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By Azizan A

The paper presents the results of chlorination of beneficiated rutile and struverite (a tantalum-niobium bearing, rutile type mineral in alluvial tin deposits) by carbon tetrachloride in the range 623¦K to 773¦K. The chlorination of rutile could reach near completion at 773¦K in about an hour. The process was found to follow a modified pore-blocking law, with the basic reaction constant K varying inversely with the particle size, so that the basic process may be a reaction under interface control (chemical control) as modified by the pore blocking effect. The pore blocking factors for the various experimental conditions were evaluated and the predicted curves showed good agreement with the experimental data. In the case of Struverite, a similar kinetic behaviour was observed but the chlorination process was relatively slower than that in rutile. It was also observed that in struverite, niobium got chlorinated faster, followed by tantalum and titanium, indicating a good possibility of separation by chlorination using carbon tetrachloride.

Jan 1, 1996

By Neil Runciman, Greg Newson, Nick Vagenas

This paper discusses simulation modelling of underground mining operations at a typical mine in the Sudbury mining area in Ontario, Canada. The PC simulation software, WITNESS Version 7 Release 6.0 by AT&T ISTEL, is used to model the drilling, blasting, hauling and ground support operations. Simulation is used to investigate the development mining cycle and determine the capabilities and flexibility of WITNESS to accurately represent the mining system under consideration. The simulation study discussed in this paper provides a first step in determining the successful application of WITNESS in the underground operational aspects of the mining industry.

Jan 1, 1996

By Vladimir Panjkovic, Ostrovski. Oieg, Campbell Cripps Clark, John Truelove

"Effects of properties of raw materials and blast on the performance of an iron bath reactor have been examined by a mathematical model. The model consists of three modules: 1) chemical reactions in the gas phase and heat transfer from gas to droplets ejected from the bath; 2) heat losses from the vessel and radiative heat transfer from the freeboard to the bath; and 3) heat and mass balances for the bath. The following parameters of the process are calculated: coal, ore, flux and oxygen consumption, post-combustion ratio and heat-transfer efficiency, temperature and composition of the off-gas, and slag and metal chemistry.IntroductionOne of the anticipated advantages of smelting reduction over conventional ironmaking is the use of lower-grade raw materials. In this work, the effect of-properties of raw materials on the performance of an iron-bath reactor is examined with a numerical model. The model is also used to assess the effect of properties of the blast (flowrate, temperature and oxygen enrichment) and ejected droplets (generation rate, size and ratio of total weights of slag and iron droplets) on the key parameters of the process. In the process coal, oxygen, ore (which may be partly prereduced) and fluxes for specified slag composition are charged to the bath. Slag and iron droplets are ejected from the bath into the gas phase, where they are heated before returning to the bath. Iron droplets undergo decarburisation and reoxidation with CO2 and H2O. Dust is also generated from the bath, and oxygen or preheated air for post combustion is injected from the top of the vessel.The model consists of three modules: 1) reactions in the gas phase and heat transfer from gas to droplets ejected from the bath; 2) heat losses from the vessel and radiative heat transfer from the freeboard to the bath; and 3) heat and mass balances for the bath. The structure of the model and the data exchange between the modules are shown in Fig. 1. The following parameters of the process are calculated: coal, ore, flux and oxygen consumption, postcombustion ratio (PCR), heat transfer efficiency (HTE), off-gas temperature and composition, slag and metal chemistry, and rates of decarburisation and reoxidation of the iron droplets."

