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By Baozhong Zhao

Laboratory experiments have been conducted on the removal of As, Sb and Bi from molten copper by SF 6 injection. The results showed that the impurities can be removed by SF6 injection in the? sequence of Sb >As >,Bi and the rate of Bi removal is affected significantly by the concentration levels of As and Sb in the copper melt. Analysis of the experimental data indicates that the impurity removal process is under chemical reaction control rather than by mass transfer of impurity through the molten copper phase. On the basis of experimental results, a kinetic model was developed and the order of chemical reaction and the volumetric chemical reaction rate coefficients of impurity removal were determined.

Jan 1, 1996

Detrital gold in the Greymouth-Hokitika area has been won from: (a) gravel of the Pliocene Old Man Group, (b) glacial outwash gravel of Middle and Late Quaternary age, (c) raised shoreline deposits of Middle and Late Quaternary age, (d) deposits resulting from the erosion of (a) to (c). The source of the gold was probably widely dispersed quartz veins in great thicknesses of greywacke and low-grade schist eroded from east of the Alpine Fault, with a contribution from veins in Greenland Group greywacke in the south. At times of high interglacial and post-glacial sea level, gold was concentrated along marine shorelines, and subsequent progressive uplift has resulted in a set of sub-parallel beach leads up to 100 m above present sea level. During glaciations, gold was concentrated in outwash streams close to moraines, especially where ice forming one moraine penetrated and destroyed an older one. Worked deposits in the Old Man Group may also be associated with glaciation. Apart from workings that are essentially extensions of past workings, significant new prospects may depend on inferences as to where prospective deposits are completely obscured by younger ones.

Jan 1, 1996

By Andrew G. Martin

In 1991, Modular Mining Systems began marketing a Slope Monitoring System (SMS) now installed at twelve mines. The SMS uses automated wire line extensometers to monitor field conditions frequently. Every few minutes, the slope displacement values and current temperature are transmitted to a central computer via a packet radio telemetry system. The desktop workstation receiving the data continuously provides updated displays of active slope monitors and generates audible and visual alarms if movement exceeds user specified thresholds. The computer system also generates numerous graphs and reports for quick analysis of slope stability. This work describes the functionality of the SMS, details improvements to the SMS hardware and software developed for several clients, outlines different installation techniques needed for wall rock and spoil monitoring, and interprets slope movement data using illustrations of stable and unstable conditions.

Jan 1, 1996

By M. Kawulak

The necessity to protect the environment can limit mining activities and make some areas less attractive for the prospecting and exploration of mineral deposits. In Poland, the main environmental factors that restrain Irumng are: 1. Regional A Protection of the landscape B. Protection of ground water from contamination and depletion 2. Local A Conservation of fertile soils B. Conservation of forest resources C. Preservation of natural, cultural, and historical monuments The regional factors listed above that can limit mining are presented on a map of Poland. These data, combined with maps of known and potential mineral deposits, make it possible to delineate general levels of limitation for various mining-related activities varying from "no existing environmental limitations" to "no allowed industrial activity" As an example, a compilation of such data is presented for lignite exploration and mining in Poland. Lignite deposits occur within Upper Paleocene to Upper Miocene clastic strata at depths ranging from a few to 300 m. The thickness of the lignite is generally a few meters, but can locally reach over 100 m within grabens. As a result, the overburden-to-lignite thickness ratio varies from less than 1 to over 20. Within the same Tertiary strata, and within overlying Quaternary strata, several aquifers exist that produce good quality water that may be contaminated or depleted during lignite mining. The protection of these ground waters is the main factor limiting lignite mining and should be addressed in mining and environmental policy and planning.

Jan 1, 1996

By Jaye Pickarts, Bret Boster, Jack McPartland

Pegasus Minera de Chile, Ltda. is completing three phases of metallurgical evaluation on the Pullalli project to develop a preliminary process flowsheet. A project feasibility study is in progress. The feasibility study includes a proposed process flowsheet designed based on results from the multiple stages of metallurgical evaluation. Phases I and II of metallurgical evaluation included laboratory scale heap leach and milling cyanidation testwork on multiple drill core composites and bulk ore samples from the Pullalli Project. Phase Ill included pilot scale milling/cyanidation testwork on Pullalli drill core composites. The proposed flowsheet includes selective mining and separate processing of low grade and high grade ores. Low grade ore will be crushed and heap leached. High grade ore will be milled leached for 12 hours in an agitated cyanidation circuit. After 12 hours of leaching, sands and slimes will be separated and the sands will be washed using a counter current cyclone (CCC) circuit. Partially leached and washed sands will be added to the crushed low grade ore for heap leaching treatment and permanent placement. Partially leached slimes will be thickened in a high capacity thickener and will be processed in a CIP circuit. Leached slimes will be placed in a tailings impoundment.

