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Heap leaching with thiosulfate is only used in one location for the treatment of a refractory preg-robbing gold ore initially pre-treated with bio-oxidation. The chemistry of thiosulfate leaching is complex. Further work is required to develop a better control of the system. A mild refractory gold ore containing pyrite and chalcopyrite was used in this study to investigate the use of thiosulfate as an alternative heap leaching technology. Preliminary bottle rolls tests indicated that similar gold extraction was obtained with cyanide and thiosulfate. In the column leach test, effects of thiosulfate, copper and ammonia concentrations, and their ratio on both gold extraction and reagent consumption, were assessed. The range of reagent concentration were: 0.1 - 1.0M (NH4)2S2O3, 0.03 - 0.10M CuSO4*5H2O, 1.0 - 6.0M NH4OH. The solid-liquid ratio was in the range of 0.83:1 to 5: 1. Best results showed that 72% of gold was extracted in 50 days with 0.3M (NH4)2S2O3, 0.05M CuSO4*5H2O and 6M NH4OH or a combination of 1.0M (NH4)2S2O3, 0.03M CuSO4*5H2O and 3M NH4OH. The reagent consumption at solid/liquid ratio of 3:1 was 37 - 48.6 kg/t (NH4)2S2O3 and 0 - 0.62 kg/t CuSO4*5H2O. The results of thiosulfate leaching were also compared with cyanide leaching.

Jan 1, 1999

By J. Leon-Torres, D. M. Stefanescu, P. A. Curreri, S. Sen

"Experiments were performed under terrestrial gravity (lg) and during parabolic flights (10·2 g) to study the solidification and macrosegregation patterns of Al-Cu alloys. Alloys having 2% and 5% Cu were solidified against a chill at two different cooling rates. Microscopic and Electron Microprobe characterization was used to produce rnicrostructural and macrosegregation maps.In all cases positive segregation occurred next to the chill because of the shrinkage flow, as expected. This positive segregation was higher in the low-g samples, apparently because of the higher heat transfer coefficient.A 2-D computational model was used to explain the experimental results. The continuum formulation was employed to describe the macroscopic transports of mass, energy, and momentum, associated with the solidification phenomena, for a two-phase system. The model considers that liquid flow is driven by thermal and solutal buoyancy, and by solidification shrinkage. The solidification event was divided into two stages. In the first one, the liquid containing freely moving equiaxed grains was described through the relative viscosity concept. In the second stage, when a fixed dendritic network was formed after dendritic coherency, the mushy zone was treated as a porous medium.The macrosegregation maps and the cooling curves obtained during experiments were used for validation of the solidification and segregation model. The model can explain the solidification and macrosegregation patterns and the differences between low- and high-gravity results."

Jan 1, 1999

By Abhoy Mukherjee

The Luanshya Smelter is a traditional Reverberatory Smelter which once worked with up to three coal-fired reverbs, and now operates one Reverb and one hot Peirce- Smith Converter, projected to produce approximately 42.000 tons per year of copper anodes. The aim of this study is to select a smelting technology which best fits the upgrading of the Smelter, such that low capital and operating costs are achieved for the projected design production capacity of 60.000 tpy, limited by the available supplies of concentrates. An equally important requisite is the compliance of present and future environmental regulations, which determines the need to install and Acid Plant to treat the smelter primary gases. In the process selection study, the following technologies were analyzed, at a Conceptual Engineering level: the Oxy-fuel Burner Reverb, the Teniente Converter, the CONTOP Cyclone Smelting Reactor, and further, the Ausmelt Furnace, the engineering of which was provided by the proprietary firm. The engineering of the other processes was developed by INDEC, which also integrated the comparative analysis of the four options. The analysis of a comprehensive set of technical factors, including integrated smelter metallurgical models, together with the evaluations of economical features, led to the selection of the CONTOP Smelting Technology for the modernization of the Luanshya Smelter.

