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By J. W. Matousek

In the flash smelting of copper sulfide concentrates, the course of reactions from the burner tip, through flame "burn-out" (the point of oxygen depletion), to settled matte and slag is of particular interest in understanding the mechanisms of the process. Numerous reaction sets can be proposed to describe the chemical changes that might be taking place, but from outside the furnace no one set offers an obvious advantage in explaining the actual processes involved. Only a combination of mathematical modeling and flame and bath sampling can achieve this result. This paper shows that flash smelting, while still reasonably orderly, is a more complex process than suggested by the technical literature.

Jan 1, 1993

Hilton Mine is located 20 km north of the city of Mount Isa and Isa Mine in far north west Queensland. The sealed road used by the 500 employees to commute from the city is part of the Barkly Highway linking Mt Isa to the Northern Territory.Although discovered in 1947, major underground development did not start until late-1982 and first cut-and-fill production in mid-1987. The J53 exploration shaft was sunk in 1970-73 and the main P49 shaft in 1973-75. Since January 1990, most of Hilton ore production has been treated in the Hilton Concentrator, and concentrates trucked in slurry tankers to Isa for smelting or shipping.

Jan 1, 1993

By Jin C, Shuyi L, Yuanbiao Z

This paper describes the structure, performance, principle and effectiveness of a new laboratory type of composed-forces field separator utilising the composition of the magnetic force, vibrating force, pulsating force, gravity and fluid-viscous force etc to separate fine feebly magnetic valuable minerals. Compared with the pulsating high gradient magnetic separator, this separator possesses unique advantages of higher enrichment ratio and higher recovery of the magnetic component.

Jan 1, 1993

By F. M. Doyle, Jiang Tao, Xu Shi, Chen Jin, E. Peters

Tafel curve technique and leaching tests have been applied to study the kinetics of gold leaching with thiosulfate. Results show that cupric ions and ammonia play the part of catalysts in the leaching of gold with thiosulfate. The activation energy of gold dissolution is calculated as 27.99 KJ/mol in the absence of both cupric ions and ammonia. However, the energy is reduced to 15.54 KJ/mol in a solution of 0.01 mol/L Cu (NH3)2 4* and 0. 5moVL total ammonia. The reaction order of Cu (NH,) g is one in the range of 0.001~0.1mol/L. These results support the electrochemical-catalytic mechanism pro- posed by the authors and explains the behavior of cupric ion and ammonia (Jiang Tao, et al., 1993)

Jan 1, 1993

By Quinn P, Robertson G, Agar GE

The replacement of diphenylguanidine (DPG) for separating INCO Bessemer matte with a water soluble collector requires a frother since most collectors do not have frothing properties. The objective of this study was to identify a non persistent frother which produced a deep froth and collapsed rapidly, while maintaining acceptable metallurgical separation. Incremental rougher flotation tests failed to differentiate any metallurgical benefit through the use of a specific frother, so other tests were employed to identify the candidate frother. The equilibrium froth height and rate of froth collapse (froth stability) of several commercial frothers were evaluated as a function of frother concentration using a 'frothmeter' apparatus. Frothers evaluated were methyl isobutyl carbinol (MIBC), Pine Oil, triethoxy butane, Dowfroth SA1263, Dowfroth 250C, Dowfroth 200 and Allied Colloids CRNI-1002. Dowfroth SA1263 produced the largest froth height, and TEB had the greatest rate of froth collapse. Frothers with properties similar to Dowfroth SA1263 and Dowfroth 250 were rejected due to their persistent froths. TEB was rejected because it has a low flash point and Pine Oil could be a nuisance to add to a flotation column. Therefore, the preferred frothers were declared to be Dowfroth 200 or Allied Colloids CRNl-1002.

