Search Documents

By Ronald J. Roman

The shrinking core model for coarse particle leaching has been generally accepted as describing the leaching of a copper oxide or sulfide ore. However, when a mixed oxide/sulfide ore-is leached this model can not be used in its simple form because at least two and possibly three separate leaching processes are occurring simultaneously (dissolution of oxide copper minerals, secondary copper minerals and primarily copper minerals). It has been impossible to isolate their individual leaching curves from the recovery/time curve generated by the column leach test. This paper describes a tests program carried out at the Groupo Mexico, Mexicana de Cobre's La Caridad operation in which the individual recovery/time curves for the leaching of copper oxide mineral, secondary copper mineral and primary copper minerals were developed from standard column leach tests. Once the individual recovery/time curves were developed scale-up of the column leach test results to the commercial heap leaching operation is possible by using the shrinking core model.

Jan 1, 1999

By I M. Howard

With the bell-less top (BLT) charging system replacing the centuries old double bell charging method, the furnace efficiency has been greatly improved together with considerable reduction in the furnace down time and operational problems. But still there are many draw-backs which need further attention to achieve better efficiency and operational effectiveness. The performance and operational problems of the BLTs have been highlighted and possible solutions to overcome some of the major problems are discussed.

Jan 1, 1999

The role of ZnSO4 in activation of sphalerite (ZnS) and deactivation of lead-activated sphalerite has been investigated. Adsorption of metallic ions at the solid-solution interface, electrokinetic results for sphalerite under different chemical conditions, and thermodynamic calculations were used to elucidate the mechanisms involved. It is shown that flotation response of sphalerite in absence of activators is rather weak and that adsorption of ethyl xanthate on the mineral mainly electrostatic in nature. Zinc sulfate is found to activate the mineral but only in a narrow acidic pH range. This is attributed to the increase of zeta potential as well as the possible increase in amount of negatively charged bulk precipitated zinc xanthate. Lead ions activate sphalerite in a wide pH range and the lead activated mineral assumes a flotation behavior similar to that of galena (PbS). However, addition of ZnSO4 depresses the lead-activated sphalerite by replacing lead ions at the mineral/solution interface.

Jan 1, 1999

By Dhar B. B, Gupta R. C

Grinding of iron ore is an essential step to utilise ore fines for pelletisation needed for DRI units. While preparing iron ore pellets for DRI production, the iron ore needs extensive grinding which is highly energy consuming step causing the process to become non-viable in some cases. In the present paper an attempt has been made to evaluate grinding performance of thermally treated ore compared to normal ore grinding. Such thermal pre-treatment has been found to reduce the energy requirement with lower consumption rate of grinding media. It has been observed that by applying thermal shock the ore is rendered weak with improved grindability. The stresses generated due to thermal treatment may extend existing micro-cracks in the ore and in some cases it may even nucleate fresh cracks. Experimental studies carried out on thermally treated hematitite ore reveals that the heating to 400¦C followed by water quenching can cause a reduction of 45 per cent in grinding energy. The paper gives the details of the experiment and the Results.

Jan 1, 1999

By C. Dixon

This paper is based on the assumption of some knowledge of the National Water Act. It will consider the question of how that Act fits in with: a) existing laws which overlap on the subject matter b) new laws either in draft or in the process of being compiled c) policies which will eventually find their provisions included in new legislation (e.g. minerals policy) d) international practices. The focus will be specifically on the interaction of legislation relating to water use and water pollution in the mining sector as well as the role of the Department of Water Affairs in mining matters. Hence the title of the presentation.

Jan 1, 1999

Laboratory scale flotation tests were done on mineral hematite and aspecular hematite ore using oleic acid and sodium oleate as collectors. The mineral hematite floated strongly in the neutral pH region, with an increased pH range of flotation at higher oleate additions. Concentrates with sufficient hematite grade to meet the paint pigment specification were produced using oleic acid and sodium oleate as hematite collectors on the specular hematite ore. Hematite recoveries of 70 per cent at 60 per cent Fe grade were obtained using stagewise roughing. The interaction between hematite and oleate was confirmed as chemisorption but the exact mechanism could not be determined, as two independent phenomena can be used to explain the fact that the pH of maximum grade increased with increasing oleate addition.

