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By J. J. Moore, B. Mishra, D. L. Olson

The production of radioactive and reactive metals, such as plutonium, uses various pyrometallurgical techniques that generate significant quantities of waste salts contaminated with hazardous, reactive or radioactive materials. Health concerns, environmental regulations and economic considerations require proper mitigation processes to recover the valuable components and for recycling or unrestricted release of these salts. The Oxygen Sparging Process converts soluble metal halides, such as chromium-, plutonium-, cerium chlorides, into insoluble oxides and/or oxychlorides which can be consolidated and separated for long-term storage or further processing. The matrix salt phase, viz. calcium and/or alkali chlorides, are clean after oxygen sparging and fit for recycling. This method has been described and its optimized parameters discussed to show that RCRA regulated elements, such as, chromium, lead, cadmium, etc. report to the consolidated phase making the salt recyclable. Salt Scrub Reduction Process for the recovery of radioactive and RCRA metals from the waste salts has been developed. The process uses a Ca-Ga intermetallic alloy which recovers over 98 percent of the reactive metals. The matrix salt phase in this process, viz. calcium or alkali metal chlorides, are clean after salt scrub reduction.

Jan 1, 1995

By Jinrong (Patrick) Mang

Three of the most challenging problems in phosphate beneficiation are discussed: flotation efficiency, resource conservation and environmental impact. Some new flotation machines offer the opportunity of reducing power and reagent consumption significantly, while increasing specific capacity many fold. Efficiency might also be improved dramatically by replacing the "double float" process with a single-collector scheme. Model based software control is a powerful tool for improving overall plant efficiency. Recovery of phosphate values from the phosphatic clays could extend phosphorus reserve life significantly. phosphate recovery from the slimes might be achieved by sizing-flotation, selective flocculation and bioleaching. Reducing the volume of phosphatic clays produced is another key stop to minimizing phoephate logs. Such a reduction may be realized by floating at finer cut size. Although an ideal' dolomite separation process is yet to be developed, a cationic flotation process may prove to 'be economically feasible. Loss of phosphate in the desliming stage is the major problem with most of the flotation schemes for removing dolomite.

Jan 1, 1995

By Dao De Xu, Heechan Cho, Mark S. Klima

A study was conducted to determine the feasibility of using dense-medium centrifugation for separating fine (-150 µm) coal. A centrifuge provides the capability of varying the rotational speed and retention time independently, which offers the potential for a higher degree of control as compared to a dense-medium cyclone. Tests were conducted with a 140-mm diameter by 76-mm long Plexiglas separator, which was fitted with appropriate feed and discharge pipes to allow continuous separations to be made. A suspension of ultrafine (-10 µm) magnetite and water was used as the dense medium. The effects of operating conditions, including the magnitude of the 'g"-force and retention time, on centrifuge performance were investigated.

Jan 1, 1995

By C. K. Nworu, L. O. Asuquo, C. O. Nebo

Selective flocculation studies of Agbaja iron ore with starch-type and nonionic polyacrylamide-type flocculants has been conducted to determine the effect of flocculant type. The results indicate that corn starch was slightly better than cassava starch in selectivity performance. Cassava starch was in turn better than Superfloc 16, while the poorest results were obtained with commercial starch. Sodium humate shows better dispersive capability, and thus enhanced flocculation results, than sodium silicate. Pulp pH affects the zeta potential, polymer chain configuration and hence selective flocculation. Overall results indicate that recovery and separation of this very fine grained iron oxide by selective flocculation is feasible.

Jan 1, 1995

By Rosenblatt M, Gilroy J. A C Cunningham C V B

Vaal Reefs Exploration and Mining Company Limited operates one of the largest producing gold mines in the world. The annual production of 76 tons of gold from 12 million tons of ore treated is obtained mainly from underground sources. Daily some 6.6 km of stope face is blasted and 41 tons of explosives is used to break the rock. The mine employs 45 000 men of whom 35 000 work underground. The company operates nine large vertical shaft systems of which seven extend more than 2000 m below surface and an eighth, currently being sunk, will bottom at 3700 m below surface.

