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By Brian H. Zelenko, Patricia M. Perry

INTRODUCTION The environmental requirements of the next section of Washington, D.C. METRO subway tunnels present unique challenges to the Contractor. The 14th Street Tunnels contract includes twin 975 m (3200 linear ft) soft ground tunnels. A stringent environmental soil and groundwater monitoring and free product recovery program was specified by the owner. A project-wide dewatering program hinges on satisfactory completion of the environmental requirements. Implementation of the Contractor's environmental program is discussed, including the pros and cons of the program, as they relate to progress of the project. Environmental issues on tunneling projects have become an important part of the urban tunnel construction process. Delays associated with environmental issues can have a major cost impact on tunneling projects. This paper will discuss the first of five Washington Metropolitan Area Transit Authority (WMATA) tunnel and station contracts awarded in 1994. These contracts are part of WMATA's Fast Track Plan to complete the original 166 km (103 mile) system by 2001. As such, stringent environmental requirements have been specified as a part of these contracts to limit delays associated with local regulators in order that the tunnels may be constructed on schedule.

Jan 1, 1995

By Dennis J. Viscusi, James H. III Rowland, Lon D. Santis, Mark H. Weslowski

This paper describes the procedure for analysis of toxic fumes from the detonation of high explosives using the Large Chamber at the U.S. Bureau of Mines (USBM), Pittsburgh Research Center (PRC). This test is specified in 30 Code of Federal Regulations (CFR) Part 15.20 (g) as a requirement for the Mine Safety and Health Administration's (MSHA) approval of an explosive as permissible for use in underground coal mines. The Large Chamber replaced the Bichel gauge and CrawshawJones (C-J) apparatus in the 1989 revision of these regulations. To determine the safety of an explosive in terms of toxic gas production, the Large Chamber Test attempts to simulate mine conditions and miners' exposure to toxic gases from explosives.

Jan 1, 1995

By Steven J. Schatzel

A study was made of frictional ignitions in the underground coal mining industry from 1980 to 1992. The population of frictional ignitions was correlated to a variety of potential contributing factors including the mined coalbed, geographic location, mine production, methane gas emissions, and the type of mining equipment in use. The number of frictional ignitions reported in 1991 and 1992 surpassed the annual totals in all previous years included in the study. Most frictional ignitions occur during cutting operations at a coal face by a continuous miner. The average coal production of mines experiencing frictional ignitions is greater than the average of all underground coal mines throughout the survey period. Methane drainage may have produced a drop in the ratio of gas emissions to coal production (E/P) in mines experiencing frictional ignitions.

Jan 1, 1995

By M. S. Moats

The treatment of oxidized residues of zinc with high iron content continues to present a technical challenge in both the steel and zinc industries. Two main problems are commonly identified and include high treatment costs and environmental concerns about contaminated, iron-bearing residuals. A new approach to this problem is described in which selective separation of the iron and zinc into salable products may be potentially feasible. The waste material is first leached to give a solution having an approximate concentration of 110 g/l Zn, 15 g/1 Fe and 40 g/1 H2SO4 and other impurities such as Pb, Cd, Cu and Sb. A suitable organic, such as D2EHPA, is used to load the majority of the iron. The aqueous phase is then acceptable for zinc electrowinning after standard solution purification. The novel step in the flow sheet is the efficient recovery of the ferric iron from the organic solvent using a solid metal to reduce the iron to the ferrous state. The Fe+2 is easily stripped into an aqueous phase in a relatively pure form, suitable for use in water treatment. Process parameters and possible flow sheet designs are described and discussed.