Jan 1, 1999

By R Blair

The Domain and Burnley Tunnels, which are major features of the Melbourne City Link Project, are MelbourneÆs first road tunnels. They are 1.6 km and 3.5 km in length respectively and are being constructed through a variety of ground conditions. Deeper sections of the tunnels have been driven through the Silurian mudstone which underlies Melbourne. Other shallower sections of the tunnels pass through a variety of ground conditions including silts, sands, clay and rock and have been constructed using both top-down and bottom-up cut and cover construction techniques. The Yarra River Crossing is a 140 m length of the Domain Tunnel which crosses under the Yarra River on a relatively shallow alignment. The crossing of the river using cut and cover techniques was identified in the early stages of design development as being one of the most challenging stages of the works on the Southern Link. The prevalence of varying geological conditions combined with the need for maintained traffic and stream flow conditions provided a demanding and often conflicting set of criteria for which there appeared to be no one clear solution. A team of designers, constructors, estimators and specialist contractors were involved in a concept evaluation and risk analysis study spanning a period of approximately 12 months. During this study, four concepts were considered as likely contenders. This paper provides a brief outline of the four concepts addressing their relative merits, disadvantages and risks followed by a detailed description of the adopted solution, namely top-down construction using secant pile walling (east bank) and bottom-up in situ construction (west bank).

Jan 1, 1999

By S. Mathur

Oxide particles are commonly used as fillers in plastics, paper, rubber, etc. (particulate composites). The successful fabrication of such composites is dependent upon the adhesive strength of the filler particles to the matrix. The compatibility of the matrix and the filler particles is generally enhanced by the adsorption of surface modifiers such as surfactants and polymers at the particle-matrix interface. To develop a scientific basis for the selection of the appropriate modifiers it is necessary to understand their adsorption mechanisms. specifically, the adsorption of polymeric additives is attributed to a combination of chemical and electrostatic interactions, hydrogen bonding and van der Waals forces. Hydrogen bonding has been suggested to be the primary adsorption mechanism for nonionic polymers. However, a literature survey of the Poly(ethylene oxide) (PEO)-oxide system suggested that PEO, a nonionic polymer, was substrate specific. A systematic study was undertaken to investigate the adsorption mechanisms of PEO on oxide particles. It was determined that strong Bronsted acid sites on the surface interact with the ether oxygen, a Lewis base, of PEO to induce adsorption. In this work, characterization of PEO binding sites on oxides is reported and the mechanisms of PEO adsorption are discussed.

Jan 1, 1999

By R. K. Paramguru, K. Srinivasa Rao

This paper describes a new approach for examining the kinetics and mechanism of zinc dissolution from sphalerite concentrate in acidic ferric sulfate solution in the presence of manganese dioxide. A literature search was performed to access the possible action of the two oxidizing agents, i.e., ferric ion and manganese dioxide. The possibility of galvanic coupling between ZnS and MnO2 and the cyclic action of the redox couple, Fe2+/Fe3+, on these two minerals were theoretically examined based on corrosion principles. Expressions for the mixed potential (Em) and the mixed current (im) were derived for the relevant corrosion and galvanic couples. Leaching experiments were conducted to establish which of the above phenomena is operative during leaching. The results indicated that the dissolution mostly occurs by the action of ferric ion on ins producing ferrous ions. The presence of MnO2 enables a quick conversion of ferrous to ferric, which maintains the rate of in dissolution. The process has promising features for commercial exploitation.