Jan 1, 1996

By S. Sundarraj

The morphological transition between columnar and equiaxed structures is an important solidification phenomenon frequently observed in castings, especially complex parts with varying cross-section, The mechanical properties and the occurrence of defects such as hot tears are strongly dependent on the structure formed in the casting. Hence, it is important to understand the conditions leading to columnar or equiaxed structures. Although extensive work has been done in modeling solidification systems, almost all of the existing models are based on the assumption that the structure formed in the casting is either purely columnar or purely equiaxed. Prediction of the columnar-equiaxed transition (CET) requires a solidification model which accounts for the formation of both columnar and equiaxed structures, along with related microscopic and macroscopic solidification phenomena. In this paper a CET model is presented which: (i) takes account of both columnar and equiaxed structures, (ii) accounts for macroscopic heat transfer coupled with microscopic phenomena such as nucleation, growth and microsegregation, (iii) satisfies solute conservation, and (iv) is easy to implement in commercial finite element and finite difference software. The proposed model predictions of CET have been validated with available experimental results for a uni-directional solidification of an aluminum-copper alloy. A sensitivity analysis has also been carried out to determine the effects of various parameters on the CET model predictions. The model is being extended to other alloy systems and more complex geometries. This work will be published in due course.

Jan 1, 1996

Much of the coal and gold mining industry of New Zealand is small scale. Funding is tight and mechanisation limited. The country has many well documented small coalfields (some with significant outcropping) and alluvial gold deposits. These are generally remote, difficult to access (physically and otherwise) and of submarginal value (largely a consequence of size when viewed for extraction by traditional techniques). The industry is also burdened by environmental and bureaucratic constraints. The above over simplified setting suggests to the Author, a newcomer to New Zealand, the opportunity to consider some novel concepts based on technology and techniques developed overseas or borrowed from other industry sectors. The objective being to make viable in economic and environmental terms projects that might otherwise be stillborn if considered for exploitation by conventional means. The paper mainly discusses 2 concepts focusing on the application of augers for exposed high wall or outcrop coal and micro-tunnelling augers for alluvial gold extraction. These may be considered high mobility 'container' (as in shipping container) packaged, or 'non invasive' mining systems. It is stressed that these are but concepts and have yet to be subjected to rigorous financial or engineering scrutiny. This could only follow their acceptance by, and input from, New Zealand miners. There will also be brief mention of a new modular conveyor system which might have application within the concepts or existing small scale mineral extraction operations and mention of a project currently in progress to apply tangible 'sustainability' to underground coal mining.

Jan 1, 1996

By George P. Schivley

The careful positioning of the drill rigs that drill the holes into which explosives are then loaded is critical to the success of the subsequent blast. Today a system of satellites in space, each transmitting radio signals, is being used to provide the data to allow for tracking and positioning of various types of ground-based mobile equipment. The system is the Global Positioning System or GPS for short. This paper focuses on the application of GPS to surface mining and in particular the navigating of rotary drills from hole-to-hole and their final precise positioning to drill each blast hole.

Jan 1, 1996

By C. B. Solnordal, R. N. Taylor

"The heat transfer conditions on the outer side of a Sirosmelt lance have been determined using experimental measurements in combination with a mathematical model. By measuring the temperature distribution along the wall of an operating Sirosmelt lance, as well as the thickness of the slag layer on it, it was possible to use the model to determine both the heat transfer coefficient between the vessel contents and the lance, as well as the effective thermal conductivity of the slag layer. The effective thermal conductivity of the slag layer was found to be within the range 0.7-1.3 W.m-1. ºCl, which was in good agreement with measured values for magnetite. The outside heat transfer coefficient varied from 80 to ISO W.m-2. ºC1, which was smaller than quoted in the literature for metal/slag systems. The discrepancy was attributed to the high thermal resistance experienced between the lance wall and the slag layer, as well as the large quantities of combustion gases that envelop the lance tip and reduce convection and conduction from the melt to the lance. INTRODUCTIONThe Sirosmelt submerged combustion smelting process [1] utilizes top injection lances to deliver fuel and air into a metallurgical melt. To help prevent lance failure from attack by liquid slag, helical vane swirlers are used within the annular lance to impart swirl to the flowing air and enhance the heat transfer from the lance wall to the air. The swirlers thus cool the wall, and enable a frozen layer of slag to form on its outer surface. This solid layer ensures liquid slag cannot reach the lance surface, and the lance is protected.A mathematical model of the heat transfer processes associated with the lance has been developed, which combines heat balance equations with engineering correlations to predict the wall and cooling air temperature of the lance, as well as the air pressure distribution. An account of the model was given by Rankin et al. [2]. To further enhance the model and enable it to predict the thickness of slag accumulating on the lance, a detailed analysis of the heat flow through the slag layer commenced in 1992. By far the most complex aspect of the model, the flow of heat from the vessel contents to the outside of the lance was dependent on many factors, including:-"

