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By C. J. N. Buisman

THIOPAQ technology developed and marketed by PAQUES Bio Systems in Balk, Netherlands, has been successfully used at commercial scale at the Budelco zinc refinery in the Netherlands for the treatment of contaminated groundwater since 1992. In essence, THIOPAQ technology consists of two biological process steps in series: sulfate reduction to hydrogen sulfide (anaerobic) and sulfide oxidation to elemental sulfur (aerobic). The biogenic sulfide produced can be employed for the chemical precipitation of metals in solution either inside the anaerobic reactor or in a separate vessel. Since the solubilities of most metal sulfides are much lower than of their respective hydroxides, considerably lower effluent metal concentrations can be achieved with THIOPAQ systems than in neutralization processes which immobilize metals predominantly by hydrolytic precipitation. In recent years, PAQUES has made significant advances in the design and operation of aerobic and anaerobic bioreactors for metal-sulfur systems. Moreover, the company has increased its technology portfolio to allow the development of more process oriented applications of THIOPAQ technology. A new PAQUES designed plant at Budelco treating sulfatecontaining proceswaters will be started up in 1999. The sulfate reduction is accomplished in a 500 m3 reactor in which hydrogen is used as electron donor. The endproduct, ZnS, is used for Zn and H2S04 production.

Jan 1, 1999

By Harald Laux, Stein Tore Johansen

The plunging jet in tapping of steel from converters or electric arc furnaces entrains gas into the steel bath contained in a ladle. Gas entrainment rate and the effect of the gas on the flow pattern in the ladle are studied by means of Computational Fluid Dynamics CFD. The work focuses on the mathematical modeling. Two numerical methods, one for free-surface flows and one for dispersed multiphase flow are combined. A transport equation for the average bubble diameter that incorporates the effect of coalescence and breakup is presented. Results from computations for one ladle and tapping configuration are shown. Our findings indicate that the gas entrainment rate is affected by the material properties of the liquid in the sense that the material properties determine the shape of the jet. Moreover, bubble sizes in the range of two-orders of magnitude are predicted in the ladle. The dispersed diameter model seems to work well. It showed the expected response to material parameters and the turbulent field. However, the presented analysis is just a first step that was limited due to certain simplifications. In order to obtain better insight in the tapping process improvements of the analysis seem necessary.

Jan 1, 1999

In constructing a financial model of a project significant effort is expended on capital and operating cost estimation, commodity price forecasts, and choice of discount rates while uncertainty in the primary input, the reserve, is often completely overlooked. The aim of this paper is to highlight the impact of uncertainty in the resource/reserve estimation process on the assessment of the financial performance of a project. Four qualitative processes have an impact on resource/reserve uncertainty. These stages are: 1.Ore definition 2.Geological interpretation 3.Resource estimation 4.Ore reserve estimation and mine planning. Each stage contains a number of tasks that may be considered as key performance activities (KPAs). Optimizing the manner in which these KPAs are completed can remove a great deal of uncertainty and error from the resource/reserve process. Examination of these KPAs within a company can also provide an insight to the quality of the information underlying the project. This will allow the company to identify any shortcomings in the data and to assess the resulting risks (Gilfillan, 1998). A hypothetical financial model based on a gold operation has been used to estimate the potential effect of resource/reserve uncertainty on revenue. Monte Carlo simulation has been employed to simulate a number of hypothetical scenarios: 1.a base case scenario which assumes no major errors or biases, but contains realistic margins for uncertainty that would exist in any project where work is being completed to the limit of best endeavours 2.a poor sampling scenario which assumes poor sampling practice and lack of understanding of sample preparation 3.a poor resource estimation scenario which assumes poor modelling and inappropriate choice of interpolation technique, and 4. a ?typical? scenario which represents a project where the majority of KPAs are not performed as best as they could be. The results show that realistic uncertainty ranges can generate changes in the estimate of potential revenue of plus or minus 30%.Therefore, it is important to allow for errors in these processes in any financial analysis or feasibility study. It is recommended that, when building a financial model, are view of relevant resource/reserve KPAs be carried out and appropriate ranges for uncertainty be applied to provide a range of potential outcomes. These outcomes can then be factored into the detailed cash flow analysis in order to ensure that technical uncertainty is built into financial decisions.