Jan 1, 1996

By Renato G. Bautista

"The chemistry of the separation of metals from each other and from the other undesirable components involve multiple simultaneous chemical reactions. In the case of leaching, the heterogeneous chemical reactions between the solid and the liquid phase may be limited to a few reactions. In the homogeneous liquid phase, the number of simultaneous chemical reactions could be double or triple that of the number of heterogeneous reactions. The rate of dissolution becomes very dependent on the changing concentrations of the significant chemical species taking part in the multiple reactions in both the heterogenous and homogeneous phase. The rate expression developed for the process must take into account the mechanism of chemical reactions in order to best represent the actual process. This paper also examine the role of mass transfer with chemical reaction in the develpoment of the rate equations for dissolution, liquid-liquid extraction, membrane separation, precipitation, and electrodeposition.IntroductionThe understanding and the elucidation of the mechanism of the rate phenomena for a specific chemical reaction system is of prime importance in the development of a successful chemical process. The development of successful emerging technologies for metals separation will depend on the accurate interpretation of the intrinsic chemical reaction kinetics and the rate of mass transfer of the desired metal species during its separation from the undesirable chemical species. This is the case whether the process application is for separation, concentration, and /or purification.The chemical processes that will be examined in this presentation will include leaching, solvent extraction, membrane separation, precipitation, and electrodeposition."

Jan 1, 1996

By Ronald C. Askin

Dredging is a common method of remediating ponds containing contaminated wastes. However, dewatering of the dredged solids is usually not well integrated with the dredging phase. As a result, overall project efficiency can be poor. Specifically, since dredges deliver material in a widely varying slurry form and since dewatering presses require the delivered material to be uniform, union of the two systems often results in inconsistent operation of the overall process. In an effort to enhance overall dredging and dewatering process production rates as well as minimize the return of suspended solids in the decant water, a new process was developed to provide a consistent dredged sludge for delivery to the press. This paper discusses modifications made to a conventional dredging and dewatering process to improve production rates and dewatering capabilities. These modifications are applicable to any project where efficient solids dewatering is required and where returning decant water must be visually free of suspended solids.

Jan 1, 1996

By Mark A. Willian

The purpose of this short paper is to present soil profiles and basic soils information for the portion of the I-880 Replacement Project alignment where highway structures are to be built. The information presented here is derived primarily from foundation investigations conducted by the Caltrans Foundation Unit (currently the Structures Foundation Branch, Office of Structural Foundations) and by others under Caltrans direction. The foundation investigation for the I-880 Replacement Project began in May of 1991. The field work was completed in May of 1992 and consisted of 93 rotary sample borings, 11 consolidation sample borings, 6 TEXAM® pressure meter borings, six in-place vane shear borings and 57 electronic cone penetrometer soundings.

Jan 1, 1996

By Jerry Dolph

In September 1855, 55-year-old Noah Spencer Kellogg and his $3 jackass named Bill discovered what was known at the time as a “blow out” of high-grade lead and silver ore. The deposit was located on the side of a North Idaho mountain high above the South Fork of the Coeur d’Alene River. The ore was later assayed at 41,141 g/t (1,200 oz/st) silver. Kellogg named his discovery the Bunker Hill Lode, after the June 17, 1775 Revolutionary War battle of Bunker Hill. A thriving pioneer settlement sprang into existence around the resulting mine’s workings and was eventually— and appropriately — named Kellogg. The peak rising hundreds of feet above the mine’s adit was named “Jack-ass Peak” after Noah Kellogg’s hairy companion.