Jan 1, 1996

Explosives are used to mine coal. Any blast results in three size categories of products, namely over-, middle-, and under-size. Boulders can still be broken smaller in further operations after blasting. The under-size, for instance coal fines, negatively affects the mining efficiency. Their reduction ensures better returns. The paper concerns investigations aimed at reducing coal fines' generation. Inherent fractures are identified as one of source of fines. The discussion is therefore centered on establishing a relationship between the fracture occurrence, the explosive properties and the blast outputs evaluated in terms of the fines generated.

Jan 1, 1996

By James Wm. White

Today a large number of open pit mines use computer-based mine management systems to automatically assign haul trucks, track equipment, and manage information. Now advances in digital communications allow the use of these systems in underground operations. Underground mine management systems help maximize production by providing impressive gains in areas such as equipment and manpower utilization, draw point equalization in block caving operations, preventive maintenance, and safety. Current systems use allocated or "locked" train and LHD dispatching. While allocated dis-patching rarely optimizes open pit production, it offers an efficient mode of operation underground where options are more limited.

Jan 1, 1996

By B. Mishra, W. A. Averill

"The application of various hydrometallurgical, pyrometallurgical and electrochemical processes in the extraction, purification and production of radioactive metals as well as the use of various materials, ego metals and alloys, ceramics, polymers, etc. in the process, construction and handling equipment in the nuclear industry has generated a large stockpile of radioactively contaminated waste material and scrap metal which can not be directly discarded, recycled or considered for long-term storage due to its volume and potential hazards, without the separation of radionuclides. This paper reviews the emerging methods that have been investigated and suggested for dealing with some of these wastes and scrap material.The separation technologies studied for the recovery of radioactive components from the pyrometallurgical and electrochemical processing wastes have been discussed in details with results from some of the recent theoretical and physical modeling work as well as the data obtained from the actual waste treatment. Specific processes shall be described in terms of its advantages and limitations. These emerging separation technologies are being considered by the US Department of Energy as alternatives for dealing with the issues of environmental management [EM] and decontamination and decommissioning [D&D].IntroductionThe high temperature carbothermic or metallothermic smelting reduction methods for metal production are associated with the generation of significant quantity of waste as slags, flue dusts, sludges, residues, effluent salts etc. Certain hydrometallurgical processes also generate lots of aqueous waste due to the inherent nature of the technique. Also, the gas-based reduction processes are not applicable to many stable metal compounds, such as alumina, titania, beryllia, lanthanide and actinide oxides, etc. due to thermodynamic considerations. All these methods cause substantial environmental hazard. There is a need to develop alternative processes which have low waste or ideally a ""zero-waste"" generation.Pyrochemical processes using molten salts provide a unique opportunity for the extraction and refining of many reactive and valuable metals either directly from the beneficiated ore (aluminum, beryllium, neodymium, plutonium, uranium, etc.) or from other process effluent that contain reactive metal compounds. The processes reduce metal compounds electrolytically (A12O 3 and BeCI2) on a carbon anode or by calciothermic reduction (Po, Nd). The by-product, in the latter case, is a calcium oxide saturated halide salt. The waste-treatment to recycle the halide has to be done as a separate step or stored as a contaminated waste. A successful separation technology can provide a new insight to the waste minimization strategy for the nuclear industry."

