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By Peng SS

This paper presents a number of mathematical models for predicting the different phases of the complete surface subsidence process associated with underground longwall mining. A computer program developed based on the mathematical models is briefly introduced.

Jan 1, 1992

By N. Agron-Olshina

The application of the QEM*SEM image acquisition and analysis system to the measurement of the mineral matter in coal and the materials in fly ash is described. A new sample mounting technique was developed using iodinated epoxy to provide a backscattered electron contrast between the coal, the mounting medium and the mineral matter. Several comprehensive and detailed species identification programs for silicate minerals and materials were developed to analyse the 1000 count x-ray spectra used for the measurements. Case studies are presented to demonstrate the capabilities of the new technique to distinguish different coals and fly ashes by their mineral and material composition rather than by conventional chemical analysis. Applications of the new technique are aimed at demonstrating that composition and size distributions obtained from OEM*SEM measurements can be used: 1. to characterize coal with respect to combustion problems in power stations, 2. to characterize coal for fine coal cleaning, 3. to characterize fly ashes in relation to problems such as erosion in combustion systems and the ease of precipitability in dust collection facilities, 4. to refine the classification systems used in marketing coal for pulverized fuel firing and fly ashes as a component of cement and building materials.

Jan 1, 1992

By C. J. Lewis

This presentation concerns calcium oxide-better known as high calcium quick lime High calcium quicklime is produced by calcining high calcium limestone, mostly in the many rotary kilns located throughout the United States and Canada. This paper presents suggestions on the handling of lime based on field experience. The subjects covered are chemical analyses, transporta¬tion, lime storage, lime slaking to form a water slurry of calcium hydroxide solids, slurry transportation, slurry viscosity, and scaling of lime slurries. It is hoped that the comments on the foregoing areas will be of use to those designing or operating lime systems.

Jan 1, 1992

By Philip E. J. Green

Two of the cornerstones of total quality management, the use of statistical and problem solving tools, and the involvement of employees, are directly applicable to environmental protection. The reduction in variation decreases the chances of violations and mishaps. Involving employees in minimizing environmental impacts is critical. One mistake, even with the best technology, and your plant can be shut down, customers lost and fines and penalties imposed - your reputation and the environment damaged. Proven strategies for involving employees in environmental protection, and over-coming the frequently strong differences of opinions about what constitutes environmental protection, will be discussed.

Jan 1, 1992

By Steve R. McCutcheon, Cees R. Van Staal, John P. Langton, Leslie R. Fyffe

The volcanic-dominated Tetagouche Group in northern New Brunswick contains numerous massive-sulfide deposits and intimately associated metalliferous sediments. The massive sulfides are generally hosted by Llanvirnian-Llandeilian volcaniclastic sedimentary rocks of the Nepisiguit Falls, Patrick Brook, and Boucher Brook formations. These formations are intercalated or closely associated with rhyolitic-dacitic flows and/or domes, and minor continental tholeiites of the Flat Landing Brook Formation. Pyroclastic rocks are relatively scarce in the silicic volcanic complex. Tuffites and epiclastic sandstones, of the Nepisiguit Falls and Patrick Brook formations, respectively, generally occur along the fringes of the silicic volcanic complex. The flows and tuffites are intruded by quartz- and feldspar-phyric rhyolite (porphyry) dykes, sills, and domes. Although the volume of the silicic volcanic complex is large, evidence for a previously proposed collapsed-caldera model is lacking. On the basis of host-rock type and stratigraphic position, the sediment-hosted massive sulfides have been divided into three groups: the Brunswick-, Caribou- and Halfmile Lake-type deposits. Syngenetic feeder pipes and asociated alteration zones are generally not present beneath the Caribou- and the Halfmile Lake-type deposits and, if present at all, are poorly developed underneath the Brunswick-type.

