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By Jong-Ren Tarng, Gin-Hwa Chen, Wen-ku Chang, Ke-Ming Lin, Yuan-Haun Lee

"The majority of early studies used X-ray diffraction, but this requires a model to interpret the diffraction processes. A turbostratic model has been applied by Warren, Franklin and Bacon to a wide range of materials including both soft and hard carbons. Maire and Mering applied the same methods to the interpretation of the (001) lines of a series of graphitic carbons. In our case, graphitic carbons undergone high temperature and high pressure graphitization processes have been evaluated by the same methods. It were found that most technological XRD data were obtained by a Rietveld method with the least-squares refinements could be in the simplest way since the full correction technique is very laborious. The behavior of carbon materials as it proceeds through the graphitization process is characterized by changes in the measured interlayer spacings (d) a~ a function of temperature. A series of graphitic carbons including the transformation of diamond to graphite through the process under high temperature and high pressure have been evaluated. A simple calibration equation has been established. IntroductionRecently, in battery industry, carbon materials are used as cathode in lithium ion batteries. However, graphitization of those carbon materials is concerned as if lithium ion intercalated into those carbon cathode. Both high-graphitization and low-graphitization carbon materials are suitable for this kind of application.As for graphitization, the starling materials from which carbons may be prepared vary extensively from pure chemical compounds, to mixtures containing II wide range of molecular weights, such as pitches. So its graphitizing, perhaps the most notable feature of the process, is the very wide range of temperature over which the perfection increase, unlike the more common transformations of solid state materials which occur in a narrow temperature range. The variables involved in the conversion of the initial hydrocarbon to a carbon residue, which may vary widely in final perfection, are time, temperature, stress and impurity content"

Jan 1, 1996

By Shenbaga R. Kaniraj

The pile loading tests are generally conducted to assess the safe load on piles in compression. In the Indian practice, the safe load is determined using the pile loading test data and the two criteria specified in the Indian Standard Code, IS.2911 (Part 4) -1985. For this, the test pile should have undergone a minimum displacement equal to 10% of the pile diameter. Often, the piles are not subjected loads that are sufficient to cause a displacement of this magnitude. If the settlement is at least 12 mm, then the safe load is determined based only on the first criterion. But, if the settlement is less than 12 mm, the safe load cannot be determined using the IS Code criteria. The paper presents two procedures called hyperbolic and generalized hyperbolic methods to estimate the safe load using the IS Code criteria even when the loading test data is insufficient. The data from two initial tests have been analyzed. The predicted safe loads have been compared with the actual safe loads.

Jan 1, 1996

By Thomas Fliess, Klaus-Christof Ritter, John R. Sturgul

The optimum flow of materials through a smelter is an extremely important phase of the mining cycle. A typical copper smelter will have up to $US 1,000,000 per day of copper being processed. The motion of the overhead cranes in moving the ladles filled with copper matte and slag from furnace to furnace is prescribed but there can be numerous variables to consider. Some of these variables to the system can be: the speed of the overhead cranes, the number of cranes, the size of the ladles, the size of the furnaces, the number of furnaces and the sequence in loading the furnaces. A simulation model was constructed of a working smelter in the SW of the United States. The model has been used to study the effect of varying parameters of the system. The program runs as follows: an input menu appears on the PC screen and the user can navigate through it and change any of the data; the simulation takes place and the results of the simulation sent to a data file. Animation of the system then is shown on the screen in "cartoon" fashion. The software chosen for the simulation was GPSSI H (') and PROOF Professional (') for the animation. The model presented here is believed to be the first reported simulation and animation model for a complete, working smelter.

Jan 1, 1996

By D. J. Wang

Based on the thermodynamic arid kinectic aspects, the vaccum distillation processes for the separation and recovery of metals from wastes are analyzed. As to the separation criteria, The separation coefficient and equilibrium composition relation between vapor phase and liquid phase are the bases of recovery of metals by vacuum distillation, The vaporization rates and condensation mechanisms are also discussed. Some experimental results which deal with metals-containing wastes are described and the performances of a new kind of horizontal vacuum furnace are introduced, which demonstrate that , vacuum distillation may be a prospective technique for circulation and regeneration of some non-ferrous metals from industrial wastes.

