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By Emil B. Milosavljevic

Problems associated with distillation and other classical methods for analyzing operationally defined cyanide (CATC, WAD, Total and Free Cyanide) will be discussed. These methods often achieve incomplete, species dependent cyanide recoveries and suffer from serious interferences. Depending on the relative concentrations of interferents and other matrix constituents, underestimation (ultimately Type II errors probability of not detecting a constituent when it is actually present) or overestimation (ultimately Type I errors -probability of deciding a constituent is present when it is actually absent) of the cyanide levels present in a ,given sample may occur, causing in the first case false security and in the second case, excessive cyanide treatment costs. Mahy, if not all, enumerated problems can be solved by using novel flow injection (FI) gas-diffusion amperometric methods. A modification of the recently approved FI ligand exchange (FIILE) method for determination of available cyanide (USEPA Method OIA-'l677) that obviates sulfide interference will be discussed. Eight laboratory round-robin data obtained for the FI UV -digestion (FIIUV) method that determines total cyanide (Proposed Method OIA-1678) will also be presented. In addition, some methods for cyanide speciation will be presented. Finally, research needed for developing reliable methods for determination of operationally defined cyanide in solid samples will be summarized.

Jan 1, 1998

By S. Ozbilen, B. Erdogan, M. Erdogan

To study by thermal analyses the response of precipitation hardenable alloys of Al-Cu-Mg and Al-Li-Cu-Mg system to natural and artificial ageing, a series of ternary and quaternary Al-alloys with nominal compositions of Al-l.13wt%Cu-0:65wt%Mg (alloy-I), Al-1.15wt%Cu-0.57wt%Mg-0.07wt%Li (alloy-2), Al-l.19wt%Cu-0.56wt%Mg-0.75wt%Li (alloy-3), Al-2.0lwt%Cu-0.89wt%Mg (alloy-4), Al-2.14wt%Cu"0.56wt%Mg-0.07wt%Li (alloy-5) were used in the present investigation. Samples in the form of rolled sheets are subjected to water quenching at 25EC after solution treatment at 530EC for 20 min. Alloys were aged naturally at room temperature (25EC) up to 2 months and artificially at 190EC up to 2 days. By using differential scanning calorimetry (DSC) in the temperature range of25-300EC, differential thermal analysis (DTA) in the temperature range of25-600EC together with Vicker's hardness measurements, the response to natural and artificial ageing of the alloys used in the present study were investigated. It was observed that in these alloys, GPB(Cu, Mg) zones [Guinier-Preston zones with Cu and Mg] do form during water quenching at 20EC following solutionizing heat treatment. Natural ageing of the same alloys causes formation of more GPB(Cu, Mg) zones, which results in hardening in the alloys. Artificial ageing at 190EC up to l day results in GPB zone dissolution causing preliminary decrease in hardness values while two days of artificial ageing in the alloys cause S' (Al2CuMg) precipitation confirmed by DSC/DTA analyses resulting in an increase in hardness values. Li addition up to 0.75wt% helps T1 (Al2CuLi) and T 2 (Al6CuLi3) phase formation together with S' precipitation as DSC/DTA analyses show after the same heat treatment.

Jan 1, 1998

By James L. Whitlock

Biological treatment of mining and industrial effluents reached full scale commercialization around 1980. These proven, low cost, technologies have been limited in application due to a number of factors, including extended periods of time and cost required for pilot testing as compared to chemical treatment technologies, lack of biological expertise in metallurgical personnel, longer treatment periods in some cases, and performance failures based on improper application. Renewed interest in biological treatment technologies is being driven by permits with lower effluent concentration criteria, permits with bioassay evaluation, the need to remove thiocyanate, nitrates, sulfates and? other parameters. Chemical treatment processes, in general, have not been able to meet these present requirements, or require elaborate? combinations of processes, in terms of effluent quality and treatment economics. This paper addresses biologieal treatment of mining and industrial waste waters and selected recent advances in these technologies. The future looks very bright for application of these low capital and operating cost technologies,