Jan 1, 1992

By R. A. Metz, William H. Breeding

The remarks that follow are based substantially on experience covering 45 years, 80% of which has been in placer work, rather than on a review of available literature. Most commercial placers have been deposited by the action of water. The richer and more difficult-to-mine placers are those in the headwater areas where gradients are steepest. The most lucrative placers are generally in intermediate areas where volumes are greater, fewer boulders are present, and gradients are from 3% to 1-1/2%. The higher volume, lower grade placers are in the lower reaches of river systems where gradients are lower. Where gold-bearing rivers have discharged into the sea, wave action can concentrate values on beaches, past and present. Most of the rich, readily accessible placers were mined by our forefathers. Current opportunities exist: (1) in remote areas where infrastructure has been absent in the past, or development has been prohibited by adverse ownership - political or commercial; (2) in deposits that could not be mined by equipment available to our forefathers; (3) in deposits unidentified by our forefathers; (4) where the-price-of-product/cost ratio is substantially better than in earlier years; or (5) a combination of those factors. When I entered the placer business in the late 1930s, and subsequently, a prevailing opinion believed that glacial deposits should be avoided as irregular in mineral content and composition, and unrewarding to explore and develop; yet an operator has been mining a fluvio-glacial deposit profitably for the past 17 years. Rich buried placer channels, often called paleo-channels were worked in the last century, generally by hand methods, and under conditions that would be unacceptable today. Exploration and mining equipment now available make some of these channels attractive targets. Well-known examples are in California and Australia. The formation of a commercial placer requires a source of valuable minerals. Above primary deposits, there may be eluvial deposits formed by the erosion of gangue minerals and the concentration "in situ" of valuable minerals. Down slope from these deposits are the hillside or colluvial deposits, and below them are the alluvial deposits of redeposited material. Most of the great placer fields of the world are the result of several generations of erosion and deposition. Well-known examples are in California and Colombia. Gold is a very resistant and malleable material, and gold placers may extend for 64 or 80 km (40 or 50 miles) along a river system. Platinum is less malleable, but is very resistant to disintegration. Diamonds are extremely hard, and (especially gem diamonds) may be found over great lengths of a river system. Cassiterite is less resistant to disintegration, and tin placers seldom extend over two miles without resupply from an additional source or sources of mineralizaton. Tungsten minerals are generally more friable, and within a few hundred yards of the source disintegrate to the point that they are uneconomical to recover. Rutile, ilmenite and zircon placers generally result from the weathering of massive deposits, and may be encountered over extensive areas; most are fine grained and durable. What does a geologist or mining engineer look for in placer exploration? The old adage to look for a mine near an existing mine is still valid. You need a source of valuable mineral. Then you require conditions for concentration, which means a satisfactory gradient and/or other conditions that will permit heavy minerals to settle. Nicely riffled gravel, often called a shingling of the bars, is conducive to placer formation. Coarser gravel is logically associated with coarser gold. Excessive clay and/or high stream velocities in narrow channels can carry gold far downstream and distribute it uncommercially over a large area. When material is extremely fine, in situ weathering and concentration become more important. Placers frequently occur distant from lode mines, and one must remember that in a larger watershed the exceptional floods that occur once in a hundred or a thousand years can move great quantities of material long distances. The carrying power of water is said to vary with the fifth or sixth power of its velocity. I am not ready to disagree with Waldemar Lindgren and accept that many commercial placers are substantially enriched by the chemical deposition of gold from solutions; however, I have seen crystalline gold in clayey material quite distant from known sources of primary gold that is dif-

Jan 1, 1992

By T. Schmidt, J. Merza

"This study considers two lead/zinc/silver orebodies which have historically had a problem with pyrite, pyrrhotite and sphalerite contamination in the lead circuit. The problem was previously addressed with high dosages of sodium cyanide as the primary depressant. However, large amounts of cyanide led to environmental problems in the effluent, especially during winter months. The objective was to reduce cyanide consumption while maintaining or improving overall lead grade and recovery via the reduction of the undesirable sulphides.Extensive laboratory and mill testing was necessary to determine the optimal operating parameters for continuous plant application. Evaluation of data received from this testing has shown that selective addition and optimization of the dosage of Unimax SD100 to specific areas of the flotation and grinding circuits has resulted in improved Pb grade and recovery. Parameters such as pH control, regrind operation, the cyanide/Unimax ratio and sulphide mineral content may also affect the performance of the depressant. Each factor is discussed and optimal operating conditions were determined based on the testing.Results are presented for two case studies. Both indicate that Unimax SD100 improves the lead grade/recovery curve by increasing iron and zinc rejection while reducing cyanide consumption and the resulting environmental concerns. 1. Hart"