Jan 1, 1999

By Kirlk Yeager

"Ammonium nitrate (AN) is commonly mixed with a wide variety of additives to produce specialty formulations. Two additives commonly utilized are sodium nitrate (SN) and sodium nitrite (SNi). Application of the nitrite is primarily limited to gassing of emulsions. The nitrate, however, is incorporated in a wide variety of formulations. The effect of both these materials on the thermal stability of AN was examined. Experiments initially utilized lab-scale testing methods (sub-milligram sample size), such as differential scanning calorimetry (DSC), with scale-up to cook-off analyses (16 g) eventually applied. Labscale testing indicated that the presence of SN and SNi (both at 5 wt%) produced no harmful effects on the thermal stability of AN. The cook-off results did not agree with those from the lab-scale analyses, with both SN and SNi creating tremendous thermal destabilization of AN. These effects were seen at additive levels as low as 0.1 wt%. When SNi was employed as the additive, cook-offs became violent enough to create explosions in the testing apparatus. Although SN did not create as spectacular a destabilization, it did lower cook-off temperatures to approximately the same level as SNi. The dangerous situation created by SN andSNi seemed to be limited to cook-offs conducted in sealed vessels. If the SN/AN or SNi/AN formulations were allowed to cook-off in vented vessels, the thermal destabilization of AN did not occur. These results seemed to indicate that even “trace” amounts of what might ordinarily be viewed as benign additives could create significant destabilization of AN-based explosives under proper circumstances. Conditions created by blocked pumps, or deep boreholes could well overlap those produced in sealed cook-off vessels. In addition to showing the hazards potentially created by “benign” additives, the study also stressed that experiments designed to evaluate thermal hazards must include duplication of field variables to the fullest extent possible. "

Jan 1, 1999

By C. Sun

In this study, numerical simulations of yield pillars employing the finite element method with time-dependent Drucker-Prager material model are conducted. The stress control mechanism of yield pillars on weak floor strata is studied. The development of pillar yield zone, the distribution of pillar stress and the development of failure zone in the weak floor strata are investigated. The study indicates that a properly selected yield pillar size may significantly reduce the peak stress induced in the weak floor strata and effectively control the development of failure zone in the floor.

Jan 1, 1999

By Levent Ozdemir, Bjorn Nilsen

For several recent TBM tunnel projects, unexpected ground conditions have been encountered, causing extra cost, considerable delay, and in some cases major claims. Undoubtedly, insufficient and/or irrelevant site investigation and testing are among the main causes of such incidents. The purpose of this paper is to review the main investigations and tests relevant for hard rock TBM projects, with particular emphasis on the considerable development that has taken place over the last few years. Also, guidelines for defining optimum scope and extent of site investigations and testing are discussed, as well as the importance of adjusting the investigations and tests according to complexity of the ground conditions and project type.

Jan 1, 1999

By H. Aminian

Copper electrowinning (EW) is an important process in connection with the solvent extraction to produce pure and marketable copper cathodes. A phenomenological model was developed to simulate the copper electrowinning process. The simulator is used to predict the operation of the Mines Gaspe pilot plant electrowinning cells put in operation in 1996. Results confirm the potential of the simulator that would subsequently be used for student training, process optimization and assessing the performances of control strategies.

Jan 1, 1999

By B. Kenny

The aim of this paper is to provide an overview of existing forms of subcontracting in the South African mining industry. A descriptive framework is developed to understand different subcontracting arrangements. We argue that, in order to do so, it is important to distinguish between labour broking and gang subcontracting. Data resulting from a research project (including an analysis of historical sources, interviews with contractors and focus group interviews with mineworkers) is presented to highlight the implications of changing formations of subcontracting for the South African mining industry in the late 1990s. Apart from the subcontracting of ?traditional? functions, such as shaft sinking, access development, catering and hostel maintenance, contractors are now used in ?core? mining activities. In some instances, whole shafts are ?outsourced? to outside agencies. It is argued that certain of the subcontracting arrangements have serious implications for the ability of the mining industry to improve health and safety standards. Some of the practices can potentially result in conflict between different categories of workers, and, as a result, instability in the industry.

