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Water and wind erosion of toxic zinc and lead smelter waste is one of the most urgent environmental problems to be solved in the Silesia region of Poland. Over 87 x 106 Mg of various mining wastes were disposed of in uncontrolled piles leading to soil, water, and air pollution in highly populated areas. Welz and Doerschel process Pb/Zn smelter wastes were stabilized in the summer of 1994 by application of heavy loads of CaCO3 (30 Mg/ha), CaO (1.5 -15 Mg/ha), and municipal biosolids (150 -300 Mg/ha), followed by seeding with a mixture of acid-and salt-tolerant grass species selected in a pot experiment. Vegetation was successfully established on 85% of the Welz material demonstration plot area (0.5 ha), even though it was initially high in water-soluble Zn, Pb, and Cd ranging from 0.4 to 1311,0.1 to 5.8, and 0.05 to 55 mg/kg, respectively. Standing biomass averaged 3.3 Mg/ha on the stabilized Welz waste zone by the end of the third growing season (1997). The revegetation of much of the Doerschel material area failed initially because of extremely high salinity (16 dS m-1), high content of water soluble metals (Cd in particular), and heavy compaction. The area was capped (15 cm) with waste lime and retreated with bio-solids (300 Mg/ha) in 1995, and standing biomass averaged 2.9 Mg/ha in the fall of 1997. The observed plant response to bio-solids and lime indicates this approach to be an environmentally beneficial technology as compared to the traditional methods utilizing topsoil covers.

Jan 1, 1999

By John L. Uhrie

Oxide stockpile leaching operations can realize increased copper recovery and decreased acid consumption from in-situ generated acid resulting from the oxidation of intentionally introduced pyrite recovered from mill tailings or other sources. While all oxide leach ores can benefit from pyrite addition, low acid consuming ores can show remarkably increased recovery and net acid generation; however, more highly acid consuming ores will show benefit more exclusively through increased copper recovery. Additional work shows that the value of highly acid consuming ores can be optimized by balancing copper recovery against acid consumption.

Jan 1, 1999

This paper presents the results of column flotation of a fine feed sample of Florida phosphate. A central composite design is used to study the main and interaction effects of parameters affecting column efficiency. The statistical design is also used to determine the optimum conditions. The results indicate that, depending on the experimental conditions, it is possible to achieve a concentrate of high grade and recovery. A concentration of 15 ppm of non-ionic frother is found to be enough to maximize the recovery at the pH of 9.5.

Jan 1, 1999

By F. Mucciardi

While flash smelting and converting are capturing a greater share of the market, injection through circular injectors will remain with us for the foreseeable future. The use of top lances for injection is a key feature in several processes (e.g. Mitsubishi, Ausmelt). Tuyeres, on the other hand, are incorporated into a number of processes (e.g. Noranda, Peirce-Smith). To date no lances or tuyeres are cooled by an external source. The reagent provides the bulk of the cooling. With limited cooling, it is normal to have substantial wear on the nozzles - especially in the case of lances. To overcome the issue of wear, a new patented injector (lance or tuyere) has been developed by Noranda and McGill University. This novel unit is based on heat pipe technology. It can operate for an extended period of time without wearing. Enhanced lance/tuyere life is achieved by operating the injector at a low enough temperature that promotes the formation of a thin frozen layer on the outer body of the unit. The vaporizing and condensing substance within the unit acts to cool' the high heat flux portions and dissipate the heat to areas of low heat flux outside the vessel. A fairly large number of tests have been conducted with a prototype unit. The tests have shown that the heat pipe lance is a viable unit. In this paper is detailed a test which illustrates how the lance functions when pure oxygen is injected into copper matte. In addition, the findings from a basic study of a heat pipe in high heat flux environments are also presented.

Jan 1, 1999

By S. A. Bradford

The twenty years before World War I was the Golden Age of copper smelting in British Columbia. In this short time, the smelters developed from small, primitive units to large, efficient operations. The first copper claims had been staked on Howe Sound and Knight Inlet in 1864, and there was extensive copper mining in the interior by the mid-1880s, but before 1895, all ore was shipped out of the country for smelting, converting and refining. The first interest in smelter construction was undoubtedly inspired by a Provincial bonus and Dominion land grants offered to smelter builders. The early smelters made use of small blast furnaces which were designed to smelt any kind of ore, but usually far too little ore was available. The first smelter seems to have been the McRae furnace on the Spillimacheen River (1883), followed by Vancouver (1889), Revelstoke (1891), and Golden (1891) (1). They each smelted a few tons of galena and then quickly closed down permanently for lack of ore. Only smelters that actually produced some copper matte are described in the following sections.

