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By J. W. Evans

Mathematical modeling has now become a standard technique in the development of new technology and the improvement of existing technology in the processing industries. Physical modeling has a longer history but a smaller following at present. The paper reviews some examples of the application of both types of modeling in non-ferrous metal extraction, particularly within the copper and aluminum industries. The objective is to show that well founded models can lead to results that have practical consequence in scaleup, design and operation.

Jan 1, 1993

By J. O. Marsden

The 1980s saw a revolution in gold extraction technology, paralleled only by the implementation of the cyanide leaching process in the late 1800s. This revolution was led by the widespread adoption of carbon adsorption processes for gold recovery, heap leaching of low-grade ores and development of a variety of oxidation processes to treat refractory ores. In the late 1980s, gold production in almost all regions of the world increased, with the notable exception of South Africa. This geographical variety is creating a greater diversity of challenges for gold metallurgists. This is due to a wider range of ore types, new and varied environmental regulations and legislation, and a requirement to select the most appropriate technology to suit local needs. North America has led this technological revolution in the gold industry and is responsible for commercialization of most of the major innovations: carbon-in-pulp, heap leaching, whole ore pressure oxidation and whole ore roasting. Process selection trends A general trend in precious metals extraction technology has been the treatment of ores with progressively lower grades. The lowest cost treatment, dump leaching of material at run-of-mine size, has been increasingly applied. ZortmanLandusky, in Montana, is successfully leaching material above a cutoff grade of 0.2 g/t (0.006 oz/st) at an average rate of about 28 kt/d (31,000 stpd). At this scale of operation and in the absence of any cyanide-consuming species in the ore, process operating costs for a ge¬neric run-of-mine leaching operation are estimated to be between 60 and 75 cents/ t (66 and 77 cents/st). One of the largest heap leach opera¬tions treating crushed ore is the Round Mountain Mine in Nevada. It processes about 45 kt/d (49,000 stpd) at an average grade of 1.1 g/t (0.032 oz/st) at a nomi¬nal crush size of 80% -19 mm (-0.7 in.). Round Mountain also treats lower grade ore above a 0.2 g/t (0.006 oz/st) cutoff by dump leaching at run-of-mine size.

Jan 1, 1993

By R. A. Haney

The Mine Safety and Health Administration (MSHA) has conducted studies both in coal and non-coal mines to evaluate methods for sampling diesel particulates in underground mines. The agency is investigating size separation techniques to distinguish between diesel particulate and respirable coal mine dust. Additionally, ashing techniques have been used to distinguish diesel particulate from mineral dust in metal and non-metal mines. As part of these studies, personal exposures to diesel particulate for various mining occupations have been measured. This paper describes the measurement techniques and summarizes the exposure levels for various underground mining operations.

Jan 1, 1993

By Sadi Medina

As it is characteristic from Custom Smelters, ENAMl Las Ventanas Smelter has to deal with different qualities and quantities of mining products from about 70 suppliers, that contain a variety of impurities that would be harmful for copper production. In order to increase the smelting capacity, an oxygen plant has been running since September of 1990. Moreover, to improve the environmental conditions, a new sulphuric acid plant started up to neutralize the metallurgycal off-gases from the Teniente Converter and partially from the Peirce-Smith converters. Based on the on-line operation among the reverberatory furnace and the Teniente Converter using oxygen enriched air to produce high grade matte, most of the volatilizing impurities, mainly arsenic, are collected as discarding compounds in the gas cleaning system of the acid plant. This paper describes the continuous performance of the Teniente Converter with acid plant, the results attained, the operation problems and how they were solved. The impurities distribution achieved in this process is also included.

Jan 1, 1993

By Maleki. Hamid

The U.S. Bureau of Mines implemented an inte¬grated static and geophysical monitoring program in a southern Wyoming mine to study changes in seismic wave propagation properties in roof strata. The purpose was to develop techniques to assess roof stability problems. The work consisted of record¬ing deformation and stress histories and calcu¬lating seismic velocity profiles. In addition. geology and roof conditions were mapped; the in¬struments were initially installed at the develop¬ment face; monitoring continued until the mecha¬nized retreat face retreated within 60 m of the instruments. Mining geometry consisted of a three-¬entry gate system using 5.2-m-wide pillars at depths of 426 m. Results were analyzed using stan¬dard history plots, velocity tomographs, and numer¬ical modeling techniques. Changes in velocity. frequency, amplitude, dynamic elastic modulus, and dynamic Poisson's ratio were related to roof defor¬mation, fracturing, and support requirements. A reduction in seismic velocity of 17 pct occurred after 60 mm of roof deformation following installa¬tion of supplementary support. Static measurements revealed significant dilation in the mine floor, spreading to the pillar and the mine roof. Failure was initiated in the floor as a result of uniform pillar penetration.

