Search Documents

By T. Shimizu

In Japan, the emission standard of selenium in effluent was set at a maximum of20 mgll in Feb. '94 for the first time, and it is scheduled to be further decreased to a maximum of 0.1 mg/I from Feb. '97 due to tightening of the Water Pollution Prevention Act. Selenium (IV) and (VI) are generally found in effluent from precious metals refineries. Although selenium (IV) can be easily eliminated by some reducing agents, selenium (VI) is more difficult to be reduced. Therefore, many smelters are having difficulty in complying with the new emission standard. At Mitsubishi Materials' Naoshima smelter, the behavior and the elimination of selenium in effluent have been extensively investigated. As a result, it was found that two strategies were particularly effective. One of them is improving the overall operation of precious metals refinery, that is, feeding uniformly the effluent to the waste-water treatment plant, reducing the effluent volume by recycling and recovering more selenium (IV) in the effluent. The other is eliminating selenium (VI) in the effluent from the precious metals refinery. It was found that selenium (VI) can be effectively reduced by using hydrazine under high? sulphuric acid concentration and high temperature conditions. By using these measures, it is considered that Naoshima Smelter will be able to comply with the new emission standard.

Jan 1, 1996

By S. A. Platias

Large amounts of dunile tailings can be recycled for olivine produdion from the existing beneficiation adivity of chromite ore in northern Greece. This olivine production aims at the preparation of a material suitable for the substitution of the environmental hazardous quartz sand in the foundries of Europe In smelting of chromite ore the losses that occur ore usually of the order of 6-8% Cr that report in the slag. Most of this is in the form of oxides that cannot be recovered, but usually 30-35% is in the form of FeCr alloy that can be recovered by gravity methods. About 90% of the produced slag is sold for road construdion after crushing to a desired grain size. Finally, recycling of chromites sludges from the ferrochrome produdion plant, through the preparation of pellets, improved the total chromite yield by 2%.

Jan 1, 1996

By Joanna LaForte

"In response to “Arctic Mineral Wealth —Equitable Participation with Aboriginal Landowners – A slow or fast process?”, this author’s impression is one that, to her, seems obvious — this is definitely going to be a slow process. To question this issue seems ridiculous, unless the mining industry is considering following the same patters of the past, thereby adding to the suppression and injustices to which the aboriginals are so accustomed. To make genuine progress, where trust and good communication has been achieved with time as a factor in proceeding, the author feels, without a doubt, that the triangle of industry, government and aboriginals will seriously have to be restructured or eliminated. Anytime you mix government with progress, along with other problems, you are looking at bureaucracy, and that takes time. Issues such as the settlement of land claims have not been resolved, and in all likelihood could take forty years to finalize. Aboriginals have been suppressed for centuries by governments and industries with ethnocentric ideologies, and now that they are in a position to reclaim their lands, attain their own economies and government, and truly secure a wealthy, self-sufficient legacy for their descendants, how can anyone imagine they’ll move quickly? This author also strongly disagrees to some sections of Mr. Wakefeld’s article and will expand on her objections.We question whether aboriginals under-stand the process of mine development. If we encounter an electrical problem in our home, o we not call an electrician without having to learn the trade ourselves? This comparison seems simplistic, but does convey a point. As cited, “there are now over 100 000 aboriginals who have completed post-secondary education.” Are the numbers revealed in Mr. Wakefeld’s paper there to scare us? Is he suggesting that without the industry’s haste, the aboriginal’s new found intelligence could pose a problem to the mineral explorer. While it is true that not all are highly educated, the aboriginals have specialists in market fluctuations, feasibility studies and the needed skills. They have specialists, such as their representative organization of COPE 1984, (the Committee for Original People’s Entitlement), who under-stand their cultures, language and desires. Their education should expedite the negotiations and end the power struggles equitably. Aboriginal people are not stupid. Once they have reason to be proud, regain their communities and know the direction that they’re headed, their self-determination will return."

Jan 1, 1996

By Gandhi

Piled raft foundation under uniformly distributed vertical loads has been analyzed using Finite Element Method. The soil is considered to be linear elastic, isotropic, homogeneous. The raft,pile and the soil have been idealized with eight noded brick elements. Parametric study have been carried out varying pile length, soil modulus, raft thickness, and pile spacing. Design charts have been produced to achieve 50% load sharing between pile and raft for optimum design. Data available in literature is compared with the design chart results and found satisfactory.

