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By M. S. Moats

Galvanic stripping, in conjunction with solvent extraction, has been proposed as a technical option to the challenging problem of iron removal in certain hydrometallurgical processes. The galvanic stripping process is based on the ability of a solid metal to directly reduce ferric ion to the ferrous state in an organic media. Stripping the iron into the aqueous phase is then easily accomplished. Previous work has shown the reaction kinetics and efficiency are affected by such operating parameters as water and oxygen contents, temperature, time and metal reductant. In this study, the optimum operating range for some of these variables was determined. Both zinc and iron metal were used in the separate stripping of iron from D2EHP A. Reasons for the differences in the extent of the reaction obtained using the various conditions are discussed.

Jan 1, 1996

By John M. Bolger, Keith E. McMaster

Excessive salt fines are undesirable in underground salt mining as they are considered a costly waste byproduct. This paper describes an extensive explosive application program conducted at The Canadian Salt Company Ltd, located in Pugwash, Nova Scotia, Canada. The prime objective of the program was to reduce the quantity of fines generated from this company’s underground production blasts. The program was known as the “The Fines Reduction Program”.

Jan 1, 1996

By Alex Harrison, K. Payne

Computer generated magnetic field reference signa- tures of steel cord belt splices are used to evaluate lay-up and fabrication irregularities of splices in operating conveyors. Used as a quality inspection tool, magnetic signature analysis is useful in auditing data collected by general non-destructive testing (NDT) consultants. The evaluation can detect irregularities that weaken a splice, as well as detecting signature changes that can be indicative of adhesion loss. The evaluation can be applied to any NDT data available from a variety of commercial sources, which means that independent review of critical splice data is possible.

Jan 1, 1996

By G. A. Doyle

The White Pine Mine is the second-largest active underground copper mine in the United States, covering an area of approximately 13 square miles in the Upper Peninsula of Michigan. The mine operator intends to initiate in-stope solution mining by circulating a solution of mine water, sulfuric acid, and ferric iron through rubblized ore and recovering copper from solution. As planned, the solution would be retired in the mined-out stopes following completion of solution mining activities. Investigations into the fate of the retired solution mining fluid indicate that the solution, through time, will change from an acidic, metal-rich solution to a near-neutral, reducing solution containing much lower concentrations of metals. Investigations include reaction path modeling (EQ3/6) and laboratory and in-mine experiments. The combination of neutralization and reduction will result in precipitation of most metals, primarily as metallic sulfates, chlorides, and sulfides.

Jan 1, 1996

By L. J. Terrill

Lateral displacement in the immediate roof beam at the Waste Isolation Pilot Plant (WIPP) is a significant factor in assessment of excavation performance for the design of ground control systems. Information on roof beam lateral displacement, expansion, fracture formation, as well as excavation convergence, is gathered using a variety of manually and remotely read instruments. Visual observations are also used when possible. This paper describes the methods used to measure lateral displacement, or offset, at the WIPP. Offset magnitudes are determined by the degree of occlusion in drillholes that intersect the offset plane. The Borehole Lateral Displacement Sensor (BLDS) was developed for installation at WIPP to monitor offset at a high degree of accuracy at a short reading frequency. Offset measurements have historically been obtained by visual estimation of borehole occlusion. Use of the BLDS will enable relationships between time dependent roof beam lateral displacement and expansion to be established in much shorter periods than is possible using visual observations. The instrument will also allow remote monitoring of roof beam displacement in areas where visual estimations are not possible. Continued monitoring of roof beam displacement, convergence, and expansion, is integral to timely and pertinent assessments of WIPP excavation performance.

Jan 1, 1996

By C. Patrick, T. Combs

The purpose of this paper is to provide a method for analyzing the sequencing of mining production processes and predicting the effects of any planned changes. Included is a description of the development and utilization of a project-scheduling simulation that combines analytical scheduling with stochastic-activity durations. The simulation is demonstrated in two realistic examples: a longwall face-to-face transfer sequence and the effect of varying advance rates on longwall development sections. Statistical data that can provide a basis for more informed production decisions are generated in the form of project activity/path criticality and project-duration distributions. In both examples, a quantitative risk assessment, regarding subjective decisions in underground production sequencing, is presented.