Jan 1, 1993

By Morley C

The Mount Charlotte gold mine is located 0.75 km east of the General Post Office in Hannan Street, Kalgoorlie WA and about 3.5 km north of the Fimiston Operations on the famous Golden Mile.Mechanised underground bulk-mining at Mount Charlotte has been in continuous operation since 1963. For the 30-year period ending December 1992, the mine produced 22 million tonnes (Mt) of ore for a recovery of 2.73 million ounces. During 1991/92, the mine produced 1.53 Mt of ore at a head grade of 3.15 gramshonne (g/t) for a recovery of 135 822 ounces.The principal ore source at Mount Charlotte has been the Charlotte Orebody which is now largely mined out. Since 1990, approximately 75 per cent of production has been sourced from the Reward Orebodies. The Charlotte Orebody was a relatively homogeneous quartz stockwork with simple geometry and average bulked grades in the range of 4.0 to 5.5 g/t. This is in contrast to the Reward Orebodies and the more recently defined Charlotte Deeps and Maritana Stockworks, which have complex grade distribution and geometry with lower average bulked grades (2 to 4 g/t). The lower grades are principally due to the decreased density and volume of stockwork venation and related vein halo alteration. Typically, these stockworks comprise a patchy mosaic of quartz veins and vein swarms, with irregular distribution and geometry within the quartz gabbro host rock.

Jan 1, 1993

By S. C. Cohen, A. F. Mikkelsen

"This paper describes the improvements made to the operation of a liquid phase, 300°C, heat transfer system in the paste plant of an aluminum smelter. These improvements were achieved by replacing the original heat transfer fluid, a synthetic aromatic, with a new technology, petroleum-based product. This new fluid, Calflo HTF, provided better thermal stability, with lower toxicity, and improved plant working conditions.The procedures for fluid selection, changeout and performance monitoring are described along with a summary of control analysis over the last three years."

Jan 1, 1993

By Milan Lj. Stamatovic

The hydrometallurgical recovery of zinc from recycled blast furnace dust from a steel plant (Smederevo Metallurgical Company - Yugoslavia) was investigated. The dust contained 22% Fe, 17% Zn and 0.2% Pb. X-ray diffractometry showed that the main components were hematite and magnetite, in combination with zinc oxide and a very low content of lead oxide. Individual particles were generally spherical and ranged in size from 10 to 150 microns; 63% were less than 33 microns in diameter. An effective hydrometallurgical approach proved to be by caustic leaching followed by electrowinning. Recovery of zinc in the form of zinc powder was over 90%. This powder can be used for the cementation of impurities in the conventional hydrometallurgical process for zinc production.

Jan 1, 1993

By John P. Dunford

U.S. Bureau of Mines researchers are investigating the ability of mine-wide monitoring systems already in place at many coal operations to provide a direct link between geotechnical instruments and the mine-wide monitoring console on the surface. This paper describes a number of field tests using instruments such as-string potentiometers to measure roof-to-floor closure and bed separation and pressure transducers to monitor pillar loading. The advantages of using existing systems include on-site data collection and analysis, real-time understanding of geological conditions, and long-term data recovery from areas that have become inaccessible to mine personnel. However, because data are generated constantly, large files develop very quickly. In many cases, the data are redundant, such as during times of reduced mining activity or in areas not yet in the vicinity of active mining. To reduce the volume of data, a software program was written that eliminates unnecessary readings and generates a more concise file that can be output to a mine-wide monitoring system, personal computer, or as hard copy.

Jan 1, 1993

By M. S. Riyaz Ulla

The Hutti Greenstone belt, located in the northern side of Dharwar Craton, India, contains several promising gold fields. It is predominantly composed of meta-volcanics with minor intercalations of meta-sedimentaries. Alkali-SiO2 and Zr-P2O5 diagrams, immobile element trends, and an iron-rich trend on the AFM diagram indicate that the volcanic suite is low-potassium tholeiitic basalt. The lower Mg number, MgO-TiO2, MgO-Ni, and Ni-Zr plots reveal that the basalt was derived from a fractionated, highly evolved magma generated by 10-20% melting of the mantle at 1100°C and 5 kb pressure. The chemical variations suggest that the Hutti metabasalt represents volcanic arc rocks generated at a converging plate margin.