Jan 1, 1995

By P. E. Richardson, N. P. Finkelstein, Z. Chen

The large band gap and insulating properties of sphalerite have limited the application of standard electrochemical techniques for studying its reactions with flotation reagents. This problem has been overcome by developing electrodes that rely on the surface conductance produced when sphalerite is activated with copper or other heavy metals. A brief exposure of the mineral in copper sulfate solutions results in electrodes that exhibit significant electrochemical activity characteristic of copper sulfides. Voltammetry studies conducted on sphalerite activated in 10-4 M CuS04, solutions at pH 4.6 provide information on both the amount and the nature of the activation product(s). It is shown that copper activation is strongly dependent on the electrochemical potential applied during activation. Activation at potentials increasingly negative of the rest potential causes a progressive increase in the amount of copper on the surface; activation at potentials positive of the rest potential decreases the amount of copper on the surface. The results indicate that both the kinetics of copper uptake and, possibly, the chemical composition (stoichiometry) of the activation product are controlled by the electrochemical potential.

Jan 1, 1995

By Serge Lavoie

Alcan's Guillaume-Tremblay plant, located in Jonquiere, Quebec, has been in operation since 1990. This was the first plasma dross processing plant ever built. In addition to the use of the plasma heating technology, Guillaume-Tremblay has other unique features making it a modern and efficient dross processing facility. This paper presents a general overview of the practical experience at the Guillaume-Tremblay plant. In particular, the utilization of plasma heating in industrial conditions, the metallurgical performance, the unique dross handling system, the control and information management system and the reclaiming of the by-products will be discussed. Finally, the use of the plasma process for salty dross will be addressed' briefly.

Jan 1, 1995

By T P. Fischer, S N. Williams, N C. Sturchio

Chemical and isotopic analyses of fumarole gases from Galeras Volcano, Colombia provide significant insights into the origin of volatile components in the magma. Water comprises a mixture of magmatic (rock-equilibrated at high temperature) and meteoric, with the relative proportions varying through time. Carbon isotopes are most consistent with a mantle source, although other contributions to the system cannot be ruled out. Nitrogen most likely originated from organic matter in subducted oceanic sediments. All of these 'primary' components have been modified somewhat by interaction or exchange with other reservoirs during ascent to the surface. In addition to information on the origin of the gases, these data show significant temporal variations precursory to eruptive events. Chemical ratios change and water becomes more meteoric in character prior to eruptions.

Jan 1, 1995

By Tukkimies M

During the late-1980s crawler-mounted crusher units established their position in the aggregates industry. Between 1986 and 1994 about 700 units were delivered to customers all over the world for surface operations, mainly in Scandinavia and central Europe. The crawler-mounted units are popular among smaller crushing operators because they are versatile and easy to move between sites. In large quarries the greatest benefit is obtained by combining a primary crawler-mounted crusher unit with mobile belt conveyors which eliminates the need for costly haulage by dump truck. Savings of up to 40 per cent in production costs prior to secondary crushing have been achieved. Today the environmental aspect in quarrying is assuming ever greater importance. Besides being costly the dump trucks are also the major source of dust and exhaust fumes within a quarry. A complete face crushing system consisting of a crawler-mounted crusher unit and mobile belt conveyors can be electrically driven and can be equipped with dust encapsulation and dust collectors. A mobile crushing unit is not a new idea. From the mid-1950s onwards the mobile and self-propelled units have been built equipped with crawlers, tyres or walking mechanisms, with weights usually of 500-1000 t. Due to their massive size these unit are not mobile in the same way as the today's mobile units. It is not feasible to move them more than a few times a year unlike today's fully mobile units which are often relocated once an hour. This means that the massive units can not continuously follow the production face and their loading always requires a certain amount of haulage. Today the mining industry is facing new challenges. With low mineral prices and high labour costs, increasing productivity is essential for survival. New standards are also being set for the labour safety and the environment. Large research programs have been launched to meet these challenges. However, technology which can partly solve these problems already exist and is only waiting to be introduced into underground applications as well - the mobile crushing unit followed by belt conveying. As in surface operations the elimination of truck haulage also brings considerable savings in operating costs in underground mines and reduces the amount of dust and exhaust gases generated. An additional benefit especially in underground applications is improved safety. In an underground mine most accidents are caused by moving vehicles.

Jan 1, 1995

By Brian Flintoff

Basic process control is an integral part of most mineral processing plants. It is widely acknowledged to have helped many operations reduce costs and increase productivity and performance. The research community is very active in the development and evaluation of both model based and Al techniques for advanced control applications. Vendors and specialist consulting or engineering firms are in business to help deliver these solutions to the plant floor. It would seem that there is a good balance between business needs and technology, and that the industry should be moving steadily forward in an aggressive pursuit of plant-wide automation. However on closer examination one sees some systemic problems which are sewing to inhibit progress. One of the mist obvious manifestations is the gap which exists between the available technology and current This paper explores the control of mineral processing systems, with a particular emphasis on some of these problem areas.