Jan 1, 1998

By Dan Eyde

Low levels of thallium were detected in the mine water drainages, and process water discharges of western mining and smelting operations. This required remediation under state regulatory standards, which allow discharges of no more than .0017 ppm thallium in mine water discharges. Influent streams containing thallium can be mitigated to state discharge standards after a single pass through the series of fluidized upflow columns. Test work to determine the optimal flow rates used pilot scale systems at two separate locations treating 5 - 25 gpm of effluent. The test system at the gold mine mimics the full-scale system, which will be based on the existing upflow carbon tanks that have been converted to zeolite columns. The system installed at ASARCO's East Helena smelter has a far more complex influent stream with a high loading of competing cations. Nevertheless the columns filled with CABSORB® are successfully mitigating the thallium contamination. CABSORB® ZS500RW is a product based on the sodium analog of the zeolite mineral chabazite named herschelite.

Jan 1, 1998

By E. Fockedey

he destruction of free cyanide on a Co3O4 doped carbon felt was studied. The experiments were done with an eiectrochemical filter press cell on dilute alkaline solutions containing 250 mg/l NaCN. No chloride ions were added to the solutions. The cobalt oxide protects the felt against corrosion and has a catalytic effect on the degradation of the cyanide. This kind of electrode allows working with current density as high as 1200 Aim without any visible degradation of the felt. The most interesting results were obtained with a current density of 400 Aim' at which the cyanide concentration can be lowered to 5 mg/l with a current efficiency of more than 70 % and a specific energy consumption of about 10 kWh/ kg CN.

Jan 1, 1998

By Roy A. Imbsen

Following the 1989 Loma Prieta earthquake, California Department of Transportation (Caltrans) expedited an effort to evaluate and retrofit important state-owned toll bridges to en­hance performance of the state's transportation systems during and after major (credible) earthquake events. Imbsen and Associates, Inc. (IAI) along with their sub-consultants, were awarded a contract to conduct seismic evaluation and to develop retrofit design for Benicia-Martinez Toll structure, to meet a "Serviceable" performance requirement after the event of a "Safety Evaluation Earthquake." This paper describes the design and construction specifications for the deep foundations supporting the main spans of the Benicia-Martinez Bridge. Benicia-Martinez Toll Structure (George Miller Bridge), a high-level deck-type welded truss bridge with welded girder approach spans, carries Interstate Route I-680 over the easterly end of Carquinez Strait near San Francisco, CA. The nearly 5000 ft long main truss structure consists of ten spans, ranging from 330' to 528' in length, supported on cellular reinforced con­crete pier structures. Foundation systems across the waterway, consist of cellular reinforced concrete footings, supported by groups of 6' diameter, concrete filled, steel caissons, resting on 5' deep rock sockets, at depths of 50' to 150' below the water level. Seismic evaluation of the existing foundation systems accounted for spatially varying ground motion along the length of the structure, variability of foundation material strength (i.e. at bed-rock), variation and effects of scour depth on the performance of the foundations, and dy­namic soil-structure interaction. Performance of caissons beyond their elastic strength, as well as their effects on the behavior of the foundations and substructures were evaluated and considered in establishing foundation vulnerabilities. Several retrofit strategies were considered leading to a final retrofit strategy to strengthen end connections of existing caissons, as well addition of new caissons to provide adequate lateral force resistance for the foundations. Final design package includes specifications as well as construction methods and requirements for existing and new caissons, under traffic, and pile load testing procedures for design loads of up to 12500 kips per caisson.

Jan 1, 1998

By G. Wendel

Uranium is a naturally occurring radioactive material in the earth?s crust. Geological processes have resulted in concentration of uranium into ore mined for its gold content in South Africa. This uranium is present in the form of discrete particles of uranium minerals, generally oxides, which are normally insoluble. Chemical and physical processes during gold mining and extraction, particularly when carried out in conjunction with uranium extraction and sulphuric acid manufacture, act on the uranium minerals and the radioactive decay products of uranium. This may result insignificant accumulations of radioactive materials in certain parts of the process. There are a number of naturally occurring radioactive materials in the earth?s crust, such as Uranium-235, Thorium-232, andPotassium-40. This paper focuses on Uranium-238, together with its decay products, and how they affect the gold mines. Water plays a significant role in the redistribution of radionuclides, both as a physical transport medium, and as a solvent in which chemical reactions take place.