Jan 1, 1999

By Misra V. N

Upgrading of a Koolanooka magnetite iron ore sample provided by Kingstream Steel Ltd was investigated using low intensity magnetic separation (LIMS) and reverse flotation. The ore contained 38.6 per cent iron, 37.8 per cent silica, 6.5 per cent magnesia and 0.54 per cent alumina, with the main minerals in the ore being amphibole (42 per cent), magnetite (39 per cent) and quartz (14 per cent). The concentrate obtained after low intensity magnetic separation contained 66.6 per cent iron and 6.34 per cent silica with an iron recovery of 72 per cent. This concentrate was further treated by reverse flotation to increase the iron content and reduce the silica content to meet the requirements for direct reduction iron (DRI) feed grade.

Jan 1, 1999

By Don Rose

Steel-fiber-reinforced-shotcrete (SFRS) methods of testing and the wording of specifications vary from country to country. In the USA ASTM C1018 is widely used. The Canadians have taken a close look at C1018 and point out that exact determination of the first crack is very subjective, and they propose a method of design that eliminates this variable. The Europeans (EFNARC) have taken the principles of testing a step further than ASTM C1018, and have added a new step in measuring the effectiveness of SFRS. EFNARC uses an "energy absorption" of a plate loaded in its center, in addition to the principles of C1018. The principles of SFRS design are also used in Japan, Norway and elsewhere.

Jan 1, 1999

By Milorad Cirkovic

Kinetics of copper concentrate oxidation in roasting processes in a fluidized bed reactor has been studied at temperatures between 600°C and 720°C using particles of 0.038 to 2.5 mm in average size. The analysis of composition of samples has been done by chemical methods. Phase composition has been determined by Siemens X-ray equipment with Cu anticathode and Ni filters at a voltage of 40 kV and a current of 18 mA. The content of sulphur has decreased from 33.23 to 19.02 mass percent with the increase of temperature, but the content of Fe304 has increased from 0.15 to 17.14 mass percent. The new mechanism of copper concentrate oxidation in a fluidized bed reactor is proposed in this study. It has been shown from the mathematical model that the velocity of oxidation of copper concentrate between 600°C and 720°C is virtually controlled by the rate of diffusion of 02 through the layer of reaction product.

Jan 1, 1999

By T. Mudder, K. Harvey

The objectives for closure of a hard rock mine include minimizing long term environmental liability, attaining regulatory compliance, and maintaining geotechnical stability, while closing as cost-effectively as possible. Proper planning for closure should come during the feasibility study, design and permitting phases, and during operations as updates. The lack of a proper or updated closure plan can result in severe environmental and economic consequences. Effective mine closure is the result of a combination of innovative concepts, long-term commitments, and multi-party cooperation. The purpose of this paper is to discuss concepts, commitments, and cooperation as they relate to an effective closure plan.

Jan 1, 1999

By V. T. Vacariu, P. D. Georgescu, N. Tomus

To assess the potential for radioactive pollution unique to the environmental conditions of the Bacau phosphogypsum waste dump, surface samples were taken, drillings were performed on the entire waste dump's height, and the Ra226 distribution on the height and surface considered to contain a medium content of the radium of 0.57 Bq/gr was studied. Thus, the waste dump's radioactive potential was estimated at 30-40 Ci in equivalent Ra226. Also analyzed was the granulometric composition of the phosphogypsum and the distribution of Ra226 on granulometric orders, which indicated that the radium was concentrated in the very fine fractions. Parameters were set up for the classification by hydrocycloning to obtain a fine class (less than 41 microns) having a radium content of more than 0.9 Bq/gr and a coarse class having less than 0.37 Bq/gr. A chemical process was devised for removal of the radium from the phosphogypsum with the possibility for recovering the contained sulfur.