Jan 1, 1995

By Baird G. R, Jurak R. N

In this study Dynamic Finite Element Modelling is used to investigate the distribution of peak particle accelerations (PPA) induced in a rock mass by a vertical decked column of explosives. The rock mass is assumed to be viscoelastic. The influence of the delay time between decking charges, the viscosity attenuation (quality factor Q), the decking configuration, and the velocity of detonation (VOD) on PPAs is examined. The results of this paper are relevant to fragmentation since the nature of the fragmentation is related to the stress magnitude and hence the PPAs. It was found that increasing the VOD, and increasing Q increases the PPAs in the neighbourhood of the blasthole. However, the VOD and rock quality factor Q have little influence upon the distribution of PPA. It was also found that an even distribution of PPAs, at a fixed distance from the blasthole, could only be obtained by increasing the ratio of charge length to stemming length. The study showed that the amplitudes and distribution of PPA surrounding the blasthole was approximately independent of the delay time between the decked charges. The modelling also shows that the particle accelerations at locations below the bottom of the charge are relatively small and so the model predicts no substantial damage below the bottom of the charge after blasting.

Jan 1, 1995

By M. Rieber

The recent history of the mercury market results almost entirely from U.S. Government actions. Its derived demand has been curtailed by U.S.E.P.A. mandates; its supply has been augmented by U.S.D.L.A. controlled stockpile releases. The resultant prices have altered its market structure, impacted mercury mining, refiners and recyclers, and affected international production and markets. From a marketplace product mercury is rapidly becoming a disposal problem. Other minerals may follow in its wake. This paper reviews developments in demand, particularly in relation to environmental constraints. Supply side impacts are considered. The impact of stockpiles, both as a market overhang and as a potential supply is reviewed. Government stockpile disposal activity is emphasized, but the size, estimated disposal rate, and quality of the private stockpiles are considered, as is the potential availability of additional material from shut-in mines.

Jan 1, 1995

By Norbert Patzelt

The high-pressure grinding roll was introduced about 10 years ago and has established itself in many applications. Most of these machines are used in grinding circuits in the cement industry. A few operate in conventional mineral-processing plants. Polysius has sold more than 350 Polycoms worldwide. An exception is diamond-ore processing in South Africa and Australia. This type of grinding system increases diamond liberation and reduces the capital costs for the downstream processing plant. There are several reasons why high-pressure grinding rolls have not been used more extensively in the mining industry: - The mining industry adheres to conventional grinding technology and regional preference for certain comminution circuits. - Design, scale-up and flowsheet assessment procedures are viewed as being immature and reduce confidence in the potential application of the technology. - Downstream process benefits are unproven on a plant scale.

Jan 1, 1995

By L. G. Austin

The general manner in which the liberation function must change during size reduction is described. Data from float-sink (washability) analysis of a coal is used as an illustration, and a Locking Index is defined and calculated. Ash is not distributed equally with respect to sieve size but is concentrated more in the finest sizes. On the other hand, the ash is less locked with coal in the finer sizes than in the larger sizes. Further crushing showed decreased locking in intermediate sizes, but the material in the fine sizes (produced from breakage of highly locked larger sizes) was more locked than material of the same size in the feed. Future work is also discussed.

Jan 1, 1995

By Winrove G. S, Herdie G. J, McCarthy C. A

Production of hot metal from the Hlsmelt Research and Development Facility at Kwinana, Western Australia commenced in October 1993. The stand-alone facility is a unique, coal-based, integrated ironworks equipped to process iron ore fines to pig iron and simultaneously undertake a wide range of research tasks. The data generated will be used to verify the commercial potential of the technology and to set the design and operating parameters for a full-scale production plant. The design, construction, commissioning and initial operation of the HRDF has required many innovative and practical solutions to be developed and implemented by the international group of organisations contributing to the Hlsmelt Project. Initial operation has produced results which demonstrate the potential of the unique process technology associated with the core plant smelting unit. The recent achievement of post-combustion levels of 60 per cent with heat transfer efficiencies greater than 85 per cent demonstrates that the performance obtained with the Small Scale Pilot Plant in Maxhutte, Germany can be reproduced at a larger scale. The results presented in this paper support the thrust for further intensification and future commercialisation of the process.

Jan 1, 1995

By Alan R. Cameron, William Forsyth, Tom H. Kleinel

Because good and bad blasting must be defined in terms of overall mining costs, blast optimization requires combined blasting and costing models. Furthermore, the models must be both accurate and comprehensive. A combined fragmentation and preliminary costing model was developed to investigate alternative blasting strategies.

