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By John A. Mavrogenes

The Texaco gasification system developed at the Monte Bello pilot plant efficiently bums petroleum-coke thereby producing syn-gas and electricity. This system produces more electricity than conventional burners, yet the only by-products are pharmaceutical grade sulfur and V -rich slag. Vanadium is known to exist in multiple valence states in compounds which possess a wide range of melting points and physical properties. Consequently, it becomes important to carefully regulate oxygen fugacity throughout the system in order to control vanadium valence state. Vanadium phase equilibria is presently poorly understood, in large part because of the multiple oxidation states of vanadium (-I, 0, +2, +3, +4, and +5) and the difficulty of unequivocally identifying the valence state(s) in many compounds. The operation of these gasifiers at approximately 1400°C is well above the melting point of V20S but considerably below the melting temperature of V02 and V 203. If J02 can be regulated to keep the burner within the V 205 field, slag material would more likely remain molten and more easily flow out of the bottom of the burner. In pure V oxides. the oxidation state is readily determined by microprobe analysis. where V20S (V+5) is 56% V, V02 (V+4) is 61.4% V, and V203 (V+3) is 68% V. However, V valence in multi-element phases (especially phases containing other elements of variable valence) cannot be resolved by microprobe analysis alone. Petroleum-coke gasification slags collected from within the gasifier under different oxidation conditions were studied by electron microprobe analysis (EMPA). X-ray diffraction (XRD). X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. Raman spectrometry in conjunction with microprobe analysis was found to resolve the valence of vanadium in the phases of these slags. Raman spectra collected from homogeneous single phase V-oxide standards in vacuum at low temperatures (-150°C) yielded peaks characteristic to each valence state. Gasifier slag samples are, however, much more complicated. Oxidized samples contain: fine grained (Ca. Mg, Fe. V) oxide matrix of variable composition, (Fe. V, Ni) spinel. (Fe, AI, V, Ni, Mg) spinel, V205laths, AI-Si glass blebs and Ni sulfides. Reduced samples contain: crystalline Ca-siIicate matrix, subhedral to euhedral (V, Fe, Mg, AI) spinel, subhedral V02, Fe and Fe-Ni sulfides, Fe-Ni alloys, and complex Ca-oxide matrix. The different spinel assemblages, the characteristic V-oxides and the distinctly different character of the matrices makes the oxidized and reduced slags readily discernible.

Jan 1, 1995

By G J. Corbett, T M. Leach

Although hosted within an Ordovician magmatic arc, the Peak Hill high sulphidation system displays features typical of youngerPacific Rim high sulphidation epithermal gold deposits. Regional NW trending transfer structures are inferred to localise the magmatic source at their intersection of the NS trending arc. Fluids have migrated from the magmatic source along NW structures and thence exploited permeable horizons, which have become silicified. Alteration displays typical zonation from silicification through assemblages characterised by alunite, pyrophyllite and kaolinite and is followed by breccia/fracture controlled sulphide and gold deposition. Sinistral rotation on the NS arc has dilated NW trending fractures to produce the WNW to EW dilational fractures which host the higher grade ore. Mineral assemblages are typical of formation distal to the magmatic source in an epithermal environment. The combination of alteration and mineralisation zonation with structure provide fluid vectors which target a magmatic source to the SE of Peak Hill.

Jan 1, 1995

By A. J. Hyett, N. Hedrick, J. Blackall

The Garford bulb anchor is a modified cable geometry developed and patented by Garford Ply Ltd. of Australia, and which has recently become widely available in Canada. It is produced by deforming the seven wires (including the central kingwire) of a standard cable into a bulb" (Fig. 1). Laboratory cable pull tests indicate that the bond capacity of the 25 mm Garford bulb anchor is comparable to the nutcase cable, in excess of the birdcage cable, and significantly higher than standard 7-wire strand. Its comparative advantage over the latter is most significant for tests at low radial confinement and high water:cement ratio grout, which corresponds to operational conditions of low quality rock (i.e. weak, highly fractured rock masses, foliated hanging walls, failed ground, etc.) and poor installation quality control (perhaps the most common explanation for cable bolt failures). It is under such conditions that cable bolting is often ineffective. The most impressive result is that for a reduction of the effective rock mass modulus by a factor of five, the Garford bulb cable capacity remains virtually unchanged.