Jan 1, 1996

By Subhash B. Bhide

Deep foundations are affected by the presence of sulphates, chlorides, organic contents and water currents present in the soil. The sulphates in soil and ground water interfere first with setting of concrete. In long term, growing of sulphate crystals in concrete, crevices can spall the concrete. The chlorides mainly affect the steel. The organic content does not allow the concrete to set. It also reduces the compressive strength of concrete. The frequency and methods of sampling and testing for above corrosive elements are discussed. Presently available methods to avoid attack due to these corrosive elements are discussed. The stipulations by various codes are summarised. A method to assess the short term impact is elaborated with results of field studies. A tool developed to study the presence and effects of underground water currents on concrete is also discussed.

Jan 1, 1996

By J. Nakayama

Down-the-hole hammer is commonly recognized as the most powerful drilling equipment for weathered to fresh rock formation including boulders. However, its drilling diameter is restricted by reasons of difficulty to actualize large diameter drillhead and to ensure discharging means of cuttings. Cuttings are usually removed by flushing i.e. uprising return air after compressed air actuates hammer, but in case of large diameter drilling, as the clearance between drill rod and surrounding wall of hole become fairly large, necessary up-hole air velocity to transport cuttings can not be maintained. In case of marine or underwater drilling or high groundwater table, orthodox down-the-hole hammer is obstructed its operation by water. This single head hammer drill combined large diameter drillhead with reverse circulation of drilling fluid enables large diameter drilling extending to 1.5 m, i.e. actualized large diameter mechanical drillhead incorporated with ensured cuttings removal means enabled this range of drilling. This paper introduces its features and actual applications to large diameter bored pile drilling for varied sorts of rocks in maritime construction projects.

Jan 1, 1996

By Troman L, Groutsch J. V

The Kwinana Nickel Refinery began operations in 1970 processing sulphide concentrates from Kambalda using the Sherritt Gordon pressure leach and hydrogen reduction process to produce nickel metal as powder and briquette. Over the years a number of changes have seen the refinery capacity increased from the original design capacity of 15 000 tpa nickel on an all concentrate feed to its current design capacity of 42 000 tpa nickel on an all matte feed. This paper outlines the changes in plant equipment and process for the most recent refinery expansion from 35 000 tpa to 42 000 tpa which have been implemented since 1992.

Jan 1, 1996

By R W. Thomas

"This paper explores the possibilities of generating radical improvements in the drihing costs andproductivity of blastholes through the efforts of integrated teams as opposed to traditionalcustomer/vendor relationships."

Jan 1, 1996

By L. Harris

The Yanacocha project is the first foreign investment in Peruvian mining since Cuajone during 1976. Three years after the project began, it has become the largest producer of gold from heap-leach operations in the world and the top producer in Latin America. The success of Minera Yanacocha SA (MYSA) opens a new chapter in Peruvian mining with the exploitation of its widely spread gold deposits. And it has attracted the interest of foreign investors in Peru’s mineral resources. Construction began on Aug. 1, 1992. The first gold bar was poured on Aug. 7, 1993 from ore from the Carachugo Mine. During 1993, Minera Yanacocha produced 2.5 t (81,000 oz) of gold and 9.4 t (304,000 oz) during1994 (40% above budget). Production was expected to exceed 15.5 t (500,000oz) during 1995 with the start-up the Maqui Maqui Mine.

Jan 1, 1996

The Olympic Dam deposit is located some 600 km north of Adelaide in South Australia. It was discovered in 1975 by Western Mining Corporation and in 1979 a joint venture was formed with British Petroleum for the evaluation and development of the project. Studies were completed and construction started in 1986 with the plant being commissioned progressively between April and August of 1988. In 1993 Western Mining acquired BP's interest and are now owners of the whole deposit. The scale of the initial development was 1.5 Mtpa of ore for the production of 45 000 tpa of copper cathode, 900 tpa of uranium oxide and some gold and silver. Two expansion programs have occurred in 1992 and 1995 and current performance is at the rate of 3 Mtpa of ore for the production of 84 000 tpa of copper cathode, 1500 tpa of uranium oxide, 24 000 oz per year of confined gold and 380 000 oz per year of confined silver (Table 1). An aerial view of the plant is shown in Figure 1. The benefit of diversifying into the production of more than one product is undoubted and the flexibility of being able to produce variable quantities of copper and uranium also allows advantage to be taken of a change in market conditions.

