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By Nathan A. Tiner

Sulfuric acid anodizing process is extensively used in many industrial and consumer products to provide corrosion resistance to aluminum alloys. The anodic coatings produced consist of amorphous alhnum oxide with a pornus structure which is easily sealed and colored with dyes. The coatings may contain defects due to surface flaws, canposition and microstructure of the aluminum alloy, and/or due to the anodizing process conditions. This paper will describe the techniques used in anodizing process, various defects which may be produced in anodic coatings and the methods to control them.

Jan 1, 1992

In 1987 Wyoming became the largest coal producing state in the country. The state is known for its extensive coal resources and extremely thick coal seams. Wyoming's coal reserves total about 69.3 billion tons, or 14.2 percent of the U.S. coal reserve. Coal seams range generally from 10 to 80 feet in thickness, although one seam is 220 feet thick. The coal-bearing areas of Wyoming underlie approximately 41 percent of the state's total land area. Wyoming's coal ranges from lignite to high volatile bituminous. Most of the coal produced is subbituminous from the Powder River coal region near Gillette. The presence of coal in Wyoming was discovered before 1834 on the Belle Fourche River. The state's first mine opened in Carbon County in 1865, and with the completion of the trans- continental railroad, the demand for coal increased. Currently approximately 80 percent of Wyoming's coal production is shipped out-of-state to meet the growing demand for low- sulfur coal to fuel electric generating plants. Wyoming received conditional regulatory approval November 26, 1980. Its Abandoned Mine Land Program was approved February 14, 1983.

Jan 1, 1992

By J. J. Moore

Combustion synthesis, or self-propagating high-temperature synthesis (SHS), reaction systems are discussed with respect to thermodynamics and kinetics. In particular, the effect of the process parameters, e.g. particle size, [All] ignition and combustion temperatures, on these self-sustaining reactions is discussed. Combustion theory is used to investigate the effect of the overall actuation energy of the SHS reaction on the combustion front propagation rate and in obtaining a clearer understanding of the transition from stable to unstable propagation. Finally, examples of the application of combustion synthesis to advanced materials processes are made, in particular the synthesis of Ni-Ti-X intermetallic shape memory alloys, TiC-AI2O3 and ZrB2-AI203 ceramic composite materials.

Jan 1, 1992

By Harry M. Edenborn, Richard W. Hammack

Experiments were done to determine if a mushroom compost-based sulfate reduction system could be used to treat nickel-contaminated mine waters. Sulfate reduction systems were established in columns containing acid-washed mushroom compost. Simulated mine waters containing 2000 mg/L sulfate and 50 to 1000 mg/L nickel were adjusted to pH 4.5 and pumped through the columns at flow rates between 15 and 25 mL/hr. During the first nine days of operation, virtually all influent nickel was removed in the columns by sorption and ion exchange mechanisms. The nickel removal rate then dropped to 18 to 30 mg Ni/day (7.8 to 12.8 nmol/ g-substrate/day), probably due to low sulfate reduction rates. When sodium lactate was added to the inflow, a sustained and seven-fold increase in the nickel removal rate was observed. Bacterial sulfate reduction rates measured in mushroom compost-based wetlands exposed to coal mine drainage are 2 to 20 times faster than the rates observed in this study. Low sulfate reduction rates in the columns may have been due to the inhibition of microbial activity by high nickel concentrations and the removal of labile organic compounds from the mushroom compost substrate during acid-washing. Results of this study indicate that bacterial sulfate reduction can effectively treat nickel concentrations up to 500 mg/L if labile carbon is nonlimiting.

Jan 1, 1992

In presenting size analysis data, one has the choice of various graphical techniques; each no doubt has been developed to highlight a particular aspect of the data. A frequency size distribution plot is used quite extensively to illustrate the importance of the finer size particles in iron ore granulation. However, the basis for such a plot is often not appreciated. As a result, cases of incorrect use can be cited. The aim of this paper is to extend the work of Alien (1981) and to provide, using examples and figures, a basic understanding of the implications of the various size distributions. A simplified method of presenting sizing data on a linear scale graph paper is presented and recommended. This involves a simple construction of a histogram of mass fraction versus particle size (in geometric progression).