Jan 1, 1998

By A. Wahib Khair

"This article first describes the impact of respirable dust on the health of miners in underground coal mines in the United States of America. Second, it identifies the major sources of dust generation, namely cutting tools in the road headings. Two surveys associated with cutting tools were made to determine the useful life of these cutting tools, and to determine the effect of cutting tool wear on productivity of the continuous miners. Third, this article presents the results of a series of experiments carried out in the Rock Mechanics Laboratories at West Virginia University in order to study: 3.1 the effect of cutting tool rate of wear on respirable dust generation, 3.1.1 the effects of rock materials on tool wear and respirable dust generation, 3.1.2 the effect of cutting tool geometric parameters on respirable dust generation, and 3.1.3 the effect of tip materials used in the cutting tool on respirable dust generation. Recommendations in regard to cutting tool design are also presented in this paper.Silica and coal dust are the two major elements affecting the health of underground miners. According to Lemen [1] approximately 1,500 men died due to breathing in silica dust in 1936 while tunneling through a mountain of mostly silica, near the town of Gauley Bridge, West Virginia. Coal dust resulting in lung diseases in one of the major health hazards in underground coal mines. The impact of black lung on miners, coal workers' pneumoconioisis (CWP), has ranged from 16,000 to 23,000 each year since 1982 [1].The trend for conventional mining to continuous machine cutting of coal, using more productive machinery, is inexorable. Intolerable level of dust generated at the face is an indication of inefficient coal/rock cutting by these machines. The federal goverment of the United States paid about 11.7 billion dollars in workmen's compensation to more than 470,000 miners with CWP [2]. Bieniawski and Zipf [3] reported that annual benefit payments were about 2 billion dollars. The enactment of the Health and Safety Act in 1969 in the United States triggered the initial investigation into coal cutting mechanisms and cutting tool designs.The surveys concerning the utilization of cutting bits and performance of continuous miners in underground coal mines were made in order to have first hand information about bit consumption and coal produ¬ction.Three types of used bits, commonly utilized cutting tools on continuous miners, were collected from different coal mines. The used bits were grouped into symmetrically and asymmetrically worn bits. Distribution analysis for weight loss and conical height loss was done. Details of the results are presented elsewhere [4], here the results are summarized briefly. The analysis shows that approximately 50% of the collected bits have worn asymmetrically, which shows that many bits do not rotate properly during cutting. Analysis of the distribution of bit wear showed that the degree of bit wear varied from one type to another and with mining conditions. On average, the weight loss of the used bits was 4% to 7% with a maximum of 31%. Correspondingly, the loss of the conical height was observed to vary between 11% and 23% with a maximum of 71%. Figure 1 shows typical data associated with some of the used bits."

Jan 1, 1998

By N. Kanari

Chalcopyrite concentrates and their pure constituents were chlorinated by C12+N2 between 25 °C and 750 °C. The reaction products were analyzed by SEM, XRD and chemical analysis. The effect of gas flow rate and chlorine content of the gas mixture on the reaction rate were investigated. At room temperature, these solids start to react with chlorine giving metal and sulfur chlorides. Complete reaction is achieved at about 300 °C and the iron and sulfur chlorides were fully volatilized. The chlorination residue is composed of valuable metals' chlorides. A simplified flow - sheet for the treatment of chalcopyrite concentrates by chlorine was suggested.