Jan 1, 1996

By W. H. Langer

The U.S. Geological Survey (USGS) in cooperation with the New Mexico Bureau of Mines is conducting an assessment of mineral resources in the 36,800 km2 Mimbres Resource Area, southwestern New Mexico. Included in the assessment is a literature-based evaluation of sand and gravel that utilizes third party geologic information. The USGS has developed a method based on existing 1:500,000 scale geologic maps supplemented by remote sensing, statistical models, and point data such as test hole or pit records. The method defines the areal extent, quality, and quantity of aggregate.

Jan 1, 1996

By M. W. Ryan

The US Bureau of Mines investigated cold-cutting alternatives to oxyacetylene torch cutting of metal. The alternatives examined were a pneumatic circular saw with an abrasive cutting wheel, a handheld abrasive water-jet cutting tool, an ultrathermic-cutting system, hydraulic punches and cutters, and a pneumatic reciprocating hacksaw. Sparks generated with the pneumatic circular saw or ultrathermic-cutting system were not completely eliminated with the use of water sprays. The water sprays also reduced the cutting rate of the pneumatic circular saw by 70%. The safety and performance of a handheld abrasive water jet cutting system requires additional research. The hydraulic cutters and punches are readily available and do not introduce any hazards. However, they are not comparable in price to the oxyacetylene gas torch and many different attachments would be needed to replace the torch. The pneumatic reciprocating hacksaw, which did not produce any sparks, is an acceptable alternative in terms of cutting rates. However, the price of the saw and blades is not comparable to that of the oxyacetylene gas torch. The results of this study will further the advancement of safe, efficient alternatives to oxyacetylene gas torches, which will improve miner safety.

Jan 1, 1996

Spatial continuity as described by a variogram is a reflection of the underlying mineralisation/geology. Modelling of the spatial continuity (variogram) must account for both the quantitative data (ie sample grades), on which the variogram calculations are based, and the qualitative information as provided by the geological interpretation. An understanding of the geology and the variogram interpretation tie together the sample values and allow us to go beyond the actual data (Journel, 1995). Variography makes geology transportable and allows the geological interpolations to be channelled downstream into mine planning, ultimately affecting the economic decisions surrounding a deposit. As such the process of variography and resource modelling is critical. Thus consistent expert decisions need to be made which force geologists to have a closer look at the available information and the geological interpretations. The aim of this paper is to provide an overview of the latest developments in visualising variography and to demonstrate their usefulness in decisions regarding the spatial continuity of mineralisation. New ideas concerning potential future developments in visualising and modelling spatial continuity through variography are introduced.

Jan 1, 1996

By E. Tondu

Separation Technologies Inc.’s (STI) electrostatic separation technology is a dry, continuous process for the separation of discrete particles. This high-volume process does not require any additives nor is any additional waste produced. In December 1993, STI, in cooperation with New England Power(NEP), installed an 18-t/h (20-stph) prototype electrostatic separator at NEP’s Salem Harbor plant. The plan was to convert waste streams of type F fly ash into commercially valuable products. In July 1995, a second separator was installed at NEP’s Brayton Pointplant. Fly ash feed, ranging from 6% to 25% carbon (loss-of-ignition fly ash or LOI), is separated into <3% LOI “clean” ash and sold as a portland cement substitute in the New England concrete markets.

Jan 1, 1996

By A. M. Marabini, G. Belardi, E. Spaziani

The objective of this research was to investigate the possible application of integrated circuits to the concentration of talc from the Valmalenco mine, located in northern Italy. The investigation was aimed at producing a high-grade product (low in impurities such as iron and carbonate) that would be suitable for industrial applications. Because of the presence of accessory minerals, the talc concentrate from this ore is not, at the present time, suitable for industrial applications.

Jan 1, 1996

By R. M. Carland, F. F. Aplan

The ion-exchange capabilities of natural zeolites from the western United States, representing the species chabazite, clinoptilolite, erionite and mordenite, have been studied because of their potential use in environmental remediation and in hydrometallurgical processes. These raw zeolite samples were found to contain Na+, K+, Ca+2 and Mg+2 as exchangeable cations, and all of these, with the exception of Na+, were found to seriously interfere with the exchange of Cu+2 from solution. Placing these zeolites in the Na+ form was found to increase their cation-exchange capacity, often massively. In addition, the elution of Cu+2 from the Na+ pre-exchanged zeolite is greatly facilitated when the deleterious K+, Ca+2 and Mg+2 have been largely expelled. The relative influence of these deleterious ions on the uptake and elution of Cu+2 was determined.

