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By Laajalehto K

The basic condition necessary for flotation is hydrophobicity of the surface of the mineral to be floated. For sulphides, this condition usually requires treatment with a collector solution. The conditions for this treatment have until recently usually been chosen by the trial and error principle which has indeed been working relatively well under favourable conditions; ie for simple homogeneous ores. However, the present tendency to increasing use of complex and often relatively lean ores sets increasing requirements for the control of the flotation process. This development is the reason for the present rapid development of process control methods in flotation. In addition to the already well-established practices of pH and reagent feed controls, the importance of measuring and controlling the electrochemical potential of the ore particles to be floated is recognised in the case of sufficiently conductive minerals. In fact, the electrochemical potential seems to be the basic quantity determining the flotation behaviour of such relatively well-conducting minerals as sulphides. Since the hydrophobicity of the mineral and, hence, its flotation properties are ultimately determined by the composition and structure of its surface, information on these under different process conditions is important for design and operation of efficient flotation processes. The basic requirement set for the methods used for obtaining this information is high surface sensitivity of the method. The recent rapid development of surface characterisation has produced several methods which fulfil this requirement. Their application to the problem of characterising surfaces of mineral samples in contact with collector solution is, however, often complicated. The main reason for this is the vacuum environment necessary for the measurement. In the case of flotation experiments this means that in most of these methods the measurement cannot be made in situ, but the sample must be extracted from the liquid and subsequently evacuated in the vacuum chamber of the instrument. It is essential to carry out these steps so as to avoid to the extent possible changes in the sample surface. For the purpose of establishing whether this has been accomplished it is important to compare the results of methods operating in vacuum with some available in situ method. An optimal choice of methods seems therefore to be a combination of the available powerful vacuum methods with in situ measurements. The most usual combination seems to be X-ray photoelectron spectroscopy (XPS or ESCA), Fourier transform infrared spectroscopy (FTIR) and electrochemical measurements. This choice combines the unique possibilities for direct elemental and chemical characterisation offered by XPS (Cecile, 1985) with the in situ capability of FTIR and electrochemistry. In the XPS measurements, it is essential to apply a special sample handling technique to avoid loss or damage of some sensitive species of the collector-based layer on the mineral surface. In the following will be given some examples of the application of the XPS technique in combination with electrochemical methods of sample treatment to studies of the layer formed on sulphide substrates in ethyl xanthate (EX)

Jan 1, 1993

By Y. K. Rao

In the carbonyl process for the refining of crude nickel CO(g) reacts with nickel in the 310-370K range producing nickel tetracarbonyl, Ni(C0)4(g). Iron and cobalt impurities also form gaseous carbonyls but their partial pressures are low. The carbonyl is led to a decomposer plant wherein the gas disproportionates in the 500-600K range depositing pure metal on nickel pellets that move countercurrent to the gas-flow. This system serves to illustrate the fundamental principles involved in the vapor phase mass transport of elements, against temperature-gradient, under the influence of chemical potential gradient. Unlike in the crystal growth, the source is at a lower temperature (say 350K) whereas the seed is in the hot-zone (say 550K) of the closed ampoule-type reactor. By assuming virtual gas-solid equilibria in the end zones, with diffusion of gaseous species between them acting as a slight perturbation, the quasi-steady- state mass-transport rates are computed for a range of CO-pressures and temperatures.

Jan 1, 1993

By Rogers M, Sullivan B

Golden Crown Mine is a narrow vein gold mine producing 75000 tpa. Production has been predominantly by shrink stoping using hand held machine and airleg. Bogging from these stopes is done with Toro 150 LHD units.Previously the standard development method consisted of developing a sill drive, a footwall drive and millholes every 7 m. This meant that for every metre of ore development, 2 m of waste development was required.

Jan 1, 1993

By A. D. MacPhail

The Highland Valley Copper partnership was formed in July 1986 and was the logical result of a mine with a large ore reserve but no adequate mill, and a mine with a large, modem mill but dwindling ore reserves. The original partners -Cominco and Lornex -were joined in January 1988 by Highmont Mining Co. which contributed a two-line concentrator. During 1988/1989, the Highmont mill was moved 7.5 km to adjoin the Lornex mill, forming what is now called the Highland mill, with a current nominal capacity of 130 000 tonnes per day. The mine is located 220 km northeast of Vancouver, British Columbia and is close to four communities in which personnel make their home: Logan Lake, Merritt, Ashcroft, and Kamloops. The map in Figure 1 2.2 shows the general area. Kamloops is a major service centre and is serviced by two railways, two major roads and a regional airport.

