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By Jennifer Murphy, Brad S. Schake, Karol Holmes, John R. FitzPatrick, Mike H. West

"The separation and purification of uranium from either nitric acid or hydrochloric acid media can be accomplished by using either solvent extraction or ion-exchange. Over the past two years at Los Alamos, emerging programs are focused on recapturing the expertise required to do limited, small-quantity processing of enriched uranium. During this period of time, we have been investigating ion-exchange as a method for extraction/purification of uranium from acidic media. In addition, waste stream polishing is associated with this effort in order to achieve more complete removal of the uranium prior to recycle of the acid. Extraction chromatography has been demonstrated to further polish the uranium from both nitric and hydrochloric acid media thus allowing for a more complete recovery of the actinide material and creation of less waste during the processing steps.We will discuss contact experiments for evaluation of eleven different resins for uranium removal from nitric acid, the evaluation (again by contact experiments) of uranium elution from the ion-exchange media by various chemicals, and small-scale experiments for the removal of 235U from nitric acid. Larger-scale (1 DO-gram) flow experiments, using depleted uranium, were done after the small-scale evaluation of the selected resin. A discussion is also included concerning the shortcomings of the contact experiments and how the flow experiments were modified in order to overcome these problems. We will also discuss the application of ion-exchange for some specific process needs at Los Alamos.Contact experiments were used to evaluate some commercially available solvent-impregnated resins in addition to evaluation of several resins of this type synthesized in our laboratory. These experiments involved both nitric and hydrochloric acid media. The data from these experiments will be used to determine the column size and amount of resin required to polish the waste stream produced by the ion-exchange process described above. Small-scale flow experiments will be described and data given on the mass balances achieved using this two step process.Future work for evaluation of new ion-exchange and solvent-impregnated resins as well as the search for new eluants will be discussed. Other future experiments for both processes, including large-scale experiments, will be discussed in detail."

Jan 1, 1996

The Mining Foundation of the Southwest will hold its 14th annual American Mining Hall of Fame awards banquet Saturday, Dec. 7, 1996 at the Leows Ventana Canyon Resort in Tucson, AZ. Each year, preceding the Arizona Conference of SME, the Mining Foundation sponsors this banquet to honor outstanding contributions by people in the mining industry. A permanent display of honoree vitae is located at the Arizona Historical Society in Tucson. Each year, one living award recipient and up to two honorees from mining’s history are chosen by the hall of fame committee and the board of governors of the Mining Foundation. In 1989, the foundation also established a medal of merit to recognize outstanding individual technical and professional contributions to the mining industry. And, in 1995, an award was created to recognize contributions made by companies and individuals in partnership with the mining industry. This year’s inductee is Richard de J. Osborne, chairman, president and chief executive officer of Asarco. He will also be the featured speaker at the banquet.

Jan 1, 1996

By P. R. Khangoankar, S. Devasahayam

An experimental study of the particle charac¬teristics of the magnesium carbonate crystals formed by the reaction between magnesium chloride and sodium bicarbon¬ate at different temperatures is described. The rate of growth of magnesium carbonate crystals for any constant tempera¬ture is established, and this rate of growth is related to the degree of supersaturation at the given temperature. The activation energy calculated using empirical constants de¬rived from the relationship between the crystal growth rate and supersaturation, is indicative of a surface-reaction mechanism.

Jan 1, 1996

Characterizing coal mine roof rock is extremely important for hazard assessment, reinforcement, and entry design. The Coal Mine Roof Rating (CMRR) is an innovative rock mass classification that has found acceptance in the coal mining industry. A disadvantage of the original CMRR is that it cannot be determined in advance of mining, because it requires underground observations. An entirely new set of procedures have now been developed to determine the CMRR from exploratory drill core, as described in this paper. The new procedures employ Point Load Tests (PLT) to determine strength parameters that account for approximately 60% of the rating. Both diametral (parallel to bedding) and axial (perpendicular to bedding) PLT are conducted. The diametral tests allow estimates of bedding plane cohesion and rock anisotropy, both of which are critical to estimating susceptibility to horizontal stress. Traditional core logging procedures are used to determine discontinuity spacing and roughness. To ensure compatibility with the original CMRR, the new rating scales were verified by comparing drill core results with nearby underground exposures. To assist mine planners in using the new CMRR procedures, a large database of strength ratings of roof rocks was assembled through extensive point load testing and logging. Over 2000 point load tests (both axial and diametral) have been made on 30 common coal measure rock types from mines representing most U.S. coalfields. This database has been merged with the popular core rating system of J.C. Ferm into a field guide for geologists and engineers. By using the pictorial classification system of Ferm to identify the rock, typical CMRR can be compared with values calculated using the new CMRR procedures.