Jan 1, 1999

By C. S. Compton, T. E. Marshall, D. R. Dolinar, R. Grau, L. J. Prosser, A. T. Iannacchione, D. C. Oyler

Unrecognized roof beam failures resulted in 69% of the falls of ground injuries occurring in underground U.S. stone mines from 1990 to 1996. Field investigations at 45 underground stone mines suggest that excessive beam sag or deflection is the principal unstable roof behavior characteristics associated with miner injuries. Laminated roof structures, common in most underground stone mines, allow the immediate roof to separate into distinct beams. The timely determination of roof beam deflection could provide stone miners with advanced knowledge of potentially hazardous roof. Existing methods to assess roof conditions consist of observational and monitoring techniques. Observational techniques include open drillholes, sounding, wedging, and borescopes. Monitoring techniques include scratch tools, extensometers, telltales, Miners Helpers, and Guardian Angels1. Miners have difficulty utilizing these techniques because roof beams are located an average of 8 m(26.5 ft) above the miner’s head in environments that are dark, dusty and noisy and these deflections are measured in millimeters of movement. To help mitigate the potential for falls of ground injuries to underground stone miners, the National Institute for Occupational Safety and Health (NIOSH) has developed the Roof Monitoring Safety System (RMSS) to aid in monitoring dangerous levels of roof beam deflection. If enough site-specific information is collected and placed on highly visible maps, individual mining operations could establish general guidelines for responding to specific roofbeam deflection occurrences. This would help in implementing a pro-active, comprehensive roof control plan for reducing falls of ground injuries.

Jan 1, 1999

By Angela K. Braden

Igneous rock exposures occupy only a minor portion of surface area (<18 mi2) in Arkansas, and are divided into two major groups: nepheline syenite (7 mi2) and syenite complexes (8 mi2), with various dikes and sills representing the remaining surface exposures. The syenite complexes have been the sites of major vanadium and minor titanium production during the past 50 years. Nepheline syenite exposures were important in the early production of locally used building stone; however, aggregate and roofing granules have now become the principal market for the production of nepheline syenite in Arkansas. Nepheline syenite intruded into a sequence of Paleozoic sedimentary rocks in Arkansas and is exposed in two areas: in Saline County near the town of Bauxite, and in Pulaski County at Granite Mountain, just southeast of Little Rock. Although the central Arkansas region had been investigated thoroughly for bauxite by the early 1950s, the nepheline syenite resources of the region have yet to be evaluated systematically by the state. Arkansas nepheline syenite was evaluated for its ceramic uses in 1952. Some recent industry interest has revolved around its potential use as a sand-blast abrasive. The largest exposed areas of nepheline syenite, located at Granite Mountain, currently are being mined by the Minnesota Mining & Manufacturing Company (3M) and McGeorge Contracting (Granite Mountain Quarry). 3M has been in operation since 1947 and mainly produces roofing granules. A fine powder produced by 3M during crushing that is marketed under the name Donnafill? recently has seen use as filler in self-compacting confined construction and as an additive (frit) in common brick. Since the early 1960s, Granite Mountain Quarries has produced a variety of aggregates, ranging from riprap to industrial sand, and recently constructed a computerized hot-mix-asphalt production facility. Approximately 4.5 million tons and 1.2 million tons of syenite were produced from Granite Mountain and 3M, respectively, during 1979. No production values are available after this date; however, combined production from both quarries is estimated to be at least 6 million tons annually.

Jan 1, 1999

By H. Polat, S. Chander

Relatively large amounts of hydrocarbons such as fuel oils are often needed in the flotation of low rank coals. The amount of oil can be decreased considerably by using surfactants as promoters. The reagents that are good candidates as surfactants to promote hydrophobicity can also act as emulsifying and wetting agents. Because the physical and chemical variables influence various subprocesses in different ways, their influence on the performance parameters is complex. The results of laboratory tests are presented to show that the dual role of reagents can be judiciously exploited to increase both the recovery and grade of the clean coal. The mode and order of reagent addition is critical in enhancing their efficacy as flotation promoters. The results demonstrate the benefits of proper conditioning of the pulp prior to flotation.