Jan 1, 1993

By Samyguin VD, Filippov LO

The aim of this paper is to emphasise the importance of knowing of the rate of the elementary flotation acts (EFA) - attachment and detachment. By studying the simplest linear model notion of the column flotation, the results of the nonlinear simulaton of flotation separation in the column with lengthwise upward mixing show two principal different types of separative mass-transfer in the column. The first is, the case of a small EFA intensity, almost without the detachment. The second is, the case of a big EFA rate, when the process is close to a local attachment-detachment equilibrium. There is also an attempt to estimate the EFA rate for three different kinds of quartz particles, floated by cation collector in the laboratory column apparatus.

Jan 1, 1993

By T. D. Traubert, J. T. Dietz, D. Catena

"Canadian process industry experts have often observed the strong trend for U.S. industrial safety and environmental laws to creep across the border. These experts will be interested in new United States (OSHA) regulations (29 CFR 1910.119), and anticipated new U.S. Environmental Protection Agency (EPA) regulations that will require over 28 000 U.S. refineries and chemical plants employing more than three million workers, to begin a comprehensive Process Hazard Analysis (PHA) of these complex plants immediately. Impending EPA regulations are expected to expand these efforts and add process Hazard Frequency and process Hazard Consequence reviews for many additional industrial locations.These regulations were created to reduce catastrophic industrial accidents, and emergency releases of hazardous chemicals which endanger employees, the public, and the environment.Accurate, and field verified Piping and Instrument Diagrams (P&IDs) are essential to permit a meaningful Process Hazard Analysis or emission release to be done. Today accurate P&IDs often do not exist. Many companies that have started to update their old P&IDs have found the process to be far more difficult, time-consuming,and expensive than they ever thought.This paper describes a new technique of computer drawn ""Intelligent"" P&IDs that can make a Process Hazard Analysis less expensive, more accurate, easier to perform, and provides lasting benefits to the plant owner long after the PHA has been completed."

Jan 1, 1993

By Jack Parker

Pillar design ought to be a matter of matching pillar strength against pillar loading conditions to come up with dimensions that will cause the pillar to behave as required - to stand forever, or for a limited time, or to fail in a controlled manner. But something has gone wrong in recent years, seriously wrong. Pillar design practices have departed from reality. The laboratory and computer have taken the place of the mind. If the mind is put to work and such pillar design practices are examined critically, it becomes obvious that they deal with conditions that do not exist in a real mine. Time, effort and money are wasted, and the end results are incorrect and misleading. These questionable pillar design practices have been passed on from generation to generation over the past 30 or 40 years. The hope here is that we can return to reality as soon as the questionable practices are generally recognized. We could then go back into the mines and define how pillars really work, and mining safety, efficiencies and costs should improve. Let us take a close look at current textbook design practices and compare them to real-life conditions. Common sense might then prevail. (At this time, we will consider only mine pillar design, but similar scrutiny should be applied to design criteria for width of openings, floor conditions and roof support systems.)

Jan 1, 1993

MODELLING FOR DESIGN AND CONTROL AT KALGOORLIE NICKEL SMELTER Modelling at KNS has been driven by a need to have better tools to answer questions about control, design and optimisation of the plant. This paper describes a number of modelling tools developed for use at KNS and how the development of modelling tools fits with a design and control strategy. In the area of control, a thermodynamic model has been developed to allow process parameters to be calculated. The model allows for the automatic selection of data from a laboratory data base, desired operating set points are input and the operating parameters are calculated. The model has the ability to adjust the burner efficiency and the furnace heat loss depending upon conditions. To assist with the testing of proposed furnace design changes, various mathematical models of the burner and shaft have been created using PHOENICS. These models are particularly well suited to combustion heat transfer and flow aspects of both the burners and shaft. Validation of these models have been based on novel sampling and measuring techniques in the shaft and also by using scale and cold models. Overall plant energy and cost structures can be analysed using a flowsheet simulation, developed to evaluate potential alterations to the plant flowsheet. This model system allows the global evaluation of process changes.

Jan 1, 1993

By R. A. Lohnes, S. M. Levorson

As part of research to develop a coal handleability index that predicts the ease with which coal will flow through a handling system, comparative tests were conducted with a Johanson Indicizer and a low-stress triaxial apparatus on 12 coals at a variety of gradations and moisture contents. The lndicizer test provides a rapid method for generating data associated with coal handling characteristics. The arching index measured with the Indicizer is a function of the geometry of the apparatus as well as the properties of the coal. The handleability index determined from triaxial data is a more direct measure of coal characteristics. The handleability index shows a wider range of values than the arching index and, therefore, appears to be more sensitive to coal variations. Neither the arching index nor the ratholing index, as measured with the Indicizer, agreed well with the handleability index. This is attributed to differences in sample preparation as well as to the tests themselves.