Jan 1, 1992

By Fernando Castro

Electric furnace steelmaking dust is a polluting residue that needs to be treated in order to recover metals contained and to produce an environmentally acceptable residue. Some hydrometallurgical approaches for its treatment have been evaluated, namely: caustic soda leaching followed by electrolytic recovery of zinc, ammonia leaching followed by zinc compounds precipitation and acetic acid leaching followed by lead, zinc hydroxide and gypsum precipitation.

Jan 1, 1992

By Aylmore M. G

Samples have been taken from a two-stage industrial gold roaster treating a pyrite/pyrrhotite/arsenopyrite concentrate, in order to describe the mineralogy, composition and surface area of the calcines. Sulphides oxidised to produce a porous magnetite in the first stage and a porous hematite in the second; pyrite predominantly roasted via a pyrrhotite intermediate. Sulphur was eliminated in both the first and second stages whereas arsenic was eliminated in the first but retained in the second, partly as rims on hematite particles. The finer sized particles from the cyclones and electrostatic precipitator, while having the greatest surface area, were the most refractory with respect to gold solubilisation, probably as a result of incomplete decomposition (through short-circuiting) in the first stage, and through a combination of factors such as overheating and entrapment of sub-microscopic gold in the second stage.

Jan 1, 1992

While coal occurs beneath about 18 percent of Utah, only 4 percent of the state has minable reserves. Utah's coal fields are mostly bituminous. Current coal production in Utah is largely by underground mining, making Utah unique among the coal-producing states. Most coal seams are more than 8 feet thick. Utah's coal resources are about 6.3 billion tons, 1.3 percent of the national reserve. Most of Utah's coal resources are held by the Federal Government and Indian tribes and are mined under lease. The climate of the Utah coal region is characterized by hot, dry summers and cold, relatively moist winters. Normal precipition varies from 6 inches in the lower valleys to more than 40 inches on some high plateaus. The growing season ranges from 5 months in some valleys to less than 3 months in mountainous regions. These extreme climatic conditions make reclamation difficult. Utah gained primacy when its regulatory program was conditionally approved January 21, 1981. Full program approval was obtained March 7, 1983. The Abandoned Mine Land Program was approved June 3,1983. A Federal Lands Cooperative Agreement was signed in March 1987; Utah performs all enforcement activities and some permitting activities on federal lands.

Jan 1, 1992

By B. J. Beaudry

The preparation of alloys containing one to two percent of the volatile lanthanide metals Sm, Eu, Tm and Yb in the high melting point (HMP) rare earth metals Sc, Y and Lu was accomplished by a vapor deposition, diffusion method without crucible contamination. The method avoids the melting of the HMP metals which would introduce impurities from the crucible, generally Ta or W. Plates of the HMP metals were hung from the lid in the upper part of the Ta crucible. The volatile metals were placed on the bottom and the lid welded in place under an atmosphere of helium. By proper selection of thee alloying temperature, the effusion of the metal vapors, through the helium atmosphere was slow enough to permit diffusion to occur and prevent refluxing of the newly formed alloy. Very volatile metals such as Mg required a Knudsen cell with a suitably sized hole to prevent too rapid transfer of the low melting metal. Electron microprobe analysis of a cross-section of the HMP metals showed a homogeneous distribution of the volatile metals. The time and temperature required to obtain a homogeneous rare earth alloy without contamination are given. The use of a Knudsen cell to form magnesium-rare earth alloys is reviewed.

