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By M. K. Mohan

During the processing of metals like Cu, Ni, Co, large quantities of solutions, which contain co- products such as Sb, Cd, Pb etc. are generated. These solutions if processed to recover the metals help in conservation of metals as well as environment preservation. The present study was taken up to recover antimony from process solutions using zeolites. The effect of pH of the solution, time and type of zeolite viz., chabazite, mordenite, erionite and clinoptilolite on the sorption of antimony was investigated. Rate of sorption increases with pH and about 77-pct. antimony sorption was observed with chabazite at a pH of 6. Optimal conditions were established for the maximum recovery of antimony fiom process solutions. The mechanism of sorption for Sb was proposed in terms of adsorption and intraparticle diffusion. The calculated adsorption constants from Langmuir and Freundlich equations indicated that the adsorption of antimony on chabazite was strong.

Jan 1, 1999

Mine closure is a legitimate element of the mining cycle and like mine development involves technical planning, permitting, and finally construction. Closure begins with the mine's operational footprint and transforms the site so that it meets the explicit requirements of the owners and regulators. Implicitly, the closure will increasingly need to meet the requirements of other interested parties such as the local community, workforce, and future land users. Golden Cross is the first modern mine closure in New Zealand. It operated for 6 + years as a mid-size gold and silver mine winning ore from both underground and open pit sources, and processing via a carbon in leach circuit including a cyanide recovery stage prior to tailings disposal. The mine is situated in a sensitive high rainfall environment, and is complicated by the existence of a large ancient landslide underlying most of the tailings dam and waste rock embankment. The regulatory process for mine closure in New Zealand is not clearly understood by operators or regulators alike. The Golden Cross mine was permitted under the Mining Act 1971 and closed primarily under the Resource Management Act. This switch of legislation, the parallel reorganisation of many government departments, and change in societal expectations with respect to long term environmental stewardship during the life of the mine resulted in the requirements of closure being significantly different to the expectations at permitting.

Jan 1, 1999

By Mustafa Akser

Dwindling economic deposits of rutile (TiO2) prompted research on recovering it from secondary sources. One such resource is in Southwestern Turkey feldspar mining rejects that contain 5%-6% TiO2 mostly rutile. Previous studies could only upgrade the TiO2 to 36% TiO2 grade, claiming that the leftover flotation reagents on the surfaces of rutile and host minerals detrimentally affected upgrading of the rutile. As a potential remedy to this concern, a laboratory sample (from an operating feldspar mine in Milas, Turkey) was first caustic scrubbed, then air calcined at 400°C to evaporate the oily reagents. Subsequent physical separation of rutile included wet screening, gravity, magnetic, and electrostatic separation technologies. Such processes indeed improved the grade of the rutile concentrate up to 83 % TiO2 Low recovery of the TiO2 (<20%), was attributed to lack of full liberation of rutile, even at 125x44 micron range; interference with impurity minerals such as sphene and zircon; and simply the process inefficiency in upgrading the fine grains through conventional separation technologies for heavy minerals.

Jan 1, 1999

By David A. Holmes

After a century of variable government-supplied housing on their cold, windswept lands, and facing extremely limited natural resources and no timber, the Standing Rock Sioux Tribe has launched a study into alternative housing approaches for their people. Considering that they have little more than the soil and limited river aggregates under their feet, the Tribe has elected to consider adobe and earthen-wall construction. Earthen construction is no stranger to the Sioux lands. Smaller tribes, including the Mandan, Arikira, and Hidatsa, lived here among the Sioux in earthlodges for centuries. Such earthlodge structures were not unlike the Southwestern jacal style-a framework of upright branches and branches covered with mud-employed by the Anasazi about A.D. 700-900. Indeed, the Sioux people themselves evolved from earlier earthlodge dwellers. Indigenous peoples in New Mexico, Arizona, and neighboring Mexico have used earthen-wall housing for many centuries, reinforcing Sioux observations that this is today an earth-friendly, cost-effective, and practical approach. The Cheyenne River and Pine Ridge Sioux Reservations also recently have conducted studies on earthen- wall construction. This paper describes the search for and evaluation of potential raw-material resources for earthen-wall/adobe construction on the Standing Rock Reservation in North and South Dakota. Significant resources of clay/silt materials (8 million tons in the Striped Cloud clay bed) suitable as adobe binders and sand-and-gravel aggregate (2.5 million tons) that could support earthen/adobe construction have been identified throughout the Fort Yates Flat area on the Reservation. Also addressed is how adobe and rammed-earth construction could add to the diversity of reservation construction and address future Tribal housing and other building needs.