Jan 1, 1996

By A. M. Raichur

Flocculation of fine coal is usually accomplished with the addition of commercially available organic flocculants. Recently it has been shown that biopolymers derived from microorganisms can be used to flocculate coal. The biopolymers flocculate coal efficiently and render the coal surface hydrophobic. The increase in hydrophobicity can be utilized either to separate the coal flocs from mineral matter. It can also be used for reducing the moisture content of fine coal. In this regard, flocculation and settling tests of fine coal with biopolymers and synthetic flocculants was undertaken and the results are discussed here. Also, a transport model was developed for the time-dependent settling tests for fine coal.

Jan 1, 1996

By V. M. Shick

For practical purposes of the use of information resources in the field of geomechanics and mine surveying with accepted mining technology in mines, the authors have developed the packaged software programs of the survey-geomechanical information system with database objects of mine field. This system enables to execute the graphical representation of workings layout in preset scale, axonometric projection, the zones of higher ground pressure: program packages for calculations of rock pressure manifestations and for selection of suitable support facilities for the permanent, development and active workings and vertical shafts based on the information resources of the State Research Institute of Mining Geomechanics & Mine Surveying (VNIMI). The program packages are applied at coal mines in Russia and in Kazakhstan. The profitable operation of coal mines can be reached only by the combined optimal engineering decisions in mine working's laying-out and their reliability and safety at the stages of their designing and exploitation, and with minimal harm of the environment as well. This problem is being complicated by the fact that today the mining-practicing engineers and designers are ordinarily facing the problem " of an information barrier", when the complexity of controlling systems exceeds the potentialities of traditional management of production practice. Coal mine is a typical representative of complicated systems, because the information about geological structure, physicomechanical properties and stress-strain state of rock mass are of fragmentary character and insufficiently reliable. A mine has a developed network of interrelated workings, by the way, some of them are productive ones being subjected to control to a certain extent, and some of them are abandoned ones being noncontrollable and hazardous in rushes of water, gas, pulp and fire. The ground pressure forces cause the disintegration of rock mass growing with depth. The progress of mining operations constantly changes the geomechanical situation forming the zones of bearing pressure, stress relieving, coal falling, as well as it leads to the pulp movement on the earth surface, breaks the ground water flow, causes deformations and changes in stability of buildings, constructions and natural objects on the earth surface. One should take into account the existence of hazardous zones within the mine field, i.e. the zones of elevated ground pressure, geological dislocations and those ones under natural water reservoirs, ponds, etc. Major coal seams are prone to rock bursts, sudden outbursts, bleeding, endogenic fire. It is obvious, that in practice it is extremely difficult to account for the mentioned above factors in their interrelation.

Jan 1, 1996

By Hong Ouyang

A unified computational model has been developed for the Bridgman growth processes of B-NiAI and CdTe crystals. To handle the geometrical and physical complexities, a two-level approach has been developed. At the gtobatlevel, conjugate heat transfer, phase change dynamics, and variable material properties along with the realistic geometries and thermal boundary conditions are accounted for inside the entire crystal growth system. Refined calculations are then made within the ampoule, with the boundary conditions supplied by the global simulations. This model can optimize the use of computational source, help understand solidification behaviors, and improve designs of crystal growth system.

Jan 1, 1996

By Norbert L. Piret

From the copper smelter operation a various outputs are to exert negative impacts on the environment. Particularly, emissions like SO2 and dusts, solid wastes like contaminated gypsum and arsenic sludge, effluents and heated cooling water are generated. Most countries have sitipulated an environmental legislation to provide the framework for an efficient environmental management. As part of the planning activities for x major greenfield copper smelter, the Following elaborations are required and were drawn up. -The Environmental Impact Assessment which is the first step of environmental management and mandatory for every new project. - The Environmental Monitoring Plan, which describes the monitoring procedures for the main impacts identified and assessed. -The Environmental Management Plan, which deals with the minimization of environmental impacts, and the methods of its implementation.

