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By KNona C. Liddell

The ion interaction model Pitzer proposed twenty years ago is today the most widely used method for calculation of osmotic coefficients and electrolyte and single ion activity coefficients in aqueous solutions. This is due in part to the accuracy of the results that have been obtained for many concentrated electrolytes. An additional factor is that, compared to alternative activity coefficient models, there are many more parameter values available for the Pitzer equations. The important features of this model are reviewed. Published parameter values for Co, Ni, Cu, Zn and Fe are tabulated, and applications of interest in the aqueous processing of these metals are described.

Jan 1, 1993

By T. P. Meloy

Riffles on a shaking table have a major effect on particle separation. This effect is modeled in a spreadsheet.

Jan 1, 1993

The transportable moisture limit of a mineral concentrate (TML) is of great importance in the shipping of that material from Australian ports. Each year Australian mining companies incur substantial costs as a consequence of delaying shipments and/or multi-handling concentrates so as to comply with transportable moisture limits. Despite this there is a general lack of in-depth knowledge concerning factors that influence the parameter. Eight major Australian mining companies supplied sizing, specific gravity and TML data for their concentrates. Zinc, lead, copper and bulk concentrates were represented in their data. Estimated surface areas of the concentrates, as calculated from their normalised sizing data, correlated strongly with the reported transportable moisture limits. This high correlation prevailed in spite of the acknowledged limitations associated with the use of multi-sourced data and the adoption of simplistic approaches in the normalisation of sizing data and the estimation of surface area. Based on the broad range of concentrates studied, concentrate sizing data were concluded to offer potential as an alternative means of reliably estimating transportable moisture limits.

Jan 1, 1993

By Charles L. Kimbell

Tables 16 through 19 continue the series of providing the world merchant fleet distribution by type of vessel and the ranking of the major fleets by country of registry. Table 20 this year provides a summary of the world's liquid gas carrier fleet. These vessels are included in the totals given for the world's tanker fleet, but gives a breakdown demonstrating the growth of the importance of natural gas in the world's energy commodity consumption. Panama and Suez Canals Tables 21 and 22 provide the latest available information on the transit of mineral commodities through the Panama Canal, by number of vessels, direction, and the commodities transported. Although the number of vessels transiting the Panama Canal dropped slightly (0.5%) between 1989 and 1990, the total amount of cargo moved rose by 3.6% and the amount of mineral commodities moved rose by 7.2%.

Jan 1, 1993

By S. K. Kawatra

Outokumpu Electronics has designed a new on-line coal slurry ash analyzer, based on an instrument developed at Michigan Technological University. The primary goal was to build an accurate instrument at the lowest possible cost. The instrument determines ash content from measurements of X-ray backscatter, iron K, fluorescence, and low-energy y-ray absorption. It is capable of measuring the ash content with a standard error of 1.1% ash over an analysis range of 9-21% ash and 7-22% solids. The analyzer was tested on coals from United States, Poland, Great Britain and the USSR.

Jan 1, 1993

By Brij M. Moudgil

Lack of understanding the major process parameters and inadequate scale-up factors have led to the belief that fundamental knowledge is not important for successful flotation plant operations. Flotation of simple and easy to process ores may not require a strong fundamental knowledge base for day to day operations. However, as low grade complex ores are mined and process control is integrated into flotation schemes, it is imperative for a plant operator to acquire a strong background in the basics of the flotation process at hand and/or have access to such a knowledge base at short notice. In order to meet the challenges of unexpected changes in the feed, reagent quality, water chemistry, physical, mechanical and hydrodynamic conditions, the flotation plant superintendent/chief metallurgist must have a strong background in the flotation fundamentals.

Jan 1, 1993

By Philip W. Holland

The U.S. Bureau of Mines has designed and built an inexpensive, weatherproof, temperature-controlled cabinet to provide temporary housing for analytical instrumentation. The cabinet consists of an inverted Styrofoam ice chest, an electric fan for air circulation, and a proportional temperature controller equipped with a thermistor sensor and a light bulb as the heater. The cabinet provides a constant-temperature environment for a moisture analyzer and a strip chart recorder when outside temperatures range from -SO to 21° c.