Jan 1, 1996

By Connor J. W

Nifty Copper Operations was established to treat a copper orebody situated in the East Pilbara area of North West WA, located approximately 70 km west of Telfer in the Great Sandy Desert. The plant was designed to treat the oxidised portion of the orebody with underground development following at a later date. Nifty was designed to produce 16 500 tpa of copper cathode. This will increase with treatment of the chalcopyrite ore (underground resource). Ore processing is similar to other operations of this type but has its unique challenges. Problems discussed are: fine clay minerals which hinder percolation; oxidation of organic by manganese in the electrolyte; crud formation by clays; third phase emulsions; and organic carryover into the electrowinning tankhouse. As the orebody utilisation progresses, some sulphide material will require leaching and further investigations into liquor chemistry.

Jan 1, 1996

By Kate Satish

M/s Konkan Railways Corporation are constructing 760 kms long rail road in the Western Coastal Region of India. The rail road encounters 75 tunnels through the Western Ghats of India with a total length of 78.35 kms, the longest tunnel being 6.5 kms long. The tunnels are of horse shoes shape having a cross section of about 37 Sq.meters

Jan 1, 1996

Today's conservation thinking is becoming increasingly polarised-a widening gap that could eventually be to the overall detriment of mankind, one way or the other. In one corner, stand the disciples of the untainted wilderness, moral protectors of the natural world who subscribe to the doctrine that the fragile balance of nature is threatened by man's very existence. On the opposite side of the ring, stands the relentless developer, with the megalomaniac notion that nature is purely there to serve humanity and civilisation, under the auspices of 'progress',

Jan 1, 1996

By Perring CS, Barnes SJ

The nickel exploration boom of the late-1960s and early-1970s led to the discovery of numerous komatiite-hosted nickel sulphide deposits, associated with variably serpentinised bodies of olivine-rich cumulates. Subsequent research has shown the importance of volcanological processes to understanding the genesis of these deposits. Crucial developments have come through consideration of the fluid dynamics of magmas and magma-crystal mixtures, through observation of the dynamics and geometry of modern day basaltic lava flows, through application of theory and experimentation on the kinetics of crystal growth from magmas, and most importantly from extensive detailed field mapping of komatiitic sequences in the Yilgarn Block and elsewhere. From these studies has emerged a new integrated view of the volcanological setting of komatiite-hosted deposits, and a recognition that a complete continuum of deposit types exists. Nevertheless, komatiite associated magmatic nickel deposits generally fall into two overall types based on the nature of the sulphide ore. In the first type the bulk of the ore is either massive Fe-Ni-Cu sulphide or a variable mixture of massive sulphide and an ore characterised by olivine crystals in a continuous matrix of sulphide occupying between 30 and 75 per cent by volume of the rock (called Matrix Ore). Nickel grades of massive sulphide ore range from 2 - 20 wt% and those of the matrix ore generally fall in the range 1 - 5 wt% (average 2.5 wt%) Ni/Cu ratios of the sulphide fraction are generally >10.

Jan 1, 1996

By Dean Ilievski

Mathematical modelling of the precipitation process requires that the kinetics of crystal growth, nucleation and agglomeration be known: This paper reviews the current state of knowledge on these precipitation sub-processes (ie. growth, nucleation and agglomeration) and describes a number of experimental techniques for estimating their kinetics. The experimental methods used to generate the precipitation data and the data analysis techniques used to extract the kinetics information from the data are discussed separately. There is no universal "best" technique for determining the kinetics. However, studies on multi-crystal systems are more reliable for modelling purposes than are single crystal studies. The selection of a technique will depend on which sub-processes are present. A problem with all kinetics studies is that there is generally a large uncertainty in the estimated kinetic parameters. This stems from the scatter in the experimental data being further propagated by the mathematical techniques used to extract the kinetic parameters.

Jan 1, 1996

By Ricardo Melamed

Metallic mercury has been extensively used for gold recovery. Although the solubility and mobility of metallic mercury is low, this metal can undergo many transformations, leading to mercury contamination in humans. The complexity of Hg chemistry in the environment reflects its different possible oxidation states and species, with different physical-chemical properties. The interaction of Hg in the terrestrial system, as well as in the aquatic environment, is important to understand the mercury cycle. This paper reports data on the adsorption of Hg onto an Oxisol soil. Results show that the interaction of Hg(II) at the soil-solution interface depends strongly on ligand concentration in solution, which can affect Hg mobility. The presence of the chloride anion in solution increases the mobility of Hg(II) through the soil, due to a relative lower affmity of mercury chloride at the oxide surface. In the absence of chloride, Hg(II) form strong complexes with the surface, and its adsorption behaviour is similar to the adsorption of other hydrolizable cations.