Jan 1, 1996

By A. Davis

Pit lake chemistry depends on the lithology and hydrologic characteristics of the ultimate pit surface, the availability of buffering capacity in the wall rock versus oxidizable sulfide content, and the alkalinity of recharging ground water. In this paper, we assess the geochemistry of 11 existing pit lakes, ranging from the acidic Red Hill and Berkeley pit lakes (pH 2.6 to 2.8) to the alkaline Yerington Pit lake (pH 8.45). Predicted pit lake chemistry is similar to that in existing pits with the long-term pit lake chemistry lying on a geochemical continuum between end members consisting of influent calcium bicarbonate ground water, and naturally occurring sulfate-rich evaporite playa lakes.

Jan 1, 1996

By L. R. Nelson

The efficiency and cost-effectiveness of the aluminothermic reduction process in the production of ferro-alloys and 'pure' metals depends strongly on appropriate balancing of the process energy required. Insufficient energy results in a poor metal yield, while over-supply can result in excessive fuming and possibly even ejection of the reactor contents in a potentially dangerous 'thermite bomb' reaction. This situation becomes even more critical when the suitability of limited quantities of oxide from new sources must be evaluated, dictating smaller-scale testwork. The resulting higher relative heat losses from the system complicates control of the energy balance, and usually requires the addition of thermal boosters or reactant preheating in order to sustain an autothermic process. This often detracts from the quality of the metal product, and adds to the hazards of batch aluminothermic- reduction testing. The development of a small-scale method (producing less than 2,5 kg of metal) for the plasma-assisted aluminothermic reduction of chromium oxide that overcomes such difficulties is described. The technique involves the use of a sealed 50 kVA plasma-arc furnace to provide controlled electrical ignition and supplementary energy to the reactants contained in a water-cooled copper crucible. The application of the method to the evaluation of the aluminothermic production of pure chromium metal from a unique chromic oxide source is reported.

Jan 1, 1996

By Takeshi Tanaka, Shinya Ono, Tsuyoshi Kato, Masaji Kato, Yuusaku Tominaga

The knowledge of the macroscopic characteristics of a ventilation network is of fundamental importance for taking counter- measures to increase air quantity in-specified branches, such as those corresponding to working faces at advancing entries or longwall panels. Because the ventilation characteristics are inherent properties of each mine, it takes a long time for an engineer to accumulate experience on how a specific regulator may affect the air quantity in a specific branch of a mine with a complicated ventilation system. A computer-simulation training system, based on the macroscopic ventilation characteristics, is presented in this paper. When a trainee selects a specific condition from five regulator option (closed, almost closed, slightly open, half open, open), the change in air quantity for a network branch is indicated by the color allocated to the ratio of the new air quantity to the old or planned air volume. After the ventilation simulation, the colors in the specified branches are defined by using the fuzzy set theory. The trainee continues practicing the selection of closed/open conditions for different regulators until each of the specified branches is displayed in good state of airflow. The ventilation net- work of the Horonai coal mine is used as an example of the training system to control air quantities in six working faces with 33 regulators.