Jan 1, 1993

As noted by D.W. Fuerstenau in his Plenary Lecture at the Conference on Extractive Metallurgy of Gold and Base Metals, Kalgoorlie, Australia, "Com¬minution of solids is surely one of the oldest technologies that, even in this day and age of DNAs, chips and space exploration, continues to challenge our scientific acumen and engineering ingenuity." Thus, the fundamentals of comminution continue to receive a great deal of attention in the literature. This was particularly true in 1992 with the publication of the proceedings from the SME-sponsored symposium, Comminution Theory and Practice. Papers covering topics ranging from liberation to comminution fundamentals to novel size reduction techniques are included in this review. Liberation Liberation continued to be a prime area of research interest, not only in terms of liberation modeling, but also in understanding the basic mechanisms involved in mineral liberation. King (Comminution - Theory and Practice, pp. 3-15) described a method for determining the interphase area between mineral grains. He showed how the mea¬surement of interphase area before and after comminution could be used to determine the presence or absence of intergranular fracture. Lin, Miller and Cortes (Kona, Vol. 7) discussed the use of computed tomography (CT) as a nondestructive means of investigating three-dimensional particle composition. The use of this technique in constructing coal washability curves from CT data was presented.

Jan 1, 1993

By L. D. Johnson

12 groups of 12 precast prestressed (PCPS) piles were driven in the lagoon of Kwajalein Island to support a dry dock. Pre-construction investigation of the calcareous coral sands and static pile loeid tests were performed to determine if the 7.9 by 7.9 cm (20 by 20 inches) by 26 m (85 ft) long PCPS piles embedded to a depth of 16 m (53 ft) would adequately support the dry dock. Driving records for production piles indicated that the blowcounts of the piles at the fincil embedment depth became substantially less than expected as piles wssre driven further toward the lagoon end of the dry dock and decreased to as low as 2 blows/ft. A supplemental investigation that included a static load test on a production pile, the driving of an indicator pile, and restrikes indicated that the pile foundation has adequate bearing capacity. The observed bearing capacity appears to be effected by several mechanisms including breakdown of cementation between sand particles, densification of the sands during driving, and dissipation of excess pore pressures and recementation after driving.

Jan 1, 1993

By Kubo H, Ninomiya R, Ojiro T, Sato T

New high-strength Zn alloys for moulds are demanded from the automobile and electric industries in Japan, because the s rength of Zn moulds is still not high enough for the mass production. There are two approaches to improve the strength of Zn alloys. One is to increase the Al content. ZA alloys (ZA-8, ZA-12, ZA-27) were developed through this approach. The other is to increase the Cu content. But it is known that an increase in Cu generally depresses the castability of Zn alloys, so that the alloys with increased Cu have been rarely studied until now. In this study a reconciliation between the strengthening and the castability of Zn alloys by enriching both with Al and Cu has been attempted. Accordingly we have studied on the Zn alloys containing 4 to 25 mass per cent Al and to 24 mass per cent Cu have been studied. Their fluidity, which primarily corresponds to the castability of the alloy, were measured first and 19 alloys were selected based upon their fluidities and casting temperatures. Mainly the mechanical properties of all 19 alloys were tested and some were found to be excellent in both strength and castability. Z1009 (Zn-IOAI-9Cu-0.02Mg alloy) cast in a sand mould has the tensile strength of 360 MPa while ZAS (Zn-4AI-3Cu-0.04Mg alloy), which is the most popular alloy for moulds, is 215 MPa. Z2520 (Zn-25AI-20Cu-0.02Mg alloy) cast in a sand mould has a Vickers hardness of 178, compared to 107 for ZAS and 104 for ZA-27 (Zn-27AI-2Cu-0.02Mg). Furthermore the castability of Z1009 is as good as that of ZAS. The underside shrinkage occuring in casting ZA-27 is restrained in Z2520.

Jan 1, 1993

By H. T. Mulryan

Talc is used as an essential ingredient in a wide variety of plastics applications ranging from polyester body patch compounds through polypropylene automotive, appliance, and household furniture components to high performance parts made from liquid crystal engineering resins. The paper focuses on polyolefin applications; the three tier market for talc in polypropylene; the effects of various talcs in typical compounds; and trends in each market segment. Emphasis is given to emerging markets, examples of which are polypropylene compounds which mimic higher cost resins, and polyethylene films, customer requirements for talcs for these purposes are discussed.

Jan 1, 1993

It is extraordinary that while Australia depends heavily on mineral wealth for its economic well-being, most Australians have no appreciation of the traditions and principles which drive and govern the mineral industry. Their understanding has been largely provided by those who campaign against the industry in one way or another and is therefore quite unrepresentative.