Jan 1, 1995

Blasting in Norwegian mines is often carried out by contractors who tend to look for the cheapest solution, without concern about fragment quality. The requirementsfor a contractor are usually only related to the maximum size of boulders and the quantity per month. Even when the owners of the mine are responsible for blasting, very little effort is made to optimise the blasting process. This paper presents test methods which were used and results from small-scale and full-scale blasting tests. In the small-scale tests, cubes 500 x 500 x 500 mm of four different rock types were blasted in a chamber, using two types of dynamite explosive. The velocity of detonation (VOD) for the dynamite explosives was 3000 m/s and 6000 m/s respectively. Three cubes of each rock type were blasted with each type of explosive, and a total of six cubes of each rock type was used. The entire muckpile (approximately 350 kg) was- sieved and weighed after each blast and fragments between 8-16 mm were tested for impact values and flakiness. The results of these tests clearly showed improvement in fragmentation the closer the acoustic impedance ratio of the explosive (VOD x density) over the rock (Cp density) was equal to one. The results also showed that the quality of the fragments (in terms of impact values) tends to be better when the cubes are blasted with the high velocity dynamite.

Jan 1, 1995

By Peter K. Weissenborn, Robert J. Pugh

The contrasting behaviour of electrolytes in inhibiting coalescence of bubbles was explained by the positive and negative distribution of anions and cations at the gadwater interface. Further, the efficiency of electrolytes which do inhibit coalescence of gas bubbles can be linked to a counter ion hydration mechanism and the effect of electrolyte concentration on gas solubility. A correlation was found between the transition concentration of electrolyte needed to prevent the coalescence of bubbles and the reduction in gas solubility. Hence, the inhibition of bubble coalescence in electrolyte solutions appears to be linked with the utilization of water molecules in the hydration of cations and a consequent reduction of water available for gas solubility.

Jan 1, 1995

By MacDonald B. Johnson, Douglass P. Bacon

With the advance of science, rise of public interest in environmental matters, and continuing erosion of air quality, Federal and state regulators are demanding an increasing complex array of data concerning emissions produced by burning and detonating energetic materials. The U.S. Department of Defense, one of the world's largest consumers of energetic materials, now must characterize combustion products resulting from open burning/open detonation disposal operations. The catch-all phrase "below detection limits" no longer satisfies the regulators who now want testing to delve into the ppt level for volatile organic compounds and ppt level for semivolatile organic compounds.

Jan 1, 1995

By N. Menad

Thermal treatments of five different types of non-ferrous metallurgical wastes, under controlled atmosphere, were carried out at temperatures lower than 800 °C. The aim of these treatments was to reduce the toxic elements content and to increase that of valuable metals in the residue. <Best results were obtained by their treatments in air or hydrogen or successively both of them. Simple treatments using air or hydrogen of three samples allowed the elimination of more than? 95 % of their toxic elements and&apos; almost doubled their valuable metals&apos; concentration. For the rest two samples, combined treatment was necessary for their efficient decontamination and the concentration of valuable metals, in the treatments residue, to a reasonable value. Most of the solids issued from these treatments can be recycled in .the current non-ferrous metallurgical processes.

Jan 1, 1995

By Lijun Xu, Ragula Bhaskar

The transport of dust particles from a turbulent air stream on to the surface of a mine entry is mainly due to the effect of diffusion, sedimentation and inertial impaction. While the literature in aerosol science contains many references on particle deposition, most studies apply to smooth surfaces in small, short tubes. The deposition data from those experiments may not be applicable to deposition in mine airways that have large areas of rough surfaces and extend several thousand meters. This paper describes the mechanisms of mine dust transportation and deposition, specifically, by estimating the turbulent deposition velocity for coal dust in mine airways. Data from in-mine experiments on ambient dust concentration and dust deposition along a straight entry were used. A statistical model for dimensionless turbulent deposition velocity was developed, and compared with the models developed by other researchers. The model shows that the distance from the dust source is an important factor in the turbulent deposition of mine dust.

