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By N. Kanari

Reactivity of MgO towards C12+air, C12+N2 and C12+CO gas mixtures was studied up to 1000 °C. Carbochlorination of MgO occurs at temperatures lower than that of its oxychlorination. Effects of gas flow rate, temperature and partial pressure of the carbochlorinating gas mixture on the reaction rate were investigated. The apparent activation energy of MgO carbochlorination is 49 kJ1 mol between 425°C and 600°C. At 550 °C, the apparent reaction orders with respect to C12+CO, C12 and CO, are 2.37, 1.47 and 0.89, respectively. At this temperature, the maximum reaction rate was obtained using a C12+CO gas mixture having a Cl2lCO molar ratio equal to about 0.6.

Jan 1, 1998

By S Harvey

An inrush of water or mud into an underground mine, or sudden subsidence above mining voids represent low probability but high impact risks in underground mining. About two such incidents involving multiple fatalities or loss of production are reported each year worldwide. On average, Australia experiences one such incident every three to four years. This paper reports the development of a Standard that is intended to eliminate fatalities due to inrushes and subsidence.

Jan 1, 1998

By A. J. Davidson

A novel sensor is described for the measurement of the copper content of copper matte. Due to the high copper concentrations found in matte, potentiometric sensors are not sufficiently sensitive. A highly sensitive sensor has been developed based on a modification of the amperometric technique using a copper ion conductor, Cusicon. The results correlate closely with the theoretical predictions.

Jan 1, 1998

By J. Alvarez, S. Helle, U. Kelm, M. Pincheira

The principal geological and mineralogical characteristics of Chilean porphyry copper deposits are described. Elevated contents of fine grained ore and gangue material may cause copper losses and pose problems or render useless the flotation process. Examples of chalcopyrite and bornite size distributions are given. The state of the art of mineralogical and mineral chemical characterization in Chile is evaluated permitting analyses to lm and nm level by lacking the regular use of direct surface analysis.

Jan 1, 1998

By Levent Ozdemir

The advantages offered by mechanical mining have been demonstrated in the underground mining of coal, evaporites and other soft minerals. Mechanical mining and the advancements in automation technoloogies have been the principal drivers towards the realization of enhanced productivity in soft rock mining. For past two decades, emphasis has been placed on developing mechanical mining technology for hard rock applications, to achieve similar productivity improvements and cost reductions. The benefits of mechanical mining are numerous, particularly in an industry where market conditions continue to dictate higher production and lower costs while maintaining high safety standards. Other benefits of mechanical mining include reduced ground support and labor requirements and the elimination of blast and diesel fumes. These benefits further make this technology an attractive alternative to drill and blast for hard rock mining. Mechanical mining is conducive to full implementation of remote control and automation technologies that are under development to achieve further productivity and safety improvements in underground mining. Mine development has been the main focus area for mechanical miners by manufacturers and mining companies. Potential applications include ore body access, haulage and ventilation drifts, undercut and exploration drifts. The economic use of this technology in mine production is still considered many years away. It would need a major technological breakthrough that would make mechanical rock fragmentation competitive with the large-scale, low-cost production blasting operations.

Jan 1, 1998

By Glatthar J. W, Lauder D. W, Manlapig E. V, Mackinnon I. R

The Ok Tedi copper orebody consists of porphyry and skarn orebodies. The skarn orebodies, identified by different mineralogies, are the source of high intermittent fluorine levels in the mill concentrates. This paper discusses the results of t

Jan 1, 1998

By D N. B Skinner, M P. Simpson

At Ohio Creek, 3 km northwest of the Thames bonanza goldfield, porphyry Cu-Au mineralisation is hosted in a dacite porphyry associated with porphyry intrusion breccias and overlying andesites and dacites. The geological setting is a Jurassic greywacke basement overlain by Late Miocene andesite-dacite volcanics which are extensively altered to propylitic and argillic assemblages. Diamond drilling at Ohio Creek in 1978-1981 by Amoco Minerals intersected low grade Cu-Au (0.12-0.20% C~ 0.23-0.4 glt Au) mineralisation An advanced argillic 'alteration cap containing quartz-alunite¦dickite or pyrophyllite-dickite¦diaspore is centred on the adjacent Lookout Rocks and has potential for high sulfidation Au-Cu mineralisation. There is a zonation from potassic K-feldspar-magnetitealteration at depth in the dacite porphyry, through an overlying phyllic quartzsericite- pyrite zone which is overprinted by pyrophyllite in the overlying advanced argillic cap. Early quartz stockwork veinlets associated with the potassic alteration contain fluid inclusions that trapped a highly saline (50-80 wt% NaCI equiv) fluid at high temperatures (450 to >600¦C) indicative of a magmatic fluid. Some chalcopyrite is associated with slightly later quartz-magnetite veinlets, but the bulk of the copper occurs as disseminated chalcopyrite associated with the phyllic alteration. The potassic alteration is surrounded and overprinted by propylitic chlorite¦epidote alteration. Late polymetallic sulfide-quartz-anhydrite veins occur within and around the margins of the porphyry system as in the Kaiser Reef. Fluid inclusions associated with these late veins were formed at temperatures of about 250-320¦C from low salinity (1-3 wfl~ NaCI equiv) fluids. The spatial association between porphyry eu-Au mineralisation, advanced argillic alteration and polymetallic sulfide veins suggests that they are genetically part of the same hydrothennal system. This is consistent with reconnaissanceK-Ar dates of 11.6-10.7 Ma for the intrusive porphyry at Ohio Creek, alunite in the advanced argillic alteration zone at Lookout Rocks and sericite selvedges from the Waiotahi gold-quartz veins at Thames.