Jan 1, 1999

By Dalton Fowler

"Pressure vessels used in pressure leaching and pressure oxidation processes in the mining industry are often lined with acid resistant brick and membrane systems. Although the options available when it comes to selecting materials and linings designs for these vessels appear somewhat limited there are, nevertheless? several choices which must be made in order to successfully design, manufacture and construct these linings. These choices require careful evaluation of materials properties which include, among others, thermal conductivity, thermal expansion, chemical swell, and modulus of elasticity, as well as a variety of construction methods.Some of the options available, and some of the means of evaluating them objective of this discussion."

Jan 1, 1999

By G. Baudet, M. Save

Ethoxylated phosphoric ester surfactants were evaluated as collectors for flotation of carbonates from sedimentary phosphate ores, at slightly acidic pulp pH, using sulfuric acid or sodium fluorosilicate as a phosphate depressant. With 12 to 15 carbon atoms in the hydrophobic chain, maximum collecting power was observed for 9 to 10 ethylene oxide units. Only fine carbonates, ranging in size from about 20 to 160 µm or 40 to 200 µm, were effectively removed with phosphoric ester collectors. Utilization of seawater, or water of extremely high hardness, did not detrimentally affect selectivity. Silica, silicates, and residual fine carbonates can be separated in a second flotation stage, with primary amine as a collector. Coarse carbonates are separated by direct flotation of phosphate with fluoride ion as a phosphate activator and primary amine as a collector. In a seawater pulp, fluoride ion was not required. Typical examples of laboratory and pilot- scale test results are given to illustrate capabilities of the various flotation flowsheets.

Jan 1, 1999

By Pier Paolo Manca

The investigated area lies close to a large town and covers an area of about lkm2. The mine was worked at depths ranging from 5 to 100 meters but mining operations actually ceased some 50 years ago. There are seven coal seams, each one to two meters thick, overlain by sedimentary rocks in a strongly faulted area. Different kinds of subsidence have occurred, crown holes, shallow depressions and hummocky ground. The results of rock mechanical characterisation (RMR method) in the area have been used to define three different types of numerical model (FLAC 2D). A large numbers of simulations has been performed to solve three different problems at three different scales: to determine the, mechanical properties of the roof rock and overburden involved in the subsidence process, to assess the crown hole subsidence potential and to define the properties of the beam foundations.

Jan 1, 1999

By John T. Ling

"This paper describes the operation of a rope haulage used as the main system of transportation in an underground coal mine. Prince Colliery, which is operated by the Cape Breton Development Corporation, has been in operation for 23 years and produces 1.2 million tonnes of coal annually. The mine extends a distance of 8000 metres under the Atlantic Ocean. All personnel and supplies are transported by means of an endless rope haulage system consisting of a train of rail cars that are operated by an electric engine on surface. The wire rope is 15 km long and weighs 63 tonnes. The system is believed to be the longest of its type used in an underground coal mine. The design of the system, safety features of the haulage, and problems encountered during the design and construction are described. IntroductionCoal has been mined commercially in Cape Breton, Nova Scotia since the 1800s. Several coal seams that are part of the Sydney coal fields, dip toward the north and northeast out under the Atlantic Ocean at angles between -4 and -15 degrees. Coal has been economically mined at depth in excess of 1200 m and more than 11 km from the coastline.Traditionally, single and double drum hoists have been used to haul the coal to the surface and also for transporting the workers and the materials required for mining up to 8 km. With the introduction of mechanized mining methods in the late 1960s, conveyor belts began to replace rope hoists for coal transportation. Improvements in hoisting system design also allowed for drums that could wind up to 6100 m of 32 mm wire rope in 15 layers.These hoists are commonly referred to as “drop hoists” because they take advantage of the gradient of the slope to assist in allowing the mine car train to reach the end of travel. The cars travel on steel rails and the rope is guided by rollers to reduce friction in the system."