Jan 1, 1993

By Eric R. Bauer

The ground control aspects of extended depth-of-cut mining are presented in this U.S. Bureau of Mines report. A trend analysis of extended cut approvals was performed. A comparative review of roof fall fatalities for extended and nonextended cut mining is included. Current ground control guidelines for extended cut approval are summarized. The problems and concerns of this extraction system are addressed, and typical extended cutting face operations are described.

Jan 1, 1993

By Ahmed M. Nofal

This article reviews some important characteristics of the known Egyptian phosphate deposits, such as mining conditions, transport criteria, quality of products affecting their export markets and utilisation in fertilizers industry. Special attention will be given to the newly discovered large deposit of Abu-Tartur with some billion tons of ore reserves. A big project is now under implementation on Abu-Tartur deposit where the long-wall method of underground mining will be applied and a flow sheet of beneficiation will be in operation including a particular feature nontraditional in phosphate processing: high-intensity magnetic separation to eliminate dolomite impurities. Comparison with some international phosphates will be tried in order to trace the situation of Egyptian phosphates in the world market.

Jan 1, 1993

From 1980 to February 1991 the Rosebery concentrator purchased ore from Aberfoyle's Que River Mine. Following the termination of the contract the concentrator reverted to treating Rosebery ore alone. Since that time it has become apparent that the circuit configuration employed was no longer optimum for zinc metallurgy. The circuit was designed to treat a difficult, slow floating sphalerite; however, the opposite was now found to be true. The sphalerite is fast floating and the circuit was cumbersome. During 1992 extensive circuit changes led to the provision of a simple open circuit flow sheet. The circuit is now easier for operators to understand and lends itself to improvements in process control. Middlings streams have been minimised, which produces a far more stable circuit. Significantly, it must be noted that the key to achieving potential results must lie in reducing variations within the process. A significant ore characterisation program has been undertaken, providing an insight into the metallurgical compatability of the ore to be mined. Using the information collected in this program, metallurgical recoveries and grades can now be predicted with a geater accuracy. Ore characterisation data suggests that an improvement from a 54 per cent zinc concentrate to a 57 per cent zinc concentrate should be achievable. By understanding the size-by-size mineral assemblage, a strategy for concentrate grade improvement has been developed. The requirements of the customer must in all cases determine the quality of the product. Pasminco is a fully-integrated zinc producer and as such significant gains can result by tailoring the concentrates to suit the Smelters.

Jan 1, 1993

By T. A. Lloyd

The use of tank cells over the years has provided a means for low cost, space efficient, extra capacity in existing flotation circuits. In some cases, new plants have selected tank cells as the machine of choice. Typical tank cells use high efficiency impellers for mixing, which results in low power draw. Unfortunately, these mixers have poor aerating characteristics that compromise metallurgical performance. This has all changed with Outokumpu's new flotation concepts. Outokumpu has recently developed the HG or High Grade flotation cell that can provide higher recovery with better selectivity while maintaining the simple operation of conventional cells.

Jan 1, 1993

By Williams M

Sheet flotation is a new two dimensional column flotation cell that produces continuous spectrum of products. Analogous to a shaking table in its performance and analysis, sheet flotation is a sheet of bubbles rising through packing contained between two walls. Feed enters the sheet at the lower left and the product exit along the top and right edges. Iligh grade materials exit at the top left, middlings exit at the top right comer and low grade waste materials exit at the bottom right. As in the case of a shaking table, two motions are required: up and right. Bubbles furnish the upwards movement for hydrophobic particles, slanted packing the rightward movement for hydrophilic particles. The sheet flotation cells is analysed as a 40 x 40 array of simple cells. In practice, 1000 x 1000 arrays of simple cells may be expected. With larger arrays, excellent separations may be expected. Because there is no recycle, there is no build-up of middlings in