Jan 1, 1993

A universal grinding circuit model suitable for an arbitrary structure of flowsheet has been suggested. In this model classifiers and mills are described in a most general form. What puts the model in a class by itself is the automatic mass balancing in all streams of the circuit. In order to provide this a special classifier model is adopted. A previously published continuous steady state process model is used as a grinding model. Non-linearity of classifier model leads to a resultant circuit model which is equivalent to a non-linear integral equation. It complicates somewhat calculation algorithm in comparison to that of linear model, but provides a physically meaningful solution.

Jan 1, 1993

In May 1993, SME contracted with The Dolecek Companies of Denver, CO to conduct a salary survey and a study of Mining Engineering. A written, four-page survey was sent to a random select sample of 1897 current SME members from the United States and Puerto Rico and to 40 current SME members from Canada. A total of 621 survey responses were input and analyzed, to guarantee the validity of the survey findings. The findings are representative of the entire SME membership. And the survey is within a statistical range of accuracy of plus or minus 5%. Salary survey SME members currently earn an average of approximately $60,000 a year. Some 45% earn less than $60,000 and 49% earn more than that. About 24% of all SME members earn $80,000 or more each year and 13% earn $100,000 or more. Not surprisingly, a statistically greater number of owners (27.5%) and those in senior management (30%) have a current income or salary of $100,000+ a year.

Jan 1, 1993

By Alan T. Nelson, Ronald D. Mariani

The Tilden concentrator was originally constructed in 1974 for the processing of low grade hematite. Flotation is a key concentrating process in the operation, and therefore flotation optimization has been a major concern since the plant startup. This paper will discuss some of the modifications made in the process to achieve optimization. The conversion that now enables the plant to process magnetite as well as hematite also will be discussed. INTRODUCTION The Tilden Mine, located in Ishpeming, Michigan, is managed by Cleveland-Cliffs Iron Company and is owned by Cleveland-Cliffs and two Canadian steel makers. It was constructed and started production in 1974 and expanded in 1979 for processing a low grade, fine-grained hematite iron formation for which there was previously no technology available. Several papers have been written describing the unique character of the concentrating operation. The hematite plant consists of 12 grinding and concentrating lines, which utilize two stages of autogenous grinding with crushing of an intermediate sized product. The ground product is deslimed in a highly dispersed alkaline environment to reject silica. Corn starch, the flocculant, has a high affinity for iron at the operating pH range of 10.5 to 11.0. The ore is upgraded from 35% to 45% iron in the desliming step. The deslime thickener underflow is the feed to flotation. Each flotation line consists of a bank of 10 rougher cells, followed by four scavenging banks incorporating 5, 4, 3, and 3 cells each. The Wemco flotation cells are each 14.1 cubic meters (500 cubic feet) in volume. A total of 12 flotation lines are available. [ ] A reverse flotation process is employed, using a straight-chain, 8 to 10 carbon primary ether amine silica collector. At the levels used in the circuit, the amine also serves as a frother. A final concentrate is produced in the rougher cells. The concentrates from the four scavenging steps are combined and recirculated to the feed end of the roughers, with the fourth scavenger froth being discarded as a final tailing. Upgrading to about 65% iron is achieved, with control of the circuit based on final concentrate silica grade. Starch is again used, this time as a depressant for iron. During the years of operation, several key areas of the flotation process have been targeted for optimization. The most significant improvements have been realized in the following areas: *Grade Control Automation *Control of Water System Chemistry *Flotation Spray Water This paper will focus on these areas, but other minor improvements also will be briefly discussed.

Jan 1, 1993

By Sehic O. A

Geology can be the root of evil or a source of bliss; there is a choice; to ignore geology is at a mine's peril.Risk can be minimised and profitability maximised by the application of a detailed understanding of geology, alteration, structure, mineralogy, chemistry, fabric and texture.Geology is dynamic, not static.The impact of geology is pervasive.The integration of ore quality control with grade control is one strategy for improving the utilisation of both the mineable reserves and existing plant and equipment. Grade maintenance is but one constraint on the problem of how best to blend the ore. Other ore characteristics such as mineralogy, hardness for grinding, and pulp fluidity or density for slurry size classification can be included to explore alternative blending Strategies.

Jan 1, 1993

By Douglas B. Silver

Study Parameters (Status as of February 1993) Time Period: 1989 -1991 151 North American Public Metal Mining Companies Fiscal not calendar year basis 85+% of Canadian and U.S. Metal Production Au, Ag, Cu, Pb, Zn, Mo, Ni, W Results are Preliminary and Research Continues Chicken Little is Alive and Well

Jan 1, 1993

By Greenhalgh L. P H

The opportunities offered by an increasingly volatile world invite the international consultant or engineering services contractor to broaden attitudes, diversify interests, expand capabilities, retain and develop specialist skills and base judgements upon sound principles and solid experience. The wide-ranging scope of this review reflects such a change but the topics of discussion are not intended to be exhaustive or to detract from many other current developments.The subject of environmental protection, effluent control and pollution prevention is a primary consideration in the application of many mineral processing technologies but is not covered here. There is an array of developments relating to noxious gas emissions and toxic wastes and the paramount importance of this matter justifies comprehensive conferences dedicated solely to the application of suitable measures. This review concentrates therefore on the main stream processing techniques for the primary recovery of values.