Jan 1, 1999

By Sergei A. Degterov

A thermodynamic database for the slag, matte and liquid copper phases in the Cu-Ca-Fe-Pb-Zn-Si-O-S system has been developed for the ranges of compositions of importance to the production of copper. When used with the Gibbs energy minimization software and other databases of the F*A*C*T thermodynamic computing system, this database will permit the calculation of matte-slag-copper-gas phase equilibria that take place during copper smelting and converting. The calculations reproduce within experimental error limits all available experimental data on phase diagrams, activities of components, enthalpies of mixing, matte - alloy miscibility gap and tie-lines. The calculated solubilities of Cu in both S-free slag and slag equilibrated with matte are also in good agreement with experiment under all studied conditions, such as at SiO2 saturation, in equilibrium with Fe, Cu or Cu-Au alloys, at fixed oxygen or SO2 partial pressures and at different contents of Pb, Zn and CaO in the slag. Sulfide contents (sulfide capacities) of the slags are predicted within experimental error limits. The distribution of Pb and Zn among matte, slag, copper and gas has been calculated. The calculations are in good agreement with experimental data and predict the distributions under conditions which are difficult to study experimentally, such as at magnetite saturation or under various oxygen partial pressures and iron to silica ratios in the slag.

Jan 1, 1999

By R. Simon

Strain-burst phenomena are generally characterised by sudden releases of energy in a volume of highly stressed rock. Strain bursts are encountered in situations such as crown pillar bursts during cut-and-fill mining, face bursts at development headings cord floor bursts in deep shaft sinking. This paper describes a simple two-dimensional linear elastic FE modeling approach that leads to the calculation of the energy-release rate (ERR) and the total energy storage rate (TESR) in the rock-mass around the openings. The merits of using such energy parameters in the analysis of strain-burst problems for identifying areas of high energy release/storage are discussed through a case stud v. However, much site-specific back analyses are needed to better understand how strain bursts and energy parameters are interrelated.

Jan 1, 1999

By D Vrkljan, Z Ester

There was no use of emulsion explosive at Croatia till 1997. Several attempts have been done to bear out the economical and technological affordability of applying the emulsion explosive for open pits and to make the contractor familiar with characteristics of emulsion explosive exepiting experimental blasts series at more open pits on different kinds of rocks. Testing the efficiencies of emulsion explosive there has been applied the original method for linear enlargement of burden of Sc.D. Josip Krsnik’s from Mining, Geology & Oil Faculty, University at Zagreb. The method of linear burden’s enlargement, in distinction from other methods concerning these problems, has been carried out in situ, under real exploitation conditions whereas the physical-mechanical rock’s features, geological conditions, bed relations and rocks’ structure influence the blast efficiencies. On such way, by mean of method the precise boring and blast sizes will be reached for each kind of rock and geological structural bed’s conditions referring to specific explosive type. The technical-economical analysis indicates the most favorable explosive type for specific bed.

Jan 1, 1999

By K. O. Fagerlund

Theoretically and experimentally determined copper matte settling rate in iron silicate slag has been discussed. Separation and settling rate measurements of sand, homogenised slag and 25%Cu concentrate, 63%Cu industrial, and 71%Cu synthetic copper mattes were carried out by mixing crushed slag and matte samples with silica sand in an alumina crucible and melting at 1300-1350°C. Two different types of slag compositions were employed, with Fe/SiO2-ratio 1.4 and 1.7. The separation rate was followed by taking samples from the .melt. As expected, the settling rate of copper matte in fayalite slag depended on the slag composition, where the increasing silica decreased the matte settling rate. Microanalysis of solidified slags showed that the rate of separation of low grade matte was low compared with high grade matte and the presence of a very small size fraction of matte droplets in slag remained unsettled in stagnant fluid. The production of sulfur dioxide gas inside the molten bath was found to be possible up to a certain iron sulfide content in the matte. Also, copper matte settling rates in industrial furnaces have been discussed.

Jan 1, 1999

By D. J. MacKinnon

"The Canadian Copper Company, formed in 1885, began mining the nickel-copper ores of Sudbury in 1887 and producing nickel-copper matte from its smelter in 1888(1). Although it was quickly appreciated that the separation of nickel and copper (i.e. refining) was critical to the production of a marketable nickel product, refined nickel was not produced in Canada until about 1918. From the beginning of the industry, there was considerable political agitation to refine nickel in the Province of Ontario(2). The companies, however, claimed that the existing processes, viz. the sodium sulphide ""tops and bottoms"" process operated by the Orford Copper Company of New Jersey, U.S.A.(1,3,4) and the carbonyl process(5,6) developed by the Mond Company at Clydach, Wales, were too costly to operate in Canada. Nickel was first refined in Ontario about 1918 when the International Nickel Company opened a nickel refinery at Port Colborne, Ontario(6). Initially, however, the refinery at Port Colborne employed the Orford sodium sulphide process, and the first electrorefined nickel in Canada was produced in 1920 by the British America Nickel Corporation whose mine and smelter were located in Sudbury, Ontario, but whose electrorefinery was located at Deschenes, Quebec, near Ottawa, Ontario. The purpose of this article is to outline the early history of nickel electrorefining and to trace the significant developments which led to the first successful commercial electrolytic nickel refinery in Canada. The development of an electrolytic process for refining nickel is due largely to the efforts of four individuals, viz. Carl Hoepfner, Hans A. Frasch, D.H. Browne and ultimately N.V. Hybinette, and the contribution of each is discussed separately below."