Jan 1, 1998

By Steven A. Tesdahl

Maintenance means keeping equipment running or restoring it to operating condition. However, the 21st century will usher in a broader need for equipment management, a cradle-to-grave strategy to preserve equipment functions, avoid the consequences of failure and ensure the productive capacity of equipment. Profitable future mining operations will have reduced the 35% of operating costs typically spent on maintenance and the unfavorable impact of downtime that often multiplied these costs by 300%. They will survive those operations that tried to carry outdated "maintenance" thinking beyond the year 2000. These surviving operations will have applied modern management techniques, technology and information to align the efforts of people with the needs of equipment. Future managers will use equipment management as an integral part of an overall production strategy. They will see it as a means of raising productivity, improving performance and minimizing downtime to maximize profitability. This global thinking will characterize all operations planning to survive in the competitive world of mining of the next century.

Jan 1, 1998

By G. D. Mcdowell, L. B. Cochrane, B. D. Thompson

"Abstract - Exploration for deep underground copper and nickel sulfide deposits in the Sudbury mining camp is carried out with surface drilling. More detailed drilling, with an advanced underground exploration program, may be necessary to establish an accurate interpretation of the deposit geology and upgrade the resource estimate to the measured category for reserve estimation and feasibility assessment. Resource evaluation is a lengthy and costly process that could result in a decision not to proceed with the project. For projects that proceed to production, significant reductions in the operating and capital costs could be achieved with a more accurate interpretative model of the deposit geology and mineralization. Quality control procedures to ensure the integrity of the drilling data and interpretation guidelines are essential steps in the development of a deposit model. The use of block modeling techniques and the application of geostatistics for resource estimation further improve the quality of the resource model.Significant improvements to the interpretive models can also be achieved by incorporating additional information from geophysical measurements to validate and constrain the geological interpretation. The geophysical models must be consistent with known geological environments and oreforming processes, which has required the concurrent development of comparative models from exploited deposits. These geophysical techniques can also provide key geotechnical information required for the optimum design of the mining method and mining sequence. The objective of this program is to improve the accuracy of the deposit model and the quality of the resource and reserve estimates in order to optimize capital investments and reduce the development and operating costs of underground mining projects. Several of these techniques are currently being tested at INCO Limited’s Sudbury operations. The results from those tests are presented and their applications are discussed within the framework of resource/reserve classification systems and project evaluation objectives."

Jan 1, 1998

By Rubén Alvarado

The markets and environmental protection rules are more and more exacting, both of which have determined that copper smelters should look for technological development and global management to ensure their viability and competitivity in the short and long term. The main facilities of the present and future Smelting-Converting Process at Codelco's Caletones Smelter, is based on Teniente Converter reactors with a high operational availability that have reached concentrate processing capacities near 2,000 tpd. These reactors are in operation in most of the smelters in Chile as well as in Zambia, Peru, Mexico and, in ?the near future, in Thailand. Since 1993, the Smelting-Converting process of the Caletones Smelter of Codelco-Chile has been based on one Reverberatory furnace, two Teniente Converters and four Peirce-Smith Converters. These facilities, together with the operation of two Fluidized Bed Dryers, three Slag Cleaning Furnaces, and two Oxygen Plants have allowed the smelter to reach concentrate smelting capacities and copper productions of 1,215 kt/year and 360 kt/year, respectively. This transitional operating scheme, combining together traditional and advanced technological equipment, needs further modernization to successfully face the modern world challenges, especially with relation to the environmental commitment, production costs and wide satisfaction of customers. For this reason, for the period 1997-2000, a Modernization Plan has been worked out. This plan considers an increase of the present throughput, which will permit a significant increase in productivity, as well as finding a definitive solution for meeting the environmental regulations. Among these projects, we can point out the definitive shut down of the Reverberatory Furnace, which is a contaminating piece of equipment of low energetic efficiency. Additionally, it considers the installation of two new Slag Cleaning Furnaces, one additional Oxygen Plant, and the incorporation of two new Sulphuric Acid Plants with a production capacity of 4,500 T/D, that will recover over 92% of the sulphur content, of process off-gases.