Jan 1, 1996

By Theo Lehner

"During my first contact with industrial metallurgy as a summer vacation worker at the Steelplant at Luleå, Sweden, I came during a visit to MEFOS into contact with works of Prof. Worner caried out during the piloting of the Worcra continuous steelmaking process. These tests are still today remarkable as an innovative step in the art of metalmaking. By that they involved the necessary ingredients for the development of our art: seeing, knowing and doing. Industrial injection as applied during slag fuming will be discussed below.Phenomena of injection metallurgyPhenomenon according to Collins dictionary is"" anything that can be perceived as an occurrence or facts by the senses"". To open the senses for the interesting phenomena in pyrometallurgy must be the main task of any educator. The investigations by Engh et al. around the mixing phenomena of the WORCRA process are an early example of combining senses with knowledge. To see what you model must be a crucial part in any development. This can also involve to see and control that one is subject to the same conditions as in published models. Below the need ""to see"" will be illustrated by some recent investigations around slag fuming. In the literature various models for reactions occuring during the fuming of slags are presented. Two recent models hint ·ata) the occurrence and importance of iron for the fuming processb) the occurrence and importance of lead droplets during respectively."

Jan 1, 1996

By Gus Van Weert

Hydrometallurgical oxidation of sulphides is capital and energy intensive, with autoclave and bio-technology competing for lowest overall cost status. The use of surface aerators instead of stirred tank reactors could provide lower costs for bio-oxidation of concentrates. With this in mind, the Delft Inclined Plate reactor was designed with inclined plates above a settler shaped reactor to continuously return slurry from the lowest point in the settler to the surface of the liquid. The multiplate superstructure overcomes the scale-up restriction of the standard circular surface aeration patterns. DIP aerator energy and volume requirements for oxygen transfer from air will be presented in terms of kg O2/kWh and kg O2/m3/h transferred as a function of wt % sand in the slurry and compared to stirred tank performance. Scale up from the 4 m3 pilot unit will be discussed.

Jan 1, 1996

By Thierry Bernard, Pierre M. Vuillaume, Michel Kiszlo

"In the context of its studies for the trench ministry of the environment and for the French national coal board, INERIS (the French institute for the industrial environment and hazards, formerly CERCHAR) has made a complete critical survey of the methods generally used to reduce the levels of blastingvibrations."

Jan 1, 1996

The Cooperative Research Centres (CRC) Program was established and is supported by the Australian Government at a total cost of $140 million per year. Six of these centres have been established to help Australia's mineral industry: three in exploration, one in mining and mineral processing and two in extractive metallurgy. Since the CRC Program has now been in operation for five years, it is a good time to ask whether the minerals industry is being served adequately by these centres. In this paper, the performance of one CRC, namely the A J Parker Cooperative Research Centre for Hydrometallurgy, will be discussed in terms of the objectives of the CRC Program. As will be shown, the Parker Centre has made considerable progress since its establishment in 1992.

Jan 1, 1996

By D. H. C. Wilton, W. A. Sears

"Abstract-The 682.8 ± 1.6 Ma Tickle Point Group consists mainly of rhyolite flows and tuffs with- in the Avalon Zone of the Appalachian Orogen in Newfoundland. Stratabound massive sulfide mineralization, consisting of pyrite, sphalerite, chalcopyrite and galena, occurs at the Winter Hill prospect, where a lower pyritic, Cu-rich zone and an upper Zn-Pb-rich zone are hosted by a carbonate-calc-silicate lens. At the Frenchman Head prospect, stringers of pyrite, minor sphalerite, chalcopyrite and rare galena are hosted by felsic volcanic rocks of the Tickle Point Group .Base metal ratios, metal zonations and the overall stratigraphic framework suggest that these sulfide occurrences represent volcanogenic massive to semi-massive sulfide mineralization (stringer type at Frenchman Head). As such these prospects represent the only known VMS occurrences within the Avalon Zone of Newfoundland. Pb isotope data indicate that galena from the Winter Hill prospect is less radiogenic and older than galena from Dunnage Zone occurrences, and suggest that the Winter Hill mineralization formed in an environment tectonically distinct (exotic) from the Dunnage Zone."

Jan 1, 1996