Jan 1, 1993

Since the 1989 Loma Prieta Earthquake in the San Francisco Bay Area, the California Department of Transportation (CALTRANS) has accelerated seismic upgrading of their bridges. Many structures can be improved with the simple addition of hinge seat restrainers. Others require modification of column bents and superstructure to column connections. Often, footing retrofits are necessary, which require the addition of tension/compression elements (compression piling and tiedowns anchors) to resist overturning moments substantially larger than those originally used for footing design. These footing retrofits may include doweled reinforced concrete footing extensions or new pile caps which transmit forces to either driven steel or drilled concrete piles. In some cases, installation of these traditional piling elements is expensive, impractical or impossible due to: low overhead clearance, ground obstructions, high water table, noise or vibration sensitivity, or the inability to laterally expand the existing plan dimensions of the footing. In the latter case, one practical option is to attach small diameter drilled and grouted tension/compression piling elements (Pin Piles) to the existing footing. The footing may be strengthened with dowels and added concrete thickness or there may be a reduced shear span due to the installation of larger or jacketed columns. A reduction of elements is available with a Pin Pile alternative, particularly when the selection of traditional standard piles is governed by the reduced tension/uplift capacity available from the traditional elements, since Pin Piles exhibit superior uplift performance.

Jan 1, 1993

By C. L. Karr

Researchers at the U. S. Bureau of Mines have developed a technique for producing adaptive control systems using fuzzy logic and genetic algorithms. These controllers can be used to efficiently manipulate complex systems in real-time. Furthermore, they can achieve an acceptable level of control despite limited feedback in the problem environment. The control systems that result from the implementation of the Bureau-developed technique are able to recognize when changes have occurred in the problem environment, evaluate the magnitude of these changes, and alter the strategy being used to control the problem environment. Fuzzy logic is used to provide the controller with a rule-base that mimics the "rule-of-thumb" approach generally adopted by humans in the area of process control. Genetic algorithms are used to provide the controller with the adaptive capabilities necessary for the control of complex time-varying processes popular in the minerals processing industry. The effectiveness of this technique is demonstrated on a laboratory pH titration system. The pH system includes a changing setpoint, titrants with varying concentrations, and the possible addition of a buffering solution.

Jan 1, 1993

By Abdurazakov A, Avrakhov A, Solozhenkin P

The flotation properties of acetic acids modified by xanthic and dithiocarbamic fragment in regards to copper and ferrous minerals and their noble metal containing ores have been investigated. The effectiveness of the co-using of these reagents with xanthates and dithiocarbamates has been shown, ie using of proposed reagent regimes for the flotation of Au-containing ores increases gold recovery by 4.2 - 4.7 per cent, and in the case of flotation of copper Re-containing ores copper recovery increases by 3.3 per cent, rhenium recovery - by 15.5 per cent. The mechanism of the action of these reagents has been explained by the data of UV and ESR-investigations of their sorption on mineral surface. The information on structure and properties of co-ordination compounds of some metals with (Diethyldithiocarbamato) acetic acid were used also for the explanation of flotation mechanism.

Jan 1, 1993

"Blasting is an inherently destructive process and inflicts damage to the immediateperiphery of an excavation, which is later manifested as ground control and dilutionproblems. Different explosives release their energy and interact with the rock in differentways."

Jan 1, 1993

By Liu H, Chen S

Natroalunite is one of colouring minerals in kaolin. In this investigation, natroalunite, on which Ca(II) was adsorbed, was flocculated by HPAM and kaolin was depressed in suspension. The adsorption of Ca(II) on the natroalunite surface was studied by zeta-potential measurement and Auger Electron Spectroscopy analysis. Ca(II) was adsorbed more on the natroalunite surface than on the kaolin surface. The mechanism of Ca(II) adsorption was considered to be chemical adsorption on natroalunite and to be physical adsorption on kaolin. It has been found that Na6P6O18 and Na2Si04 can strongly affect Ca(II) adsorption on the surface of kaolin, but weakly on the surface of natroalunite. The effects of degree of hydrolysis and the molecular weight of HPAM, the effect of pH and the effect of Ca(II) have been studied. The kaolin ore, containing SO3 1.05 per cent has been processed with this method. The products only containing S03 0.36 per cent and the weight ratio of concentrate 52.27 per cent were Obtained.

Jan 1, 1993