Jan 1, 1996

By Norbert Steiner

For the desulfurization of weak SO2 gas streams, Degussa developed a process using dilute H2SO4 solution containing H2O, instead of conventional gas scrubbing with all solid absorbent medium (limestone, MgO). The process is based on fast reaction of H2O, with SO2 yielding H2SO4 up to 70% strength, depending on off-gas temperature. Compared to the conventional systems with typically < 95% efficiency, independent on the raw gas SO2 concentration, residual SO2 concentrations of less than 20 mg/Nm3 can be easily achieved, corresponding to nearly 100% removal. These features render the H2O, process a very attractive, low capital cost technology to retrofit existing conventional desulfurization plants.

Jan 1, 1996

By Michail G. Egorov

As well as destruction and moving rock, the blast energy sets up a seismic wave in the ground and a shock wave in the air, which can present danger to buildings and disturbance to human occupants. This shock air wave potentially can cause to destruction of a window glass, the window and door frames and partitions of buildings. In modern buildings, distinguished with high flexibility, the shock air wave can cause to the intensive wall vibration, dangerous for these buildings.

Jan 1, 1996

By G. E. Blight

Several aspects of the behaviour and properties of backfills consisting of cemented cyclone underflow tailings are illustrated by means of examples, and guidelines are given on the optimization of the performance of cemented fills. The stretch characteristics of the geofabric used to contain freshly placed backfill are described, as well as the relationship between these characteristics and the forces acting on retaining barricades. The properties required to achieve a self-supporting, stable free face in cemented backfill are explored, and a graphic relationship between stable height and shear strength is presented and compared with that for uncemented (classified) tailings. After a description of the characteristics of Witwatersrand quartzite gold-tailings backfill and commonly used cements, the process of drainage and air entry into backfill is outlined. Following this, the early-age gain in strength and the shear-strength characteristics, as well as the compressibility characteristics of cemented backfill, are described. Two phenomena that are potentially damaging to cemented backfill are seismic effects (or blasting acceleration) and the closure that takes place during the curing of cement. Investigations show that neither of these phenomena is actually significantly deleterious to gold-tailings backfill: liquefaction does not Occur as a result of seismicity, and hydration of cemented fill is not significantly impeded by closure.

Jan 1, 1996

The alluvial diamond deposit in the Kimberley Region of Western Australia which became to be known as the Bow River Diamond Mine was discovered in 1982 by joint venture partners Freeport of Australia Inc and Gem Exploration and Minerals Ltd. Mining commenced in 1987. This paper describes the exploration programs and results from discovery to commencement of mining and reviews the public reporting of this process in the light of 1992 Ore Reserves Code (JORC, 1992). This case study illustrates the difficulties involved in resource estimation of alluvial diamond deposits. The study also shows that current reporting standards were, to a large extent, adhered to a full ten years before the diamond reporting section to the Code was formulated.

Jan 1, 1996

By David C. Lynch

FeCl3 particulate of 10 to 100 um in diameter was reacted with radicals produced in an oxygen plasma at pressures between 1 to 20 Torr. The particulate, in a fluidized bed, was positioned above the plasma to avoid over heating the oxide product which is known to lead to crust and clinker formation[ 1 ]. Reaction between the iron chloride and the gas phase occurred at temperatures between 66 and 226 °C. Oxygen radicals react with the surface material to a depth of approximately 2.5 4m. Surface material, analyzed with a x-ray technique, indicates that the maximum amount of FeCl3 reacted on a weight basis was found to be approximately 67%. More typically, 40 to 50 wt% of the chloride was reacted within 30 minutes to 1 hour.