Jan 1, 1999

By T Galvin

Drilling and blasting at Westside Mine near Wallsend, NSW, has presented a challenge for Orica Explosives, Australia. The colliery produces 600 000 tonnes of steaming coal per year from two seams using surface mining techniques. Tapping into underlying coal will greatly improve the yield, but there are many issues which make this an enormous challenge. Hunter Valley Earthmoving engaged Orica Explosives to supply the explosives products and to provide much of the blasting expertise that is needed on the minesite. Hunter Valley Earthmoving and Orica Explosives have proven to be an outstanding, unified technical team on this project. The success of the team is based on good communication, progressive attitudes, extensive expertise in blast design and most importantly, care and accuracy in implementing the agreed upon designs.

Jan 1, 1999

Over the last 15 years working in the mining, construction and extractive industries, one of the areas that has always concerned and at the same time drawn the author to it is the application of drilling and blasting in the underground development mining and civil construction tunnelling fields. In that time, the author has come across many drives and tunnels that are larger than design or badly damaged in the perimeter or both. When the question is asked as to why this is the case, the reply is generally æthatÆs the way it is and always has beenÆ. Sometimes it is blamed on bad ground, bad drilling, bad explosives, bad initiation or just plain bad. Most operators build a dilution factor into development and tunneling costs as an acceptance of overbreak and similarly pattern bolt everything to overcome excessive perimeter damage. This paper will attempt to unravel some of the mysteries behind perimeter drilling and blasting in underground drives and tunnels and discuss methods to reduce overbreak and therefore reduce costly dilution and to minimise perimeter damage which in turn will allow more cost-effective ground support. It should not be assumed that better drilling and blasting alone would automatically allow an operation to reduce ground support. The operator must still æreadÆ the ground and its characteristics in order to ensure sufficient ground support is placed to allow the operation to progress safely. This paper will not go into the intricacies of bolting, meshing, shotcreting, concreting and other ground support, but it will use indicative costs for the primary areas of drilling, explosives, excavation and labor to show the magnitude of cost-efficiencies which can be obtained through improved drilling and blasting applications. Drill and blast remains the most flexible and cost-effective method of underground excavation as long as it is applied safely and effectively.

Jan 1, 1999

By Joel A. Huffinan

"This presentation is being given to better inform the audience of the dependability of precious metal analysis by fire assay. A brief explanation, however, of standard fire assay exploration procedures will be given. An overview of other types of analyses by fire assay will be discussed as well, and the operation of a modern day assay laboratory.IntroductionThe use of lead oxide for the fire assay process dates back to the finds in Troy II and the Cappadocian Tablets about 3,000 B.C. Some advances have been made in the basic procedures due to instrumentation and electronics, but the fusion and cupellation procedures used in fire assay remain much the same as during this period.In 1600 AD. Agricola was the first to take a scientific approach to fire assay recording methods and procedures used (Hillerbrand and Allen, 1905) [1]. Since this period, much of the recognized research into the analysis of ores and metals was carried out in the late 1800's and early 1900's prior to World War II, and again after the deregulation of precious metals. The renewed interest in precious metals mining and metallurgy are due much to advances in precious metals heap leaching in late 1970's."

Jan 1, 1999

By C Mpodozis

Central Andean (22¦S to 34¦S latitude) Miocene giant ore deposits share common features that reveal their origin. Tectonic and magmatic features include a relation to a shallow subduction zone, an association with the waning or initiation of a magmatic episode, emplacement at the time of uplift associated with crustal thickening and formation at times of major magmatic changes along the Andean margin. Rare Earth Element (REE) signatures in magmas erupted near the time of mineralisation indicate a progressive change from equilibration at depth with a hydrous, intermediate-pressure amphibole-bearing mineral residue to equilibration with an anhydrous high-pressure garnet-bearing assemblage. These features point to a common history. First, a relatively shallow subduction zone leads to hydration of a cool mantle wedge providing a source of fluids which builds up over at least several million years. Arc magmas formed at this time equilibrate with a hornblende-bearing residual mineralogy. Second, a compressive tectonic regime leads to crustal shortening and thickening that facilitates entrapment of arc magmas in the crust. Eventually, the magma-weakened crust yields to horizontal compression causing rapid crustal thickening. Fluids required for mineralisation are liberated as amphibole-bearing assemblages break down to garnet-bearing ones and over pressured fluids are released from plutons. Mineralisation subsequently ceases in the region unless continued dehydration of the slab and mechanical thinning of the continental lithosphere causes the previous conditions to repeat. The type of mineral deposit generated depends on the pre-existing continental lithosphere and the distance from the trench.

