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By Gus Van Weert

Solvent extraction of iron from zinc refinery liquors has been investigated before, mainly on the MEHPA / HC1 stripping combination. Leakage of chloride into the zinc electrolyte and the costs of handling the ferric chloride eluate have prevented this option from being adopted. This work explores the stripping of the ferric loaded organic phase with nitric acid to take advantage of the possibility of regenerating up to 6N nitric acid, and clean spheroidal hematite production by autoclave treatment of ferric nitrate solution. The work was carried out with DEHPA (di 2-ethyl-hexyl phosphoric acid) in kerosine. Degradation testing proved the DEHPA to be very stable, when exposed to nitric acid solutions up to 6N and temperatures up to 70" C over a period of five days. Ferric iron was removed completely froma synthetic hot acid leach liquor, irrespective of the DEHPA concentration. Stripping the ferric turned out to be the problematic step. Although the stripping efficiency was considerable better at 50 than at 20° C, it decreased with increasing DEHPA/Fe ration in the organic phase. Eluates of no more than 5-10 g/l ferric nitrate were produced. surprisingly, nitric acid was found to be a less efficient stripping agent than sulphuric at equivalent normality and its efficacy levelled off above 4N. It was concluded that DEHPA does not appear to be the S.X. reagent to take advantage of the low cost autoclave decomposition of ferric nitrate opportunity in zinc hydrometallurgy and that another S.X. reagent, also resistant to nitric acid, but based on weaker compound formation is needed.

Jan 1, 1998

By Tony van der Steen

Subsea mining system are designed for the following, principally different, tasks: Dreding - The destruction and removal of seabed sediments overlaying the bedrock. Cleaning - The competence of the system to systematically remove the deposits from an undulating hard bedrock with irregular pulleys, channels and fissures. Factors that influence the choice of dredging equipment for a specific project are project requirements such as environmental conditions, location and water depth. However, the most important selection criteria are soil conditions. As a consequence, possible dredging systems, must be evaluated for the following, principally different, characteristics: Dredging proficiency - The destruction of the strata by the equipment. System stability - The capability of the soil to support the subsea equipment The above parameters are determined by the strength characteristics and the bearing capacitv_ of the soil. The author describes the processes involved in excavating the subsea deposits and (transporting the gathered soil as a water-soil mixture to the surface using different excavation and transport methods.

Jan 1, 1998

By Stanton Johnson

Africa has a long history of mining and has been one’of the world’s greatest sources of gold and other mineral resources since the days of the Egyptian pharaohs. Mining in Africa has been dominated by South Africa since World War II. However, in the past 10 to 15 years, other African countries are beginning to slowly catch up with South Africa. Ghana, formerly called the “Gold Coast” is located on the West Coast of Africa. Ghana has been involved in mining activities for well over 100 years. Most of the mining activities centered on the mining of gold and were to a large extent limited to underground mining methods. With a more liberal economic policy regarding the exploration and exploitation of Ghana’s mineral resources, mining activities are beginning to evolve to a much larger scale. Drilling and blasting which is an important aspect of this evolution is also changing due to the involvement of foreign-based mining and explosives companies.

Jan 1, 1998

By L. Katgerman, H. J. Brinkman, J. Duszczyk

"The phase formation sequence in the in-situ synthesis ofTiB2 in A1 from elemental A1, Ti and B powders is identified with a combination of DSC and XRD. After the melting of A1, A1B2 and A13 Ti are formed at the contact areas between A1-B and A1-Ti. The influence of variations in starting composition on the reaction kinetics is explained in terms of there effect on the different processes in the formation sequence. Parameters in the starting composition that were investigated are; fraction ofTiB2 forming reactants, non stoichiometric Ti:2B ratio's, and addition of alloying element Cu.It was found that a liquid Al phase is necessary for the in-situ TiB2 forming reaction from the intermediate A1B2 and A13 Ti phases. If all Al is consumed by the formation of A1B2 and A13 Ti the TiB2 formation is halted until the decomposition of A1B2 and A13 Ti .Overstoichiometric amounts of B are needed for complete conversion of the Ti, present in A13Ti, into TiB2 This is explained by the fact that some of the stable A1B12 phase is formed after the decomposition of A1B2•The addition of Cu leads to an increasing reaction rate in the A1-Ti reaction. A possible explanation for this is that the A1-Cu liquid penetrates more easily between the Ti and its surface oxide than the unalloyed A1 liquid."