Jan 1, 1995

By Frank E. Kottlowski

Widespread high-calcium (HC) limestones in New Mexico and adjoining areas, are low in magnesium, but some units include shale interbeds that would be deleterious for usage in sulfur removal. In southwest New Mexico, southeast Arizona, and adjoining parts of Mexico, limestones in the thick Mississippian Escabrosa, Pennsylvanian-Permian Horquilla, and Cretaceous U-Bar units are HC as are strata in the Mississippian Lake Valley, Pennsylvanian formations, Permian Hueco, and parts of the Permian Capitan Limestone of south-central and southeast New Mexico and west Texas. In north-central and central New Mexico, many limestones in the Pennsylvanian Madera Formation are HC as are some of the Cenozoic travertines. In northwest New Mexico, where the present-day mine-mouth coal- fired power plants occur, there are no HC limestones, but to the north in southwest Colorado some beds of the Mississippian Leadville Limestone and Pennsylvanian Hermosa Formations are HC. HC limestones considered contain at least 95 percent calcium carbonate and less than 3 to 5 percent magnesium carbonate. Limits for other impurities are alumina, 1 percent; silica, 2 percent; sulfur 0.05 percent; phosphorous, 0.02 percent; and iron oxide, about 1 percent. Chemical and physical requirements differ slightly depending upon the ultimate use.

Jan 1, 1995

By Roger D. Sharpe

The United States Gypsum Company operation at Plaster City, in Imperial County, California, consists of the largest gypsum quarry in the United States, a company-owned, narrow-gauge railroad and wallboard and plaster manufacturing facilities. A variety of gypsum products, including many types of wallboard, construction plasters, portland cement setting agent, and agricultural gypsum are manufactured. Gypsum is quarried from the Miocene age Fish Creek Gypsum. Evaporite minerals were deposited in a clastic-rich sabkha environment along the margin of a small embayment in the Salton Trough. The Salton Trough is a major regional structure that formed by rifting and transform faulting along the Elsinore, San Jacinto, and San Andreas fault zones. Sedimentary basins were formed between tilted fault blocks. The basins were filled by prograding alluvial fans, basin margin sabkha and marine sediments, and deltaic deposits from the Colorado River. Gypsum is exposed in the quarry on rounded hills with 250-300 feet of relief. The evaporites are up to 200 feet thick and average 125 feet in thickness. Anhydrite commonly occurs in the lower part of the evaporites under the crests of hills and beneath thick alluvial cover.

Jan 1, 1995

The use of controlled recirculation can be dated back to the early 1930s. Although this method has been applied in many mines since then, a generalized comprehensive network analysis is still lacking. This paper presents a unique approach in which the ventilation network with a controlled district recirculation is divided into two subsystems: a main subsystem and a recirculation subsystem. The subsystems are analyzed individually and the results and their relationships are then integrated into discussions of the total ventilation system. The analysis of the recirculation subsystem is facilitated by introducing a non-dimensional parameter A, which represents the ratio of the air quantity for the working face to that for the subsystem. As a result, fan and regulator pressures and air power for various recirculation arrangements can be effectively expressed as a function of A and the subsystem air quantity. Numerical examples are included.

Jan 1, 1995

By Yoshihiro Moriyama, Toshihiro Okitsu, Ryouichi Banno

The fracturing composition using the gas pressure generated by the thermit decomposition reaction gives the following performances.

Jan 1, 1995

By Joseph C. Milbourne

Tetra Technologies CCIX? (continuous countercurrent ion exchange) system has been involved in a wide range of uranium concentration, separation and purification applications over the past 40 years. Uranium ion exchange applications have ranged from the treatment of copper heap leach solution containing 5 parts per million of uranium to the treatment of high strength sulfuric acid solutions containing several thousand parts per million of uranium. The flexibility and the countercurrent mode of operation and other unique features of the CCIX? have resulted in successful uranium recovery from these solutions and many others.

Jan 1, 1995