Jan 1, 1992

By T. D. Murphy

In the fall of 1988 it became evident that the accuracy of sulfur forecasts for Monterey Coal's No.1 Mine needed to be improved. In addition, it became necessary to predict if any individual train shipments during a month would exceed a contract sulfur limit. The challenge was to develop a forecasting process that would take into account the variability of the coal in the ground as well as the difference between laboratory and preparation plant sulfur reduction efficiency, and the effects of mining coal with multiple units. This paper describes how geostatistics and simulation techniques were used to meet this challenge.

Jan 1, 1992

By Deni Côte, Marcel Vallée

"The Guide to the Evaluation of Gold Deposits reviews the successive evaluation steps in the domains of geology, engineering, and economics. The Guide analyzes, in a systemic perspective, the sequence of exploration, development, and evaluation work required to bring a mineral deposit to production. The aim is to identify the metal/mineralization losses and ore dilution that each work step contributes to the evaluation and mining process. The procedure allows one to maximize the income and profits of a mining operation, and to reduce the risks of financial losses tied to investment decisions in the mining sector. For greater efficiency, the criteria of reserve estimation and classification should be integrated with the evaluation steps and methods. At earlier stages of deposit development, when quantitative knowledge is available mainly on the geological axis, the term ""delimited mineral deposit"" should be used. The term ""reserve"" should be used only in an operating mine or in a mining project, when information in the geological, engineering, and economic domains is adequate to ensure technical and financial feasibility. ""Reserves"" are by definition ""mining reserves"". Each category of proven/probable reserves and measured/indicated deposits should be subdivided into two classes to express better the many steps of mineral valuation. The category of ""possible reserves"" shall be replaced by that of ""inferred mineralization"". This system, derived from the Australasian Code, can easily be integrated into current practices of the exploration and mining industry within a short timeframe. The proposal to develop the use of the margins of error of the estimates at a confidence level of90% should be viewed in a longer timeframe. Establishing the precision of the mineral inventories and distinguishing between categories and classes by means of the margin of error will require more work and a longer break-in period.SOMMAIRELe ""Guide d’évaluation des gisements d'or"" analyse, dans une approche systémique, les travaux d'évaluation et de mise en valeur des gisements minéraux dans l'axe de la géologie, dans l'axée l'ingénierie et dans I ‘axe de l'économique. L’objectif est d'identifier la contribution aux pertes de métal et à la dilution du minerai des diverses étapes de l'évaluation et de l'exploitation du gisement. Ceci aid erra à maximiser les revenus et les profits, et ainsi, à réduire les risques départe financière que comportent les décisions d'investissements dans le secteur minier. Pour atteindre ces objectifs, iI est essentiel de relier les critères d'inventorie et de classification des réserves aux méthodes d'évaluation des gisements. Aux stades antérieurs du développement minéral, lorsque les connaissances quantitatives ne s'étendent qu’à l'axe géologique, le terme ""gisement délimite"" sera utilisé. Le terme ""réserve"" ne sera utilisé que dans une mine en exploitation au dans un projet minier, lorsque l'information dans les axes de la géologie, de l'ingénierie et de l'économique sera appropriée pour en garantir la faisabilité technique et économique. Chaque catégories des réserves, prouvée et probable sera subdivisée en deux classes pour mieux qualifier les niveaux d'évaluation du projet. La catégorie actuelle des réserves possibles sera remplacée par celle des ""minéralisations inférées"". Plusieurs essais démontrent que le système propose, qui s'inspire du Code australasien, peut facilement et rapidement s'intégrer dans les pratiques de l'industrie. II pourrait également contribuer à une standardisation des méthodes et des nomenclatures à l'échelle internationale. La proposition d'utiliser les marges d'erreur des estimes au niveau de confiance de90%pour caractériser les estimations se situe dans une plus longue perspective. Cette application demandera des développement méthodologiques additionnels ainsi qu'une période de rodage."

