Search Documents

By Yuan Zeping

This paper describes the distribution and removal of the main impurities in the pyrometallurgical process ?at the Guixi Smelter. The paper discusses in detail our converting schedule?of3S-SB and injecting deeply a mixture ofNa2CO) and CaO flux into the converters to enhance impurity removal.

Jan 1, 1998

By M. H. Leite, R. Corthésy, D. E. Gill

"La connaissance des contraintes naturelles qui prévalent dans les massifs rocheux est un prérequis indispensable pour la conception sécuritaire et économique des excavations comme on en retrouve dans les exploitations minières souterraines. Certains chercheurs se sont attardés à colliger les résultats de mesures de ces contraintes et les ont utilisés pour produire des modèles de prédiction basés sur leur traitement statistique. Ces modèles de prédiction sont très populaires auprès des exploitants miniers puisqu’ils permettent, du moins dans les étapes préliminaires de design, d’obtenir de façon s’apéconomique mais approximative, une partie des paramètres dont ils ont besoin. Dans le cadre d’un projet initié en 1994 avec la collaboration de l’IRSST, il a été décidé de produire un modèle de prédiction englobant une partie de la zone périphérique de la faille de Cadillac, soit une zone plus restreinte que le Bouclier Canadien utilisé jusqu’ici comme région pour l’élaboration de tels modèles. Pour produire ce modèle de nouvelles données obtenues avec une technique permettant d’exercer un excellent contrôle de qualité ont été ajoutées à celles déjà disponibles. Une telle régionalisation des données de base permet d’obtenir un modèle où les intensités et les orientations des contraintes principales sont beaucoup moins dispersées que ce que rapportent les modèles publiés jusqu’à ce jour. Enfin, il est démontré que le modèle proposé pour la région étudiée est en toute probabilité plus sécuritaire que les modèles plus généraux publiés à ce jour. Knowledge of the in situ state of stress existing in a rock mass is essential to the safe and economical design of underground mining excavations. Prediction models have been published, based on the statistical treatment of stress measurement results. Such prediction models are very popular among mine operators because they allow them, at least at a preliminary design stage, to economically obtain part of the information needed, even if this information is approximative. In 1994, a research project financed by IRSST was initiated aiming to produce a prediction model that would comprise a peripheral zone around the Cadillac fault. This region is more confined than the Canadian Shield on which the existing prediction models have been based up to now. In order to produce such a model, existing stress measurement results have been used in conjunction with new stress measurements that have been performed based on a technique which allows full control of the quality of the measurements. Restricting the data upon which the model is based to a more specific region gives a model in which the intensities and the orientations of principal stresses are far less scattered than the results published to date. Finally, it is shown that the proposed model is probably safer for the studied region than the models previously published."

Jan 1, 1998

By M. Grenon

"The presence, size, orientation, nature, and persistence of geological discontinuities dictate the behaviour of a rock mass. Block size, which is defined by discontinuity spacing, by the number of joint sets, and by the persistence of the discontinuities delineating potential blocks is an important indicator of the degree of fracturing of a rock mass. Consequently, block size is represented either explicitly or implicitly in all rock mass classification systems employed for analysis and design of surface and underground mining structures. Insitu block size distributions may provide a better means to describe the structural complexity of a rock mass. These are the distributions that would be derived if the in-situ rock mass was separated into its constitutive blocks, delineated by existing discontinuities, and each block measured. This paper presents the results of a field campaign at Louvicourt Mine aiming to characterize the rock mass using different methods for determining block size and block size distributions. IntroductionGeological structural data are used to provide input data for analysis and design methods for surface and underground structures. As the collection of structural data involves considerable investment of time and effort, it is sometimes overlooked, thus denying an important source of information for mine design. What is somewhat surprising, however, is that when structural data are available, they are not used to their full potential. Recent work has shown that data on block size have potential applications in different areas of rock engineering:• Blasting — Hudson (1993) has described the excavation process as the change of a preexisting natural block size distribution to the debris fragment size distribution (Fig. 1). Lizotte and Scoble (1994) have reviewed previous efforts on integrating site specific geological conditions into blast design. Grenon et al. (1997) provide a case study where in-situ block size distributions are compared to photogrammetric studies of blasted rock.• Rock mass classifications — Block size is used in the majority of rock mass classification systems either explicitly, as in the RMi classification system Palmstrøm (1995), or implicitly, such as in the NGI system, Barton et al. (1974)."