Jan 1, 1995

By Robert Rautenberg, Ted Budd

The paper will discuss the successful construction of the largest dollar value ($194.5 million, U.S.) TARP (Tunnel and Reservoir Plan) project built to date for the Metropolitan Water Reclamation District of Greater Chicago. The mining and lining of the 18.5km (11.54 miles) tunnels will be emphasized. The tunnels were driven utilizing three TBMs ranging in size from 9.85m (32.33 ft) to 3.70m (12.16 ft) in diameter. The operations surrounding the 11,546m (37,876 ft) long 9.85m (32.33 ft) diameter tunnel will be highlighted. A total system concept was utilized to attain mining rates up to 29.3m (96 ft) per shift and lining productions of 58.5m (192 ft) per day. The reliability of these systems was instrumental in the completion of the project more than a year ahead of schedule.

Jan 1, 1995

By George P. Jr Schivley

Data is presented showing Penetration Rate (PR) versus Force-on-the Bit (FB) and Bit Angular Speed (N). Using this data, it is shown how FB and N each uniquely contribute to the PR for any particular drilling situation. This data represents many mining situations; including coal, copper, gold, iron ore and limestone quarrying. The important relationship between Penetration per Revolution (P/R) and the height of the cutting elements of the bit (CH) is discussed. Drill performance is then reviewed, considering the effect of FB and N on bit life. All this leads to recommendations for the operating values of FB and N for drilling situations where the rock is not highly abrasive and bit replacements are because of catastrophic failure of the bit cone bearings.

Jan 1, 1995

By Robin J. Batterham, Stephen H. Algie

It is often stated that innovation is central to the economic survival of mining and mineral processing in the face of global competition, and yet technology is often far from a core strategy in our industry - hence the concerns that are often voiced about the apparent slow rate at which new technology is applied. Much of the discussion stems from a lack of understanding of the role of technology in innovation, and of the role of R&D within the innovation process. To a large extent this has all been said, however, the messages are clear and deserve repetition. This paper expresses the personal views of the authors, based on experience in government-funded (CSIRO and universities) research, and in CRA Ltd, a large mining and mineral processing company. Further than this, it explains how our own development unit within the CRA Group has come to see its key roles as including the transfer of technology, and the training of technologists to move into the operating business units. We conclude that these critical tasks are the keys to creating the environment that will allow us to maximise the contribution of technology.

Jan 1, 1995

By P. R. A. Andrews

"Garnet occurs in schists and gneisses in all provinces of Canada, all mainly in Quebec and Ontario. There is currently a renewed interest in exploration for economic sources of garnet for abrasive applications because of the inherent dangers from exposure to ground silica from sandblasting operations.High-quality garnet is used for lapping and grinding of glass and ceramics; for coated and bonded products such as sandpaper and cloth; and abrasive wheels for grinding and finishing various metals, woods, rubber and plastics. Low-quality garnet is used for cleaning and conditioning aluminum and other soft mewls, particularly by aircraft manufactures. Garnet may be added to grouting cements for oil-well drilling applications, and it has also been used for low- to medium-level radiation shielding. Garnet has been studied extensively by CANMET and its predecessor, Mines Branch, between 1917 and 1990. Twenty-nine studies relating 10 various aspects of beneficiation are presented and a review of the more important studies is presented. The information includes mineralogy, beneficiation methods, product sizes and analyses."