Jan 1, 1999

By D. P. Cook, Jr. Jones, J. W. Evans

"It is well understood that the flow of liquid metal in the mold region of the caster can have a notable effect on the overall solidification behavior in aluminum casting. Previously our group has characterized the flow in this region in a water model, using particle imaging velocimetry. The flow is significantly effected by the specifics of the metal delivery system, i.e. size, geometry, used during the cast. Recently, a time-averaged 3D numerical model of the nozzle, combo bag and sump region has been developed and its validity has been tested against experimental data. Cases were run for different sized combo bags as well as bags that have been blocked. The results show satisfactory agreement between the physical and mathematical models.IntroductionFluid flow in the head of an electromagnetic (EM) and direct chill (DC) ingots has been shown to effect many important operational parameters in casting such as superheat removal, macrosegregation, and hot cracking. In most cases, the momentum from the nozzle is diverted through a delivery system, termed a bag, before entering the mold region. The specific geometries of the bags vary widely from operator to operator suggesting that there is still some question as to the optimum design. Several studies [1-4] have been carried out to understand the influence of the bag design on the solidification behavior in aluminum casters. However, few studies have included numerical prediction with experimental verification. Unfortunately, many simulations performed today still do not accurately account for flow in such devices.Recently, a significant amount of research into the flow resulting from the metal delivery systems has been performed [5-8]. The thrust of this research has been characterizing the flow patterns by a measurement technique called particle imaging velocimetry. The data suggest that the method of delivering the liquid metal into the mold region has a significant effect on the nature of the flow. With a detailed set of quantitative data from a water model, a numerical model can be built and tested to ensure a proper description of the flow field. The computational model used in these simulations is designed to represent a laboratory scale model of a caster in which ""combo"" bags were simulated. Such bags are mostly of a densely woven glass fiber material with low permeability to aluminum. ""Windows"", of a more open weave, permit aluminum to flow from the bag, see Fig. I. Two different sized combo bags were modeled, each subject to two different outflow window configurations. Furthermore, experimental measurements [9] were used to validate the model results."

Jan 1, 1999

By R. L. Wiegel

There are approximately 40 million tons per year of phosphate rock produced in the United States, half of it by flotation. The bulk of this is used to produce diammonium phosphate, an essential ingredient in the commercial fertilizer mixes used by the thriving U.S. agricultural community. This paper describes the mineral beneficiation practices of the phosphate industry, with special emphasis on flotation. There is also an attempt to include those items that might be considered emerging technologies for the industry as it faces the problems of a diminishing high-grade reserve and the necessity for implementing dolomite/francolite separations.

Jan 1, 1999

By K. N. Han

The leaching behavior of palladium in ammoniacal solutions was investigated by using the rotating-disk technique in an autoclave. The study included the effects of rotation speed, temperature, oxygen pressure, composition of ammoniacal solutions and catalysts on the overall leaching rate. The dissolution of palladium in ammoniacal solutions was discussed in terms of the thermodynamics and a kinetic model. Even though the Eh-pH diagram suggests that palladium metal can dissolve in ammoniacal solutions at room temperature, it was found that the dissolution was very slow at temperatures below 100 °C but was significantly improved at higher temperatures. It was also found that the rotating speed of the palladium disk had no effect on the leaching rate. The apparent activation energy was found to he 69.7 kJ/mole. Based on the results obtained, it was concluded that the dissolution of palladium is controlled by chemical reaction.

Jan 1, 1999

By S Porter

The Melbourne City Link Project is a privately funded road infrastructure project linking three significant existing freeways in the vicinity of the Central Business District. The State Government, through the Melbourne City Link Authority, has contracted Transurban to build, own and operate City Link for a concession period of 34 years before the road network is transferred to the State. Transurban has a contract with Transfield Obayashi Joint Venture (TOJV) to design and construct the works. The project is divided into the southern and western sections and the tunnel works comprised the significant component of the Southern Link. Outside of the cut and cover tunnels at the portals, the driven tunnels component was constructed by TOJV direct labour. TOJV subcontracted all design work to a joint venture of Hyder Consulting and CMPS&F (Hyder/CMP). The geology in the tunnel corridor and generally below the city of Melbourne is highly variable and constantly changing. The tunnels were driven, for the most part, in siltstone and sandstone of the Silurian age, but also intersected overlying basalts and clays. The Silurian bedrock is a fractured aquifer that is connected to overlying alluvial aquifers. Consequently, the construction of the tunnels was a complex engineering task. This paper details the operational relationships and procedures developed to deliver a design that was aligned to the construction constraints and delivered an end product that met all technical, quality, cost and program goals.

Jan 1, 1999

By Kenneth K. Eltschlager, Richard R. Brochu

At the International Society of Explosives Engineers Annual Conference held in Nashville, Tennessee in February 1995, a Seismograph Standards Committee was established. The purpose of this committee was to develop objective performance specifications for vibration measurement instrumentation and field use practices. It was also understood that due to geology, temperature, and moisture in the soils, it is not possible to design and build an instrument to give results which are absolutely comparable for ground vibration. It was, however, considered essential to standardize instrumentation by which vibration can be measured under closely defined conditions so that results obtained by users of seismographs are always the same within stated tolerances.