Jan 1, 1996

By Kadri Dagdelen

The importance of factoring mining dilution into feasibility stage ore reserve estimates is discussed. An example that relates the issue of mining dilution to the size of smallest volumes that can be mined selectively is given. Relationship between the size of the selective mining units (SMU's) and the variance of their average grade is presented. The concept of variance reduction and its use in factoring mining dilution into geostatistical ore reserve estimation is described. An approach to estimate variance reduction factor by way of conditional simulation is introduced.

Jan 1, 1996

By A. Khan

The effect of sulfur dioxide on collectorless and collector induced flotation of chalcopyrite was studied by cyclic voltammetry on a rotating disc electrode. Contact angle measurements were made to determine the effect of sulfur dioxide concentration and electrochemical treatment. The benefits of sulfur dioxide in enhancing the selectivity of separating chalcopyrite from complex sulfide ores are discussed.

Jan 1, 1996

By George J. Hartman

The Fort Cady in situ borate-mining project involves recovering boron from a deposit more than 400 m (1,300 ft) below the surface. The resource recovery method is a new in situ mining technology that uses weak acid solution injected directly into the ore body. As the acid contacts the calcium-based ore (primarily natural colemanite), the contained borate values are digested as boric acid. This boric acid solution is then pumped to the surface by submersible pumps. A series of chemical reactions and precipitations are performed that result in the production of calcium borate. The borate values are then recovered as a finely divided solid white powder. The refined product is sold under the trade name Cadycal 100. The Fort Cady in situ borate-mining project is located about halfway between Los Angeles, CA and Las Vegas, NV in the Mohave Desert.

Jan 1, 1996

By Peniti Niskanen

Outokumpu metals & Resources (OMR) is a sub-group of Outokumpu Oy. OMR is a Mining and Metallurgy group of about 75 companies in 16 countries. The main activities are exploration, mine development and, mining and metallurgical processing of base metals.

Jan 1, 1996

By Brian Wingfield, Rick Givens, Greg Williams

Many technological advancements have been made in explosive products and applications over the last 15 years resulting in productivity and cost gains. However, the application of total energy (engine horsepower) in the majority of rotary drilling technology, has remained virtually unchanged over that period. While advancements have been made in components, efficiency, and types of hydraulic systems used on drills, the application of current hydraulic technology to improve drilling productivity has not been interactive with end users.

Jan 1, 1996

By Y. M. Jiang

From underground instrumentation data and from direct observation of longwall panels, it was demonstrated that growth of the main-roof overhang causes an extremely high roof weighting on the face supports. This can result in catastrophic effects on the supports when the roof-weighting intensity far exceeds the support capacity. In this paper, a comprehensive study was conducted on the characteristics of main-roof breakage and its effects on shields at different locations along the face. The study was based on monitored shield data, theoretical analysis and finite element analysis. With the help of theoretical analysis and numerical modeling, stress distribution and redistribution in the main roof were analyzed to define the main-roof failure modes and to understand the maximum roof-weighting intensity imposed on the shields. From this study, it was found that the effects of main-roof breakage on shields are chiefly related to the shield's initial-setting condition and to the final failure mode of the main roof.

Jan 1, 1996

By Subrata Ray

A large no of power stations are being set up in Chandrapur area having coal deposits. Several industries are also coning up in this area. The subsurface is geologically formed under Gondwana system and consists of shale strata at depths ranging from 8 to 12 m. The stress deformation characteristics of shale exhibits wide variation because of it's geological origin. In view of this, a study was conducted on bored cast in-situ piles installed for a Switch yard project to evaluate load settlement characteristics of three test piles to understand the probable engineering behaviour of the material at the tip and the sides. An approach is developed to simulate the load settlement behaviour as observed in the field, theoretically. This is based on the concept of load transfer. The fit is obtained by varying the parameters, thus may be considered as iterative in nature. The theoretical curves closely matched the observed curves. The results of this study are presented in this paper.