Jan 1, 1998

By John Smyth

Mining through in panel entries and the full face recovery method has been successfully practiced at U.S. Stwl, Mine 50. Suppat of the cut-through entries and recovery room is critical. Traditionally, concrete crib or fly ash cement backfill has been utilized. However, these traditional methods are not feasible at Mine 50 due to the difficulties of the plow face mining through these types of support. Recent development of new cable support systems provides an option for cut-through entry support. Mine 50 and Jennmar Corporation personnel have worked together to design and apply the cable systems in the cut-through entries and full face recovery room to eliminate standing support. To date, a number of full face recovery rooms and cut-through inpanel entries have been successfully mined. The results indicate that the cable systems combined with high capacity shields, have provided sufficient capacity to support the roof. Utilizing the Jennmar Finite Element Analysis (JFEA) computer program (Stankus and Guo, 1996), an analysis of the stress and roof deflection changes as the longwall gradually cut through was conducted. From the finite element analysis data, a supplemental support plan was designed. The history and experiences at Mine 50 are presented. Based on the case experiences and modifications made to the finite element analysis, an improved design criteria for future use has been formulated.

Jan 1, 1998

By E. N. Mounsey

Ausmelt Technology was selected by Bindura Nickel Corporation (BNC) as the basis for a new copper circuit to process nickel plant copper leach residue to blister, anode and finally cathode copper and recover PGM values at the Bindura Smelter Refinery (BSR). The process selected, based on Ausmelt Technology to smelt and convert the residue to matte and blister copper and produce a discard slag, is novel incorporating smelting, converting and slag reduction process steps in a single Ausmelt vessel. The process demands a high quality blister copper product with low levels of arsenic and nickel. This paper reviews the project and the initial operational results to the end of 1997 of the Ausmelt Top Submerged Lancing (TSL) smelter and discusses the implications for the wider TSL converter market.

Jan 1, 1998

By Zhang Chuanfu, Tan Pengfu

"A thermodynamic model is developed to simulate nickel flash smelting process. In the nickel flash furnace, oxidation of concentrate occurs at one end, and reduction of slag occurs at the other. The model makes use two zones, namely the reaction shaft/settler zone and the appendage zone and accounts for 6 phases (matte, slag, silica, magnetite, Cu-Ni alloy and gaseous phase), 13 elements (Ni, Co, Cu, Fe, S, 0, N, C, H, Si, Al, Mg and Ca) and 33 chemical components in nickel flash smelting system. The compositions of matte, slag and gaseous phases in equilibrium are calculated by using the data of free energies of formation and activity coefficients of components. Two nickel sulfide species are used to allow for the modeling of sulfur-deficient mattes. The model predictions are compared with the known industrail data from Kalgoorlie Nickel Smelter, and excellent agreement is obtained. The model can be a very useful tool for monitoring and optimizing the actual industrial operations of nickel smelting process. The distribution behaviors of Ni, Co, Cu, Fe, S and 0 in the nickel smelting furnace depend on the process parameters such as smelting temperature, volumes of air, the content of the elements~ charge and oil.1. IntroductionThe nickel flash smelting furnace essentially consists of a reaction shaft where nickel sulfide concentrate is partially oxidized with air, a settle zone where matte and slag are allowed to separate, and a slag cleaning end where coke is added to provide for the reduction of the oxidized nickel from slag, and electrodes are used to provide heat.The theoretical model to consider a mass balance for copper flash furnace is developed by S. Goto and R. Shimpo[1][2J. However, this can not be true for nickel flash furnace as a whole since oxidation of concentrate occurs at one end (in the reaction shaft/settler), and reduction of slag occurs at the other (in the appendage). Despite these limitations, an acceptable pseudo-thermodynamic description of the furnace can be achieved using essentially two zones, namely the reaction shaft/settler zone and the appendage zone. Compositions of gas, slag and matte in two zones are calculated."