Jan 1, 1993

By G. H. Hope, D. Green

"Recent process advances at Lac Minerals Est Malartic Division are discussed. The Est Malartic mill treats massive sulphide, copper/gold ore from the Bousquet 2 mine, to produce a gravity gold product, a copper flotation concentrate and a gold precipitate. The mill operation has been improved by the application of Knelson concentrators to replace jigs, the application of Outukumpu high grade tank cells and optimizing the cyanide leach to minimize cyanide consumption.IntroductionThe Est Malartic mill is located near the town of Malartic in the Abitibi Region of north western Quebec. The mill has been in production since the mid- J 930's processing mainly clean, free milling gold ore. Active mining from the Est Malartic mine ceased in 1980 and the mill was switched to custom processing of ore from La Mine Doyon located some 45 km to the west. This custom processing arrangement continued until 1987 when the expanded mill at Doyon became available to process all of the Doyon production. In 1987, Lac Minerals commenced development of a second mine at the Bousquet site located 40 km west of Malartic. This mine, Bousquet 2, is the down dip extension of the La Ronde mine developed by Agnico Eagle. During pre-feasibility evaluations, it was determined that modification of the Est Malartic mill to handle this new ore source was economically more attractive than building a new facility on site. Modifications to the mill to process the high copper/gold ore from the Bousquet 2 mine began in late 1989 and the new circuits were commissioned in mid-1990. Modifications included the addition of both gravity and flotation concentration circuits to recover coarse, free gold and the copper. The existing leach circuit continued operating on the copper flotation tailings with some minor modifications to the solution handling systems. An SO,/air cyanide destruction circuit was also added at this time."

Jan 1, 1993

By Dennis R. Dolinar

The U.S. Bureau of Mines has modeled yield pillars to determine the effects of reinforcement techniques on pillar performance. Model pillars with width-to-height (w/h) ratios ranging from one to four were reinforced using advanced lateral support systems. To evaluate reinforcement and pillar performance, the model pillars were strained up to 18.6 pct in compression. The results show that the reinforcement had a significant effect on the postfailure characteristics of the pillar but had only a small effect on it's maximum failure strength. Pillar residual strengths increased up to 10 times, while the energy capacity increased by a factor of three depending on the reinforcement method. At maximum deformation, the residual strengths of several types of reinforced specimens exceeded the maximum compressive strength up to 2.5 times and resulted in an increasing positive postfailure stiffness. Test results, data analysis, and application of the results to underground mining are discussed.

Jan 1, 1993

By Ghiani M, Satta F, Zucca A, Peretti R

After a brief introduction on the principles of contact electrification and a synthetic illustration of the Turbocharger separator, the successful results obtained with different raw materials are given and discussed, with particular reference to a North African run-of-mine with carbonate gangue, a crude ore from India containing pyrite and a mineral sample from Angola having quartzeous gangue. The pre-eminent effect of target surface temperature in the charging device of the separator is emphasised. On the basis of the results of both batch experiments and long-run tests the prospects of industrial application appear very interesting both from the technical and economic points of view, even when compared with froth flotation.

Jan 1, 1993

By S. Behl

In the selective flocculation process, polymers with specific functional groups can yield highly selective adsorption and, therefore, high separation efficiency. Selectivity in polymer adsorption may also be attained by specific additives that inhibit the adsorption of the flocculant on some solid surfaces but not on others. Generally, these additives have a different chemical nature than the flocculant. In this study, the lower molecular weight fraction of the flocculant was successfully evaluated as a site blocking agent, leading to higher separation efficiency than obtained otherwise.

Jan 1, 1993

By D. B. Dreisinger, H. J. Sohn, J. S. Sohn, G. A. Kordosky

The transport of lithium through a supported liquid membrane was studied with a mixture of D2EHPA and TBP in kerosene as a mobile carrier. In the flat- sheet supported liquid membrane(SLM) system, experiments were carried out to investigate the effects of concentration of mobile carriers in the membrane solution, hydrogen ion in the feed solution, and temperature on the transport of lithium. Experimental results agreed well with a transport model for permeating lithium across the liquid membrane. The permeation rates of lithium can be explained in terms of diffusion of a Li-complex through the membrane phase. For a practical application of an SLM method, a hollow fiber module has been used and lithium can be concentrated more than three times in 24 hours.