Jan 1, 1995

By Richard A. Williams

The design, modelling and simulation of solid-liquid mixers remains one of the least advanced aspects of minerals processing, due to difficulties in quantifying complex slurry hydrodynamics from first principles, and in acquiring reliable experimental data for model verification and development. This contribution describes the application of electrical resistance tomography (ERT) for three dimensional imaging of the concentration of mineral particulates in a slurry mixer as a function of key process variables (particle size, impeller type, agitation speed). It is demonstrated how ERT can provide a wealth of detailed data to allow model development, which ultimately will lead to much improved design capabilities and the generation of mixing models which could reside within Particle Process Simulators. This principle is illustrated using descriptions of mixer behaviour based on an empirical approach, although the measurement methodology described is equally suited to development of computational fluid dynamics models, cellular models or design approaches based on artificial intelligence. The experimental data can be built into a visualisation data bank, which acts as a "process toolkit" by allowing a library of process responses to be catalogued. Hence these data can be accessed for the purposes of model development, equipment selection, optimisation of operating conditions or testing on-line control strategies.

Jan 1, 1995

By Bragg R, McMahon B, Lenton R

In 1992 environmental audits were carried out at seven coal mines operated by Oakbridge Limited in the Hunter Valley and Lithgow areas of NSW. The audit reports recommended a course of action designed to improve the environmental management system already in operation at the mines. This program started with training in environmental awareness for the Board of Directors, and the development and authorisation of an environmental policy. On-going programs at each mine were expanded to include environmental awareness training for all 2000 employees at the mines, and the development of a 20-module environmental training program which included air, water, soil and noise management, oil and chemical handling, sampling and monitoring, rehabilitation techniques and many more. Environmental incident reporting was introduced, and a system of reporting from the coal face through individual mine site environmental committees, to a Corporate Environmental Committee and up to the Board Environmental Committee became an effective part of a due diligence program. The Board resolved to undertake external independent environmental audits every two years, with internal reviews in the alternate years. An Environmental Management Group was formed, consisting of four internal environmental personnel and Oakbridge's appointed environmental consultant, to effectively resolve many of the environmental issues facing the Group. This program is continuing to evolve as an industry leader in environmental management Practice.

Jan 1, 1995

By Anthony J. Peach

With the new generation of so called "Super TBM", we would all expect to witness the implied super-performance. In some instances this is occurring, but one must ask why is it not occurring in the majority of applications? For hard rock TBM related projects, we are observing a decrease in the volume of projects in the previously traditional areas such as North America and Western Europe and an increase in Asia (Hong Kong, Indonesia, China, Korea etc). As a consequence less experienced contractors are acquiring the latest ultra high power equipment, without the knowledge necessary to achieve optimum performance. The interdependence of TBM and muck removal systems has been assessed with emphasis on the emergence of the continuously extending conveyor technology, as a means of achieving dramatic productivity increases. The Australian system assessed here at the time of drafting this paper holds the world record tunnel excavation production of 2,166 metres. A little considered aspect of the adoption of conveyors is the associated improvement in safety.

Jan 1, 1995

By Krystyna Raszka, Jerzy Iskra

The paper presents results of spectrophotometric investigations concerning the adsorption of sodium oleate on silicon carbide in the presence of the cations of multivalent metals, applying the ATR IR technique with computer-aidedprocessing of the spectrum. The analysis of these spectra indicates the occurance of distinct OH and COOH bands in the pH range in which the hydroxy complexes of metals of the type MeOH+ and MeOH++ reach in the respective cases the highest concentration in the solution. The correlation of these results with those of flotation, measurements of the zeta potential confirms the proposed mechanism of activation of the flotation of silicon carbide, applying sodium oleate as a collector, the collection taking place over the adsorption of hydroxy complexes of the type MeOH+ and MeOH++