Jan 1, 1999

By G. E. S. Valadao, J. D. Miller, C. L. Lin

Filtration is an important solid liquid separation technology employed widely in the mineral processing industries. The effectiveness of the filtration operation can be influenced by numerous variables, related to the particulate phase, the slurry rheology and the equipment. The classical approach for analysis is based on Darcy's law. Knowledge of the cake poremicro structure and its correlation to macroscopic cake properties is required to model the filtration operation from a fundamental point of view. Since cake formation seems to occur randomly, a 3D Monte Carlo method was used to simulate cake formation. The configuration for simulation was a space with width of 500 m, length of 500 m and height of 4000 m. Size distributions of five different industrial products whose particle size distributions follow the Rosin Rammler distribution function were used. The particle shape was assumed to be spherical. The simulated cake structures were described in terms of volume porosity (volume of pore space per unit volume of cake) and surface porosity (area of pore space per unit area of a cross section). The results indicate: 1) it is possible to simulate 3D packing, which mimics cake structure, using the Monte Carlo method,2) segregation phenomena occurs during simulated cake formation, 3) the values of calculated porosity for simulated samples B, C, D, and E were lower than those determined for corresponding industrial products Br, Cr, Dr, and Er, and 4)some structures of simulated samples seem to correlate with laboratory leaf test data obtained for different products from plant operations.

Jan 1, 1999

By Peter L. Dunn

With the advent of new high-strength magnetic materials, rare-earth magnetic separators have become more common place for processing heavy mineral sands. In many instances, rare-earth magnets have replaced conventional separators such as electromagnetic cross-belt and induced-roll type machines. This paper will present the results from a detailed test program developed to evaluate the performance of rare-earth drum and roll separators for processing heavy mineral sands. The effect of machine design parameters, such as magnetic element configuration and separator diameter, will be reviewed in light of these test results. The impact of basic operating parameters (i.e. feed rate and roll speed) on separation efficiency will also be presented.

Jan 1, 1999

By R. Pickering

The purpose of this paper is to explore the application of technology to stoping systems. Technology, because for the past 100 years the South African narrow reef mining industry has battled to control working costs in a labour-intensive industry. Stoping systems, because it is the stoping method and methodology which is at the heart of the mining system. Introduce a more efficient stoping system and the mining system will look after itself. The technology applied to stoping over the past 100 years can be categorized as follows: ?The introduction of pneumatic rockdrills early this century, the cumbersome rig mounted units being replaced by smaller, lighter hand-held units which were then made easier to use with the addition of an air leg ?Scraper winches to replace gravity and shovels to move rock both in the face and the gullies were first introduced in the late 1920s ?Hydraulic props as a support method arrived in the1960s ?Some people argue that tungsten carbide inserts were equally important. There have been a number of attempts to introduce different technologies into stoping, the most recent being trackless equipment. Where the stoping layout suits the technology it has been successful. There have been too many instances where a technology has been installed because it is fashionable. At the end of the day the outcome from change in the stoping systems has to be safer and more profitable mining systems. It is the contention of the author that change is only likely to be effective if it is supported by the introduction and application of appropriate technology.

Jan 1, 1999

By Y Wada, Y Ogata, T Nishida

"Shaped charge is used for blast demolition of steel construction in general. It is important tocontrol movement of cutting part with shaped charge for the blast demolition of steel construction.Movement of cutting part was studied in the small scale experiment with steel bar. A numericalsimulation using the Discontinuous Deformation Analysis (DDA) was carried out. The DDAmethod was applied to the full scale blast demolition of steel construction. Results of thesenumerical simulation was compared with the blasting demolition work of steel tower."