Jan 1, 1999

By M. S. Celik

The principal impurities in some feldspar ores are titanium and iron which impart color and in turn degrade the quality of the ore. The mineralogical investigations indicate that titanium element originates from mainly rutile with small amounts of sphene. Conventionally, fatty acids and particularly sodium oleate are extensively used in the flotation of colored minerals from feldspar ores with reasonable success. In this study, new reagents, oleoyl sarcosine and hydroxamate have been used to float colored impurities before and after magnetic separation. Oleoyl sarcosine is found to exhibit better results compared to fatty acids and hydroxamate. The mechanism of the action is elaborated on the basis of experimental data.

Jan 1, 1999

By Daniel W. H. Su

Underground roof geology reconnaissance is being conducted by CONSOL Inc. to enhance mine productivity. Often, roof instability within mine entries is the consequence of highly variable geology that cannot always be detected from information provided by widely-spaced surface core holes. Utilizing a combination of roof drilling data, geophysical logs, and borehole camera and fiberscope observations, roof geology mapping is conducted within longwall development entries in areas of specific concern prior to commencement of longwall mining, Depending on the uniformity of the site-specific roof geology, data point spacing along the longwall development generally ranges from one to five crosscuts. Surface core hole data are correlated with the roof geology mapped underground to validate the underground observations. Detailed roof geology maps can then be produced to enable ground control engineers and mine management to select cost-effective ground control techniques. However, this procedure is not necessary or useful in all situations and it is employed only when there is strong geologic evidence to justify a closer inspection.

Jan 1, 1999

By K. T. Audt

The Yayoi period, from about 300 B.C. to A.O. 300, represents a time of important changes in Japanese history. During this period the advanced rice culture of the Asian continent was introduced to Japan, along with the techniques of animal husbandry, spinning, bronze casting and metal working(1) . As was the case in the Jomon period (11000 B.C. to 300 B.C.), the Yayoi period is traditionally defined by a particular type of pottery, characterized by the use of the potter's wheel and an extreme simplicity of decoration and form(2) . Pieces of this pottery were found in 1884 in a district of Tokyo, known as Yayoi-Cho, not far from Tokyo University. Within a decade the name Yayoi had come to be used for the period which also saw the first casting of metals in Japan121. During the Yayoi period, the foundation of the ancient Japanese state was laid as the individual small communities were unified and as labour specialization and social levels developed. In fact, the Yayoi may be the true ancestral culture of Japan(3) . However, the origin of the Yayoi is not definitely known. One theory indicates that the Yayoi people may have been driven from the Asian mainland (via Korea) by the dynastic wars that accompanied the unification of China under the Ch'in and Han and that these settlers rapidly displaced the Jomon. Bronze objects and the cultivation of rice may have arrived about the same time - in the third century B.C. Iron was in Japan within another century, but since it rusts badly and disintegrates, only a few small pieces are known from such an early date(4) . After about 50 B.C., the Yayoi cultures of western Japan were in fairly close and regular contact with the continent via Korea(5)

Jan 1, 1999

By D. Pillay

Outsourcing? and ?sub-contracting? have become buzzwords in recent years, as SA industry becomes increasingly exposed to the global economy, and global competitiveness. In its effort to ?catch up? after years of relative isolation, there is a concerted effort to learn from global ?best practice?, in order for South African companies, and the SA economy, to become ?winners?. There seems nothing wrong with this approach at face value. Companies need to compete and be profitable if they are to remain in business. Failure will in the end mean bankruptcy, and the loss of jobs. However, if one interrogates the precise practices, and their implications for all concerned?not just shareholders and employers, but workers, communities, the environment, future generations, the national economy?then the picture can change dramatically. ?Best practice? for whom?

Jan 1, 1999