Jan 1, 1993

By I. M. Wolf, S. A. Usmar, L. A. Cornish

The limiting criterion in the use of stainless steel for certain forming operations such as coining is its hardness, which determines parameters such as required striking pressure, wear on dies, and integrity of pattern detail. Attention is given here to the development of ultra-soft ferritic stainless steels for coinage. In the first instance, the influence of carbon content on the striking properties of a series of commercial and experimental 17%Cr alloys was evaluated. It was found that a lower carbon content permitted the striking of relatively highly profiled and intricate patterns, provided that the hardness did not exceed 125 HV. Hardnesses as low as 115 HV were achieved in the fully annealed condition, but these alloys required high striking pressures. In a further study, three grades of experimental 14%Cr ferritic stainless steels were produced with a view to optimizing the ductility. When the residual impurities were minimized, hardness values of about 100 HV and lower were achieved. Micro-alloying additions allowed the heat-treatment response and grain size to be controlled. Excellent tensile properties, with elongations of up to 42 per cent, were achieved in the fuly annealed condition, and highly profiled patterns were produced in coining trials.

Jan 1, 1993

By Anthony Delvescovo, Gregory F. Aluce, Joseph A. Sopko, Lyle C. Smith

Construction of a 13m shaft through approximately 100m of water bearing soils and another 100m of bedrock was attempted using the Slurry Diaphragm Wall Method with a combination of deep dewatering wells. During excavation within the slurry wall, unexpected groundwater inflows occurred in a structure of loose silty sands. Artificial ground freezing was selected as a remedial method to seal the leaking slurry wall, and as a primary excavation support and groundwater control method for the 30m of overburden material below the base of the wall. Design of the ground freezing system required analysis of both the structural requirements of the unsupported soil, the frost effects against the existing slurry wall and the groundwater control in the area of the breech in the wall. These design procedures are summarized, and construction and excavation techniques and corresponding schedules compared in this paper. Advanced drilling techniques, ground freezing quality control and general contractor procedures for efficient shaft construction are discussed.

Jan 1, 1993

By Po-Wei Tun, Kuen-Yuh Wu, Tso-Min Shih, Hsi-Chiang Fang

The purpose of this study is to investgate the coal dust explosion characteristics and to search for the prevention methods of the coal dust explosion as well as the propagation of the explosion flame of the middle-bearing coal formation in Taiwan by an open type coal dust explosion apparatus in laboratory. The coal samples were taken from the typical middle-bearing formations of the Sam-Ming,Tai-Ho and Lee-Fong coal mines The rock dusts, the free water mixture with coal dust samples and the interval clean out the coal dust in the testing chambers were applied for preventing the coal dust explosion and the propagation of the explosion flame.

Jan 1, 1993

By George Kazonich

The high costs and environmental problems associated with making iron and steel in the United States is driving the development of new technologies to replace the blast furnace. A prototype reactor incorporating rocket technology was designed and built. This rapid rate reactor was operated successfully and consistently made iron metal. Minus 325-mesh magnetite particles could be reduced to iron metal in less than 50 ms in a high temperature flow through reactor. Iron product was recovered inside the reactor and in a downstream cyclonic separator. The results of typical operation and how parametric changes affected the reduction of iron ore concentrates are discussed.

Jan 1, 1993

By J. A. Brierley, C. L. Brierley, R. C. II Blake, S. McGinness

A principal long-term goal of this laboratory is to achieve a detailed understanding at the molecular level of the microbial-dependent solubilization of minerals. Three recent advances in this research are summarized. (i) An in situ electrolytic procedure is described whereby large quantities of autotrophic iron-oxidizing organisms may be achieved for fundamental or applied studies. Over 600 grams wet weight of Thiobacillus ferrooxidans were harvested from a single 55-gallon growth vessel. (ii) A basis is presented for classifying some 70 different iron-oxidizing bacteria into one of 4 categories, depending on the type of redox-active electron transport proteins expressed during aerobic respiration on reduced iron. Comparative spectroscopic analyses indicated that different electron transport mechanisms exist in different genera and species of acidophilic bacteria that respire on iron. (iii) A method is introduced to investigate the binding interaction between bacteria and minerals, based on changes in the electrokinetic properties of the two species. Preliminary experiments indicated that the electrophoretic mobilities of pyrite and Thiobacillus ferrooxidans were both altered when the two colloid particles were mixed prior to the actual electrokinetic measurement. The need for more basic information regarding all aspects of the microbial-dependent solubilization of minerals is evident.