Jan 1, 1992

By M. Brian Maple

A rich variety of phenomena are produced by superconducting-magnetic interactions in rare earth and actinide compounds. These phenomena, and the materials in. which they have been observed, are described in this talk, with an emphasis on the new high superconducting transition temperature (Tc) copper oxides. The Materials The-materials in which these phenomena occur can' be divided into two classes. In the first group, there are two distinct interpenetrating systems of electrons, a set of localized 4f or 5f electrons and a set of itinerant electrons. The localized f electrons carry magnetic moments and interact with the spins and momenta of the the itinerant electrons, which are involved in the superconductivity, via exchange and electromagnetic interactions; respectively. This category includes materials containing rare earth (R) and actinide elements with partially-filled f electron shells which have been inroduced as substitutional impurities [e.g., La1-xCexA12, Th1-xUx] or form a sublattice in compounds [e.g., RRh4B4, RMo6S8, RMo6Se8, the high Tc. superconductors RBa2Cu3O7-d(d - 0.05)]. Materials of the second type are characterized by a single band of electrons that is responsible for both superconductivity and magnetic order. This group includes heavy electron rare earth and actinide compounds [e.g., CeCu2Si2, UBe13, UPt3, URu2Si2], and the high Tc copper oxide superconductors such as the hole-doped systems Lag- MxCuO4 (M = Ca, Sr, Ba, Na) and RBa2Cu3O7-d(0 =d= 1) and the electron-dope system Ln2-xMxCuO4-y (Ln = Pr, Nd, Sm, Eu; M = Ce, Th; x = 0.15; y - 0.02).

Jan 1, 1992

By Peter A. Rona

The Mid-Atlantic Ridge in the central North Atlantic and the Gorda Ridge within the U.S. Exclusive Economic Zone off northern California and southern Oregon are yielding new discoveries of seafloor hydrothermal mineralization. The TAG hydrothermal field in the rift valley of the Mid-Atlantic Ridge near 26 degree N, 45 degree W has been a site of international collaborative research since the discovery there of extensive manganese deposits associated with low temperature hydrothermal activity in 1973 as part of the TAG (Trans-Atlantic Geotraverse Project). The first high-temperature hydrothermal activity, massive sulfide deposits and vent biota discovered in the Atlantic were found at the TAG hydrothermal field in 1985. Collaborative dive series with DSV ALVIN in 1990 and in 1991 with the two Russian MIR submersibles in the TAG field have found and sampled large inactive sulfide mounds in addition to the previously known active sulfide mound. The active sulfide mound on the floor of the rift valley is about 250 m in diameter and 40 m high with a concentric zonation of mineral types and flow regimes decreasing in temperature from 365 degree C black smokers at the center to white smokers and diffuse flow toward the margins. The recent dive series in coordination deep-towed instrument surveys have delineated a zone extending about 5 km along the lower east wall of the rift valley of inactive sulfide mounds up to a kilometer in diameter. MIR Mound in this zone consists of a central sulfide zone about 400 m in diameter and 50 m high surrounded by a halo of low-temperature deposits to 200 m wide. Inactive sulfide chimneys contain the first primary, free gold grains found at a hydrothermal site on a mid-ocean ridge (P.A. Rona, Y.A. Bogdanov, E.G. Gurvich, N.A. Rimski-Korsakov, A.M. Sagalevitch and M. D. Hannington, 199 1 EOS, Transactions, American Geophysical Union, 72:470-471 and Journal of Geophysical Research, submitted).

Jan 1, 1992

By J. A. Herbst

Successful transitions from micro- to macro-engineering are the keys to effective technology transfer between research and development organizations and industrial end users. At the same time, it has proven to be one of the most difficult tasks that the minerals industry has had to manage. Typically, developers of fundamental information concerning how mineral processing subsystems work have been academics and government scientists. These are the individuals giving the most important input to micro-engineering models that can benefit industrial operations. Publication is the usual route for "attempting" to transfer this technology to the end users. Unfortunately, with such publications, very little direct communication occurs concerning real industry needs or the future steps required to make the particular micro-engineering model useful. In the past, the industry has relied on in-house R&D groups and plant metallurgists to "translate" publications, to provide useful macro-engineering tools for plant applications. To some extent, engineering companies have also been asked to serve this function. However, these firms have been rather ineffective in this area since their conservative nature has caused them to look rather suspiciously at new technology. This approach to technology transfer has worked, albeit clumsily, for the last several decades. This communication system is now on the verge of total collapse due to conditions of the minerals industry. Mining companies can no longer afford the significant overhead expenses of specialized technical staffs. Universities are finding it extremely difficult to interest US students in mineral engineering programs, and funding for such programs is weak. Faculty members involved in micro-engineering research today tend to focus on pure (non-application-oriented) research.