Jan 1, 1999

By J. M. Velazquez, J. H. Meza Viveros

This paper describes some of the parameters and technologies used at the Mexicana de Cobre smelter, and discusses the principal design parameters and new technologies that are being implemented in a smelter-expansion project designed to increase the production capacity of anode copper from 180 to 300 kt/year (200 to 330,000 stpy). In addition, some parallel projects under construction in the smelter plant are described.

Jan 1, 1999

By R M. Briggs

Kapowai Caldera Complex (KCC), located 10 km west of Tairua (eastern Coromandel Peninsula), is a late Miocene composite collapse caldera, formed during eruption of several small and large volume andesitic rhyolitic ignimbrites. Numerous epithermal Au-Ag mineral deposits and associated alteration zones at the KCC are related to caldera (rhyolite lava domes, intracaldera faults) or regional structures (faults). The main epithermal deposit exposed in the central KCC is associated with an E-W striking structural boundary fault that cuts the Welcome Jack rhyolite dome. Propylitic (calcite - chlorite) and sericitic (quartz - sericite) alteration haloes surround this deposit. Sporadic zones of sericitic alteration are also exposed within and on the margins of the Bulls Run rhyolite dome complex. Epithermal systems post-dated emplacement of these rhyolite domes, but were controlled by them. Propylitic alteration of ignimbrite in the floor of the Kapowai and Kauaeranga valleys is related to the major NE-trending Kapowai Fault which extends SW to south of Thames. Alteration along this fault pre-dates alteration associated with the rhyolite lava domes. Numerous sericitic and propylitic altered welded ignimbrite, rhyolite and andesite lava lithic fragments have been sampled from intracaldera ignimbrites, and although no direct source is known, they infer the presence of buried epithermal systems. Repeated epithermal activity at the KCC is inferred by the exposed epithermal deposits/alteration zones and the older buried geothermal systems. Silicic caldera volcanoes are considered to be critical volcanic environments for epithermal Au-Ag mineralisation in Coromandel, but are highly variable and need detailed stratigraphic, structural, petrologic, and geophysical studies to characterise them.

Jan 1, 1999

By Michael S. Wieland

"This report investigates whether it is tractable and thereupon reasonable to remove the boosterinfluences when ranking the toxic fumes of non-cap-sensitive mining explosives. The hazard potential is represented by relative fume toxicity RFT, the resultant influence computed from a formulated rule with a restricted set (tally) of fume components and multiplying constants. The RFT result is compared to the rule criterion that represents the worst case tolerable toxicity stipulated by regulations or otherwise. The typical nonstoichiometric booster composition can render notable unwanted influence on the RFT ranking results. Historically, the remedy was to shoot the booster separately and reduce the trial concentrations by the relevant subtractions. Unreal negative concentration results were noted on rare occasions, revealing the faulty nature of the reduction procedure. With thermodynamic reaction chemistry codes TDRC, on the other hand, the booster ingredients can be retained in or removed from the reactant tabulation, yielding reduction factors taken as the concentration ratios for the two circumstances. The underlying presumption regarding reduction factors is that the ratios of component concentrations with and without the booster ingredients when resolved theoretically ought to equal those rendered experimentally, when tractable. Upon rearranging the presumed relationship, the unadjusted fume concentrations divided by theoretical reduction factors yield the wanted readjusted fume concentrations, thereby removing the booster influence without generating unreal negative concentrations."

Jan 1, 1999

By M. Sadayappan

The grain refinement characteristics of four low-lead and lead-free copper base alloys for plumbing applications were investigated. These are leaded yellow brass (C85800). SeBiLOY III (C89550), silicon brasses (C87500 & C87800) and silicon bronzes (C87600 & C87610); Boron and zirconium were found to be the most effective .grain refiners for copper .alloys produced using the permanent mold cast processes. The study indicates that the type of grain refiner to be used is dependent on the alloy type, alloying constituents and their content. After grain refinement, hot tearing resistance of the alloys was improved but mechanical properties remained unaffected. Alloys refined with boron are prone to the formation of hard spots, which will have adverse effect on the surface quality of the castings during polishing and buffing.

Jan 1, 1999

By Karl Zipf

In highwall mining, once a sufficient number of web pillars are developed, they can fail catastrophically in a domino-type failure, posing a safety hazard to highwall miners and sterilizing mineable reserves. Three recent case histories of catastrophic web pillar failure in U.S. and Australian mines are documented and analyzed with two design approaches. The conventional design approach uses only a strength criterion, while the postfailure design approach uses both strength and stability criteria to insure an acceptable failure mode should strength failure occur. Catastrophic highwall web pillar failures can cost money through equipment losses, production losses, coal reserve sterilization and lost opportunity costs. Coal recovery may be higher. but the benefits of higher recovery must balance the potential costs of failure. Application of the conventional or postfailure design approach will decrease coal recovery and revenues, but the risk of potentially costly failure is much less.