Jan 1, 1998

By Callcott R

Prediction of raw coal size distributions and those generated by processing are examined using spreadsheets and the matrix analysis of breakage processes. Run of mine coal size distributions are predicted from the lithotype properties using a

Jan 1, 1998

By I. E. Odom

An electron optical and microprobe study was made to determine the physical and chemical nature of the silica minerals that occur as natural impurities in bentonite and montmorillonitic fuller&apos;s earth clay products (both granular and powder) and that occur in <10-µm dusts from plants that process these products. The purpose of the study was to determine if discrete "free" silica minerals, such as quartz, could be observed using SEM and EDS methods. No “free" silica minerals could be observed in the SEM images of the granular and powdered products, either among or on the surfaces of the particles. Also, no “free" silica could be identified by either SEM or EDS analyses of the dusts, even though quantitative X-ray diffraction analysis indicated that trace amounts of quartz occurred in all samples. It was determined that these quartz and other silica minerals were encapsulated or coated by montmorillonite. Vigorous washing, however, removed some of the clay coatings, so that small amounts of silica minerals could be seen by SEM and EDS analysis. It was found that all primary crystalline quartz grains in the bentonites have diagenetic overgrowths consisting of a mixture of montmorillonite, opaline silica and possibly microcrystalline quartz. Detrital quartz grains in the fuller&apos;s earth have thin diagenetic overgrowths of opaline silica, also containing montmorillonite. The clay encapsulation of the silica minerals in the products studied, as well as in the potentially respirable (<10-µm) dust produced during manufacturing of bentonite and montmorillonitic fuller&apos;s earth clay products, is considered to be an important factor influencing the potential health effects (e.g.. silicosis) of the contained silica. Even if clay dust containing silica should be inhaled, the montmorillonite encapsulating the quartz and other silica minerals would prevent direct contact of the silica with lung tissue. The clay encapsulation of quartz, as well as the highly hydroscopic nature of montmorillonite, may explain why not a single confirmed case of silicosis has ever been reported among plant workers in more than 65 years of production.

Jan 1, 1998

By T. S. Golosinski

This article reviews current contract mining practices in Australia. Various types of contracts are reviewed, including partnering arrangements and alliances between the contractor and the mine owner. Applicability is also discussed of various types of contracts to specific mining situations, as is their effect on overall mine performance.

Jan 1, 1998

By Ian B. Corbett

De Beers Marine Pty Ltd. (South Africa) (DEBMARINE), a wholly owned subsidiary of De Beers Consolidated Mines Ltd. specializes in the provision of contracting and consulting services for offshore diamond exploration, Mineral Resource Management and mining. Established in 1983, the company is strongly focused on driving and sustaining growth of the offshore diamond mining industry into the 21st century. DEBMARINE provides full Mineral Resource Management and produce almost half a million carats annually for the Namibian Diamond Corporation (Pty) Ltd. from their offshore mining licence. The company is also extensively involved in feasibility studies to establish new mining ventures and in the exploration of several offshore Prospecting Licence Areas for other clients. As a pioneer in this field, DEBMARINE remains highly focused on technological development. A specialized section, the Technical Development Business Unit, has been established. Through relationships with various technology leaders, this unit develops new sub-sea mining technology and delivers productivity innovations aimed at realizing maximized carat extraction. This talk provides a broad perspective on the development of the Namibian offshore deposits and examines the critical role played by high-resolution orebody characterization and high-confidence Mineral Resource development at De Beers Marine.

Jan 1, 1998

By P. Groleau, O. Tavchandjian, D. Marcotte

In open pit mining, each small mining unit (SMU) is selected for mill processing based on an estimate of its true grade. The estimation is usually done using analyses of cuttings from blast holes within that SMU. One common estimator used for selection is the arithmetic average of within-SMU samples. This estimator is conditionally biased. The effect of a conditional bias is to overestimate the profit really recovered from the deposit. For this reason, a conditionally unbiased estimator is preferable. Increasing the number of samples generally improves the accuracy of the estimation (and diminishes the conditional bias, if present, of most estimators). However, there exists a practical limit where an additional sample does not improve the estimation sufficiently to cover the expense of making the analysis. This limit is specific to each deposit and depends on geostatistical parameters, economic factors, and mining parameters. This study examines how the number of samples affects the recovered reserves and the resulting profit. Also, the effects on optimal profit of varying the different factors are examined. Globally, the number of samples required increases with the selectivity of the operation. For a given ore deposit, the greater the number of SMUs selected for processing, the fewer samples are required and vice-versa.