Jan 1, 1992

By J. S. Kirkaldy

A theoretical procedure is demonstrated for calculating two-dimensional binary cellular single-valued interfaces and extended to triple-valued (remelt) shapes. The numerical calculations for the single-valued local equilibrium problem which yield unique shapes as functions of the supersaturation parameter a and the partition coefficient k are reviewed. The cell amplitude L and wavelength A scale identically as the inverse velocity to the 112 power and the aspect ratio r is a constant equal to 312, independently of a and k for a < 0.5.. For 0.5 < a < m, L, A and r decrease asymptotically to zero indicating the finite amplitude nature of the instability at a = 1 and the existence of sub-marginal states which converge to a flat interface at a- m (Glv- m). Scaling comparisons between equilibrium single-valued and triple-valued and deep-rooted non- equilibrium cells are made.

Jan 1, 1992

By K. A. Foo

Minproc Resources Inc. is developing a tailings retreatment project in Bolivia at the Colquiri zinc-tin-silver mine, in the Bolivian Andes. Mining at Colquiri has been continuous since 1940 and COMIBOL, the Bolivian state mining company, has owned and operated the underground mine since 1964. There are 10 million tonnes of tailings at Colquiri containing 0.51% Sn, 4.21% Zn and 50 g/t Ag. Minproc plans to mine and concentrate the tailings at 1.15 million tonnes per year to produce feed for pyrometallurgical upgrading. The tailings are moderately complex, with cassiterite grain size ranging from 200 to 5 pm. The marmatite (ZnFeS) in the tailings is relatively easily recovered, with zinc recovery of 80% to a 40%-45% Zn concentrate. The major problem with the zinc metallurgy is that the marmatite is complexed with iron, which results in iron contents of 14%-17% Fe in concentrate. This makes the product very difficult to sell because of the low Zn:Fe ratio. Most zinc smelters require a Zn:Fe ratio of 6:1 or 7:1, whereas this concentrate has a 3:1 ratio. Concentrate sale terms are therefore unfavorable, and the high cost of transportation from Bolivia to the smelters is an additional burden.

Jan 1, 1992

Plenary SpeechI have given considerable thought about what I might say to such a group of professionals, given that I am not an extractive metallurgist. It was immediately apparent that I would quickly be out of my depth if I tried to present some technical aspect of extractive metallurgy. So, instead I thought it might be useful to review the subject from the minerals business management point of view in order to improve understanding for the extractive metallurgist who some times finds it difficult to comprehend directions being given by management.

Jan 1, 1992

By Kenneth N. Han, Jianshe Liu

Various techniques used in the removal of metal ions from effluent streams have been reviewed. These techniques include recovery of metals by biological treatment, chelating agents, adsorption, ion- exchange and chemical precipitation. The main thrust of this paper however, is concerned with the removal of cadmium and zinc ions from the solution by adsorption utilizing liquid fluidized beds. The bed particles used were silica of 150x200 mesh. The range of the concentration of these ions studied was 10-3 to 10-5 M. Important variables examined included flow rate, concentration of metal ions and amount of bed particles. A mathematical model describing the concentration profile of metal ions in the axial direction in liquid fluidized beds has been developed. The equation of continuity was solved numerically and the results were used to predict the recovery of metal ions in fluidized beds.

Jan 1, 1992

By Dunlop G. A, Cantrell R. A

The metallurgical and engineering requirements that form the basis for planning column flotation Pilot Plant testwork are reviewed. Pilot plant operating issues are discussed and a basis for the testwork program formulated. The application of the testwork results to engineering design and scale-up is briefly reviewed.