Jan 1, 1999

By David A. Newman

Severe roof control problems have plagued a West Virginia underground mine since its initial development in the late 1970&apos;s. Adverse roof conditions in the Eastern portion of the reserve result from a combination of mining: - perpendicular to the major principal horizontal stress direction, - near lineament intersections, - in areas where the ratio of horizontal stress to vertical stress exceeds 2.00 to 4.00, and - where laminated strata are present in the immediate roof. The focus of this study is to identify the engineering (mine orientation, roof safety factor) and geological parameters (lineament and horizontal stress orientation, horizontal to vertical stress ratio, and immediate roof lithology) causing poor roof conditions and to quantify their influence on projected mining conditions in the Western portion of the reserve Rose diagrams were used to illustrate the correlation between the orientation of eight hundred thirty-six (836) roof falls with that of forty-four (44) lineaments and the principal horizontal stress Similarly a composite map was used to demonstrate the relationship between roof falls and the ratio of horizontal stress to vertical stress The immediate roof strata across the property were categorized as either laminated or non-laminated based upon a thorough examination of one hundred sixty-two core logs. The presence or absence of fireclay, a rider coal, and carbonaceous shale was also noted because of the historic correlation with poor roof conditions. Rock strength and physical property tests were conducted on selected immediate roof strata recovered from coreholes drilled along the mains projected to the Western portion of the reserve Potential roof control problems in the Western reserve were quantified based upon the correlations developed by analyzing engineering and geological data The main conclusion is that laminated roof strata, the rider seam, and its associated fireclay will have the greatest influence on mining conditions. Roof problems attributable to horizontal stresses will not be as severe in the West due to an increase in overburden depth and corresponding decrease in the stress ratio. Recommendations are provided for mining orientation, the layout of mains and submains, panel location, and roof support based on intended service life.

Jan 1, 1999

By P. Ruz

A melt transfer ladle was 3D modeled by means of a mathematical fluid dynamics and heat transfer program. Internal temperature profiles were calculated as a time function for a normal ladle and for a pre-heated refractory lined ladle. It was shown that in a normal ladle the molten metal cools down quickly forming accretions. By using an inner lining there are practically no accretions build up within a typical time of operation. Therefore, by applying a refractory lining to a melt transfer ladle and keeping it at a moderate to high temperature it is possible to reduce cold dope circulation in the smelter.

Jan 1, 1999

By Jonathan J. Owen

We will describe modifications to air-sparged hydrocyclones (ASH) that enhance collisions and reaction of wastewater contaminants with sparged gas. These new ASH-based reaction chambers are combined with flotation tanks that are designed to optimize separation of bubbles and particles from water. In combination, these systems have achieved unprecedented removal of contaminants from industrial wastewater and process water while requiring smaller footprints with lower capital and operating costs. Real-world examples of chemical and nonchemical water treatments that demonstrate the outstanding flexibility and applicability of these systems are shown. Design enhancements that resolve the operational problems of traditional ASH are discussed.

Jan 1, 1999

By A. J. Stewart, M. Guay, J. W. Critchfield, A. P. Hoddeson

The MetroWest Water Supply Tunnel project includes three main work shafts, excavated primarily in rock. Shaft L is 9.8 m (32 ft) diameter and 124.1 m (407 ft)deep. Shaft E is 7.0 by 12.8 m (23 by 42 ft) and 91.4 m (300 ft) deep. Shaft 5A is 7.9m (26 ft) diameter and 72.5 m (238 ft) deep. Construction methods are compared and contrasted. Lessons learned involve a differing site condition in soil overburden, contractor-proposed modifications, and remedial slurry wall work. Other aspects discussed include noise and vibration control, groundwater inflow, water treatment, muck handling and contract administration issues.