Jan 1, 1993

By R. S. Kramer

A bulk compositional chemical analysis often provides incomplete information to help the mineral processor when faced with the problem of removing troublesome contaminants in low concentrations. Michigan Tech has developed a unique approach for addressing this problem. A combination of Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), and image analysis was successfully used to characterize the species responsible for phosphorus contamination of less than . 05 weight percent in iron ore. An automated routine acquired the chemical signature of each particle on a back scattered electron image. The few particles containing phosphorus were identified from the hundreds of particles examined, and the phosphate phases present were easily characterized.

Jan 1, 1993

By W. R. Dengler

In Canada, most of the rock being broken in underground metal mines is being done by using traditional drilling and blasting methods. Despite advances being made in hardrock boring and other, more exotic techniques, Dynatec believes that the traditional methods will prevail for many years. It is also believed that modest research efforts expended on the traditional methods will result in substantial financial benefits to the mining and rock tunneling businesses. Dynatec has pursued productivity improvements through the use of long rounds in shaft sinking and lateral development. The concept of longer rounds was developed by Dynatec on the Craig Shaft Sinking Project (RETC, 1991). This technology was subsequently used to sink the two shafts at Aur Resources with great success. The development of a Long Round Jumbo for tunneling is a natural progression of the long round technology developed for the Craig Shaft. The Dynatec Long Round System has been patented in the United States and South Africa, with additional patent applications pending in Canada and Australia.

Jan 1, 1993

By Pollmans GJ, Hoberg H, Schneider FU

The Institute of Mineral Processing at Aachen University of Technology has been engaged in fine and ultrafine comminution for several years. Former investigations had been dealing with the mechanical activation with the aim of increasing the solubility of highly resistant oxides such as tantalite and niobite while research on the product of ultrafine powders is of major importance at the moment. Materials of that kind are of increasing interest in the production of extremely resistant ceramics, in the development of new raw materials, in powder metallurgy and in the production of fillers (extender pigments) and pigments. The creation of ultrafine powders is difficult and very expensive. They can be produced by means of condensation or dispersion methods. One important method of dispersion is mechanical comminution. Due to long and intensive research and development all over the world important advances have been achieved but still a great number of questions and problems occur especially in producing materials of submicron and nanometer grain sizes which could be answered or solved only insufficiently up to now. These mentioned difficulties refer especially to: ò the required energy input into the feed material, ò the forming of strong agglomerates and wall stickings, ò the required product qualities, and ò the entire and reliable characterisation of the products. Basic investigation aim to clarify the micro and macro processes of ultrafine grinding and work towards solutions to the difficulties mentioned above. The aim of the Institute's research is the development of a new grinding device for producing ultrafine powders. First results of a laboratory scale mill of that type will be presented in this paper.

Jan 1, 1993

By S. Raghavan

The thermodynamic activities of MgO in the solid solutions that can exist in the system NiO-Mg0-Zn0 are determined by measuring the EMF of the cell: O2 (g), Pt / MgO, MgF2 // MgF2 // x MgO + yNiO + (1-x-y)ZnO / Pt, O2 (g) / MgF2 in the temperature range 1190-1237 K. Equilibrium phases were prepared along the quasi- binary lines MgO/NiO = 0.1765,0.3333, 1.0,3.0 and 5.667 with the ZnO contents being 0.1, 0.2, 0.25, 0.35, 0.5, 0.75 and 0.9. The crystal structures of the phases were identified by X-ray diffraction. Results obtained so far show that a single phase MgO-rich cubic solid solution exists upto 0.2 ZnO content and for compositions above 0.25 ZnO, a second ZnO rich wurtzite phase forms in addition. Activity measurements show that for low MgO and ZnO contents, the MgO activities exhibit ideal to slight positive deviation from ideality and at higher MgO contents, a negative deviation is shown. Further studies are in progress.

Jan 1, 1993

By I. Iwasaki, X. Cheng

A series of batch flotation tests was performed on chalcopyrite-quartzite, on pyrrhotite-quartzite and on chalcopyrite-pyrrhotite-quartzite mixtures. Pulp potential measurements in the flotation tests with single sulfide minerals indicated that each sulfide mineral had its own optimal potential range for flotation. When these results were used to select the potential ranges for the separation of the two minerals from their mixture, their flotation responses changed, and the selectivity of separation was adversely affected. A possible mechanism involving surface alteration through galvanic interaction is discussed, and a method to improve the selectivity of flotation separation is proposed.