Jan 1, 1998

By M. P. Nesterov

The method of predicting the time-dependent surface subsidence for gently-inclined potash deposits where total extraction using various sizes of yielding bamier pillars was discussed.

Jan 1, 1998

By Sam Bang Jr, Rodney Burke

As mining progresses in the West, the depth of material has increased, making highwall stability a major factor in safety and production. The Jim Bridger Coal Mine’has made highwall stability a priority, concentrating on safety as well as increasing and improving production. Overburden depths are increasing dramatically; the geological environment consists of medium to sot? material, faulting, water, and current pit alignment not favorable to joint planes. Angle drilling the presplit at 20 degrees became necessaryas vertical presplit drilling produced wall failures.

Jan 1, 1998

Jan 1, 1998

By E. M. Hillary, D. F. Sangster

"Abstract - As a contribution to the World Minerals Geoscience Database Project, an index-level database comprising information on 142 SEDEX Pb-Zn deposits and occurrences was constructed in Microsoft Access 95 format. Although consisting of only basic information, the compilation, with full referencing of all data, is possibly the largest non-corporate SEDEX Pb-Zn database in the world. It thus provides an opportunity to make geoscience queries of SEDEX Pb-Zn deposits on a scale not previously available. This report provides a summary of the results of a few such queries both as a contribution to a better understanding of SEDEX lead-zinc deposits and as a demonstration of what even such a simple database can offer.During the compilation process, it became apparent that SEDEX Pb-Zn deposits could be assigned to one of the following three sub-types: Type 1 (53.5% of total) in which sulfide minerals are the only exhalative components; Type 2 (33.1%) in which the exhalative components are sulfides plus chert, siderite/ankerite, and/or barite; Type 3 (13.4%) which contains any components of Types 1 and 2 plus abundant iron-oxide minerals (commonly magnetite) and/or is associated with iron oxide-rich sedimentary rocks.Highlights of systematic queries of the database reveal that:1. a majority (84%) of the world’s SEDEX Pb-Zn deposits are not underlain by a discordant footwall feeder zone or vent complex;2. 63.6% of deposits occur in Proterozoic strata followed by a second peak in the Devonian (16.8%). Of those in the Proterozoic, 83% of Type 3 deposits occur in the Gondwanaland supercontinent, whereas only 42% of Type 2 and 39% of Type 1 are located in this large paleo-landmass;3. median (Pb+Zn) grades in Types 1 and 2 fall between 9% and 10% with a majority clustering within this range. Type 3 grades, however, range from ~1% to ~20% (Pb+Zn) with a median of 5%; 4. median size of Type 3 deposits is ~33 Mt, whereas Type 1 and 2 median sizes are ~7 Mt and ~8 Mt, respectively.The report concludes with a brief discussion of how an index-level database such as this can be used in conjunction with other, similar databases to reveal interesting and instructive relationships for guiding both research and exploration."

Jan 1, 1998

By Yoji Imai, Akio Watanabe, Masakazu Mukaida

"To clarify the feasibility of alkoxides and acetylacetonates as precursors for laser CVD of metal oxides, vapors of tantalum or titanium alkoxides and zirconium acetylacetonate were irradiated by KrF excimer laser and deposits were characterized by XRD and XPS measurements. As for tantalum and titanium, non-stoichiometric crystalline oxides grew nearly phototropically, however, zirconium oxides deposited showed only halo-pattern by XRD measurements. Electric conductivity measurements of tantalum oxides implied the improvement of the insulating properties by the addition of activated oxygen to the ambient.IntroductionThere has been renewed increasing attention to the metallic oxide thin films because ofits promising usefulness in many applications, such as high-Tc superconductors and ferroelectric devices. A variety of thin film preparation techniques have been studied such as sputtering, chemical liquid deposition (sol-gel and metalorganic decomposition), pulsed laser deposition and chemical vapor deposition (CVD). Among them, we think CVD is the most promising method because it offers a high controllability of morphology and good step coverage at relatively high growth rate. Preparation of oxide films by CVD can be achieved using a precursor containing metallic element and oxygen containing gas such as N20 at the same time. However, metalorganic (MO) compounds which contain both metallic element and oxygen, directly bonded to metallic element, seems to be more favorable because some of MO has a good properties for CVD such as a rather high vapor pressure, stability in ambient and low toxicity."