Jan 1, 1999

By B Whiteley, B Gee

The Northside Storage Tunnel is a TBM driven rock tunnel system designed to collect and store sewage from four major storm overflow points along the existing Northern Suburbs Ocean Outfall Sewer. At present, sewage overflows during wet weather are the main source of pollution for Sydney Harbour. The tunnel system comprises a 16 km long by 3.8 m to 6.5 m diameter tunnel from Lane Cove to the North Head Sewage Treatment Plant and a 4 km long by 6.3 m diameter branch tunnel from West Chatswood. The tunnel will have a typical rock cover of about 50 m to 150 m. Most of the tunnel alignment is contained within the Hawkesbury Sandstone Formation which is generally an excellent tunnelling stratum, and offers few geotechnical constraints. However, the tunnel is required to pass beneath incised palaeochannels at Middle Harbour and Manly with each palaeochannel containing about 70 m of sediment.Innovative geotechnical and geophysical investigations were undertaken to examine the tunnel route and characterise the rock beneath the palaeochannels. These investigations have located zones of poor quality rock beneath one palaeochannel in particular, suggesting significant stress relief had taken place in the rock at times of lower sealevel producing structural features indicative of valley bulging. This paper presents the geotechnical model developed for the tunnel, and the models and constraints for tunnelling beneath the palaeochannels.

Jan 1, 1999

By S. Veeramasuneni

The recent nonequilibrium electrophoretic mobility measurements by laser-Doppler electrophoresis coupled with the stability and prevalence of collector colloids in soluble-salt flotation systems suggest that the selective flotation of alkali halides is due to the adsorption of oppositely charged collector colloids by heterocoagulation. Previously reported flotation results confirm this surface charge/collector colloid adsorption model. These results also indicate that the sign of the surface charge has a significant effect on the extent of particle dispersion/aggregation. In this regard, the nature of such particle interaction forces at high ionic strengths are examined to improve our understanding of these systems. Atomic force microscopy (AFM) is now being used to directly measure the interaction forces responsible for the stability of these alkali halide aggregates observed in optical microscopy studies. Results from this study indicate that, while repulsive hydration forces exist between similarly charged hydrophilic particles, attractive forces exist between oppositely charged hydrophilic particles in high ionic strength solutions.

Jan 1, 1999

By C. A. Rowland

Introduction Comminution efficiency, as measured by relating circuit performance to the consumption of energy and the time and money required, can be determined by the following comparisons: Theoretical efficiency: The theoretical efficiency is the actual energy consumed in a comminution machine compared to the theoretical energy required to perform the size reduction. Operating efficiency: The operating efficiency compares the operating work index of a comminution machine to the Bond work index of the ore, as determined from bench-scale crushing and grindability tests or pilot-plant tests. Economic efficiency: The economic efficiency is comparing income from production to predicted income. Key words: Comminution, Bond work index, Grinding, Crushing, Ball mills, Rod Mills. Theoretical efficiency In their book Process Engineering of Size Reduction - Ball Milling, Austin, Klimpel and Luckie (1984) stated that, "We have tried throughout this book to avoid the use of the term grinding efficiency because the degree of conversion of energy to useful size reduction is an ill-defined concept. In addition, the only efficiency, which is of real interest, is the meeting of product specifications at the minimum cost." The National Materials Advisory Board, National Re¬search Council (1981), in the abstract of a report titled "Comminution and Energy Consumption" stated that, "Up to 99% of the energy consumed in grinding these ores may be expended in the movement of machinery, with noise and heat the undesirable byproducts, thus leaving only 1% of the energy available for size reduction. Coupled with this is evidence that many of today's crushing and grinding techniques not only are antiquated but have little or no scientific base of understanding." Throughout the past 50-plus years, grinding efficiency has been referred to as being from 1 % to 10%. The measurable basis for these observations is difficult to establish, but they appear to be based on production performance compared to theoretical energy requirements for the work done. The theoretical energy requirements were determined from the energy required to break a single particle or a thin layer of monosized particles by compression or by a single impact from an impact-testing device. King, Tavaras and Middlemiss (1997), in a paper titled "Establishing the energy efficiency of a ball mill" described such a test. These batch single-breakage tests generally do not duplicate the continuous-breakage process in the comminution machinery used in ore concentrators. Operating efficiency The currently available crushers and grinding mills are fed at a controlled continuous flow rate, and they impart the breakage pattern needed to produce the desired size reduc¬tion. While theoretically inefficient, they are the most practical comminution machines available. The operation of this machinery is relatively simple and can be controlled with available control systems. The essential factors in determining the operating efficiency of comminution machines are energy, as consumed in the machinery, and the required energy, as determined from test work. Bond work indices, obtained from bench-scale or pilot-plant crushability and grindability tests are used in the following Bond equation (Bond, 1960) to determine the energy required to produce the required size reduction