Jan 1, 1996

Continuing with the effort of providing new and more effective exploration methods to the mining industry, where direct methods (drilling, cross-cutting, etc.) are not applicable, either for logistical or environmental reasons or because they are costly and sometimes ineffective, we present here a new seismic technique based on full wave recording of 3-D channel waves generated within the coal seam across a longwall. In the past two years we reported the application on In-Seam High Resolution Seismic Reflection (ISHRSR) and In-Seam Seismic Tomography (ISST) to map non-coal inclusions that disrupt the coal seam continuity. In the present paper we present a 3-D In-Seam Seismic Tomography (3-DTSST) method using 3-D channel waves recorded by three component high resolution geophones. The method allows to distinguish longitudinal and transversal components of the channel waves, similar to the spheroidal and toroidal modes for the free oscillations of the earth. The recording of these waves allows a more complete analysis of the free modal vibrations of channel waves, permitting a more complete inversion of the structure of the coal seam through which they travel. The full wave analysis provides additional insights of the detailed coal structure for larger, distances than for the ones previously reported using the one dimensional method. The refinement of the inversion software is also a contribution towards the better definition of the coal seam geometry and structures disturbing them such as sandstone channels, sandstone rolls, partings, mine voids, faults, fractures, etc. The method is illustrated with three case studies where subsequent mining revealed the virtues and limitations. The first example deals with the problem of mapping mine works in one side of a longwall panel which geometry is well known, to verify its applicability to map old mine works. The second example deals with a sandstone body that partially scoured the coal seam withing a longwall panel. The third shows an application of the method to map roof conditions in a longwall panel where this problem critically affected production scheduling and costs

Jan 1, 1996

By C. G. Anderson

The treatment of materials for the recovery of the precious metals imposes many processing and environmental challenges. Sunshine Mining and Refining Company has developed hydrometallurgical technology for recovery of values from refractory precious metal materials. At Sunshine, the industrial focus of these processes has been for the direct recovery of silver without cyanidation. However, recent work has indicated that these technologies can provide a means for treating complex, refractory gold concentrates. This will be the focus of this paper. The practice of pretreating ores and concentrates to make them more amenable to cyanidation is becoming more common. Several pretreatment options for sulfide concentrates containing gold include roasting, bio-leaching, direct pressure oxidation and nitrogen species catalyzed pressure oxidation. The industrial use of nitrogen species catalyzed pressure oxidation has been limited to the Sunshine refinery where its focus has been for the treatment of silver concentrates. Much of the reluctance, outside of Sunshine, to use this type of technology may be based on the perception that high costs are associated with using nitrogen species (e.g. nitric acid, sodium nitrite) to leach. Also, the use of nitrogen species catalyzed pressure oxidation on an industrial scale is unfamiliar to most metallurgical professionals. A summary of pressure leaching processes which utilize nitrogen species as a catalyst is presented in Tables 1 and 2.

Jan 1, 1996

By John W. Padan

The 1982 United Nations Convention on the Law of the Sea contains major provisions that U.S. negotiators have sought for over two decades. The internationally recognized right to the mineral resources of a broad continental margin is of potentially enormous future importance to the United States. Although water depths reach 10,000 feet in some of the deeper areas of the margin, technology is rapidly making those depths economically accessible. In 1997, production in the Gulf of Mexico will reach a world record water depth of 5400 feet. Of perhaps even greater importance to the oil and gas industry is the broadly acknowledged right for tanker transport of oil to take place throughout all parts of the world's oceans.

Jan 1, 1996

By C. Lupi

Electric arc furnace dust generated during the production of steels is regarded as hazardous waste because of the presence of leachable elements such as Cr, Pb, Cd .... Different processes are available according to the management policy chosen by the steelmaker: disposal. recycle and/or recovery. The feasibility of an hydrometallurgical Zn recovery process on fumes generated during the pyrometallurgical treatment of EAF dust has been investigated. The recovery of metallic iron, chromium and nickel as molten metal provides fumes very rich in zinc oxide ( 63.1% ) and poor in zinc ferrite. This secondary dust is still an hazardous waste and represents the raw material for the recovery of Zn and Pb. The waste material is first leached in 1.5 M sulphuric acid at 30°C to provide a Zn, Fe and Mn rich aqueous solution and a Pb and Ca sulphate rich sludge. The iron is eliminated by precipitation because is harmful to the following electrowinning process. The ftltered and purified leached solution is acidified in order to obtain good electrowinning conditions. A pure cathodic deposit of zinc is then produced in an electrolytic cell at laboratory scale.

Jan 1, 1996

By R. L. Grayson

Following lip on a USBM-sponsored research project, the authors have utilized the knowledge-base structure and system concepts from the Sun Sparcstation-based worker scheduling system of the Mine Management Support System to develop a PC-based application. The new software adopts the nested-window concept to facilitate data collection and modification on personnel, their availability on a shift, and work priorities for a shift as well as to allocate manpower optimally on a work shift and delineate supervisory training responsibilities. The various components of the software are described in detail, along with enhancements made to the original system.