Jan 1, 1998

By R. R. Klimpel

The industrial processing of ores containing precious metals such as gold is generally very mining site specific, e. g. McQuiston and Shoemaker (1985), vanZyl et. a1. (1988), Fuerstenau and Hendrix (1990), and Hausen et. a1. (1990). The variety of various mineral processing techniques employed is extensive and includes size reduction, size classification, gravity separation, roasting, cyanidation, chemical and/or bacterial leaching, ion exchange and/or solvent extraction, and froth flotation. Gold occurs in the earth's crust on the average in very low concentration estimated by various sources to be between two and five parts per billion. For a specific ore deposit to be considered as an economic source of gold, generally a concentration of near one part-per million (one gram / Mton) or more is required. From a mineralogical viewpoint, gold often occurs in its native or free form. However, it can also occur as gold compounds of telluride, antimony, and selenium contained within either sulfide minerals such as pyrite, arsenopyrite. and pyrrhotite or, to a less extent, within silicate, oxide, and carbonate minerals. In many locations, alloying of gold with silver is found. The optimal processing method for recovering gold is determined by many factors such as the mineralogy of the gold bearing minerals as well as the associated mineralogy of the gangue minerals, the type of liberation profile of the gold bearing minerals upon' size reduction, and the particle size of the gold itself. Free or native gold particles can vary in size from the extreme of large nuggets to very finely disseminated gold associated in a complex sulfide mineral matrix. Typically free gold particles of several hundred microns or larger are efficiently recovered by one or more of a number of gravity based techniques due to the large specific gravity differential of gold (19.3 to 15) versus typical gangue minerals (5 to 2.7). When gold is associated with a sulfide (usually pyrite) matrix, historically most industrial plants involving size reduction and subsequent liberation have operated in a size range of 50 to 80 percent less than 75 microns. Grinding finer than this has been normally not economical unless the ore has a high gold content in the feed ore.

Jan 1, 1998

The removal of tritium from tritiated water (-0.5 µCiIL) was studied by metallothermic reduction using aluminum. The influence of the three variables namely the aluminum powder amount, the NaOH concentration and the reaction time has been studied on the tritium activity reduction. The experimental results and statistical analysis showed that more than 85% of tritium can be removed from the tritiated water. Further work on the tritium recovery as well as efforts to totally decontaminate water by incorporating a cryogenic concept is currently pursued.

Jan 1, 1998

By Ellicott C, Webb N

In November 1996 the NSW Minister for Mineral Resources, Hon Bob Martin MP, commissioned ACiL Economics and Policy Pty Ltd to conduct a wide ranging review of safety within the New South Wales mining industry.The review was a response to a disturbing number of fatalities which had occurred in the industry during the Minister's term of office together with a number of alarming near misses where serious failures in mining systems had occurred. Shortly after the review was commissioned, four mine workers died at Gretley Colliery near Newcastle. An inquiry is currently being conducted into the incident.

Jan 1, 1998

By D. E. Woolley

The rate of reduction of iron oxide from calcia-silica-alumina slag by carbon in liquid iron has been measured over the temperature range 1400-1600°C by monitoring the rate of carbon monoxide (CO) evolution. Slags containing ferric iron have been used in order to study the reduction of both ferric and ferrous cations. Results show that ferric iron is reduced before ferrous iron, so that the ferrous iron concentration increases initially. It is also shown that the rate constant, k, decreases at low reaction rates, or, equivalently, at low concentrations. The authors conclude that the reaction occurs in two periods. During the first period, ferric iron is reduced to ferrous iron. During the second period, ferrous iron is reduced to metallic iron, and the rate-limiting step during the second period is the mass transfer of ferrous cations in the slag phase to the slag-metal interface.