Jan 1, 1999

The underground storage of LPG and other hydrocarbons is in current commercial use in Northern Hemisphere countries in Europe, Asia and the USA.Elgas Pty Ltd, a 50 per cent joint venture between AGL and BOC, embarked on a worldwide feasibility investigation in 1989 to establish the viability of constructing an underground LPG storage facility in Sydney, Australia, the first of its kind in the country. Elgas recognised that with the limited 19 000 tonnes of storage capacity at Port Botany and the limitations imposed by use of small coastal ships (up to 10 000 tonnes capacity), a larger storage facility was required to utilise higher capacity ships from more remote sources such as the North West shelf and overseas. This would achieve security of supply in high demand periods and economies of scale. The underground option also provides improvements to safety and environmental standards.

Jan 1, 1999

By Kenneth L. Nash

The control of solubility of waste actinide ions, by conversion to highly insoluble mineral phases has been demonstrated in the laboratory. Actinide metal ions are removed from neutral pH solutions by a combined ion exchange-decomposition-mineralization process based on the application of the naturally-occurring hydrolytically unstable.polyphosphate organic compound phytic acid.

Jan 1, 1999

By Iwao Iwasaki

Since the oil crises in the 1970s, the mining industry in the developed countries has faced strong competition from developing countries. In order for the North American iron ore industry to remain competitive with high-grade overseas sources, research on low-cost beneficiation methods that ensure high-quality and uniform-quality products must be maintained in order to prepare for ever-tightening specifications on iron making raw materials for blast furnaces and also for the future iron- and steelmaking processes that can directly utilize finely ground concentrates.