Jan 1, 1996

By D. Gu, R. G. Anthony, C. V. Philip, M. E. Huckman

"In this paper, we review the equations needed to construct an ion exchange column model. These models contain three major components: 1) a differential material balance around the column, 2) a differential material balance around an ion exchange particle, and 3) a constitutive equation for diffusive flux. We then examine the ability of a fairly simple mathematical model to predict ion exchange column experimental data. This model contains the traditional absorption theory equations and is used to predict the behavior of a column filled with a hydrous crystalline silico-titanate and which is removing trace amounts of Cs+ from a high pH, complex electrolyte solution. Finally, we propose replacing Fick's law with the Nemst-Planck equation as the constitutive equation for diffusive flux. We use a NemstPlanck type model to predict batch experimental data, then evaluate it by comparing it's ability to predict experimental data to that of a more traditional Fick's law type model. The data from this comparison suggests that the Nemst-Planck type model yields better results.IntroductionMillions of gallons of strongly basic, radioactive waste are currently stored in underground storage tanks at Hanford and Savannah River and several locations within the United States. Due to the limited life expectancy of the tanks, there is a pressing need to remediate these wastes. This need has prompted the recent development of new ion-exchange materials for removing radioactive elements from aqueous solutions. A novel material called TAM-5 has been developed jointly by Texas A&M University and Sandia National Laboratories. TAM- 5, a crystalline silico-titanate, is highly selective for Cs + in the complex electrolytic solutions typical of these wastes. It is stable in very basic solutions and in radioactive environments [1, 2 ,3]. In laboratory testing to determine the selectivity of various materials, TAM-5 was superior to other candidate ion exchangers [4, 5]. The selectivities were determined by measuring a distribution coefficient, Kd, which is defined as the concentration, gig or mmols/g of Cs in the solid phase divided by the concentration, mg/L or mmols/mL, of Cs in the liquid phase. The units of Kd are ml/g or L/kg. Table 1 shows Kd values for TAM-5 compared to 9 other candidate materials in a typical waste solution [6]."

Jan 1, 1996

By E. T. White, Dean Ilievski

"Mathematical modelling of the precipitation process requires that the kinetics of crystal growth, nucleation and agglomeration be known. This paper reviews the current state of knowledge on these precipitation sub-processes (ie. growth, nucleation and agglomeration) and describes a number of experimental techniques for estimating their kinetics. The experimental methods used to generate the precipitation data and the data analysis techniques used to extract the kinetics information from the data are discussed separately. There is no universal ""best"" technique for determining the kinetics. However, studies on multi-crystal systems are more reliable for modelling purposes than are single crystal studies. The selection of a technique will depend on which sub-processes are present. A problem with all kinetics studies is that there is generally a large uncertainty in the estimated kinetic parameters. This stems from the scatter in the experimental data being further propagated by the mathematical techniques used to extract the kinetic parameters.IntroductionCrystallisation operations, including precipitation, are widely used in a number of hydrometallurgical processes to recover a desired component or to remove an undesired impurity. The goals of industrial precipitation processes are to maximise the recovery while maintaining product quality (generally product crystal size distribution, purity and morphology and product handling properties). Knowledge of the precipitation mechanisms and kinetics is invaluable for designing new precipitators or for improving existing units. The mechanistic and kinetic information is generally incorporated into mathematical precipitator models, which are then used for process design and optimisation."

Jan 1, 1996

By N. A. Barcza

INFACON 7, the seventh International Ferro Alloys Congress, took place in Trondheim, Norway, in June 1995. The main aim of the Congress, which was held under the auspices of Euroalliages and the Norwegian Ferroalloy Research Organization, was to present the challenges facing the ferro-alloys industry on the road to the 21st century. Halyard Tveit, Chairman of the Technical Committee, summarized these as: ? the transition to a single global market economy ? new demands with regards to quality arising from customer needs, and ? increased awareness of the global environment. In the Plenary Sessions Kouichi Nakamura (Nippon Steel) outlined, from the steel industry's point of view, the relationship between technical advances in the products and more demanding ferro-alloy specifications. Advances in steel manufacturing technology and higher product quality have been supported in the past by raising the quality standards of ferro-alloys. Future requirements are bound to bring about more severe standards, and these need to be established by common agreement between both industries.