Jan 1, 1999

By Anibal Gajardo

Because of the Chilean Ministry of Mining&apos;s interest in the development of industrial minerals, the Chilean Geological and Mining Service (Servicio Nacional de Geología y Minería, SERNAGEOMIN) has carried out a research program during the last two years to identify projects that represent interesting investment opportunities for small- to medium-scale operations in Chile. Most important of these projects are: (1) Quebrada Lluta aluminum sulphate, for drinking- and industrial-water treatment, with a potential domestic and foreign mar- ket of almost 43,000 tonnes per year and investments of about US$1.8 million; (2) Quebrada Lluta-Quebrada Cardones pumice, for abrasives, filters, fillers, and light- weight aggregates, with a potential market of about 30,000 tonnes per year, and in- vestments of US$2.0 million; (3) El Maule dolomite, for soil conditioner and iron smelting, with a total potential domestic market of some 60,000 tonnes per year, and estimated investments of US$2.0 million; (4) Las Escaleras bentonite, for animal feed, pelletising, and oil absorbents, with a potential market of almost 6,000 tonnes per year, and investments of about US$2.4 million; (5) Laraquete-Carampangue andalucite, for alumina refractories, with a future total domestic and foreign demand of about 15,000 tonnes per year, and estimated investments of US$2-2.5 million; (6) Rio Lía garnet, for fillers and sand-blasting abrasives, whose domestic market represents 10,000 tonnes per year, with investments of US$2.3 million; and (7) Munilque pumice, for building bricks and panels, with a potential domestic market of 250,000 tonnes per year, and investments of US$1.4 million. The development of these projects will represent an important increase and a significant diversification in Chilean industrial-minerals production.

Jan 1, 1999

By Roy T. Bowles

This paper focusses on technological developments which occurred in the village of Deloro, Ontario between 1868 and 1919. These developments illustrate the manner in which improved metallurgical processes linked Ontario mineral resources to industrial expansion. Overview of Deloro The village of Deloro is in Hastings county, about 5 miles from the village of Marmora, the site of the old Marmora iron works and the more recent Marmoraton iron mine. In this area, the Canadian Shield meets the Great Lakes lowlands. The first settlement in the vicinity occurred in the 1820s and was associated with the Marmora iron works. Settlement grew around agriculture. Gold was discovered in Hastings county in 1868. Deloro - the name derives from gold - developed as a concentrated settlement in proximity to several gold mines and the related processing activities. By 1901, substantial smelting works were successfully producing gold and arsenic from local ores. The village was developing as a company town within the framework of benevolent paternalism. For reasons associated with markets and with local ore supplies, the Deloro mills were idle for a period beginning in 1902. Developments in later periods connected Deloro to world events. In 1903, silver was discovered at Cobalt, Ontario. By 1907, M.J. O&apos;Brien, who owned mines at Cobalt, had purchased the Deloro works and was using them to process Cobalt-area ores*.

Jan 1, 1999

By S. S. Babu, T. Hong, T. DebRoy, S. A. David

"Oxide inclusions form in welds because of deoxidation reactions in the weld pool. These inclusions control the weld microstructure development. Thermodynamic and kinetic calculation of oxidation reaction can describe inclusion characteristics such as number density, size, and composition. Experimental work has shown that fluid-flow velocity gradients in the weld pool can accelerate inclusion growth by collision and coalescence. Moreover, fluid flow in welds can transport inclusions to different temperature regions that may lead to repeated dissolution and growth of inclusions. These phenomena are being studied with the help of computational coupled heat transfer, fluid-flow, thermodynamic, and kinetic models. The results show that the inclusion formation in steel welds can be described as a function of the welding processes, process parameters, and steel composition.IntroductionThe relationship between inclusions and formation of a high-toughness phase, namely acicular ferrite in low-alloy steel welds, is well known (1-4). Past research has focused on maximizing acicular ferrite amount in welds by controlling welding processes, process variables, and welding consumable parameters. Research has shown that there is a complex interaction between inclusion characteristics, prior austenite grain size, and weld metal hardenability. In a low-alloy steel weld, the small addition of titanium lead to a change in the inclusion composition and resulted in a transition in the microstructure from bainitic to acicular ferrite [see Fig. I]. This in turn lead to the best combination of strength and toughness. This paper describes the inclusion formation in low-alloy steel welds."