Jan 1, 1996

By F. W. Petersen

The Conference Minerals & Materials '96 was held in Somerset West, South Africa, from 31st July to 2nd August, 1996. It was organized by the Universities of Stellenbosch and Cape Town, the Cape Technikon, and the Western Cape Branch of The South African institute of Mining and Metallurgy (SAIMM). The three-day Conference was attended by 180 delegates, representing countries such as Australia, South Africa, United Kingdom, Finland, Sweden, Germany, Poland, Zambia, and Zimbabwe. The programme and associated exhibition were well organized, and each of the delegates received two volumes of proceedings containing the 77 papers presented at the Conference.

Jan 1, 1996

By T. K. Mukherjee

The importance of the processing of secondary resources such as solid industrial wastes and liquid effuents as well as byroducts for the recovery of the associated metal values hardly needs any elaboration. Such processing contributes in no small measure.towards the augmentation of the availability and the supply position of resources. As an added benefit, it leads to a reduction in environmental pollution caused by the undesirable waste materials. As some typical examples of secondary resources in the Indian scenario, mention' can be made of spent catalysts, metal/alloy scrap, ash, consumed batteries, flue dust, slag, sludge and slime, pickling solutions, spent acids; plating rinse solutions, spent etchants, waste water from synthetic fibre manufacture and from tanneries etc. These wastes constitute a source of a variety of non ferrous metals. In the processing of secondary resources like these, the techniques of hydrometallurgy such as solvent extraction play a pivotal role. This paper outlines the efforts made to use solvent extraction to recover (1) base metals such as copper, zinc, nickel and cobalt from a number of secondary resources like cake, and sludge(2) refractory metals like molybdenum and vanadium from sulphidic, byproducts and spent catalyst and (3:) nuclear metal like uranium from phosphoric acid. In the case of base metals, process flowsheet involving the use of acidic extractants such as DEHPA and PC88A have been optimised. The problem of iron removal from the leach liquor, "which influences the metal recovery process significantly, has drawn a special emphasis. hi the case of refractory metals, basic extractants .like Alamine 336 has been pressed into service to produce kilogramme. quantities of pure salts of molybdenum and vanadium, Finally, the paper gives a brief account of plant experience in recovering uranium from phosphoric acid, using 'a solvent system comosed of DEHPA and TOPO.

Jan 1, 1996

By T. W. Eddy

Research was conducted in which elemental mercury and its sulfide mineral (cinnabar) are removed from a copper sulfide concentrate by low temperature thermal applications. The goal of this research was to reduce, volatilize, and collect mercury vapor from concentrated smelter feed in a simulated drying environment while maintaining the chemical integrity of the residual. The study used synthesized concentrates composed of copper sulfide and mercury bearing minerals (such as cinnabar (HgS) or elemental mercury) to determine optimal residence times and temperature ranges.

Jan 1, 1996

By Thomas M. Barczak

With the development of the shield support, the primary requirement for successful ground control in longwall mining is to provide stable gate road and bleeder entries. Wood cribbing has been the dominant form of secondary support. However, the cost and limited availability of timber, along with the poor performance of softwood crib supports, has forced western U.S. mines to explore the utilization of other support systems. The recent success of cable bolts has engendered much interest from western operators. Several innovative freestanding support systems have been developed recently including: (1) "The Can"' support by Burrell Mining Products International, Inc., (2) Hercules and Link-N-Lock wood cribs and Propsetter by Strata Products (USA) Inc., (3) Variable Yielding Crib and Power Crib supports by Mountainland Support Systems, (4) the Confined Core Crib developed by Southern Utah Fuels Corporation; and (5) the MEGA prop by MBK Hydraulik. This paper assesses design considerations and compares the performance and application of these alternative secondary support systems.

Jan 1, 1996