Jan 1, 1995

By P. I. Prescott

Ground calcium carbonate (GCC) is used in the paper, plastics, paint, rubber, caulks, and sealants industries. The favorable properties of GCC include high whiteness and brightness, low hardness, and outstanding rheology in water systems. The quality of calcitic GCC ores, which include chalk, limestone, and marble, is dependent on calcite purity and the nature and quantity of ancillary minerals. Wet and dry grinding is used in the manufacture of GCC. Ore processed by optical sorting, flotation, and/or particle size classification has higher brightness and lower abrasion. GCC markets are a function of the product's properties, purity, and cost.

Jan 1, 1995

Production scheduling is an important element of the mine planning process. The production schedule specifies the quantities of mineral to extract, the source of this ore, the timing of extraction and, where necessary, the quantity and timing of backfill placement. These details are important in linking long-term strategic goals to short-term operational planning. Mine scheduling techniques form the basis for communicating information concerning the overall impact of design and planning changes to a wide range of people at many levels within an organisation. Consequently the techniques used for mine scheduling must support the decision-making process by consistently providing high quality schedules in response to revised and updated data. A new mixed integer programming (MIP) model has been developed to generate optimal production schedules for underground stoping operations. The model maximised the before-tax Net Present Value of the production schedule while satisfying constraints such as contained metal tonnage, hoisting capacity, stope geometry relationships and stope backfilling demands. Zero-one variables were used to represent the decision to extract or backfill each stope in a particular time period. Continuous variables, capable of having non-integer values, were used to denote the quantity of ore or backfill associated with a specific stope in a given time period. A case study is presented to demonstrate the significant improvement in before-tax NPV over a comparative manual production schedule in a large underground mine. The MIP model allows for further modification to reduce solution times and meet the needs of individual mines.

Jan 1, 1995

The quality of life in many countries of both the developed and the developing world is strongly affected by the products and processes of mining industries. The first Issue in this new series brings together a set of review articles by leading authorities in the field which, taken together, provide a thorough and detailed survey of many of the key topics of current concern relating to the environmental impact of mining. The level of treatment of most topics is at first introductory but evolves through to the advanced level of current research, backed up by extensive citations of relevant primary literature and other sources. Thus the Issue as a whole will be found equally valuable by students of environmental science and those actively engaged in research related to this theme.

Jan 1, 1995

By Donna L. Bodine

The ability of oxidized Upper Freeport bituminous coal to adsorb Cu2+, Cd2+ and Mn(VII) from very dilute aqueous solutions has been studied. Low-rank coal is known to adsorb heavy metal ions from dilute, aqueous solutions, probably by ion exchange and/or chelation by acidic functional groups on the coal surface. However, it would be advantageous to use higher rank coals for water treatment. Coal samples were oxidized thermally or by 30% H202 to increase the surface concentration of phenolic and carboxylic groups, then portions were shaken with Cu2+ and Cd2+ solutions. Acidic KMnO4 was also used to oxidize coal, with concurrent sorption of the resulting Mn(IV) and Mn(ll). The effect of oxidation treatment, metal ion concentration, and solution pH on metal uptake kinetics was investigated. Potential applications for treating effluents, especially those containing oxidizing ions, are discussed, along with possible flowsheet options.

Jan 1, 1995

By S. B. Bortnikova

This paper presents the results of an investigation of the gold-silver oxidized ores at the Salair mine. West Siberia. High losses of precious metals during primary ore processing are the result of outdated technology that is not suited to treat the present ore compositions. The main mineralogical forms of gold and silver and their confinement to different grain size fractions have been determined. About 50% of gold in the slime fraction and 60% of the silver in the form of acanthite that are scattered from the secondary minerals are lost to the waste. The results of these investigations have provided the basis for the recommendation of a new technological process to upgrade the current practice of the gold extraction plant and for methods to reprocess the concentrates.

Jan 1, 1995

By P D. Katsabanis

Explosives malfunction due to shock waves is a serious concern for successful blasting results. Malfunction includes sympathetic detonation and desensitization of explosive charges as well as the modification of firing times of conventional pyrotechnic detonators.