Jan 1, 1993

By D. M. Bodily, M. D. Deo, E. M. Whitney

Field data from coalbed methane wells indicate a significant variation in composition as a function of flow rate and time. In particular, San Juan Basin wells have displayed an increase in C02 concentration over time. Prediction of gas quality is critical to the economic evaluation of any coalbed project. Previous models have forecast only pressure and production profiles, ignoring compositional variations. In this study a multicomponent model that incorporates binary isotherms for methane and carbon dioxide has been developed. An extended Langmuir isotherm is used for the adsorption representation and a constant separation factor (similar to relative volatilities in distillation) describes the phase distribution of the species. This separation factor depends both on the surface characteristics of the coal and on the adsorbing species. The chromatographic separation equations have been superimposed on Darcy's law flow. The formulation allows decoupling of the pressure and compositional partial differential equations. The equations have been cast in dimensionless form and solved for pressures and compositions. It is observed that the composition of the preferentially adsorbed C02 increases at the wellbore as a function of dimensionless time. The dimensionless time is directly proportional to the real time and coalbed permeability and is inversely proportional to the gas viscosity, coal porosity and the square of the length of the reservoir. As the separation factor increases, the compositional variation increases. This variation in produced C02 concentration is also greater when the initial C02 concentration in the reservoir is higher. A sensitivity study has been performed to identify the effects of important parameters such as isotherm variables and reservoir characteristics on pressure and composition profiles.

Jan 1, 1993

Hydrocyclones are widely used in both mining and various industrial sectors. Considerable fundamental research work on the modelling of hydrocyclone classifiers has been carried out through the past 25 years. Based on the similarity principle, the hydrocyclone classification was taken as a whole physical process and a group of similarity numbers were obtained with the help of dimensional analysis in this paper. Then, the functional dependences of the similarity numbers have been established. The variables optimisation was carried out with the multiple objectives linear planning programs developed in this study.

Jan 1, 1993

By Kadoya H, Kondo Y

The Harima works were established in 1964 and started operation in 1966. The initial capacity was 3500 t/month of zinc and 1500 t/month of lead. Until 1990 a lot of improvements had been made and the capacity had increased 6600 t/month of zinc and 2200 t/month of lead without enlarging the furnace size. During the ten weeks campaign shut-down at the end of 1990, many modifications were carried out including the enlargement of the furnace shaft area. By these changes, the capacity has gone up to 7500 t/month of zinc and 2500 t/month of lead. In the sinter plant, the amount of SO2 rich gas supplied to the acid plant was raised to 50 000 Nm3/h from 43 500 Nm3/h. An electrostatic precipitator was adopted instead of a venturi scrubber to clean the rich gas. Oxygen enrichment has been continuously operated since August 1991, because the furnace capacity is more than the rate of sinter production. Utilisation of the sinter plant is high being as much as 97 per cent and the sulphur burning rate has been increased. In 1990 the furnace was replaced except the hearth. The shaft area was enlarged to 19.4 m2 from 15.3 m2. The target blast was designed to be more than 36 000 Nm3/h. Tuyere layout was changed to prevent slag breakouts. Due to these modifications shaft condition has been very good. Automatic launder jacket cleaners were installed to increase the lead cooling efficiency. Many other improvements and developments were also made. Coke powder injection from the tuyeres has been successfully operated since April 1987.

Jan 1, 1993

By A. E. Hall, K. R. Mutama

The wind tunnel has been used extensively for mine ventilation research and continues to be a valuable tool. The advent of the powerful personal computer has reduced the use of wind tunnels because several flow problems car be simulated and investigated quickly. This paper describes the recent design and construction of a wind tunnel which is now being used for mine ventilation aerodynamic research and teaching purposes. The wind tunnel has a square cross section measuring 900 by 900 mm and is 8485 mm long from the entrance to where it joins the fan. The tunnel was designed as an open circuit suction type and is attached to a 7.5 kW variable pitch axial flow fan capable of producing over 6 m3/s of airflow. The entire length of the wind tunnel can be used for flow investigations and all activities are visible since the sides are made of plexiglass. Results are presented from the test program to show that even without honeycombs and screens air flow symmetry is achieved.

Jan 1, 1993

By Baoqi S, Zhengbing C, Wenguang L

A new flotation method is introduced for separating zircon from rutile and other Ti-bearing minerals at normal temperature, using a mixture of cationic and anionic collectors without any acid, alkali or fluoride as regulators. By combining the method with gravity concentration and magnetic separation to process the seabeach placer, the technological flowsheet can be simplified and the pollution of environment and the corrosion of acids, alkalis and fluorides on equipment can be removed.

Jan 1, 1993