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By D M R Stone

Failings di,posal presents many challenges at metal mines in Peru where the extreme relief yields very little useable land area. These challenges are amplified by other hazards such as the high seismic environment, high rainfall, and frequent debris torrents down the steep hillsides. As a result many mining operations have resorted to in-river disposal of mill tailings. This paper presents a case history of one underground metal mine located in the high Andes mountains of Peru where in-river disposal of tailings has been used for some 30 years. The paper outlines a comprehensive engineering study that was aimed at increasing the utilisation of tailings disposal underground. The scope of this study included modifications to the grinding and flotation circuits to produce a high sulphide and low sulphide tailings for underground and surface disposal respectively: mapping and cataloguing of abandoned stopes for hackfilling: modifications to the existing backfill system to improve icliahility and throughput, and a preliminary evaluation of alternatives Such as silicated and paste fills.

Jan 1, 1998

By Andersson PO

Boliden Mineral AB Boliden Mineral AB operates nine mines in Northern and Central Sweden, producing zinc, lead and silver concentrates and copper and gold. Seven of these mines use cut and fill (C&F) mining with a total production of 2 Mtonnes of ore per year.

Jan 1, 1998

By A G McLean

This paper will first discuss the fundamental requirements for reliable discharge of backfill by gravity alone at high per cent solids. This discussion will include brief mention of the underlying principles of saturated solids flow contrasted to that of stirred tank or dilute discharge systems. Here the need to possess full knowledge of the flow properties of the stored material will be highlighted. In regard to attainment of reliable discharge it will he revealed flow from a backfill silo will only occur provided: ò the flowing material in the converging channel is yielding throughout; ò slip is occurring along the walls; ò an arched stress field is present in the vicinity of the outlet; ò the flowing backfill must be dilating to flow in response to the dilating stress field; ò sufficient dilation water is injected, in the hopper, to eliminate the formation of adverse interstitial pressure gradients; ò sufficient dilution water is injected, downstream from the hopper outlet, to generate a pumpable slurry of maximum per cent solids; ò the silo level must be sufficient to prevent the pump suction forming a rathole; ò the system must be configured and operated to generate stable discharge density; and ò the system must be configured and operated to minimise damage to the pump liners. In addition proper account must be made of the silo overflow weir and settling capacity to match plant throughput. Here opportunity will be taken to highlight the complexity of this multi-phase flow situation as well as the general yet paramount requirements for reliable solids flow. It will be shown that by proper attention to the multi-phase considerations gravity discharge of slurries as a consolidated bed with minimal water content is possible. Such high solids discharge results in greatly reduced demand for process water. In addition pumping costs are reduced as is the delay time associated with the mine drainage operation. Confirmation of successful applications will be highlighted by reference to several recent case studies. In the concluding phase mention will be made of the key yet very simple and effective operation techniques which enhance reliable Discharge.

Jan 1, 1998

By S. Partney

Waste clay ponds are a necessary part of the phosphate rock beneficiation process. They are large, averaging a square mile in size; unsightly, in that they protrude 20 to 50 feet (6 -15 meters) above natural grade; stabilization and reclamation is slow; and they have had a history of catastrophic failure. The State of Florida has never published a specific rule regarding the configuration or height of these ponds, but has enforced numerous policies along these lines. The current rules are given and interpreted, along with the reasoning for current policy. In addition, an overview of the history of the policies, and an attempt at explaining the reasons for the changes that have occurred is given. The industry has been forced to make major monetary decisions, having effect for decades on mine economics, in a constantly changing regulatory environment. The Bureau of Mine Reclamation is confident that a direction of regulation has been solidified, but changes are still to be anticipated.