Jan 1, 1998

By K. Fagerlund

In this work, the rate of dissolution, melting behaviour and phase separation of silica flux with molten slag and matte were investigated. Mutual dissolution between high-grade matte and silica was chemically determined. Silica dissolution rates ,in various iron silicate slags was determined using the rotating rod method. The reaction and separation phenomena of slightly oxidised chalcopyrite samples and cuprous sulphide-magnetite mixtures with silica sand were examined all about 1350°C. The samples were water quenched, and polished specimens were studied and analysed using a light optical microscope ,and a scanning electron microscope with energy dispersive spectrometer. The silica dissolution rate in slag was found to increase with decreasing silica content and increasing ferric iron content. The reaction rate of silica sand' with matte was found to increase with increasing oxidation degree and magnetite content of matte:

Jan 1, 1998

By Suresh Menon

The explosive industry in India has passed through various stages - from a period of total dependency to a period of self sufficiency and now, is saddled with large spare capacity. The last decade and a half saw the emergence of small scale manufacturers, which until then was thriving on International technology.

Jan 1, 1998

By Jennifer B. Leinart, Otto L. Schumacher

JIM ARNOLD: Our next speaker is Otto Schumacher. He's president of Western Mining Engineering in Spokane, Washington. His company offers services in the area of mining feasibility analysis and publishes Mining Cost Service. Otto's talk will be "Are Metallurgists Overpaid?" [laughter] I know one that's not. [laughter] OTTO SCHUMACHER: I really think it's kind of a dirty trick for Doug to put me up here and pose that question since I'm a mining engineer. However, it's probably most appropriate that a mining engineer address the question because I can be more objective than the rest of you. [laughter] SPEAKER. Otto, do you promise to say something nice about metallurgists? [laughter] OTTO SCHUMACHER: I'll see how much time I have. [laughter]

Jan 1, 1998

By John R. Turney

MARY KORPI: Harry Hinds will be filling in for John Turney today. Harry is an exception to the industry these days, in more ways than one. He has worked for the same mining company for 33 years. That is something very few of us can claim. He is currently metallurgical superintendent for Homestake Mining Company in Lead, South Dakota. Harry is also the envy of many of us as he will be retiring this year and working on lowering that handicap! Harry will be discussing the "Role of Consultants."

Jan 1, 1998

By Mallett C

Coal mines are dynamic systems that change continually in size, shape, and condition. Large quantities of data about production, coal quality, ground stability, ventilation monitoring, equipment performance and location, vehicle and personnel movements and geology, are generated from all parts of the mine.Internet technology and virtual reality technology are now being combined to provide an intuitive, multi-dimensional information system which can simultaneously display any information that can be collected and stored by a computer. Physical information is directly displayed as 3-dimensional objects in the mine model. Numerical and text information is dynamically linked to these objects and accessed by "clicking" on them.

Jan 1, 1998

Experimental petrology may be used to accurately constrain PTX conditions in order to calibrate and understand geologic processes. This method may be used to answer postulated questions, by recreating known geologic conditions and observing changes in the experimental charges. The purpose of this project was to determine the eutectic composition and temperature in the ternary system PbS-FeS-ZnS ¦ (Ag2S), at ambient and elevated pressures and elucidate if the sulfides of the Broken Hill orebody may have been partially molten during highgrade (granulite facies) metamorphism. The study determined the eutectic temperature and composition in the system PbS-FeS-ZnS to be 800¦2¦C and 62.5% PbS, 30.5%FeS, 7% ZnS respectively, at one atmosphere, and the eutectic temperature at 27 kbars was found to be 960¦C¦10¦C, with a eutectic composition enriched in ZnS relative to the one atmosphere eutectic. the addition of lwt.% Ag2S to the system depresses the eutectic temperature to 772¦2¦C at 1 atmosphere and below 810¦5¦C at 5 kbars. The conditions of peak metamotphism for the cental and southern areas of the Broken Hill Block, New South Wales, Australia , lie above the solidus of the PbS-FeS-ZnS-Ag2S system, strongly suggesting that partial melting occurred in the orebody.

Jan 1, 1998

By D. A. Stanley

Researchers at BCD Technologies and the University of Alabama have applied three statistical techniques to the information contained in a large database of measurements from a phosphate ore processing plant. The rust, Principal Components Analysis (PCA), replaces many measured variables with a few fundamental and un-correlated variables. The second technique, Projection to Latent Structures (PLS), is an extension of PCA that explores the relation between variables identified as either independent or dependent. The third technique, Cluster Analysis (CA), is applied to the results of the PCA or the PLS calculations, and identifies individual data clusters that represent uniform operating conditions in the plant. All three statistical methods can be seen as geometrical operations on the data viewed as points in space. A Viewer gives a corresponding graphical presentation of the data points. This paper describes the use of the above three techniques and the Viewer to explore part of the phosphate flotation database.