Jan 1, 1993

By Prakash M. . P. E. Donde

1. INTRODUCTION The Washington Metropolitan Area Transit Authority (WMATA) has often taken a leading role in introducing innovative construction technologies to build its transit system. Most recently, Contract Section E-5a, which included Fort Totten Station and Tunnels was constructed utilizing the New Austrian Tunneling Method (NATM) in soft ground. Along with the station and tunnels, two permanent shafts were also constructed in soft ground employing the NATM technique. This project is located within the District of Columbia on the Greenbelt Route. The subject of this paper is to discuss the unique method of construction of these two shafts, and explore the benefits of applying the NATM technique to the construction of deep shafts. The design of the shafts was performed jointly by Jenny Engineering Corporation of Springfield, New Jersey, and Mayreder Consult of Linz, Austria. The designers also provided construction support services and a resident NATM expert at the site during construction. The construction of the project started in April 1988 by a joint venture of Mergentime Corporation and H. T. Construction, a subsidiary of Hochtief Company from Germany. This $48.7 million construction project has been completed. 2. SUBSURFACE CONDITIONS The two NATM shafts are located primarily in Cretaceous-age deposits that are over 100 million years old. These deposits are intermixed and lenticular in nature

Jan 1, 1993

By B. Cavender

The operating lifetime, or production rate, selected for a mining project is among the most important factors influencing the project's design and ultimate economic success. Incorrectly-determined lifetimes can lead to the erroneous rejection of projects as uneconomic as well as the suboptimal exploitation of producing properties. This paper examines the optimal lifetime calculation using traditional discounted cash flow and recently-proposed option pricing techniques. Using each method, the production rate is determined as that rate at which the project's net present value is maximized.

Jan 1, 1993

By W. Peters, W. A. H. Poppmeier

An overview is given of the present state of traditional and new steelmaking equipment and techniques, and one of the direct steelmaking methods that are currently being developed is described. In steelmaking processes, coal is used to supplement the energy input and to reduce iron oxides in the slag. Foamy slag practice is discussed, and the most widely used types of ladle recarburizers, their properties, and manufacture are described. It is concluded that the use of carbon sources, mainly for supplementing energy and as reductants, will increase in the future, but that demands on the purity of the materials will probably become more stringent. If hydrogen were manufactured at a competitive cost, it could become an alternative fuel and reductant in the field of iron and steelmaking.

Jan 1, 1993

By Steven W. Hunt, Phillip U. Santacroce, Roger C. Ilsley

Consolidation grouting from the surface prior to mining a shaft is commonly performed to reduce groundwater inflows to a manageable rate. This paper describes the inflow reductions obtained within dolomite and limestone formations at several shafts and chambers due to grouting programs for the Milwaukee Water Pollution Abatement Program. The resulting inflow reduction factors are compared to results reported in the literature for other projects. Post-grouting pump tests are also evaluated as an aid in grouting assessment. Important considerations for estimating shaft inflows from pump test results are discussed. These considerations include loss of grouted mass during mining and influence of blasting and rock features on grouting effectiveness. This information should be helpful to design engineers and contractors who need to estimate inflows after pre-excavation consolidation grouting has been performed.

Jan 1, 1993

By Jae-Chun Lee, Kang-In Rhee, D. B. Dreisinger, Hyo-Shin Yu, G. A. Kordosky

The development of a process for direct synthesis of very pure ZnO powders from zinc-bearing waste was investigated. The zinc waste which contains 55% zinc was leached with sulfuric acid. After iron removal by hydrolysis from this zinc solution, purification through solvent extraction by the use of D2EHPA as an extractant was carried out. Then, loaded zinc in the organic solution was stripped and precipitated simultaneously using oxalic acid as a precipitant. Synthesized ZnC2O4 precursors by precipitation stripping were calcined to obtain ZnO powders exceeding 99.9% purity. The effects of sulfuric acid concentration, leaching time, and pulp density on the extraction of zinc were studied and optimum conditions for the solvent extraction were obtained through purification of the zinc solution. The size, morphology, and size distribution of synthesized ZnC204 powders were studied in terms of oxalic acid concentration, temperature, surfactant added, precipitation time, etc.

Jan 1, 1993