 NC-7, (2) 45 NC-13, (3) 80 NC-7, and (4) 80 NC-13. Explosive gas mixtures were prepared by a dynamic flow system. Ignition was by a low-voltage arc. Each grade of RETIMET metal foam successfully arrested the flame front in all methane-air tests. To evaluate RETIMET metal foam on large, commercial size enclosures, a multicompartmented enclosure was designed and tested in MSHA&apos;s explosion gallery in Triadelphia, WV. Extensive explosion testing revealed that a minimum vent-area-to-enclosure-volume ratio of 11.33 in2/ft3 is required to keep internal pressure rises below 3 psig. The RETIMET metal foam functioned satisfactorily in all tests as evidenced by the absence of external ignitions.

Jan 1, 1992

By D. E. Healy

In 1989, an autogenous grinding task force was formed to study potential autogenous grinding circuits to replace the existing semi-autogenous grinding (SAG) at the National Steel Pellet Plant in Keewatin, MN. Pilot plant test work, performed by the Hanna Research Center (HRC), indicated that fully autogenous grinding with pebble extraction and crushing could be incorporated into the existing circuits. In 1990, one of the existing 10 grinding mills was converted for an in-plant test incorporating pebble crushing. Full-scale test work were conducted in 1990 and 1991. They verified the pilot plant projections with primary mill throughputs from the fully autogenous circuit using pebble crushing being greater than throughput of the existing SAG mill circuits. The plant produces 5 Mt/a (4.9 million ltpy) of iron ore pellets from 17.6 Mt (17.3 million It) of crude taconite. Crude ore is single-stage crushed by gyratory crushers. Primary grinding is performed by 10 semi-autogenous wet grinding mills. Secondary grinding is performed by five ball mills. Induration is with an Allis Chalmers grate-kiln pelletizing system. The primary grinding circuit consists of 108.2-m-diam x 5.5-m long (27 ft-diam x 18-ft) SAG mills. The mills are charged with 127 mm-diam (5 in.diam) steel grinding balls at from 3% to 5% by volume. Ball consumption rate is about 0.55 kg/t (1.25 lbs/lt) of crude ore feed to the mill. Each SAG mill is powered by two 2.6 MW (3500 hp) motors drawing 5450 kW (7300 hp) at 76% of critical speed. The mills are grate discharge with 16 mm (0.6 in.) slotted grate openings when new. The mill discharge is sized on a trommel screen having 4.5 mm (0.2 in.) openings. The plus 4.5 mm (+0.2 in.) oversize material is returned to the discharge end of the mill by a reverse screw auger located in the center of the trommel. The -4.5 mm (-0.2 in.) trommel screen undersize is pumped to magnetic cobbers.

Jan 1, 1992

By Y. Maeda

Non-ferrous smelting furnaces generally install a gas cooling system for treatment of waste gas containing SO2,. From the point of view of corrosion resistance and recovery of waste heat, the high pressure boiler system is the best way to cool gas, however this system requires high initial investment and relatively higher operating costs. Because the feasibility of this boiler system greatly depends on the smelting process and scale, other lower temperature systems, e.g. water-cooled jacket system, are more suitable if the smelting process does not produce enough steam nor generate enough electricity to compensate operating cost. In additton, the water-cooled jacket system is simple in structure and easy to operate. For those reasons, it is applied widely. A new smelting furnace was planned in our factory and it was necessary to install waste gas cooling equipment. In our case, a water-cooled jacket system was more feasible because of the low gas volume and high dust content. It was also expected to operate without maintenance for ten years. On the other hand, some leakage problems with the water-cooled jacket had been experienced in the past. That is because SO2 In the waste gas changed into sulfuric acid which corroded the jacket material. As the first step, several data from actual&apos; usage were reviewed to throw light on the corrosion process, and an appropriate procedure to determine the operating temperature of cooling water was obtained. For the basis of this study, a water-cooled jacket system was newly designed and tested for three months in a pilot plant. After this system&apos;s performance was confirmed, it was installed in a new furnace as a commercial plant. After one year of operation, the initial thickness of carbon steel jacket remains almost the same.

Jan 1, 1992

By Chris M. Healey

"Perhaps the single most significant variable in the evaluation of a mining project is the reserve estimate. Many parameters are considered when estimating reserves, among them geology. This paper examines the link between the quality of a reserve estimate and a good understanding of the geological controls for the deposit. A clear understanding of the geometry is essential to the accurate definition of the shape and size of the deposit. This includes the definition of any structural controls as well as the proper interpretation of the stratigraphy. Further when the distribution of grades is erratic and there is consequently a high nugget effect, there are significant problems in estimating the true grade of the deposit.Two Saskatchewan examples are presented, one with good knowledge of the controls and therefore good estimates of reserves, and the other with a poor understanding of the geology and resultant problems in deriving good estimates. In both cases the reserve estimates at various stages in the project development are compared to actual results from underground work. The first example is the Star Lake Mine where just about all the estimates were within 10070 of the actual on both tonnage and grade. The Laurel Lake deposit is discussed to show how problems in interpreting the geological data make reserve estimation very difficult. Laurel Lake has the additional problem of erratic grade distribution."