Jan 1, 1998

By Zhang Chuanfu, Tan Pengfu

"A thermodynamic model is developed to predict the distribution behaviors of Ni, Co, Sn, Pb, Zn, As, Sb, Bi, Au and Ag in copper pyrometallurgical process. In this model, as more as 21 elements (Cu, S, Fe, Ni, Co, Sn, As, Sb, Bi, Pb, Zn, Au, Ag, 0, N, C, H, Ca, Mg, Al, and Si) and 72 compounds (in fayalite-slag-making system) or 74 compounds (in ferrite-slag-making system) are considered. Accessory-element behavior is studied for two types of slag , fayalite and ferrite, and two levels of oxidation. The allowance is also made to account for physical entrainment in the melts.-Model simulations are carried out to study the effects of controllable process parameters such as feed composition, smelting temperature, degree of oxygen enrichment and volume of oxygen enriched air. The model can be used in copper flash process, Mitsubishi process and Noranda process. The predictions by the present computer model are compared with the known industrial data from Gui Xi Smelter in China, Home Smelter in Canada and Naoshima Smelter in Japan and excellent agreement between calculations and industrial data is obtained. In this paper, the effects of oxygen enrichment, matte grade, smelting temperature, and types of slag on accessory-element behavior among matte, slag and gaseous phase have been elucidated.I . IntroductionThe presence of trace quantities of minor elements such as As, Sb and Bi in copper significantly reduces its ductility, electrical conductivity, and lowers its thermal conductivity. Embrittlement of copper also occurs due to impurity-phase precipitates at the copper grain boundary interfaces. They deteriorate not only the electrical conductivity of copper but its workability in hot working."

Jan 1, 1998

By D R Van Eck

Western Deep Levels, a seismically active deep level told mine. stalled placing backfill in their narrow tabular workings as part of the regional support strategy in 1986. Over the years the percentage of working places being backfilled has been gradually increasing. At the end of 1995 the support efficiency and the labour productiveness relating to support installation were scrutinised to determine if resources were being optimised. Owing to financial, safety and productivity constraints it was decided to redesign stope support to be less labour intensive, safer and provide an integrated stope support system. This new integrated system will thus combine the previously used temporary, permanent and back area support consisting of mechanical props, hydraulic props and backfill respectively. Backfill previously formed an integral part of the regional support in conjunction with strike stabilising pillars. To design the integrated support system the backfill placement quality has to be exceptionally good and placement must be done as close as possible to the working face. The backfill to face distance was reduced by 30 per cent and in some areas by more than 50 per cent with an increase of square metres filled to increase the effect of the backfill even more. This paper addresses the design and successful implementation of an integrated stope support system based on the optimisation of backfill to he extent where installation of mechanical and hydraulic jacks could he Eliminated

Jan 1, 1998

By Norbert Patzelt

Today the standard method for grinding ore is the wet process. This is mainly due to the fact that the downstream process is wet and considering the total circuit dry grinding is not the most eco­nomical method for the comminution of the ore. Presently in gold ore processing dry grinding is only applied in cases where whole ore roasting is required downstream from the milling plant or if organic carbonaceous matters and sulfides are the primary reasons for the refractoriness. Since dry ore can be fed to the roaster, a dry grinding mill can advantageously be applied. In cases where d1y grinding could be applied advantageously for instance if the ore contains water soluble material and wet grinding is not possible there are serious concerns prevailing within the industty against this technology due to several reasons. Besides of the aspects as discussed later in this paper, there are several plants in operation with little success and considerable operational prob­lems. The reasons for this often lie in the fact that the several com­ponents of such a plant are bought from independent sources with­out considering the system requirements. It is essential that the dry grinding plants require accurate design between drying, pneumatic transport and grinding of the ore in the circuit. This paper will address some of these concerns raised in the industiy from a mill vendor's view along with discussing the development for the selection and configuration of the various dty grinding circuits.