Jan 1, 1996

By M. Misra

A sample of thorium-contaminated soil from Kirtland Air Force Base (AFB) was subjected to froth flotation for removing thorium contaminants. A series of flotation tests were conducted to screen and evaluate the reagents. Among the collectors used, sodium oleate exhibited to show the promising results. Preliminary tests showed that a concentrate having activity as high as 5300 pCi/g can be obtained from the contaminated feed soil having activity 800 pCi/g. The volume reduction obtained was 89% and the activity recovery in the concentrate was 68%. The paper discusses the physico-chemical characterization data and the potential physical separation decontamination schemes for the thorium contaminated soils.

Jan 1, 1996

By Walker G. S

Infrared and Raman spectroscopy have been used to study a range of solid state and aqueous solution species which are of interest in extractive metallurgy. In the solid state new Cu(II)/CN&apos;/NH3 complexes have been detected, iron impurities in kaolin characterised, aluminium substitution in hematite and goethite quantified, and the crystallinity and orientation of zircon determined in heterogeneous crystals. In aqueous solution metal cyanide complexes and equilibria were readily characterised, the thermal decomposition of SO2 monitored and products identified, and complexation of AI(III) by hydroxycarboxylates observed. Attempts to monitor the early stages of the gelling of silicate solutions were less successful, with only changes in the gel being detected. However, the degradation of 12-tungstosilicic acid was readily monitored as a function of both time and pH.

Jan 1, 1996

By T. Foster

The continuous operation of decanters in the mining industry relies heavily on the use of synthetic flocculants. Today, as plants seek to lower production costs by increasing throughput it is necessary to obtain optimum performance from the flocculant. Factors affecting such optimization include charge and molecular weight selection, and efficiency of mixing the highly viscous polymer solution with the feed slurry. Beyond maximizing dilution of the solution, the last factor is often ignored. This paper describes a series of calculations, based on fundamental transport theories, that have been used to describe flow conditions within decanter feed wells and to help select flocculant addition points. Examples are shown for the case of hydroxamated polyacrylamide flocculants in the Bayer Process, where proper selection of the addition points can result in lower flocculant dosage and better control of the decanters.

Jan 1, 1996

n interesting situation arose last week when two Vaal River residents wrote to me (and a third telephoned) giving me details of how Sasol wanted to develop an open-cast coal mine on the south bank of the Vaal, just upstream of the Barrage. This is agricultural land and is across the river from Millionaire?s Row, where a number of wealthy people have built river-side mansions. The mine would be hidden by a 30 m-high (10 storeys) earth wall set 300 m back from the edge of the river. It could operate 24 hours a day.

Jan 1, 1996

By Dhanvin B. Mehta

Pile testing is generally understood as static load test. It is our common experience that for high capacity, large diameter bored piles, static testing is expensive and time consuming. It is practically impossible to test large number of piles by traditional testing methods. The escalating cost in carrying out a static load test, as well as incomplete information derived therefrom compelled researchers in United States to look for an alternative method of testing for both bored and driven piles. The original research work was carried out at Case Western Reserve University in early 70&apos;s, under the funding of Federal Highway Administration as well as several State Depts. of transportation in United States. The outcome of the research was the development of a state of art field computer for capacity determination, based onOne Dimensional Wave Mechanics.

Jan 1, 1996

"Blasthole deviation is a frequent, well documented and undesirable occurrence in mining operations. It is caused by the drill string mechanics, operating variables and the 'interactionbetween the drill bit and the rock mass characteristics. It is composed of three distinct components: collaring or marking error, alignment error and trajectory deviation. This study has focussedon the dependence of trajectory or natural deviation on the geological features of the rock mass being drilled."