Jan 1, 1996

The fifth Annual RMCMI Mine Rescue Evaluation was held June 29 through July 2 in conjunction with the 92nd RMCMI Convention. Eight teams from four states participated. They were: BHP La Plata Mine NM Capt. Jonathon Sorrell BHP Navajo Mine NM Capt. Ron Miller BHP San Juan Mine NM Capt. Albert Nelson Bridger Coal Company WY Capt. Ted Laughlin Coteau Properties Co ND Capt. Terry Davis Kerr-McGee Coal Corp WY Capt. Elvin Stanton Sabine Mining Company TX Capt. Spencer Thompson Solvay Minerals WY Capt. Ray Blaisdell Activities started with a Rope Rescue class taught by John Peleaux, from Innovative Access, at 1:00 p.m. on Saturday. The Mine Rescue Reception, Team Meeting, and Equipment Inspection was held Saturday evening. All participants received a T-shirt and cap. The Mine Rescue Evaluation started Sunday morning and ran until it was rained out around 3:00 p.m. There was a team swap meet Sunday evening at which teams bought extra caps and shirts. They also traded with other teams. [ ] The Evaluation resumed Monday morning and ran until mid-afternoon. The Evaluation was made up of seven stations. There were six scenarios and a written test. Teams were also challenged by a 14-foot confidence course wall to get their team over. The teams were evaluated by: Jack Knight Champion International, Pensacola, FL Becki Pickert Colorado Northwestern Community College, Craig, CO John Peleaux Innovative Access, Evergreen, CO Lynn Busskohl Kerr-McGee Coal Corp., Gillette, WY Lenny Altenburg Kerr-McGee Coal Corp., Gillette, WY Elvin Stanton Kerr-McGee Coal Corp., Gillette, WY Clarence Baker Kerr-McGee Coal Corp., Gillette, WY The victims for the scenarios were from the Kerr-McGee Mine Rescue-Team. They were: Dana Cooper, Doland Zink, Suzanne Ott, Mike Szuma, and Craig Moore. Also helping as a victim was Candy Cobb from Casper, WY. [ ] The program concluded Tuesday morning with the Awards Breakfast. A medical kit, donated by Strategic Supply, was given to the Solvay Minerals Team for the fastest time over the confidence wall. Engraved stone awards were given to the teams indicating the rating they achieved. Four teams received Level Ill (The highest rating) and three received Level II. The Kerr-McGee team also received an award for helping put on the evaluation. Additional stones were presented to Jack Knight, John Peleaux, Becki Pickert, and RMCMI President. Marcie Greenberg. The current plans for the 1997 Mine Rescue program are that Jim Andrews with Colowyo Coal will assume the chairmanship. Goals for next year are to increase funding and participation by establishing sub-committees or task groups. With the chair located in Colorado, coordination of the evaluation should be easier. Comments from all the teams were positive and they intend to return next year at Steamboat Springs. [ ]

Jan 1, 1996

By Peter Cain

In response to the appearance of excessive convergence of bolted gateroads in the front abutment zone of retreating coal faces at Phalen Colliery, staff from the CANMET Cape Breton Coal Research Laboratory in Sydney, N.S. initiated a programme of roof profile measurements in the front abutment zone of longwall headgates. The results of these measurements allowed a characteristic deformation curve to be determined for each headgate, and the early identification of areas showing an unstable deformation trend. These areas were then reinforced with supplementary support. The monitoring programme was adopted and enlarged by the rock mechanics staff of the Cape Breton Development Corporation, and has been continuing for a period of approximately two years. A sufficient quantity of data now exists to be able to make an assessment of the effects of a number of mining parameters on the performance of the gateroad in the front abutment zone. The following paper describes the method of measurement, illustrated by typical results, and goes on to relate variations in rate and patterns of movement to geology, interaction, method of support and pre-mining stresses.

Jan 1, 1996

By D. R. Zeni

Today's mine development requires the safe, expedient and economical construction of vertical shafts for both ventilation and access. This construction must be accomplished within diverse ground conditions. Advancements in large-diameter shaft drilling have led to many exceptional mechanical refinements in shaft-drilling technology. The author traces the history of the equipment and methods employed by the large-diameter shaft-drilling industry and explores the likely paths of future development. Case histories that illustrate the adaptability of shaft drilling as a versatile tool for advanced, worldwide mining operations are cited. Safety, scheduling, costs, environmental impacts and capabilities are discussed.