Jan 1, 1998

Political events during the past decade have caused businesses throughout the world to think globally. Countries once closed to free market enterprises are now open and seeking out foreign investment to help improve the well being of their populations. The mining industry has always been a global one. Today, though, the industry has become even more global. The driving forces behind this include the opening up of higher grade, lower cost mineral deposits in undeveloped and developing nations. In addition, permitting delays in the United States, coupled with stricter environmental guidelines and a general anti-mining attitude, have forced the mining industry to look outside US borders. The Mineral Economics and Management Society (MEMS) took as the theme of its seventh annual professional program "Economic Globalization of the Mining Industry." About 100 people attended the conference held in Arlington, VA in late March. Speakers included members of the investment community, academia, government and the mining industry.

Jan 1, 1998

By Janene Barter

Telfer Gold Mine treats both gold/copper oxide and sulfide ores in a remote location in the Great Sandy Desert, Western Australia. Currently, the oxide gold ore is treated in a conventional CIL circuit by blending the low and high grade copper ores to minimise cyanide consumption and allow smooth operation. The sulfide ore is treated through a flotation circuit to produce pyrite and copper concentrates. The pyrite concentrate is treated in the CIL. Copper concentrate is stockpiled and sold to a smelter for further processing. In recent times, as the depth of the pit has increased the copper head grade has also increased, to the point where the ore was becoming uneconomical to treat. In addition, it was desirable to reduce the amount of cyanide reporting to the tails dam both from an environmental and economical viewpoint. Newcrest Mining Limited engaged GRD Minproc Limited to evaluated a process to reduce the amount of cyanide entering the tail dam with consideration given to copper recovery. From this investigation, the Sulfidisation, Acidification, Recycle and Thickening (SART) process was selected. A detailed testwork program for SART was undertaken with the objective to design and construct a SART plant at Telfer. This paper outlines how the SART process was chosen and summarises the testwork that led to the design of the SART plant. It also touches on some of the important issues for designing this type of process.

Jan 1, 1998

By Jinsheng Chen

The major functions of longwall headgate entries are to provide access ways to the outby submains or mains for coal transportation and to the longwall face for fresh air and for transporting men and material during longwall operations. Any roof control problems such as cutter roofs or roof falls in the outby headgate entries could result in significant production delays to the longwall face and may be a threat to miners' safety Under a thinly laminated immediate roof and a high horizontal stress field, even a longwall headgate entry that has an angle of less than 45 degree to the maximum horizontal stress may experience roof deterioration in the outby headgate if the longwall panel mining sequence and retreat direction are not properly considered. This paper attempts to analyze the causes of the roof control problems experienced in the longwall gate entries at our Cumberland and Emerald mines in Pennsylvania and to determine the optimal longwall panel mining sequence and retreat direction for the future mining area at Cumberland

Jan 1, 1998

By W. H. (Bill) Jay

The destruction of cyanide creates a significant impost on the financial returns of gold mines. These losses increase substantially when ores containing cyanide-soluble copper are treated. Failure to remove or destroy free or WAD cyanide before it is discharged into tailings dams has, on a number of occasions, led to significant fish, bird and animal deaths. Thus, the retention of cyanide within the leach circuit and the recovery or removal of stable metal cyanide complexes needs to become standard practice for all gold mining operations. Furthermore, reducing cyanide purchases will minimise the quantity of cyanide transported to the mine site thereby reducing the opportunity for spillage of this chemical. Many different physical and chemical methods have been investigated for the removal of cyanide from process solutions. All cyanide destruction methods create a financial impost on the economic viability of the gold mine. To reduce these costs, the recycle of cyanide and the economic recovery of the metals solubilised by cyanide is of prime importance. The alternative methods currently in use, or under consideration for the treatment of copper cyanide, entail high reagent costs, produce the recovered metal in a contaminated form and require the safe handling of hydrogen cyanide. These processes will be briefly discussed within this report Environmental and financial benefits are enhanced by recent laboratory and pilot plant studies conducted by Oretek Limited. The Oretek CPC process for the recovery of copper and the recycle of cyanide from copper cyanide-containing solutions does not require pH adjustment to the alkaline cyanide leach conditions. Copper ions are coordinated to a water-soluble and/or an organic soluble polychelating agent under alkaline conditions and the cyanide ions are displaced Membrane separation, or phase separation of the polychelated copper from the cyanide ions enables the cyanide ions to be recycled and the copper to be directly electrowon from the polychelating polymer. The polychelating polymer is then recycled. Ion exchange resins and solvent extraction systems which may be incorporated into the above process will also be discussed in detail.