Jan 1, 1999

By G. Chi, M. C. Fuerstenau, R. C. Bradt, A. Ghosh

Technical Papers, Mining Engineering Vol. 49, No. 12, pp. 70-75, Discussion by McIvor, R. and Fink, R. P. We must challenge what we consider to be dubious statements in the above-mentioned article. Much of what is reported was published elsewhere over a year ago (i.e., in their reference: Chi, G., Fuerstenau, M.C., Brandt, R.C. and Ghosh, A., 1996, "Improved comminution efficiency through controlled blasting during mining," International Journal of Min¬eral Processing, Vol. 47, p. 93). There is nothing unusual or significant about a 10% or more difference in grindability between two materials of apparently similar origin and other attributes (such as chemical assays, hardness and specific gravity). Consider also that: • the materials came from different locations in the pit; • only two sets of four blastholes were considered per blast: • spatial orientation with respect to the face and other blastholes was also altered; • only two pairs of data were collected; • the impact of sampling error and bias, • both of which could be significant in this case; and • normal experimental error in parameter measurement and calculation. It is clearly inappropriate to draw any conclusions with regard to cause-and-effect relationships without first presenting a thorough error analysis. A substantial number of randomly selected test and control areas might provide meaningful statistical evidence of the claimed effect of the variables being studied. Even that appears doubtful, however, because Figures 3 and 4 show about as much variation in crushing energy for the two "regular" conditions vs. regular and altered conditions. On a separate, but also important issue, broad experience with autogenous/semiautogenous milling has shown that smaller or weaker feed material results in reduced tonnage. ? Reply Thank you for the opportunity to respond to the comments of Messrs. Mclvor ant Fink. The points raised are addressed in the order of presentation. As the commenters noted, there are parallels between this article and a previous manuscript. The reason for these complementary articles is that the audiences for the two publications are different, although there is obviously some overlap. We believe that the different audiences each profit from the technical aspects of the two manuscripts. We are not in agreement that a grindability difference of 10% is insignificant. The laboratory work is corroborated by data obtained at plant scale, which confirms that an increase in throughput of the same magnitude (between 5% and 10%) is achieved when the blasting pattern is modified, i.e., reduced from 9 to 8 m (29.5 to 26.2 ft). This increase in throughput translates into substantial power savings for ore grinding. No differences in appearance in the rock were noted between the two adjacent areas. Rock in both areas belonged to the same rock mass/block, which was quite homogeneous and without geological features in between that could create drastic differences in comminution characteristics. Given the resources, we would have sampled from all of the holes. Additional data would certainly have been desirable, as would have been additional funding to expand the study. Their comment, "spatial orientation with respect to the face and other blastholes was also altered," is not clear. Figure 1 does not show the initiation sequence. Without the initiation sequence, we do not understand how the commenters concluded that spatial orientation with respect to the face and other blastholes was altered. The commenters may be trying to make the point that the four-hole configurations with respect to the original bench face are not exactly the same. In fragmenting the

Jan 1, 1999

By M. Misra, J. Nanor

The precipitation and removal of arsenic from process waters can be accomplished with addition of lanthanum chloride alone or in conjunction with ferric sulfate. The long term stability of these corresponding precipitated compounds is critical from the disposal stand-point. In this paper the characterization of ferric, lanthanum and lanthanum-ferric arsenate compounds formed at room temperature in acidic and alkaline pH is presented. The characterization techniques used included zeta potential, XRD and SEM. Zeta potential measurements of ferric and lanthanum hydroxides in the presence of arsenate indicate that oxyanions of arsenate are chemically adsorbed onto the positively charged surfaces of these hydroxides. In alkaline pH there is desorption of arsenate species from the ferric hydroxide surface, hence the product is thought to be unstable. On the contrary, lanthanum arsenate is stable in alkaline pH. XRD patterns show that the ferric arsenate formed in acidic and alkaline pH is amorphous, whereas lanthanum arsenate and lanthanum-ferric arsenate formed in acidic and alkaline pH are crystalline.

Jan 1, 1999

By G Munro

he Melbourne City Link project will complete a missing link between two existing major freeways in the Melbourne road network, providing a much needed bypass of the Central Business District for through traffic. The project, which is being financed under a BOOT arrangement with the Victorian State Government, involves the upgrading of significant stretches of existing freeway and the construction of new sections involving viaducts and tunnels. The tunnel sections, which are the focus of this paper, are beneath residential and business areas, the Yarra River, the Royal Botanic Gardens and significant sporting facilities where surface construction would be either impossible or unacceptable (reference Figure 1). The shorter, 1.62 km west bound Domain tunnel comprises two cut and cover sections through Olympic Park then the Yarra River, the driven section of 0.68 km length and exits through a common cut and cover section with the east bound tunnel under St Kilda Road and Sturt Street. The longer 3.76 km east bound tunnel commences at the common portal, through cut and cover under St Kilda Road then 2.86 km of driven section before exiting at a cut and cover section at Burnley. The longer Burnley tunnel has an access and ventilation shaft at approximately its mid point.

Jan 1, 1999