Jan 1, 1996

By F. N. Voskoboyev

The suggested new method for control of geomechanical state of undermined rock mass ensures, as a safety measure for the earth surface protection, the decrease of deformations by 2,5 - 10 times in mining the single seam, and by 1,5 - 5 times - in mining bed series, i. e. approximately within the seam ranges as in the application of full packing with various compressive properties or partial extraction of resources over the area with different coefficients of extraction. It should be noted that this new method has the following advantages o\w rhr. conventional methods: a) the decrease of the packing area and packing works volume by 2 - 4 fold including the operating and productive expenses; b) the elimination of mineral losses due to the increase of extraction coefficient up to 100 5%; c) rock utilization from workings drivage by its placing in the mined - out space. Perspective field of application of this method: disconservation of mineral resources in the left protective pillars of various designation.

Jan 1, 1996

INTRODUCTION ò World coal production, Exporters and Importers òNew Zealand Exports, Markets and Products ò Types of Markets and Price Setting ò Bench Mark Prices and Exchange Rate ò Transport ò International Marketing - Key Factors ò Coal New Zealand , the Challenges

Jan 1, 1996

Cerro Matoso (CMSA) in Colombia produces ferro-nickel from lateritic ore containing approximately three per cent nickel, using a Rotary Kiln - Electric Furnace (RKEF) process, in which the calcining of the mineral within the kiln is second in importance only to the smelting of the mineral in the Electrical Furnace. This article discusses the installation and operation of an expert system to control the kiln of CMSA. In the CMSA process, the run-of-mine ore is crushed, homogenised, dried and mixed with a small percentage of coal, before being heated up to 900¦C in a rotary kiln in the presence of natural gas mixed with air in a controlled proportion (air/gas constant ratio). The final objectives of the process are the following: ò To reduce to a minimum the iron and nickel oxides in order to convert these into metallic ions; this is a reduction process to facilitate largely the smelting in the electric furnace. Since the reduction is made with natural gas, it is much more economical than the subsequent complete reduction in the electric furnace, since electrical energy is much more expensive by unit of processed mineral. ò To heat the mineral as much as possible to facilitate the subsequent smelting. ò To eliminate totally the moisture content of the ore. An expert system with fuzzy logic was commissioned in 1994 for the control of the kiln and it has operated with good results ever since.

Jan 1, 1996

By Scott G. Honan, Wayne F. Luinstra

"Since 1992, the concentration of gold using gravity methods has progressed to become an important part of production at Hemlo Gold's Golden Giant Mine. Currently, the gravity circuit accounts for approximately 25% of the Golden Giant Mine's Gold production. This circuit consists of a 30 inch Center-Drain Knelson Concentrator and a Shaking Table. The evolution of gravity concentration will be discussed with an emphasis on the economic justification for a gravity circuit as well as the practical aspects and metallurgical impact of operating such a circuit. It will be demonstrated that the operation of a gravity circuit has definite benefits to the operation of the Golden Giant Mill and will continue to play an important role in future gold production.1.0 IntroductionHemlo Gold Mines Inc. Golden Giant Mine is a 3000 TPD underground gold mine and milling facility located 40 km east of Marathon, Ontario. Mining is accomplished by means of sublevel longhole open stoping. The ore is processed using conventional crushing, 3-stage ball milling, conventional cyanidation and CIP processes. The mill and concentrator are described in more detail in other publications1,2.Since July of 1992, the Golden Giant Mine has been using a gravity circuit for gold recovery in the mill's grinding circuit. Despite the fact that gold recovery averages over 96% using conventional cyanidation and carbon-in-pulp processes, the gravity circuit has become an integral part of milling operations. This paper will discuss the economic justification for a gravity circuit as well as the practical and metallurgical aspects of its operation."