Jan 1, 1998

By K Kuganathan

This paper describes a new methodology that can be applied to compare several bench extraction strategies requiring backfill. The method is applicable at the planning or operational stages and can be used to maintain dilution within design parameters and improve the overall economics of bench stoping operations. The parameters influencing bench performance have been empirically rated based on economical, geomechanical, operational and backfill properties. Four different extraction strategies have been considered and rated from most preferred to less preferred using an integrated approach to bench extraction.

Jan 1, 1998

By Cocker J, Urosevic M

Seismic methods have become common for the detection of low-throw faults ahead of underground coal mining. Surface seismic methods cannot theoretically be used where dykes occur, because seismic waves transmit from the surface down to the seams, and reflect back to the surface. Consequently, where sub-vertical structure such as dykes occurs, the surface seismic method fails.The ability of seismic methods to image dykes depends on the geometry used, the dyke thickness and the seismic wave propagation mode in relation to dyke composition and internal structure. Surface seismic methods find it difficult to distinguish between faults/fractures and very thin dykes (1-2m in thickness) when the dyke's thickness is less than the seismic wavelength. Consequently, borehole seismic methods have to be used to detect the presence of such thin dykes.

Jan 1, 1998

By G. Schubert, H. Hoberg

A large number of diverse size reduction machines is currently available for the comminution of waste materials. Equipment selection is determined by the nature of the material to be treated and by its behavior under external mechanical stressing. Accordingly, wastes can be divided into those with elastictbrittle and those with ductile/viscous behavior. The scientific understanding of the comminution of wastes is lagging strongly as compared to that of the grain-shaped mineral raw materials. Only in a few unique cases have the fundamentals of the comminution of ductile or viscous materials been presented. The paper centers on a characterization and systematic analysis of the types of stress fundamental to comminution. On the basis of this discussion an overview is presented of the currently available technologies for the comminution of wastes, with attention centering on those machines designed for materials with ductile or viscous behavior.

Jan 1, 1998

By Richard H. De Voto

The McDonald Gold Project and two satellite gold deposits near Lincoln, Montana, contain at least 9.9 million ounces of gold and 30 million ounces of silver. The McDonald gold deposit alone contains 7.2 million ounces of gold reserves that can be open-pit mined and processed by cyanide heap leaching at a projected cash operating cost of $190 per ounce. The deposit is predominantly oxidized with no chance of acid production, and can be mined, operated, and reclaimed with minimal permanent environmental disturbance other than the creation of an open pit filled with a fresh-water lake which would support trout. The Seven-Up Pete Joint Venture, the owner of the McDonald Gold Project, commenced permitting of an open-pit, heap-leach operation in November 1994. In 1998, Montana citizens passed an anti-cyanide, open-pit mining initiative, 1-137, which banned any new open-pit gold mine which uses cyanide processing, The Venture has conducted extensive studies, including metallurgical testing of the treatability of McDonald ores with alternative lixiviants, and has determined that all other mining and metallurgical treatment systems are vastly uneconomical in the recovery of gold and silver from the McDonald deposit. Therefore, the Venture's proposed open-pit mining and cyanide heap-leach processing is the only technology that can be applied economically to the McDonald deposit. Further, the analyses convincingly demonstrate that the proposed open-pit, cyanide heap leaching technology results in maximum resource conservation of this valuable and unique deposit and poses far less risk to human health and the environment than any of the alternative technologies.

Jan 1, 1998

By Keith Heasley

As part of the initial investigation and validation of a new boundary-clement formulation for stress modeling in coal mines. the underground stresses and displacements at two multiple-seam coal mines with unique stress problems are modeled and predicted. The new program, LAMODEL, calculates stresses and displacements at the seam level and at requested locations in the overburden or at the surface. Both linear elastic and non-linear seam materials can he used: and surface effects, multiple seams, and multiple mining steps can be simulated. In order to most efficiently use LAMODEL for accurate stress prediction, the program is first calibrated to the site-specific geo-mechanics based on previously observed stress conditions at the mine. For this calibration process. a previously mined area is "stress mapped" by quantifying the observed pillar and strata behavior using a numerical rating system. Then, the site-specific mechanical properties in the model are adjusted to provide the best correlation between the predicted stresses and the observed underground stress rating. Once calibrated, the model is then used to predict future stress problems abead of mining. At the two case study mines, the calibrated models showed good correlation with the observed stresses, and also accurately predicted upcoming high stress areas for preventive action by the mines.