Jan 1, 1992

By P. A. Lindberg

Early Proterozoic ore deposits in the Verde district at Jerome, Arizona have produced 33.7 million metric tons of ore (1893-1975). The United Verde and United Verde Extension deposits produced most of the ore that yielded 1,644,323,100 kg Cu plus large amounts of Au, Ag, and Zn. These deposits are situated on the fractured and hydrothermally altered apex of a large submarine rhyolitic extrusive (Cleopatra formation). Precambrian lithologies are penetratively deformed and at Jerome the Fl folds plunge steep to the NNW. For the past two decades the volcanogenic model has superseded the replacement theory of ore formation.

Jan 1, 1992

By R. P. Stahura

In many ways, conveyors are the lifeline of mining and processing operations. Like arteries in the human body, they continuously supply materials to and carry finished products and waste away from vital on-going operations. And like arteries, when the conveyors are running with less than maximum efficiency and productivity, it spells serious trouble for the operation's overall health. Inefficient conveyors suffer carryback, leading to the build-up of materials on idlers and other expensive components. They spill and leak material at loading zones and conveyor transfer points, causing accumulations that can damage the belt, wear moving components, and increase both clean-up labor and maintenance expense. They wander or mistrack, spilling material and endangering personnel and conveyor components including the belt itself. And through these inefficiencies, they multiply the operation's hidden costs. These added expenses are created in lost production, increased downtime for service and maintenance, and the cost of the replacement of prematurely worn equipment. In addition, the attitude that inefficiency is "good enough" is recognized elsewhere in the organization; as a result, other departments relax or operate at less than peak performance. Quality goes down and with it employee morale.

Jan 1, 1992

By J. C. Norman

The boron review arrived too late to appear in the June issue. The United States was the world's second largest producer and the largest consumer of boron compounds during 1991. According to the US Bureau of Mines, boron mineral concentrate and chemical production in the US totaled about 1.1 Mt (1.2 million st), yielding about 608 kt (670,000 st) of BO, in 1991. Total estimated value was $440 million. That level of production was equal to 1990 revised production figures. Value was greater by $37 million, however, reflecting a strengthening of boron product prices. The US continued to supply essentially all its own boron while maintaining a strong position as a source to foreign markets of sodium borate products and boric acid. Domestic employment in the mining and beneficiation of boron products in 1991 remained at 1100 people, about the same level as in 1989. The Bureau of Mines estimated total world production of boron in 1991 - mineral concentrate and chemical - at about 2.9 Mt (3.2 million st). That corresponds to about 1.2 Mt (1.3 million st) of BO ,. World production in 1991 was about equal to revised 1990 levels. US production Mines and processing operations in southern California were the only domestic sources of boron mineral concentrates and chemicals in 1991. US producers, in order of quantity of production, were US Borax and Chemical Corp., North American Chemical Co., and American Borate Co.

Jan 1, 1992

By Shining Z

The properties of coal or rock containing gas are very important both for studying coal and methane outburst mechanism and for controlling underground rock in mining. The rheological fracture properties of coal containing gas were studied to obtain its rheological fracture principle both in microscopic scale and in macroscopic scale. The application of this principle is successful in explaining coal and methane outburst mechanism and for putting forward a rheological hypothesis of coal and methane outburst.

Jan 1, 1992

By S. Behl

A major limitation in developing successful selective flocculation schemes is the difficulty encountered in adsorbing the polymeric flocculant only on the desired substrate. In this paper a correlation between selectivity of flocculant adsorption and separation efficiency is outlined and a potential technique to achieve selective adsorption of flocculants is discussed.

Jan 1, 1992

By L. C. Atkinson

A three-dimensional finite element Ground-water flow code has been developed that incorporates saturated/unsaturated, two-regime flow (i.e., both Darcian and non-Darcian) and solves for the seepage face at a surface of outflow. This code is capable of more realistically predicting ground-water inflows to an open-pit mine under the throttling effects of non-Darcian flow. The height of the seepage face on highwalls and the shape of the phreatic surface in the vicinity of the pit that it calculates can also produce more probable estimates of pore pressures for analysis of slope stability.