Jan 1, 1996

By Charles L. Karr

Researchers at the University of Alabama in cooperation with the U.S. Bureau of Mines have developed adaptive process control systems in which genetic algorithms (GAS) are used to augment fuzzy logic controllers (FLCs). GAS are search algorithms that rapidly locate near-optimum solutions to a wide spectrum of problems by mimicking the search procedures of natural genetics. FLCs are rule based systems that efficiently manipulate a problem environment by modeling the "rule-of-thumb" strategy used in human decision making. GAS and FLCs can be combined to produce powerful, efficient, and robust adaptive control systems. To perform efficiently, such control systems require a control element to manipulate the problem environment, an analysis element to recognize changes in the problem environment, and a learning element to adjust to the changes in the problem environment. I" this paper, the details of an ongoing research effort to develop and implement an adaptive process control system for a column flotation unit are discussed.

Jan 1, 1996

By B. K. Cantrell

The U.S. Bureau of Mines and others have conducted a number of occupational exposure surveys since the publication of the International Agency for Research on Cancer report of 1989, which labeled diesel exhaust as a probable human carcinogen. These surveys have assessed diesel exhaust exposure using measurement of diesel aerosol and/or specific polycyclic aromatic hydrocarbons as indicators of exposure. This paper reviews present diesel emission standards, available diesel exhaust aerosol measurement techniques, and the results of the occupational exposure surveys. In the surveys, diesel aerosol was emphasized because it is a major component of diesel exhaust, is suspected to contribute to the health hazard, and is readily measurable. Three primary aerosol measurement techniques were used: respirable combustible dust, size-selective sampling, and measurement of the elemental carbon fraction. Occupations surveyed included mine workers, railroad workers, forklift operators, fire fighters and truck drivers. The studies found mean diesel aerosol concentration levels in the range of 0.004 to 1.74 mg/m3? Highest aerosol exposures were in confined spaces such as mines where heavy diesel equipment is used. Polycyclic aromatic hydrocarbons typically are found at very low concentration levels and are not unique to diesel exhaust.

Jan 1, 1996

By Hassan Madani, A. Malek Mohammadi

Dorreh barite mine located in the central part of Iran is one of the largest barite mines, in the country. The mine is subdivided into three blocks, which are called block 1,2,3 according the barite quality. In the central part of each block, a heavily concentrated grid of exploratory drill holes have been drilled and the reserves of area was calculated based on these holes, some years ago. It was decided to compute the reserve of the area by geostatistical methods, in the form of an M.Sc. project. In order to study the area, three regionalized variables including density, thickness and density-thickness (accumulation) was studied and the spherical variograms were fitted to these variables. These models were evaluated by cross-validation method. The optimized block size was chosen in order to compute the reserves by kriging method. The reserves of explored parts of each block of mine was calculated and the results were extended to the whole area of the blocks. The reserve of the explored parts and the total reserve of the area were calculated to be 96,000t and 1,670,000t respectively.

Jan 1, 1996

By Larry A. Morris

The environmental impacts of industrial activities have become very serious concerns of the public over the past few decades. Not surprisingly, governments have responded with legislation and regulations to force industry to operate in a more environmentally responsible manner and, more recently, have prompted industry to initiate voluntary measures in response to specific environmental issues. The concept of Product Stewardship has evolved as a system or vehicle for the industrial sector to demonstrate an active concern about the environmental impact of their products, services and processes.

Jan 1, 1996

Power plants that utilize conventional wet flue-gas desulfurization methods produce enormous amounts of flue-gas scrubber sludge. A typical 400 MW power station that burns a high sulfur coal produces 170,000 tons of wet flue-gas scrubber sludge per year. This scrubber sludge is currently landfilled at an enormous cost to utility companies. This material could be used as a raw material for industries that use gypsum, such as the wallboard and plaster industries. However, before it can be used as feedstock for these industries, some of the impurities such as unreacted limestone and silicates must be removed from the scrubber sludge. Froth flotation has tremendous potential for separating these impurities from scrubber sludge. In order to select an optimum flotation process, it is necessary to characterize the surface properties of the major components in the scrubber sludge, which consist of calcium sulfite, calcium sulfate, calcium carbonate (limestone), and silica. In this study zeta potential measurements were used to determine the surface charge of the components in scrubber sludge, with the goal of optimizing a froth flotation process to produce a marketable gypsum product for the wallboard and plaster industries.

Jan 1, 1996