Jan 1, 1992

By Xaykhamphoune, Ward B

Draglines have been used exclusively for primary overburden stripping at the German Creek Mine complex in central Queensland, where coal has been extracted from a series of ten open cut pits working seams of the German Creek Coal Measures. Due to the dip of the seams, most of the pits have now reached the limit of current economic viability and the emphasis has switched to underground extraction using longwall methods and to a new area of open cut reserves in the nearby Rangal Coal Measures at German Creek East. This area is characterised by weak Tertiary overburden, relatively steep dips and low strength intraformational shear planes at the top and bottom of the coal.The first pit, with a maximum depth to coal of 15 m at the low wall, avoided any major slope failure through use of scrapers to excavate the boxcut and dump the spoil away from the low wall. However, this method was not considered economically viable for the second pit where low wall depths reached 44 m. Following geotechnical investigations the boxcut was divided into a number of zones depending on depth of cover, dip and thickness of Tertiary clay. Slope stability was assessed for each zone using several analytical techniques to ensure that dragline mining would be acceptable. Slope design parameters incorporating various stabilisation techniques, notably an updip trench backfilled with competent spoil to form a low wall buttress prior to excavation of the boxcut panel, were successfully integrated into the mine plan after careful consideration of the complex scheduling to minimise rehandle.

Jan 1, 1992

By J. C. Monette

Stripping of gold and silver from carbon is effected by means of two main processes (AARL and ZADRA ). The main rate-enhancing parameter in the stripping of gold and silver is temperature. A secondary rate-enhancing parameter is ionic strength. (1) Stripping is usually conducted within a solution containing sodium cyanide (0.1 -0.5% ) and caustic ( 1 -3%). The development of a chemistry that increases the rate of gold and silver stripping from carbon in a manner proportional to its concentration is described. Its use in atmospheric and pressure strips is also outlined.

Jan 1, 1992

By M. B. McClenaghan, O. P. Lavin, Ian Nichol

"Exploration in most areas of Canada has to contend with problems posed by glacial overburden. In many areas exploration for gold has been based on the sampling of tills, frequently by deep overburden drilling, and analyses of heavy mineral concentrates. Notwithstanding the significant role that till geochemistry has played in the discovery of some important gold deposits over the last few years, increased appreciation of the nature of the glacial history and stratigraphy and the character of gold within till has led to the recognition of a number of ways whereby the effectiveness of exploration can be improved upon.In order for till geochemistry to be useful in exploration, a number of conditions must be fulfilled, including:1. mineralization, or alteration halo related to mineralization, subcropping at the bedrock/overburden interface;2. glacial erosion and dispersal of a recognizable signature of mineralization into the glacial sediments;3. preservation of glacial sediments containing this geochemical component (trace metal or mineral) at positions subsequently selected for sampling (normally drill sites);4. correct identification of specific till units and associated ice movement history;5. collection of adequately large and representative samples;6. appropriate sample preparation and processing;7. appropriate geochemical analyses; and8. correct data processing and interpretation.While we have no control over the first two geological conditions, and only limited control over till availability, we can control the quality and thoroughness of sampling, sample identification, sample preparation, analysis and interpretation. In particular attention needs to be focussed on obtaining a large enough sample to be adequately representative, an unbiased sample must be collected, together with appropriate sample processing, analysis, data processing and interpretation. It is considered that by modifying or extending existing approaches to gold exploration the chances of exploration success can be increased. In particular, analyses of both the heavy mineral and minus 63 µ m fractions of till is recommended because gold in till may occur in different size fractions."

Jan 1, 1992

By P. D. Rao, D. E. Walsh

A pilot-scale study was performed to evaluate the potential for gravity concentration of gold from -13 mm (-1/2 in.) crushed ore from Ester Dome, AK. 9.04 t (9.94 st) of crushed ore were sampled and processed through a Pan-American jig-Wilfley table pilot plant. Plant products were sampled for assay and material balance calculations. Gold recovery through one stage of jigging and two stages of tabling was 17.4% at a concentration ratio of 615:1. Concentrate grade was 766.3 g/t (22.4 oz/st). The feed grade to the plant was calculated at 1.71 g/t (0.05 oz/st). Jig tailings, primary table tailings and secondary table tailings grades were 1.44 g/t (0.042 oz/st), 1.30 g/t (0.038 oz/st), and 5.47 g/t (0.16 oz/st, respectively. Significant coarse, free-milling gold values were shown to remain in the, jig tailings. Concentrate mineralogy is discussed.

Jan 1, 1992