Jan 1, 1992

The objective in controlled blasting is to reduce overbreak to control the final pit wall slope, shaft, drift ditch, bench, etc. to the final planned excavation limit. The six main types of controlled blasting utilized today are: 1) Line Drilling 2) Cushion Blasting 3 Smooth Wall Blasting 4) Buffer Blasting 5) Presplitting or Preshearing 6) Air Deck Presplitting

Jan 1, 1992

By Nicholas Kyriazi, John P. Shubilla

A joint effort by the U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) was undertaken to determine how well self-contained self-rescuers (SCSR&apos;s), deployed in accordance with Federal regulations (30 CFR 75.1714), survived the underground environment with regard to both impact damage and aging. This report presents findings regarding laboratory-tested SCSR&apos;s from 1982 through 1990. The SCSR&apos;s were tested on human subjects and on a breathing and metabolic simulator (BMS). These results indicate that most of the apparatus, if they pass their inspection criteria, perform as expected except for units with manufacturing defects or design deficiencies. However, when the apparatus are carried in and out of the mine daily and stored at the working section, they may suffer abuse. Physical signs of abuse, unless extremely obvious, are frequently not detected by the miners or mine operators. This poses a potential danger to a user in an emergency. Recommendations include improved training in inspection procedures.

Jan 1, 1992

By LeJuge G. E, McKenzie C. K

Innovative mining and blasting techniques were demanded at the Richmont Mines, Francoeur Mine in Quebec, Canada, by a narrow, shallowly dipping high grade gold ore body. The ore body being mined occurs as a thin tabular deposit varying in thickness between 1.5 and 3.7 metres, and dipping at 36¦. The mine proposed experimenting with open stoping techniques using small diameter drill-holes. The hangingwall required progressive, full face rockbolting after each production blast, utilising a specially manufactured machine which provided access to the hangingwall for both scaling and bolting. Blasted material is mucked from the stope by scraper and hoisted directly to surface without benefit of primary crushing.

Jan 1, 1992

By Kim Lapakko

As part of a project funded by the US EPA, through the Western Governors&apos; Association, the recent literature on the prediction of acid drainage from metal mine wastes was reviewed. Static tests such as Acid Base Accounting, Modified Acid Base Accounting, B. C. Research Initial Test, and APP:S Test attempt to quantify the total capacities for a mine waste to produce and consume acid. In kinetic tests (e.g. humidity cells, soxhlet extraction, elevated temperature oxidation, column tests, batch reactor tests, B. C. Research Confirmation Test) mine waste samples are subjected to oxidation and the resultant drainage pH is assumed to reflect that of mine wastes dissolving in the field. This paper summarizes information presented in the recent literature on static tests.

Jan 1, 1992

By Tyler DB, Thin LGT

Coal mass strength properties must be estimated to obtain realistic estimates of coal pillar strength. The limitations of existing techniques for approximating these properties are discussed. The coal mass is anisotropic. The Hoek and Brown approach to rock mass property estimation is modified to allow for this. This approach requires the Rock Mass Rating (RMR) for the strata. In the normal case where bedding is sub-horizontal, these major planes of weakness have little effect on the strength of pillars. As a result of this the RMR must be measured parallel to bedding. This means that a significantly higher rating than that usually obtained for coal is observed. The use of mass strength property estimates in extant empirical relationships is outlined. At high width to height ratios, an acceleration in the rate of increase in pillar strength with increasing width to height ratio has been observed. The empirical relationship developed by Salamon (the so called squat pillar formula) takes account of this. This relationship was found to have significant limitations with respect to its universal application. Modifications are made to Bieniawski&apos;s empirical formula to extend its use to large width to height ratio (squat) pillars. This new squat pillar formula has none of the disadvantages associated with Salamon&apos;s relationship. Strain softening was incorporated into non-linear finite difference numerical modelling to estimate pillar strengths. The technique outlined above is used to obtain peak coal mass properties. Modelled pillar strength was found to be sensitive to both peak and post peak mass strength properties. Post peak properties were found to be difficult to obtain and required some back analysis. Modelling results were used to estimate both the strength of squat pillars and parameters for use in a new squat pillar empirical strength relationship.

Jan 1, 1992

By Mostyn G. R

An important problem in rock engineering is to control the properties of artificial rock. A compaction technique for casting artificial rock specimens with controlled properties is described, i.e. using a compression-testing machine to compress the mixture. Uniform density is necessary to achieve uniformity of properties of the specimens, and uniform density can be obtained by using the specific pressing method presented. Rebound and borax content are important to the technique and have been studied as well.

Jan 1, 1992

Through 1986, Kentucky was the nation&apos;s largest coal producer. Currently it ranks third in production, behind Wyoming and West Virginia. Because of the size and variety of Kentucky&apos;s coal industry, virtually every kind of surface coal mining and reclamation activity takes place in the state. Extensive coal deposits occur in two separate areas: the eastern coal field, which is part of the Appalachian coal field, and the western coal field. Kentucky&apos;s reserves are estimated at 65 billion tons, with 27 billion tons in eastern Kentucky and 38 billion tons in western Kentucky. Kentucky coal is high in volatile matter, low in sulfur and ash, and relatively high in heating value. Coal from Kentucky&apos;s eastern coal fields contains a sulfur content of less than 1 percent. Conditional primacy was granted to Kentucky May 18,1982. Since then, all conditions have been removed; final regulatory approval was granted on May 30,1985. The Abandoned Mine Land Program was approved with the regulatory program May 18, 1982.

Jan 1, 1992

By Harris RW, Wood BR

At any given time, the tidal force subjects massive regions to a spatially uniform load. The deformation of any large structure due to these forces is proportional to the elastic properties of the structure. In this aspect, the tidal force applies a load in a manner similar to that of a large-scale testing machine. Any anomalies in the measured tidal response must reflect alterations in the average elastic response of the massive structure. In the present work, tidal tilt measurements obtained in the wall of a large dam are used to infer changes in the response of the dam to applied loads. In particular, it is found that the dam response has changed by approximately 13 percent, on average, for two monitoring periods separated by 5 years. It is possible that these changes were produced by the different volumes of water in the dam for the monitoring periods. The tidal measurement technique can also be applied to monitor changes In the average structural response of large underground and surface masses relevant to coal and metal mines.

Jan 1, 1992