Jan 1, 1996

In this paper, we present design and implementation details of a fuzzy-behavior-based controller for an automated excavator. This robotic excavator must be equipped with sensors, actuators and an embedded control system. The excavator controller uses neural-networks to interpret forces and torques gathered from bucket mounted force sensors during the excavation process. Implementation details and experimental results using the fuzzy behavior based excavation controller are given for several excavation tasks. These excavation tasks demonstrate some of the complex skills that are essential for an autonomous mining excavator controller.

Jan 1, 1996

By Y. A. Chang, L. M. Pike, C. R. Kao

"Knowledge of the site preference of ternary solute additions is essential to developing an understanding of how these solutes affect the properties of B2 intermetallic compounds. A quasichemical model will be presented which is able to predict the site preferences of dilute solute additions to tliple defect B2 compounds. The only parameters required are enthalpies of formation at the stoichiometric composition. General equations are developed which can be used to determine site occupations and defect concentrations for dilute as well as non-dilute solute additions. These equations use atom pair bond enthalpies as the parameters. It is found that the site preferences of dilute additions are not always in agreement with predictions based on the solubility lobes in ternary Gibbs isothelms. Predictions for dilute additions to NiAl and FeAl are compared to expel1mental results found in the literature. Satisfactory correlation is found between the model and the experimental results. In addition, the predictions from the model on vacancy concentrations in Fe doped NiAl are compared to recent experimental results by the authors.1.0 IntroductionIntennetallic compounds with the B2 crystal structure such as NiAl and FeAl have been investigated recently for possible use as structural materials in high temperature, oxidizing, and/or corrosive environments. The major limiting property of these materials has been a lack of sufficient room temperature ductility. Attempts to improve the ductility have often been made through ternary or higher order alloying. For B2 compounds, substitutional alloying additions can occupy either of the two sublattices and this site occupancy can be crucial in determining how the alloying addition affects the properties of the alloy. In this manuscript we will discuss the use of thelmodynamic modeling to predict the site occupancies of ternary alloying additions in B2 compounds with the triple defect structure."

Jan 1, 1996

By M. Yoshida, S. Hanada, T. Takasugi

"A study has been conducted to examine the effect of ternary alloying elements on high temperature deformation of the C15 NbCr2 based intermetallics in Nb-Cr-X (X=V, Mo and W) alloy systems, which have attractive properties as high temperature structural materials. The high temperature deformation of the C15 NbCr2 intermetallics can be improved by two alloying methods. One method is based on geometrical consideration for site occupation and atomic size factor of component elements and additive elements in the single phase C15 lattice; addition of Mo and V can promote dislocation movement without introducing significant hardening. The other method is based on microstructural modification through ternary alloying; moderate addition of these elements results in a variety of duplex microstructure consisting of the C15 phase and bee solid solution without forming any intermediate phases, and can enhance the high temperature deformability. Particularly, alloys with duplex microstructure equilibrating with Cr-rich bee solid solution is shown to exhibit superior deform ability. Also, lattice property of the additive atoms in the C15 structure and phase relation between the C15 structure and the bee solid solution are investigated by OM, XRD, TEM and ALCHEMI observations and then discussed in association with observed mechanical behavior.IntroductionLaves intermetallics with AB2 stoichiometry belong to the largest group in a large number of intermetallics with various kind of crystal structures, and have a variation of the cubic CIS, the hexagonal C14 and the dihexagonal C36 structures, depending on stacking sequence of XYZ type, each of which consists of four interpenetrating atomic layers (1-3). Some of the Laves intermetallics have good functional properties and therefore are considered to be used as, for instance, magnetic materials, magneto-optical materials, hydrogen storage materials and superconducting materials (2). Also, the Laves intermetallics are considered to be good candidate as high temperature structural materials operating at high temperatures and in severe environment because they have high melting point, low density, and potential resistance to corrosion and oxidation. However, the Laves intermetallics are very brittle at low temperatures because they consist of complex crystal structures similar to many other intermetallics."

Jan 1, 1996