Jan 1, 1999

By Charles N. Speltz

The cost of transportation of industrial minerals frequently is higher than the cost of the product. When a mine, industrial-mineral plant, or customer is served by a single railroad, because of the lack of competition, that railroad may in- crease rates and/or reduce service so that the economics of that mine, plant, or customer are affected adversely. Transloading of industrial minerals from rail-to-truck or truck-to-rail to improve economics and sales of product is not a new concept. However, transloading to create competition and reduce freight costs or to improve service is a relatively new concept brought on by the recent mergers of many of the main-line railroads, both in the eastern and western United States. For example, in 1998, with completion of the Burlington Northern/Santa Fe (BNSF) and the Union Pacific/Southern Pacific mergers (UPSP), the western United States has only two main-line railroads. The industrial-mineral producer, to reduce the cost of transportation or increase the level of service, must evaluate potential transloading opportunities in light of higher prices and reduced service brought on by reduced railroad competition. This paper discusses industrial-mineral transloading and examines the case history of the Tucker Hill perlite project in southern Oregon. The Tucker Hill project is a classic study of industrial-minerals transloading where the project would have failed without the transloading.

Jan 1, 1999

By Kurt B. Oakes, Brian M. Fortelka

Unimin Corporation operates an underground Silica Sand mine at Guion, AR located in North Central Arkansas. The Silica Sand deposit at Guion is part of the St. Peter Sandstone Formation, which is overlain by a competent dolomitic limestone from the Joachim formation, acting as the roof directly above. Both the St. Peter and the Joachirn Formations are of Middle Ordovician age.

Jan 1, 1999

By Alexander I. Raitchenko

"An electroconductive viscous liquid may flow in laminar or turbulent regime under Lorentz-force generated by the intercrossed electric current and magnetic field. When there is a starting flat layer between hard and free boundaries with surface tension the spatial Lorentz-force can create a specific stationary regime of flow: the plane free surface will transform into the wavy one, and the movement in the depth will be not laminar and not turbulent, but this regime will be characterized by organized forms with indications of ""rolling of long cylindrical drops"". Wave-length is determined by the viscosity, the density, the surface tension, the average thickness of layer, and Lorentz-force. ·The limit of wavy regime is determined by most long of wave which is directly proportional to the critical value of specific flow and inversely proportional to the kinetic viscosity. The proper critical value of Reynolds number is determined by the dimensionless combination containing surface tension, density, viscosity, and Lorentz-force. The mentioned dimensio.nless combination in our case is some criterion substituting the known Kapitsa number for case of the thin viscous liquid layers under gravity. Spreading of admixture by mechanism of wavy regime is more rapid than by common diffusion or by laminar flow. The suggested conception can be a contribution into the theoretical basis for elaboration of some specific liquid metals technologies."

Jan 1, 1999

Laboratory experiments show that the delay detonators, either electric (copper coated or aluminium) or non-electric (down-the-hole) as generally used in opencast mines and quarries have some scattering from the actual firing time due to manufacturing inaccuracy and variations in basic ingredients of the product. This scattering varies from 1 to 4 % depending on the product quality. Due to this component scatter, adverse blasting effects like misfires, overbreak, underbreak or fly-rock may occur if the design patterns are not judiciously made. It has also direct impact on muck profile and fragmentation.

Jan 1, 1999

By Karl J. Ellefsen

A geophysical investigation can provide valuable geologic information needed to characterize sand-and- gravel deposits and can be an attractive complement to more common characterization methods such as drilling. Although such investigations have been conducted already, a comparison of the different geophysical methods used in these investigations apparently has never been done. For this reason, a study was initiated by the Mineral Resources Program of the U.S. Geological Survey to determine the advantages and the limitations of different geophysical methods when used to evaluate alluvial sand-and-gravel deposits. The study is focused on those geophysical methods that are commonly available, because these are most likely to be used by industry. Furthermore, the study is focused on surface geophysical methods. Heretofore, four different methods have been evaluated. Three of the four methods-time-domain electro-magnetic (TEM) soundings, frequency-domain electro-magnetic profiling, DC-resistivity soundings-are similar in that they all measure the electrical resistivity of the ground with depth. Ground-penetrating radar, however, maps changes in the dielectric permittivity and for the electrical resistivity with depth. For all, four methods, the objective is to relate the measured physical quantity to the stratigraphy of the alluvial sediments.

Jan 1, 1999