Jan 1, 1995

By Heinz Giegerich

This paper deals with a new development in recycling second generation catalytic converters, namely metal substrate converters (MSC). It describes a patented dismantling process, whereby the MSC is segregated into it's three components outer steel shell, metal substrate carrier foil and ceramic W8shcoat with embedded precious metals.

Jan 1, 1995

By D Craw

Quaternary warping and uplift of antiformal schist ranges in Central Otago, New Zealand, has resulted in recycling of alluvial gold from widespread, generally weakly auriferous, Miocene fluvial gravels that unconformably overlie the schist, into aprons of fan sediments along the range margins. Basement erosion during uplift has been limited and so gold input from sparse gold-bearing quartz veins in the schist has been relatively minor. In an eluvial cycle on the slopes of the ranges, chemical remobilization of gold occurs during oxidation and erosion of the Miocene sediments. The typically fine-grained (300 - 400 ¦m) gold undergoes chemical modification and grain size enhancement of up to two orders of magnitude, and much of it is redeposited in a large number of relatively small alluvial fans along the range margins. Groundwater mobility within the fans results in minor additional gold mobility and grain size enhancement. During range uplift, a small number of relatively large axial streams and rivers have developed in structural lows between growing antiformal folds. Axial streams 'gather' their flow from consequent streams draining the folds, and flow parallel to a range axis for some distance before cutting across it in an antecedent gorge. The axial streams rework alluvial fan sediments along the range margins, and transport mainly fine-grained gold from the fans along the ranges. This gold is redeposited where the axial streams emerge from a range in the neighbouring structural basin. Axial streams drain relatively large areas of range surface, and thus reconcentrate significant quantities of gold in a small number of relatively large fans and fluvial deposits. The processes of gold collection and re-deposition by axial streams are essentially the same, regardless of stream size. Coarse-grained gold produced by chemical remobilization, is more difficult to transport in fluvial systems, and thus remains in close proximity to eluvial environment where it was formed.

Jan 1, 1995

By Morland R

Recent influence of backfill stability on stope production in the Copper Mine at Mount Isa Mines Limited is described. Changes to the mining process to improve fill stability are described, including increased focus on fill performance, modifications to extraction techniques, increased fill quality, changes to drill and blast practice, and research into backfill stability. Several case studies are described.

Jan 1, 1995

By R. J. Kuczynski

The U.S. Bureau of Mines Reno Research Center operated a batch pilot plant to demonstrate high-temperature cyanide leaching for recovering platinum group metals (PGM) from automobile catalysts. Approximately 1,600 kg of used pellet, monolith, and metal support catalyst containing 1,680 g (54 tr oz) of PGM were processed. Forty-five-kilogram batches of used catalyst were leached with sodium cyanide solution at 160° C for 1 h under basic conditions in a countercurrent processing sequence to dissolve the PGM. Extractions from the used pellet catalyst ranged from 94 to 95 pct for Pd, 95 to 97 pct for Pt, and 64 to 81 pct for Rh. Extractions from the used monolith catalyst ranged from 7B to BB pct for Pd, 75 to 90 pct for Pt, and 43 to 71 pct for Rh. Heating the pregnant leach solutions to 275' C for 4 h destroyed the PGM-cyanide complexes, resulting in over 99.7 pct of the PGM precipitating from solution. The PGM precipitate was predominantly a powder metallic concentrate, typically analyzing greater than 50 pct PGM. Heating destroyed cyanide to less than 0.2 mg/L. Both the pellet and monolith residues were evaluated for disposal using the EPA Toxicity Characteristic Leaching Procedure.