Jan 1, 1998

By G. Tapia, R. J. Kelley

Empresa Minera de Mantos Blancos S.A. operates two copper mines in Chile: Mantos Blancos and Mantoverde. Oxide ore is processed by acid leaching followed by SX-EW to produce copper cathodes. In order to define the leach process adequately for each ore, an extensive metallurgical testwork program was carried out during the feasibility study for each of these projects. A combination of heap and dump leaching was selected for Mantoverde, while a modification to the existing vat leach operation was selected for Mantos Blancos.

Jan 1, 1998

By Seeley D, Buckley N, Goodall J

Improving the performance and reducing the costs associated with export logistics chains is critical to the competitiveness of export coal mines. The fundamental practices associated with the use of export logistics chains made up of mine, trucking, rail and port operations are being challenged by the advent of third party operators on rail systems and the use of the Internet.Whilst individual mines can improve their processes to drive down their mining costs, they face major challenges in their endeavour to improve the performance of export logistics chains and reduce the significant logistics costs of moving coal from the mine to export ships, via the shared infrastructure of rail systems and ports. There is an increasing realisation that global competition is not only between mines but between coal export regions that are defined by their rail system and ports infrastructure.

Jan 1, 1998

By J. R. Batista, J. C. Young

Leachates from gold heap-leaching mines may contain selenium concentrations as high as 2 mg/L. Previous studies report satisfactory selenium adsorption by activated alumina from relatively "clean" drinking waters. However, the findings of these studies cannot be directly applied to the treatment of mine leachate where other ions compete for the alumina adsorption sites. This study evaluated the adsorption of selenium from a mine leachate to develop design parameters for a full-scale activated alumina process. The study revealed that 68% of the selenium in the leachate could be removed by alumina at pH levels greater than 5.0. At pH levels less than 4, silica was poorly adsorbed by alumina, and selenium adsorption was improved. Silica adversely affected the selenium adsorption capacity.

Jan 1, 1998

By Williams DJ, Battino S

The rapid crushing technique for the measurement of gas content of coal consists of accelerating the rate of gas desorption from coal by crushing. This technique allows the determination of gas content in the space of hours rather than days or weeks as required for the traditional slow desorption technique. The crushing technique is used particularly when gas content determinations are urgently required for mine safety purposes. The method is now routinely used in underground coal mines of NSW and to a lesser extent in QLD. Despite the rapidity and efficiency of this method, concerns have been raised upon the reliability of the method to deliver accurate results. Experience in Australia has shown that there is in fact some discrepancy in results between gas laboratories using the rapid crush technique. The development of rapid crushing techniques for seam gas content measurements in Australia and the main causes of variability in the gas content test results were investigated. The gas laboratories participating in the gas content testing were CSIRO Division of Coal and Energy, BHP Technical Services and GeoGas Pty. Ltd.

Jan 1, 1998

By J. K. Wolski

This paper addresses the effects of using jet fans as booster fans in mine ventilation networks. A method was developed to determine the pressure generated by jet fans using the momentum theory. The influence of a reduction cone and other ventilation parameters on the jet fan pressure was analyzed. Verification experiments conducted in the Waldo Mine are described. Examples are given to demonstrate the conditions for the effective use of jet fans.

Jan 1, 1998