Jan 1, 1998

By C Woodall, G Jardine

The Henty Gold Mine, located in Western Tasmania uses innovative solutions to effectively manage a mining operation in an environmentally sensitive setting and has been presented with several environmental awards. Fill is required as part of the mining method to provide passive ground support, minimise rock exposure and ensure maximum recovery of the small but high-grade orebody. The use of the whole portion of leach residue in the backfill reduces the surface tailing disposal requirements. Therefore, High Density Paste Fill (HDPF) has been selected as the most appropriate fill method to meet these objectives. Additional benefits include the minimisation of excess water from fill and the subsequent need for the collection and treatment of water and slimes. There are minimal equipment requirements during placement, thereby optimising mine resources for production. This paper covers the development of a suitable paste fill system to meet the specific needs of the Henty Gold Mine and the successful commissioning of this system for the first time in Australia.

Jan 1, 1998

By G. G. O. O. Uwadiale, M. A. U. Nwoke

The flotation of Azara barite tailings was investigated using crude rubber nut oil (RNOc), refined rubber nut oil (RNOR) and oleic acid as fatty acid collectors. Chemical characterization of the rubber nut oils indicated high acidity, high saponification values and high iodine indexes, which are indicative of a high fatty acid compositions. The Azara barite tailings analyzed 64.6% BaSO4 by atomic absorption spectrophotometry. Gravity and magnetic separation techniques yielded a BaSO4 concentrate with a grade of 74.8% and a recovery of 92.5%. Barium sulfate grades of 90.0%, 92.8% and 94.8% with recoveries of 80.3%, 85.4% and 86.7% were achieved with collector dosages of 750g/t crude rubber nut oils, refined rubber nut oils and oleic acid, respectively. Hence, rubber nut oils are effective fatty acid collectors for the flotation of barite tailings.

Jan 1, 1998

By Jorge Lanza

SUMMARY La Granja copper deposit, in terms of volume, is among the five largest deposits in the world and represents reserves of three thousand million tones. The field consists of a 40 m. thick layer of copper lying over the secondary ore and further down the primary copper. The flotation process has indicated a recovery rate of 88 to 90 percent and concentrates of 27 to 32 percent of copper. The acid leaching process of low grade ore produces financially acceptable results. To carry out the project, it is necessary to build long distance pipelines and a port. Both the Feasibility Study and the Environmental Impact Study on the project have been approved by the Peruvian government. INTRODUCTION La Granja is located in the district of Querecoto, province of Chota, in the department of Cajamarca, in the Northwest of the country (Figure 1). Geographically it is situated on the eastern slopes of the Andean mountains at an altitude of 2,000 to 2,700 m.a.s.1. (Figure 1). The site is an 8 hour car ride from the city of Chiclayo, capital of the department. The first 60 km. are over a paved road and the remaining distance is over a narrow hard dirt road. The copper porphyry of La Granja was discovered between 1969 to 1971 during some geochemical prospecting activities carried out by the State mining institution, Ingeomin (currently Ingemmet). From 1978 to 1982, Ingemmet continued with its geochemical and geophysical studies supported by a German technical assistance program. A total of 19 bore- holes were drilled (5,814 m.) and a 90 m. long tunnel made. This study calculated reserves of 175 million MT. In 1993, Minero Peru drew up a technical-financial study based on the above studies and proposed a 12 year extraction operating program: 20,000 MT daily using the leaching process, followed by 13 years of operation using the flotation process with the same daily volumes. In 1994, Cambior Inc. won an international auction in order to carry on further exploration work and to have a purchasing option. Since that date the company

Jan 1, 1998