Jan 1, 1996

By Kafui Nyavor

The indirect, and the direct contact mechanisms of bacteria oxidation of sulfides were studied using Thiobacillus ferrooxidans and pyrite. The aim was to determine which of the two generally aeeepted mechanisms played a dominant role, if any, during acid mine drainage (AMD) formation from the oxidation of sulfide minerals. The results show that at a pH of 4.5 where T. ferrooxidans are quite active, but where initial chemical oxidation of pyrite to Fe2+ is limited, the bacteria were unable to directly oxidize pyrite to any significant extent. Whereas, in the presence of Fe2+, T. ferrooxidallS assisted oxidation of pyrite by the indirect mechanism was observed and sustained over the pH and Eb range where the bacteria is active. The results lead to the conclusion that the direct contactmechanism of pyrite oxidition by T. ferrooxidans is insignificant. The predominant, and possibly the only, pathway involves the indirect bacteria oxidation of available Fe2+ to Fe3+, which in turn oxidizes FeS2 to generate additional Fe2+ and acidity in a cyclic process.

Jan 1, 1996

By Junji Shibata

It is important to recover and reuse the metal values contained in various industrial wastes in a viewpoint of environmental preservation. Most of industrial products are made through the processes to separate impurities in raw materials, solid and liquid wastes being necessarily discharged as industrial wastes. Chemical methods such as solvent extraction, ion exchange and membrane, and physical methods such as heavy media separation, magnetic separation and electrostatic separation are considered as the methods for separation and recovery of the metal values from the wastes. In this paper, some examples of the application of solvent extraction to the treatment of wastes are introduced. The treatment of solid wastes such as Ni-Co alloy scrap, Sm-Co alloy scrap, fly ash and flue dust, and liquid wastes such as plating solution, the rinse water, etching solution and pickling solution are accomplished using solvent extraction technique.

Jan 1, 1996

By Jim Lauder, Russ Calow, Ken Maley, Michael Ounpuu, Stuart T. Caverly

"Stuart T. Caverly, Section Head XRF Laboratory, Jim Lauder, Systems Engineer, Russ Stuart T. Caverly, Section Head XRF Laboratory, Jim Lauder, Systems Engineer, Russ Concession Street, Lakefield, Ontario KOL 2HOAbstractOn-stream X-ray analyzers have become an integral part of modem milling operations. The calibration of these instruments is not difficult but must be performed carefully and with consideration for the principles of X-ray spectrometry. A discussion of successful calibration procedures as well as examples of several common mistakes is presented.IntroductionOn-stream X-ray analyzers (OSA) have become an integral part of modem mineral dressing plants. Advances in instrumentation and computer software make the analysis of process streams fast, accurate and precise. Proper instrument calibration that respects the fundamentals of X-ray spectrometry is essential if the data generated are to be reliable. Often the importance of this task is underestimated and delegated to a person with inadequate XRF training. Successful OSA calibration is the result of careful, systematic procedures.On-stream analysis is perhaps the most important tool that has been provided for the concentrator metallurgist. Combined with powerful, low cost PC's and distributed control systems, real-time elemental analysis affords today's metallurgist many opportunities to troubleshoot and optimize his process.Before OSA, operators had to be very experienced if they were to achieve good results. Even with hourly grab samples, most changes in control approach would still be based on visual cues from the circuit and gut instinct. Real-time analyses have changed that completely.The last two decades have seen a persistent drive to reduce production costs. Operations utilizing OSA have been the most successful in this endeavor. Direct benefits from the application of OSA are fairly obvious. Operators are able to make incremental changes in operational parameters (e.g. reagent addition, pH, cell level), and immediately monitor the effects. Variations in the characteristics of the mill feed can be identified and addressed immediately. More progressive operations have linked analyses to control loops to adjust process setpoints ( e.g. reagent additions), and to change them automatically according to formulas based on previous experience."

Jan 1, 1996

By Thomas C. Rube, T S. Bajpayee

The Bureau of Mines conducted research to determine the safe operating conditions for using recycled (used) lubricating oil from mining equipment as a partial replacement for diesel fuel to make ANFO-type blasting agents. The use of recycled oil (RO) saves energy, reduces oil imports, and reduces mining costs.

Jan 1, 1996