Jan 1, 1998

By Leslie Thompson, Randy Hiebert, Marietta Canty

A paper is presented in which an innovative biological process is described for the treatment of cyanide-, metals-, and nitrate-contaminated mine process water. The technology is capable of detoxifying cyanide and nitrate and immobilizing metals in wastewater from agitation cyanide leaching as well as heap leaching. A pilot-scale demonstration is described in which a pilot plant was constructed to detoxify cyanide and immobilize several metals from a mine process wastestream at a mine in Nevada. The demonstration was performed jointly under the Mine Waste Technology Program (MWTP), which is funded by the U.S. Environmental Protection Agency (EPA) and is jointly administered by the U.S. Department of Energy's (DOE) Western Environmental Technology Office (WETO) and the Superfund Innovative Technology Evaluation (SITE) Demonstration Program under Interagency Agreement Number DW89938513-01-0. MSE Technology Applications, Inc. (MSE) located in Butte, Montana, was the contractor responsible for conducting the project, and Pintail Systems Inc. of Aurora, Colorado, was the technology provider. The pilot-scale unit was field tested at the Echo Bay McCoy/Cove Mine southwest of Battle Mountain, Nevada. The biotreatment process was con­sidered to be very successful in detoxifying cyanide from the mine process water. The process was also determined to be very effective in removing metals. The pH was consistently neutral­ized and nitrates were successfully removed in the mine process water. As a result of conducting these pilot-scale tests, the biotreatment process was concluded to offer an innovative, cost­effective alternative for the treatment of mining wastewaters.

Jan 1, 1998

By Gus Van Weert

Capital and operating costs for a 10 tpd NITROX PROCESS® demonstration plant are being established. The flowsheet is based on Dickenson Mines' Red Lake arsenopyrite concentrate. Support for the work comes from a number of mining companies, engineering firms and the Northern Development fund of the Ontario Government.

Jan 1, 1998

By W. Kemp Wait

Electronic ore sorting is a coarse particle beneliciating process which performs a function which in the past was primarily achieved through the use of hand picking belts. Photometric ore sorting is capable of separating waste from mineral bearing rock having a distinct difference in surface light reflectance levels. This type of ore sorter can be applied to gold and silver ores which are contained in quartz veining. Photometric ore sorting has been used at gold mines in South Africa as well as the Black Pinc silver mine in Montana. A new ore sorter has recently been developed with precious metal ores in mind. This ore sorter is capable of sorting ores on both photometric and conductivity sensing parameters. The first production machine has been installed at a gold mine near Beardmore, Ontario and currently is being used to process low grade waste dumps.

Jan 1, 1998

By R. E. Mclaughlin, R. J. McLaughlin, A. H. Danzberger

Acid mine drainage (AMD) can occur as a natural phenome­non through oxidation of sulfide minerals. Oxidation by air and water can be exacerbated by mining. Because AMD can exhib­it low pH, it is capable of extracting heavy metals from mineral deposits. The result is highly acidic drainage with elevated heavy metal concentrations - the combination of which can cause extensive environmental damage. Because of the importance of these factors, this paper is focused on sulfate based AMD. Due to widespread mining, the occurrence of AMD is ubiqui­tous. As a result, several approaches to treatment have been developed. Chemical treatment using alkali is most commonly employed to treat AMD. There are alternative methods of treat­ment, as well as alternative ways of handling treatment sludges or concentrates. Dewatering of sludge or concentrates is beyond the scope of this paper. Within the family of chemical treatment processes, there are three principal recognized methods, namely, "Conventional," "High Density Sludge" (HDS) and "Heavy Metals Removal Process" (HMRP). All three are now employed or specified for treating AMO at mining sites which are being reclaimed under Superfund. Only limited data are available for more specialized chemical treatment processes such as "ferrate", borohydride membrane and electrochemical methods. Therefore, these data are not included here. Performance data for these three processes are presented in this paper and comparison among them is made. Comparisons include consideration of water quality, sludge characteristics, and operational ease. Capital and operational cost comparisons of these processes were addressed in a previous paper by the authors (see bibliography). The results presented here are impo1tant not only to metals mining, but are also applicable to other industries experiencing metals-laden acidic wastes including: coal mining and prepara­tion, metal plating, and electronics circuit board manufacturing. The acceptance of any process should be based on bench scale demonstration before implementation is contemplated. The three processes included herein are discussed in relation to the particular sites at which they are in use, or their use is planned. The sites selected were representative of the various types of processes and the wastewater parameters.