Jan 1, 1999

By Baron Miya, Keith Hanks, William Edgerton, Francis Fong

The City of Los Angeles capital improvement program includes the construction of a new 35-km interceptor sewer. This sewer will be built as a deep tunnel with finished diameters ranging from 2- to- 4 meters. The project will be constructed concurrently in two phases; an 18-km East-West and a 17-km North-South segment. The new sewer provides additional conveyance capacity for an existing deteriorating sewer that is scheduled for rehabilitation. Large sewage spills during the El Niño storms of 1998 resulted in a Cease and Desist Order that established an aggressive schedule for the completion of the project.

Jan 1, 1999

By David R. Wayman

This paper summarizes environmental compliance and related issues associated with underground construction and tunneling operations, whether new work or rehabilitation. Underground construction and tunneling operations have (in most cases) both an underground and surface component. Since many of the major tunneling projects occur in urban areas, often is areas inhabited for several decades or centuries, environmental problems may already exist in a project area, though that may not yet have been formally recognized. Large projects often attract more than their fair share of regulator attention. This paper addresses the issues with the greatest potential to be encountered by underground constructors, with the emphasis on minimizing contractor liabilities, both in the short- and long-term. Minimizing contractor liability begins with understanding bid documents, contract provisions and necessary means of protection, and carries through project execution by responsible control of hazardous materials, avoidance of media contamination, proper waste disposition, as well as compliance with other environmental requirements.

Jan 1, 1999

By A. H. Castillejos E., F. A. Acosta G.

Filtration is widely used as a terminal refining step for metals, particularly for the casting of aluminum alloys, but still more knowledge is required to understand how several factors affect the efficiency of removal of inclusions. In this study, both, initial and long term filtration efficiencies of a ceramic foam filter have been obtained from the computed trajectories of solid particles suspended in molten aluminum. The complex structure of the foam filters is represented by a unit cell which is formed by a pair of pores with average dimensions. The fluid flow field was determined from the numerical solution of the Navier-Stokes equation, and periodic fully developed flow was assumed at the inlet of the calculation domain, as a boundary condition. This flow field corresponds to laminar flow as that found in ceramic filters operating under normal conditions. Computed initial filtration efficiencies showed that filtration efficiency decreases sharply with fluid velocity for particles larger than 30 µm, but smaller particles are better trapped at higher fluid velocities. Finally, it was found that long term filtration efficiency for particles of 8 µm decreased with time, in spite that perfect particle-wall attachment was assumed. Filter aging was considered in this study, and it was found that the distorted flow field, around the already trapped small inclusions prevented further collection.

Jan 1, 1999

By Don Bachman, Larry Heywood

Artificial release of snow avalanches, through the use of explosives, is a necessary component of safety planning and operations for ski areas throughout the Western United States, as well as in other alpine regions of the world. Climatic, meteorological and terrain factors leading to the development of avalanche conditions, in addition to release mechanisms and magnitude of the avalanche problem to ski areas will be discussed.

Jan 1, 1999

By Jerry Wallace

A highway bridge demolition project to allow shipping access to a new container port in Puget Sound ran into trouble when contract-stipulated mechanical means of demolition failed. Blasting was then employed under less than ideal conditions and was successful.

Jan 1, 1999

By D. R. East

Recent experiences within certain sectors of the international mining industry suggest an underestimation of the environmental risk associated with the design of mine waste management facilities. These experiences show that the technical and managerial challenge of responsible mine waste management is not always fully appreciated. Unfortunately, the image of the mining industry&apos;s environmental performance is negatively impacted by a relatively few number of failures. This negative view overrides the many positive contributions made by the majority of mining companies. The fact that these failures continue to occur to this day in both developed and developing countries is indeed remarkable, and indicates a degree of risk-taking approaching unacceptable levels. The design requirements for tailing storage facilities are, in many cases, more demanding than those of conventional water dams, because seepage of fluids which contain dissolved metals may pose a greater threat than the mere loss of water.

Jan 1, 1999

By H G. Poulos

Prediction of ground deformation caused by soft ground tunnelling is an important problem facing design engineers. The ground deformations are caused by the closure of the gap formed around the tunnel due to the tunnelling procedure and soil intrusion via the tunnel face into the tunnel. There are three different approaches that are commonly used in practice to estimate the ground deformations due to tunnelling, namely, empirical methods, analytical methods and finite element methods. One of the important issues of tunnelling in urban areas is the assessment of the likely impact on adjacent pile foundations of ground movements arising from tunnel construction. The main objectives of this paper are two-fold: first, to assess the available methods to estimate the tunnelling-induced ground deformations, and second, to examine the effect of such ground deformations on adjacent piles. Analytical solutions to predict the tunnelling-induced ground deformation developed by the authors are used in this study. These estimated ground deformations are imposed on the pile in simplified boundary element analyses to compute pile responses. The influence of various factors such as tunnel geometry, ground loss ratio, pile diameter and ratio of pile length to tunnel depth are examined in this study.

Jan 1, 1999