Jan 1, 1998

This paper outlines the mechanism of Stress Corrosion Cracking (SCC) and how it can cause premature failure of rock bolts. SCC occurs due to the progressive development and growth of cracks in the surface of a metal, and it is caused by the combined effects of stress and a corrosive environment affecting susceptible metals and alloys. It can occur in most metals including stainless steel. It is not a new phenomenon, but its effect on rock bolts has only been recognised recently.Rock bolt failures caused by SCC appear to be brittle failures which occur at less than the ultimate tensile strength of the bolt. In the mining industry, SCC failures of rock bolts can occur a few months, or after many years of exposure to stress and a corrosive environment. If SCC of rock bolts is suspected, then the rock bolts should be examined by a metallurgist, and steps should be taken to reduce the problem.

Jan 1, 1998

By John H. Weigand, Stephen V. Crum

"VIBRONICS, INC. instrumented and monitored a residential structure for response to,blasting at aMidwestern surface coal operation. The residence was owned by the mining company and was extremely close to the operation. Blasting was conducted within 120 feet (36.5 meters) of the test structure. Up to seventeen (17), four (4)-channel seismographs were used during the monitoring period. The basement walls and floor were monitored. VIBRONICS, INC. also monitored a brick chimney in the basement and attic. Structural responses were then compared to outside vibration measurements taken in the soil near the foundation."

Jan 1, 1998

By Steven I. Baskin

Cyanides are utilized in many industrial applications including preparation of chemical intermediates, electroplating, and&apos; mining, Cyanide has been utilized in chemical warfare operations as well Cyanide is also synthesized and found in plants and animals including man where it is thought to perform multiple functions. A variety of enzymes are known to detoxify cyanide under different conditions. These include rhodanese, 3-mercaptopyruvate-sulfur transferase, thiosulfate reductase, cystathionaseand albumin. Cyanide appears tQ exert its toxic effect primarily by inhibiting cytochrome oxidase? although other enzymes are also inhibited. Therapeutic antagonist categories to treat cyanide include methemoglobin formers such as nitrite, sulfane-sulfur donors such as thiosulfate, metal salts or complexes such as cobalt and cyanohydrin-forming compounds such as dihydroxyacetone or alpha keto-glutaric acid. Advantages and disadvantages of each category will be discussed. Newer compounds under development have been found that may allow for prophylactic therapy for cyanide poisoning with minimal side effects; In addition, portable co-oximetry devices may provide real-time measurement of cyanide in field units.

Jan 1, 1998

By I. Kim, J. C. Choi, W. D. Cho

"The effect of yttrium addition on the oxidation behavior of Fe3Al intermetallic compound was investigated in the range of temperature 800 to 1100 °C in 0.2 atm 02 in terms of oxidation rate and oxide adhesion. The oxidation rate of alloys, Fe-14.3 wt% Al and Fe-14.1 wt% Al-0.3 wt% Y, was nearly identical and the parabolic rate constant calculated as a function of temperature is Kp=5128 exp[-39506(cal/mol)/RT] mg2/cm4 hr.Rapid cooling and ultrasonic stress tests were carried out to test adhesion of scale formed on the alloys. While the oxide layer formed on the Fe-Al alloy without Y was found to be fragile and detached easily during the tests, the oxide layer formed on the Fe-Al alloy containing Y was protective, dense, and adhesive. The following two mechanisms were proposed to explain the adhesion improvement of Ah03 formed on the Fe3Al containing yttrium : (1) the addition of yttrium decrease generation of growth stress in alumina scale because the preferential diffusion of yttrium through grain boundary in alumina scale prevent internal oxidation of Al, one of main causes of growth stress, and (2) the second phase formed on the oxide scales prevents crack propagation through the scales, leading to better mechanical stability of the oxide scales.IntroductionIron aluminides have attracted the attention of many researchers as a candidate for use at high temperature because of their excellent oxidation resistance due to the formation of protective alumina scale. In order to resist aggressive environments at elevated temperatures, oxide scale formed on iron-uluminum alloy must satisfy the following three requirements : (1) thermodynamic stability (2) slow growth rate (3) adherence on substrate. According to Wallwork and Hed [l], the most suitable alloys for high temperature application are Fe, Ni, and Co alloys with the protection of Si02, Cr203, and Ah03 scales. While chromium oxide can vaporize as Cr03 above 1000 °C and silicon oxide may form low melting silicate [2,3], Alz03 has a high melting point and is the most stable among the three oxides thermodynamically [6]. In this respect, iron aluminides forming alumina seem to be most suitable for use at high temperature. However, alumina scale formed on the iron aluminum alloys tends to be easily spalled during oxidation due to the combination of growth stress and thermal stress."