Jan 1, 1992

By K. L. Whitehead, R. A. Jankowski, N. I. Jayaraman

Most continuous miner sections utilizing flooded-bed scrubbers also use blowing face ventilation. Blowing ventilation, however, interferes with dust capture and minimizes scrubber effectiveness. To enhance the efficiency of the scrubber system and reduce dust concentrations, the Bureau of Mines tested various combinations of operating parameters. Experiments for system efficiency took place in a full- scale model mine at 3.05 m roof height. In general, higher values for scrubber and face airflows resulted in lower dust concentrations. In addition, optimum dust controls would include a face ventilation to scrubber airflow ratio of one. When the airflow ratio was either less than or greater than one, the dust levels in the return and at the operator locations increased. No single dust control technique was the most effective one at all locations due to mutual interaction among techniques.

Jan 1, 1992

By McNicol M. D

Petroleum exploration in onshore Gippsland was directed in the 1950s and 1960s towards plays in the basal Latrobe and Strzelecki Groups, but these became forgotten in the 1970s with the Latrobe play discoveries offshore. The principal explorationists of the time were Woodside Oil and Arco Ltd, who then departed the scene after drilling some 18 wells without major success. In the late-1980s successful hydrocarbon finds in equivalent age Otway Group sediments in the Otway Basin were made and in early 1990 Tyers Petroleum began investigations into Strzelecki Group prospects as applied to the onshore Gippsland Basin. Some 18 anticlines have been mapped, based on shallower coal exploration drilling in the Latrobe Group, which from seismic and gravity evidence are believed to unconformably overlie similar anticlinal structures in the underlying Strzelecki Group. Strzelecki targets of interest within drilling depth are the basal Tyers Conglomerate/Rintouls Creek Sandstone Formations which outcrop in the north of the Latrobe Valley and are analogous to the Pretty Hill Sandstone in the Otway Basin. In addition, intra-Strzelecki Group targets similar to Heathfield and Windermere Sandstone Members are also considered to be present. Good source rocks are abundant including coal seams and carbonaceous sediments of Neocomian and Jurassic age, which lie within the oil window. Seal is provided by the overlying Aptian-Albian aged volcanogenic sediments. The Tyers/Rintouls sandstones - a target in the Woodside/Arco wells, with two exceptions, were not reached. Encouraging intra-Strzelecki shows were reported in many of the wells. Basal and intra-Strzelecki porous quartzose sandstones remain one of the few untested plays left in the Gippsland Basin and, in the onshore, merit extra attention as they he within the oil window at economically drillable depths.

Jan 1, 1992

By McGuckin P. H

The Cadjebut orebody is a MississippiValleyType (MVT) zinc-lead deposit, and is located approximately 80 km southeast of Fitzroy Crossing in the Kimberley region of Western Australia. It is one of five zinc rich orebodies discovered by BHP Minerals in the region.The participation in the Cadjebut Joint Venture is BHP Minerals limited (Manager), 58 per cent and Billiton Australia Limited, 42 per cent.The mineralisation is contained in gently dipping dolomitised limestone sediments (part of the Lennard Shelf carbonate sequence) with an orebody width of between 60 and 120 m and a strike length of approximately 3 km. The deposit consists of two thin, stratabound shallow dipping orebodies, one overlying the other, to provide discrete but not independent mining areas. The orebody contains approximately 2.1 million tonnes of recoverable ore at an approximate grade of 12 per cent zinc and four per cent Lead.

Jan 1, 1992

By J. Bhattacharya, S. K. Mukhopadhyay, S. K. Pal

"While time and again many authors have categorically stressed the restoration of the environment, very little effort has been made in the mineral industry to develop the economy of environmental control. There are many abatement procedures that search a maze of variants. Among them pricing environmental damage seems to be more logical and easily implementable.IntroductionMining as an operation has a severe impact on the Earth's natural resources. While economical environment control is much sought after, solutions are often varied and complex, and can differ in the problems of single or multiple mine sites.Determination of Optimum use LevelsIn “mining environmental control"" it is required to strike a balance to find optimum use levels. The solution is to find where the welfare benefits equal the cost involved to curb the degree of environmental damage (Fig . I) . In the mining industries this can be done by modifying the production/extraction process itself. For most pollutants, the marginal costs of control will exceed the benefits from further reduction of damage long before the zero pollution damage point is reached (Fig. I). From an economic perspective the optimal alteration of environment by mining would occur at z; pollution continues to be caused by ""zy"" control units, but it would be inefficient to pursue the redemption efforts further because the marginal cost involved would exceed marginal welfare benefits."

Jan 1, 1992