Jan 1, 1993

By Matthew J. DeMarco

Research personnel at the U.S. Bureau of Mines have conducted longwall gate stability studies at four western U.S. mines attempting to employ yield pillars for improved ground conditions. Located in the Book Cliffs and Wasatch Plateau coalfields of north-central Utah, these operations are generally characterized by multiple-seam mining, cover depths averaging 450 - 600 m (1,500 - 2,000 fl), occasionally extending beyond 760 m (2,500 ft), abrupt cover depth variation due to the overlying canyon/mesa topography, and massive, rigid sandstone roof units. Such conditions encourage severe gate and panel coal bumping, as well as various types of roof instabilities and occasional floor-heave problems. To alleviate these adverse conditions, several mines have employed yield pillars to-reduce hazard-inducing excessive gateroad stress concentrations. This paper describes the evolution of gateroad designs at four of these operations, the specific mining conditions involved, and the general stability performance attained by using yielding gate systems. Mine experiences are "compared" in terms of basic setting conditions, and the general concepts of yielding system applicability and success potential are summarized.

Jan 1, 1993

By Peter N. Gabby

In 1992, the Bureau of Mines conducted a mineral resource investigation of the 27,034-hectare Steel Mountain/Yuba River study area and the 16,544-hectare Breadwinner study area. There were approximately 535 lode and placer claims in or partially in the Steel Mountain/Yuba River study area, and 84 lode and placer claims in or partially in the Breadwinner study area. In the Atlanta and Rocky Bar mining districts, both adjacent to and in the Steel Mountain/Yuba River study area, 30,232.4 kg (972,000 02) of gold and 62,838.3 kg (2,020,000 02) of silver had been produced. Most of this production came from outside the study area. Placer properties adjacent to (and a few in) the Breadwinner study area had production of 93.1 kg (2,992 oz) of gold and 20.0 kg (642 02) of silver. Twelve properties in the Steel Mountain/Yuba River study area have potential for resources; eleven have alteration and/or mineralization similar to that found at Atlanta with potential for gold, silver, and tungsten resources, and one has alteration and mineralization associated with polymetallic vein type deposits with potential for gold, silver, copper, lead, zinc, and tungsten resources. Adjacent to the study area, large bars of gold-bearing gravel can be found along the Middle Fork Boise River. Four properties in the Breadwinner study area have potential for mineral resources; one has alteration and mineralization associated with skarn, polymetallic vein, and, possibly, copper-molybdenum and molybdenum porphyry types of deposits; two have alteration and metal assays associated with polymetallic vein, and possibly copper-molybdenum and molybdenum porphyry types of deposits; and one has alteration and mineralization similar to that found at Atlanta. These four have potential for gold, silver, copper, lead, zinc, molybdenum, and tungsten resources Adjacent to and extending into the Breadwinner study area are large bars of gold-bearing gravel along North and Middle Forks Boise River.

Jan 1, 1993

By R. E. Molnar, P. A. Riveros, V. M. McNamara

"This paper describes some recent research done at CANMET in the areas of ion exchange and A VR (Acidification- Volatilization Reneutralization), as applied to the recovery of gold and cyanide, respectively. It also discusses the ways in which these two technologies may be combined in order to minimize the environmental impact of gold milling operations and optimize reagent usage. IntroductionGold milling operations can essentially be divided into those that carry out a liquid/solid separation after leaching and those that recover gold directly from a leach pulp. The former produce a barren solution which may contain considerable amounts of cyanide, either free or cornplexed with metals. The latter produce a similar solution but this is now part of a slurry rather than a clear stream. Due to its toxicity, any excess cyanide must be destroyed before the effluent is discharged into the environment. Ideally, this should be (and sometimes is) accomplished by natural degradation. However, in many cases natural degradation alone cannot remove the last traces of rnetallocyanide compounds from the effluent and , as a result, most Canadian gold producers utilize a supplementary chemical oxidation system. This not only increases the operating costs, but concerns have also arisen in recent years about the formation of ammonia as a result of the chemical oxidation of cyanide (via CN--CNO--HCNO-NH3) ·"

Jan 1, 1993