Jan 1, 1995

By P. J. Brown, R. W. Nice

The Thalanga Copper-Lead-Zinc Concentrator in Northern Queensland was commissioned in early 1990. The design of a flotation process for the sequential production of separate copper, lead, and zinc concentrates has always been a most formidable mineral processing challenge. In 1988-1989 during the process design phase, sized fractions of various samples were subjected to quantitative and qualitative mineral analyses. These analytical techniques are collectively known as modal analysis. Modal analysis aided in the selection of key process treatment parameters for the initial laboratory testwork on the Thalanga ore. The work also guided the flowsheet development and quantified the mineralogically imposed limitations on the separation process. This paper describes in general terms how these modal techniques were used to guide the program of laboratory flotation testwork which constituted the flowsheet design phase of this project. During these design studies, the primary grind and regrind requirements were deduced and the basic flowsheet configuration selected. Recent operating plant performance data are to illustrate the value of modal methods in addressing complex metallurgical separation problems.

Jan 1, 1995

By Jim Truman

Appalachian coal mines include operations in eastern Kentucky, Maryland, Pennsylvania, Virginia and West Virginia. During 1994, they produced a total of about 342.5 Mt (377.6 million st) of bituminous coal. This figure represents 37% of the total production from the United States. This region contains nearly all of the nation's coking coal reserves and high-quality compliance steam coal that will be in demand after the turn of the century as utilities comply with phase two of the 1990 Clean Air Act Amendment. Figure 1 shows the location of the study area and the general regions that supply various coal types. Data for the study reviewed here were compiled and interpreted from Mine Safety and Health Administration (MSHA) production reports, Federal Energy Regulatory Commission 423 reports, King's Export database and additional data from the US Department of Energy's (DOE) Energy Information Administration (EIA). Table I is an overview of the total production from Appalachia and the delivered tonnage to various sales categories.

Jan 1, 1995

The epizonal Ag-Pb-Zn vein deposit at San Bartolome is characterised by a base-metal sulphide assemblage containing the spectacular development of interpenetrating, bladed networks of pyrrhotite which have been replaced by marcasite and pyrite. A similar assemblage displaying the same crystal habits and textures are also a diagnostic feature of the Sn and Sn- Ag deposits of Bolivia. On this basis, it is reasonable to conclude that both deposits were formed from fluids of similar nature and origin. Although no economic accumulation of Sn is known in San Bartolomr, further comparison of the geologic setting, age, mineralogy, fluid inclusion data and magmatic association of this deposit with the Bolivian systems has highlighted additional similarities consistent with a hypothesis that more extensive Sn mineralisation might exist in the San Bartolomd area.

Jan 1, 1995

By Gregor Mori

Niobium electrolysis has been performed in a NaCl-KCl-NaF-NbCls electrolyte. By means of electrolytic .refining the average valency of the niobium ions was determined as well as the crystallization behaviour. In electrowinning runs the influence of the main parameters such as temperature, RF (mole ratio F/Nb), chemical prereduction, niobium content of the melt and current density has been determined with respect to low specific energy consumption and high purity of the deposit.

Jan 1, 1995

By James J. Gusek

Passive-treatment systems that mitigate acid-rock drainage (ARD) from coal mines have operating since the mid-1980s. Large systems at metal mines are being contemplated. A 95L/sec (1500-gpm) capacity system is planned this year at an underground lead mine in Missouri. Mine, process and environmental managers need to understand how and why passive-treatment systems work. They must understand what operational limitations to expect, as well as the economics of construction and operation compared to the alternatives, like lime precipitation. Wetlands have been recognized as nature's method of improving water quality. Contaminant reductions can occur through the precipitation of metal hydroxides, sulfides and carbonates and pH adjustments. Local conditions, oxidation state and water and soil chemistries dictate whether these natural reactions will occur under oxidizing (aerobic) or reducing (anaerobic) conditions.

Jan 1, 1995

By E. Topuz, M. J. McPherson, J. Banik

This paper summarizes the analyses of ventilation layouts for mines that experience both spontaneous combustion. The major focus is placed on the longwall coal mine layouts used in several countries. Each of the different layouts is modeled in the form of a ventilation network. The gob of a longwall panel is the most critical location for the occurrence of spontaneous combustion. Airflow leakage paths inside the gob are simulated by using a simplified grid-like network. Computer simulations with this model indicates that the W-system of ventilation is most effective in minimizing air leakage into the gob. Homer, the U-system of ventilation, with pressure balancing behind the face support line, is also found promising for longwall panels. The magnitude of air leakage into the gob is observed to change with the advance or retreat of bee, thus requiring appropriate balancing of pressure to maintain the leakage at a minimum.

Jan 1, 1995