Jan 1, 1999

By George P. Demopoulos

n this study we have sought to highlight the critical linkage between individual reaction kinetic parameters (usually determined in small bench scale experiments) and large continuous reactor performance by focusing on the industrially significant zinc pressure leach process. To this end a comprehensive mathematical model previously developed for the description of this process was employed. In this paper we have examined in particular how small variations in key kinetic parameters impact on the autoclave&apos;s performance, i.e. attainment of autogenous steady-state temperature, zinc conversion and solution chemistry. The reaction parameters studied were: (i) stoichiometry of the marmatite leaching reaction; (ii) the activation energy of the same reaction, E,; (iii) the rate constant of the ferrous to ferric oxidation reaction, k,; and (iv) the apparent equilibrium constant for ferric precipitation, K,. This parameter sensitivity analysis was done under no oxygen mass transfer control limitations. Model predictions were found to be more sensitive to the kinetic parameters under certain conditions than others. The most dramatic finding was the one related to the small amount of sulfate produced during marmatite leaching. In connection to this it was found that the small percentage (< 5 %) of sulfate produced enhances the autothermal operational stability of the autoclave. The need for accurate kinetic parameter determination under conditions similar to those encountered in industrial zinc pressure leaching was demonstrated.

Jan 1, 1999

By J. R. Sturgul

A dynamic input-output model for a coal power enterprise that now includes four underground coal mines, three coal washing plants, a power plant and a railway transportation system was developed. The model is applied to analyze investment alternatives for long-term development, including the expansion of existing mines, the opening of new mines, the construction of new coal washing and power plants and the upgrading of the railway system. As a result, the optimal investment strategy with capital schedules and projected sector outputs is obtained. Also, the importance of the new power plant to the strategic development of the company is demonstrated. It is concluded that, without applying a dynamic input-output model, it would be much more difficult or impossible to conduct such a systematic and compete analysis.

Jan 1, 1999

By Kenneth C. Mills

Interfacial phenomena can have a dramatic effect on the separation of phases. Furthermore, since they involve surface-active materials, concentrations at ppm levels are enough to cause dramatic effects on separation processes. The effects of (i) emulsification, (ii) contact angle and wettability and (iii) Marangoni flows on phase separation are reviewed.

Jan 1, 1999

By Stavros A. Argyropoulos, Michael Trovant, Norman J. Goudie

"Two studies were carried out to estimate the thermal resistance of various interfaces using experimental and computational techniques. Three types of interfaces were examined. The first study investigated metal-mold interfaces, and the second study focused on metal-metal and metal-oxide interfaces.For the metal-mold interface, the air gap size was measured and subsequently correlated with the interface thermal resistance. The procedural details are outlined for the development of a correlation which predicts thermal resistance as a function of air gap size.Investigation of the metal-metal and metal-oxide interfaces employed data from a series of experiments as input into a model, which solved the inverse heat conduction problem in terms of a resistance estimate. These experiments, involved dipping a cold cylindrical metal into a liquid metal or liquid oxide, respectively. Under these conditions, a shell freezes around the cylindrical addition and a thermal resistance develops during the time period which shell exists . The Heat Transfer Coefficient (HTC) at the addition shell interface differs significantly among the various types of metals and oxides used. In the case of an oxide shell, the (HTC) is about an order of magnitude lower than the (HTC) of the metal shell.INTRODUCTIONIn many metals processing operations there is a need to estimate the thermal resistance at metal-metal, metal-oxide, metal-mold interfaces. This need was further intensified with the recent proliferation of mathematical models, which predict various transport phenomena events. There are many factors which can influence the magnitude of the interfacial thermal resistance. Some of the factors, among others, are as follows: contact temperature, metal thermal conductivity, apparent contact pressure, surface roughness, interstitial gas conductivity, and interstitial gas pressure.In this paper, two studies are reported on the estimation of thermal resistance. The first involves, the development of heat transfer coefficient-air gap relationships at the metal-mold interfaces. The second includes, estimations of thermal resistance at the addition-shell interface. The former case is encountered in the metals solidification and the latter during the melting and/or dissolution of additions to liquid metals or slags."

Jan 1, 1999