Jan 1, 1998

By S. Ozbilen

"Al-Li binary alloys with nominal Li contents of0.15, 1.1and2.8 (in wt%) were aged naturally at room temperature for two months, aged at low temperatures ( 65 and 1 OOEC) for up to 2 months and aged artificially at 190EC for 4 days after water quenching to 25EC following solutionizing at 530EC for 20 minutes. Ageing behavior of these binary alloys were studied by Vicker's Hardness measurements and DSC thermal analysis. Thermal analysis results indicate the formation of GP zones of Al-Li system in Al-2.8wt%Li binary alloy. In the same alloy, rapid quenching from one phase region (a) gives rise to precipitation of small o' particles in a matrix (a) with still high supersaturation. During ageing of this alloy below lOOEC an additional transformation, i.e., GP zone formation occurs proceeding at a very high rate which is described on the basis of the theoretical analysis for the quenched Al-Li system proposed by Khachaturyan et al [6]. Ageing at temperatures below 11 OEC takes place slowly by the formation of small d' particles of lower thermal stability than the quenched-in d precipitates in addition to GP zones resulting in an increase in hardness compared to water quenched samples. During artificial ageing, GP zones transform by dissolution to d' precipitates while d' particles already in the microstructure coarsen during under aged condition at which hardness increases with time till peak aged condition.IntroductionIn binary Al-Li alloys the d' (Al3Li) fully coherent internally ordered inetastable phase of Li2 structure with a=0.4038d [1-5] forms homogeneously between 120 and 190EC before the formation of stable d' (A!Li) phase and cause the superior mechanical properties. This is due to an appreciable age hardening effect resulting because of the d' precipitation during ageing [1]. The response of d' to decomposition and its formation kinetics have been studied previously and it is believed that the decomposition of the a-supersaturated solid solution occurs in a two stage process; i.e., a 6 d' (Al3Li) 6 d(A!Li). Khachturyan et al [6] theoretically investigated precipitation of the d' phase and gave an interpretation of the transformation paths of the quenched Al-Li alloys. They predict that the disordered supersaturated solid solution congruently orders, and then the uniformly ordered solution decomposes into ordered regions that differ in Li-content. Finally, ordered d' phase forms in the disordered matrix."

Jan 1, 1998

Much attention in controlling blast vibrations has been centred on the probability of causing damage to structures in the area adjacent to where blasting is carried out. In most cases these structures are residential properties and the effect of the vibrations on the occupiers has not been studied to any great extent. This paper looks at the sources of disturbance caused by blasting and their psychological effect. A comparison of ground vibration levels for compliance is examined within the framework of structural and human response.

Jan 1, 1998

By Harper B

The mining industry has developed a comprehensive view of the need to have production personnel well trained in the use and maintenance of mining equipment. A strong commitment from the industry to this view has been instrumental in creating an efficient, profitable and productive industry based on modem production processes, sophisticated equipment and a multi skilled workforce. As the industry continues to develop, and the skills and knowledge needed by productive workers continues to expand, the training processes adopted by the industry will need to develop in parallel, not only making use of the latest advances in learning theories, instructional design and technology, but also using these knew ideas in more efficient ways.

Jan 1, 1998