Jan 1, 1998

By Donn A. Calder, Wayne C. Henderson

The Calmet Process for extraction and recovery of gold and silver from concentrates and high:grade ores has been a commercial reality for over two years. During that time period, almost seventy-five different concentrate (or ore) types have been processed in approximately 200 separate lots (a total of almost 2000 short tons). During commercial operation of the process at the plant in Fountain, Colorado, recovery of gold and silver into <lore' has averaged almost 93% for gold (range 81-98%) and over 90% for silver (range 76-97%) based on a fire assay target and calculated head values.

Jan 1, 1998

By Wolfgang Baum

The objective of this presentation is to demonstrate the utilization of process mineralogy to improve the plant performance of a large gold-silver operation. From raw ore to tailings, from concentrate to off-gases, nearly all aspects of the recovery process have benefited from the mineralogical work. The involvement of a process-oriented mineralogist on a routine basis permitted the plant to "unlock" the reasons for process problems and to take corrective measures such as adjusting and modifying the mill circuit and the process parameters. Process mineralogy has also been of substantial value for the selection and operation of equipment. This resulted in a more cost-effective operation with improved precious metals recovery and better by-product quality. Specific modifications made in recent years are largely related to mineralogical factors, particularly the inherent precious metals mineralogy and alteration characteristics of the ore.

Jan 1, 1998

By Kevin Bell

The TRAC™ Program was developed to provide our clients with a mechanism that allows them to better manage site remedia­tion and closure costs. This program provides a fixed-price contract for site remediation and case closure and is well suited for large pro­jects with multiple PRPs, such as Superfund sites. Because Kvaerner is a large engineering/construction firm and not a consult­ing firm, we can offer this type of contracting mechanism that envi­ronmental consulting firms are hesitant or unable to provide. With TRAC™, Kvaerner assumes financial and technical responsibilities for carrying a site through the closure process for a fixed price. Liabilities carried on our client's balance sheet for site closure can be removed when they sign up forTRAC™. In many instances, a profit can be realized as the liability on the balance sheet may exceed our TRAC™ fixed-price cost to close the site. Bonds and other sureties securing the site can be released and set­tlement with other involved parties can be quickly reached. For a project to be considered for this program, it typically meets the following criteria: 1) The project site should be physically separated from other contaminated sites 2) A reasonable quantity of site investigation data must be avail­able including site-usage history with or without a projected fea­sibility study(ies) and/or remediation design 3) Access to perform all necessary work must be available. After a review of all site data, K vaerner develops a "risk menu" to manage financial risks. In this "menu", each compo­nent of the project is assigned a level of probability that the costs will occur. Then the base cost of each activity is "weighted" by multiplying the potential cost growth by the probability. This analysis assures that the financial risks are appropriately defined, weighted, and mitigated and a realistic fixed price is developed. Upon acceptance of our proposal and conclusion of contract negotiations, Kvaerner takes over future responsibility for clos­ing your site. This allows the client to: 4) Release reserves obligated on financial statements for the site (and potentially realize a profit if the TRAC™ fixed-price cost is less than our client's booked obligation) 5) Finalize cost settlement with other responsible parties, insur­ers, etc. 6) Redirect resources involved in the environmental manage­ment of the site 7) Cap legal and administrative costs In addition to performing the site cleanup and closure work, at our client's request we are able to: 8) conclude lease obligations for property 9) dispose of equipment and buildings

Jan 1, 1998

By Leslie M. Burnside, Gene E. McClelland, Roy R. Cellan

Revegetation of neutralized heap leach material in the arid environment of the Great Basin represents a challenge of avail­able technology. The chemical and physical environment of spent and neutralized ore is inhospitable for germination and establishment of desirable long term vegetation. Common soil amendments were tested to dete1mine if the heap material could be made more conducive to plant growth. Decommissioned heap material profile samples were collected and reconstructed in columns at bench scale. The column profiles were amended and subjected to three leaching regimes, and representative meteoric conditions. The soil amendments provided positive results for ameliorating the heap material limitations and providing a medi­um conducive to plant growth. The bench scale study also pro­vided insight for the future of heap leach planning and design with successful reclamation in mind at the forefront.