Jan 1, 1998

By John Rusnak

The Coal Mine Roof Rating (CMRR) is a practical rock mass classification system for use in design of mine openings. Data can be obtained for this purpose from exploration drill cores if simple geotechnical logging and rock mechanics testing is conducted. The CMRR is an excellent method to quantify rock characteristics for engineering purposes. It bridges the gap between geologic description and engineering design. The CMRR was utilized in the design of a 10,000 fl. long coal belt conveyor tunnel connecting an Eastern Associated Coal Corp. mine and preparation plant in Boone County, West Virginia. Data gathering and analysis techniques are discussed involving the calculation of the CMRR and its application in the design of the tunnel, which was driven through a thin coal bed zone. The preliminary findings have correlated well with actual roof and mining conditions encountered during driving the tunnel and it is concluded the CMRR is an effective method to utilize geologic data from exploration core holes for engineering analysis and design.

Jan 1, 1998

The Australian industrial relations system is in a state of constant change. We are undergoing a transformation from a compulsory arbitration and an award based system to one which is fundamentally rooted in the concepts of enterprise bargaining. This is true both at the State and Federal level. The structural changes which facilitate the movement away from the predominance of Awards to enterprise agreements has been fostered by both sides of the political spectrum and is a cornerstone of their respective industrial relations platforms.In determining what form or combination of forms of industrial instrument(s) should apply to the individual enterprise, employers must have regard to the viability and sustainability of each form in the changing industrial climate. In particular employers should have regard to the needs and agendas of their employees and unions which may purport to represent Them.

Jan 1, 1998

By Dennis Greene

Real-time GPS position monitoring of mining equipment is becoming more and more commonplace. Digital mining plans can now be used onboard properly equipped earthmoving equipment and excavation status is available in real-time via high bandwidth data radio systems. These systems provide a closely integrated link between operations and planning. No longer must operations wait for or be hindered by insufficient survey marks, nor is engineering delayed by lack of timely mine status information. Unprecedented efficiency gains become feasible -from the engineering office, to drilling and mucking, to reclamation, as well as in mine construction projects. Direct economic benefits of these systems will be explored as will the less tangible, but very significant, indirect operational efficiency gains.

Jan 1, 1998

By Michael S. Wieland

Toxic fumes cause fatal and nonfatal incidents in underground mining, where the working environment tends to trap the fumes, hindering the restoration of nonharmful conditions. Workers can underestimate the residual fume toxicity and return to the work site too quickly. The toxic fumes from charge explosions depend upon a number things: formulation ingredients, mixture uniformity, water resistance, hole contaminates, rock hardness, and dust interactions. Hole-to-hole shock waves and rift compressions can partially desensitize charges, ruin the reaction kinetics, and worsen the fume toxicity. Traditionally the fume hazards for candidate explosives are resolved for a restricted set or tally of theoretical or measured fume components, transformed to standard reference conditions. The relative fume toxicity RFT is the resultant influence reckoned from a formulated sum of concentrations within the tally that are unweighted or weighted with chosen multiplying constants. The RFT result is compared to a rule criterion that represents the worst case tolerable fume toxicity stipulated by regulations or otherwise. The ranking and comparison of different hazard potentials that would otherwise remain unwieldy is rendered tractable by the common format of the RFT notation.

Jan 1, 1998

By Peter J. Nicholson

A new method of constructing retaining walls, in-situ, prior to excavation has been developed. This "Vertical Earth Reinforcement Technique" VERT, has been demonstrated at a full scale test wall at the National Geotechnical Experimentation Site at Texas A&M University. This 10 meter high wall, was constructed of elements of soil mixing in an array that forced composite behavior between the soil mixed elements and the in-situ soils. Inclinometers and extensometers were used to verify the performance of the wall. The construction and results of the testing are presented.

Jan 1, 1998

By Kenneth N. Han

Ammonia has been found to be an effective leaching reagent for gold, silver and platinum group metals in the presence of appropriate oxidants. Electrochemical and kinetic aspects of the dissolution of elemental gold in ammoniacal solutions have been investigated. The cathodic reaction of aurous di-ammine on the gold cathode has been investigated first. From this investigation, the standard electro-potential of the cathodic reaction .and hence. the Gibbs free energy of formation of the aurous di-ammine were established. The solubility of gold in ammoniacal solutions was also examined in relation to ammonia concentration, temperature and concentration of various oxidants. The anodic reaction of the gold disk in ammonia? in the presence? of various oxidants including oxygen, ozon, hypochlorite, hydrogen peroxide, cupric and cobaltic ammine, and iodine was also examined and the results have been discussed. Excellent dissolution yielding of gold and many other metals, typically better than 95% recovery in 1'-2 'hours of leaching at a temperature ranging 80°C to 190°C has been observed. Test results of the dissolution of gold from elemental state as well as other sources including sulfidic ores and scrap are presented.

Jan 1, 1998