Jan 1, 1995

By J. Kalynchuk, R. Poulin, R. Pakalnis, D. Peterson

"A market survey of all underground mines in Canada (Fig. 1) was completed to determine the ex1ent to which cable bolts are being used as ground support. One hundred and nine questionnaires were distributed with 65% of them being returned completed. As a result, the quantity, types and locations of cable bolt installations have been determined. In addition, the grout pumps used, time required and cost of installations have been addressed. The popularity of other support types used in underground mines is summarized.IntroductionRock reinforcement consists of installing support within the rock mass (internal) or within the excavation (external). Within the past twenty-five years several new types of ground support have been introduced within the mining industry. Cable bolts were first introduced to the Canadian mining industry in the 19605 (Gramoli, 1975).Cable bolts have gained increased acceptance as a method of ground support during the past decade. The cable bolt is comprised of one central wire surrounded by six slightly smaller outside wires and typically having an over-all diameter of 15.2 nun to 15.9 nun (0.6 in. to 0.625 in.). The cable wires are made from high-strength steel with an ultimate strength of 26 tonnes (58 000 Ibs) (Goris, 1990). Current cable bolting practice consists of cement grouting one or more steel cables within a drill hole in order to reinforce the surrounding rock mass. Cable bolts are a form of internal support and are generally used in open stoping and cut-and-fill mining methods (Fig. 2).They can be either tensioned (active support) or untensioned (passive support) and may be of any length, though for underground mining applications, they are generally less than 20 m (65.5 ft) and are untensioned. A major advantage compared to previously used ground support is that the cables are flexible and can be coiled to approximately 1 m (3.3 ft) diameter coils allowing relatively long support to be installed in areas with limited head room (1.8 m).With the advent of bulk mining methods which require comparatively large stopes, it has necessitated the use of relatively long support tendons to stabilize the large spans being created. As a result, the use of cable bolts for ground support in mines has increased significantly within the past decade."

Jan 1, 1995

By John F. Papp

International and U.S. chromium material flow, losses, and environmental releases and transfers from mining through industrial processing, end use, and recycling are identified and quantified. Average (1983-92) U.S. consumption has been: metallurgical industry, 87 pct; chemical industry, 10 pet; and refractory industry, 3 pct. Average chromium content of aluminum, cobalt, copper, nickel, and titanium alloys and alloy, carbon, and stainless steel alloys was estimated. Anthropogenic chromium consumption was estimated for the cement and copper industries. N on-commodity cycle anthropogenic chromium mobilization resulting from U.S. fuel and fertilizer use was estimated. Commodity cycle anthropogenic world chromium loss from mining and primary consumer industry was estimated to be equivalent to about 56 pct of chromium contained in chromite ore production and represented a loss rate of 181 kt-Cr/Mt-CrOre. Chromium released to the atmosphere from natural and from anthropogenic sources were comparable in magnitude. Chromium released to soil was mostly from anthropogenic sources, and aquatic releases were all anthropogenic. Domestic product chromium losses exceed process losses by more than a factor of 10 showing the importance and potential environmental impact of post-consumer recycling. The location of historical and current domestic chromium industry processing sites in 23 States were reported. Chromium releases and transfers to the environment were estimated from 1973 through 2002 by primary consumer industry. A decrease in chromium releases and transfers to the environment was anticipated.

Jan 1, 1995

Various influences determine how an Environmental Management System (EMS) for a mining or petroleum project is developed and administered. These influences include the environmental and resource legislation applying to the project, the culture of the organisation, the environmental sensitivity of the area, and the administrative policies of the regulatory agencies involved. While financial penalties and even imprisonment may be imposed for non-compliance with environmental legislation, there are other compelling reasons for the establishment of an effective EMS. If a company wishes to be considered by Governments for the grant of exploration or mining rights, it is important that it can demonstrate environmentally responsible operations at existing facilities. The development of an effective EMS requires commitment from the Board of the company and the issue of an Environmental Policy to empower all levels of the staff and workforce to achieve environmentally responsible operations. This must be supported by the provision of appropriate human and financial resources, and environmental training of staff at all levels from the Board to the mine site, workshop and office. A regular environmental auditing programme is essential to ensure that the EMS is in place and is effective in achieving compliance with regulatory requirements, corporate policies and protection of the environment. An EMS can be developed on the basis of existing management systems, quality management systems, existing and emerging environmental management standards (such as BS7750 and ISOI4000), or sophisticated computerised systems which may incorporate international experience, standards, and codes of practice.

Jan 1, 1995