Jan 1, 1998

By Gary E. Geiger

laboratory studies were performed to assess the calcium carbonate inhibition performance of phsophonates and polymeric dispersants at high hardness and high pH conditions. Based on the results of these studies, a new calcium carbonate treatment program was developed that shows excellent Inhibition characteristics and Is not sensitive to calcium hardness.

Jan 1, 1998

By David Martin Menne, Chris Campbell-Hicks

Optimisation of many oxide gold processing facilities, in most cases, either does not really take place or if it does take place it happens too late or takes too long. This is unf01tunate as extra profits and early cash flows are lost, in new projects, and/or may not be realised at all in others. The situation is easily avoid­ed by ensuring that the plant optimisation happens immediately following commissioning or for an established operation simply 'biting the bullet' and making it happen immediately as a 'better late than never' decision. This type of optimisation requires intense undiluted focus on each and every problem or restriction that contributes to reduced plant performance or bottlenecks, without letting go, until the predetermined outcome is produced. Thus a dedicated person with specific quantative goals is required for these tasks. Methodology and strategies for optimi­sation are discussed and numerous examples presented. The secret of successful heap leaching is discussed.

Jan 1, 1998

By Wendi H. Cooksey

This paper examines two comminution circuits on a hypo­thetical gold ore deposit with both small-scale (1,000 short tons per day) and large-scale (35,000 short tons per day) production rates. The most appropriate circuit is dependent on the highest economic performance with a combination of crushing and grinding equipment to achieve the desired product size. The selected circuit is dependent on costs associated with project cri­teria, equipment selection and ore characteristics. Factors influ­encing the selection of the comminution circuit require system­atic evaluation to optimize plant performance and maximize eco­nomic return. The small-scale circuit economics responded best to three-stage crushing followed by a single-stage ball mill. The large-scale plant favors a primary crusher followed by SAG milling and ball milling. The conclusions from this paper indi­cate that each project must be evaluated separately to determine the most economic means of reducing the size of the ore.

Jan 1, 1998

By Rodney H. Sergent

After being forgotten or ignored for nearly 100 years, the ability of bromine chemistry to extract gold from ore has been rediscovered. While bromine chemistry is similar to chlorine, there are some important differences. Bromine in its elemental form is a dense, fuming, red liquid. Elemental chlorine is a gas and requires a substantial amount of equipment to handle, store and deliver to solution. Bromine has an advantage in its ability to rapidly and completely oxidize heavy metals to water soluble halide salts. The first patent for use of bromine chemistry for gold extraction was issued in 1881 (1). By 1895, work done in Colorado concluded well roasted ores required approximately 1-1/2 lbs/ton of elemental bromine for superior extraction of metals (2)). At that time, bromine was deemed to be cost effective vs. chlorine even though it was more expensive on a pound basis than chlorine. The advent of cyanide technology virtually eliminated both chlorine and bromine from consideration for leaching of ores. Cyanide was so inexpensive that it made deposits requiring unique technologies unattractive for mining. Only since the deregulation of gold price has bromine/chlorine technology been considered for those ores not amenable to cyanide. While chlorine has found its way into the pretreatment steps, bromine is just beginning to realize its niche in the marketplace.

Jan 1, 1998

By M. Misra, J. Nanor

The removal and stability of arsenic over a wide pH range (3.0-10.0) from synthetic solutions and industrial waste effluents (including mining waste tailing slurry) can be accomplished with addition of impure lanthanum chloride alone or in conjunction with ferric sulfate. The long term stability of these correspond­ing precipitated compounds is critical from the disposal stand­point. In this paper test results of this new process for arsenic removal and stabilization from the above mentioned systems are presented. Also, precipitated arsenic compounds (lanthanum arsenate, lanthanum-ferric arsenate, ferric-lanthanum arsenate and ferric arsenate) from synthetic solutions have been charac­terized. The characterization technique used was XRD. XRD patterns which shows that the lanthanum arsenate and lan­thanum-ferric arsenate formed in acidic and alkaline pH at room temperature are crystalline. On the contrary, ferric arsenate and ferric-lanthanum arsenate compounds formed under the same conditions as lanthanum arsenate were amorphous.

Jan 1, 1998