Jan 1, 1996

Contribution by W. Assibey-Bonsu I congratulate Mr N.O. Lotter on his paper. There are two main aspects of the paper on which I would like to comment. One aspect is his review of P. Gy's sampling theory under the heading 'Sampling the mill feed' (p. 153). The other aspect relates to his reference to one of our papers1 that was published in the Journal (p. 152). My comments on the former will be given elsewhere'. Authors' reply: Dr Assibey-Bonsu's contribution to the subject is appreciated.

Jan 1, 1996

By A. A. Peshkov, N. A. Matsko, K. N. Trubetskoy

It is possible to divide the general objectives of a company into two components: maximum expected profits and viability over time. These components are designed to maximize the companies value over time. The evaluation of a project includes both a discounted cash flow (DCF) analysis and a risk analysis. The DCF analysis determines whether the project should be accepted or rejected, and the risk analysis helps to forecast possible deviations from the original estimates. However, the results of both methods do not allow for a quantitative comparison between the main objectives of the venture, and they do not resolve the issue of whether it is advisable to sacrifice immediate profits for future profits. This paper attempts to resolve this issue. The present research was carried out on mining projects with different waste-extraction schedules. Calculations were made using the US Bureau of Mines' usage-of-costs model. Russian experience in open-pit mining is reflected in this paper.

Jan 1, 1996

By C. R. Speers

The induced elastic stresses in the sidewalls of gold-mining tunnels at a depth of 4000 m in the Witwatersrand exceed the peak compressive strength of even the best-quality quartzite rocks. Laboratory tests measuring post-yield stress versus strain response show that brittle fracture occurs, followed by a loss in strength associated with strain-softening behaviour. Numerical modeling based on an assumed Mohr-Coulomb criterion fitted to the test results shows that large ongoing deformations of the sidewall occur, leading to total tunnel failure without adequate support. A methodology is presented to enable a quick assessment to be made of support requirements in terms of ground characteristic curves for numerically derived pressure versus displacement. From these curves, estimates can be made of the force levels for cable bolting and of the thickness and strength requirements for shotcrete linings. As an example of its application, the methodology is used in a comparison of the relative stability efficiencies of a square-shaped tunnel and a horizontal ellipse-shaped tunnel.

Jan 1, 1996

By J. D. Miller

The recent non-equilibrium electro-phoretic mobility measurements by laser-Doppler electrophoresis coupled with the stability and prevalence of collector colloids in soluble salt flotation systems suggest that the selective flotation of alkali halides is due to the adsorption of oppositely charged collector colloids by hetero-coagulation. Previously reported flotation results confirm this surface charge/collector colloid adsorption model. However, the nature of the inter-particle forces responsible for hetero-coagulation of such oppositely charged particles at high ionic strengths remains to be determined. In this regard, atomic force microscopy was used for inter-particle force measurements at high ionic strengths. Model systems such as polystyrene/quartz and silica/sapphire were studied to measure the particle interaction forces prevalent at high ionic strengths. Results from this study indicate that while repulsive hydration forces exist between similarly charged hydrophilic particles, attractive forces exist between oppositely charged hydrophilic particles in high ionic strength solutions. The repulsive forces between similarly charged hydrophilic surfaces at high ionic strengths (2-4 M) are described by a double exponential function with decay lengths of 0.17 and 1.4 nm depending upon the surfaces involved. On the other hand, attractive forces were observed between oppositely charged hydrophilic surfaces at high ionic strengths (2-4M) and were described by a single exponential function with decay lengths of up to 9 nm depending upon the surfaces involved.

Jan 1, 1996