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By Peter Wells, Laxman M. Amaratuga, Todd M. Kanhai

"Certain mining methods (eg. Cut-and-fill) result in the contamination of run-of-mine ore with shotcrete. This shotcrete remains mixed with the ore throughout processing. Experimentation performed by Falconbridge Limited revealed that underground contamination of ore by shotcrete (eg. as little as 1% by weight) has led to ill-effects on the nickel recoveries from the flotation process in the mill. The nickel recoveries of contaminated samples were lower than tests without the shotcrete Contamination.To optimize flotation circuits it is important to know why the contamination has created these effects and also to find a method to abate or remove them. Laboratory testing showed that the age of the shotcrete was a factor in it’s effect on nickel recoveries. Younger aged shotcrete gave nickel recoveries lower than baseline nickel recoveries with no contamination. Older shotcrete gave nickel recoveries similar to the baseline.Literature on other cementitious material contaminations on ore revealed that a possible means of remediating this problem is the use of acid in the flotation. The initial pH in the flotation pulp was designed to be pH 9.2, but with the young shotcrete contamination the pH was in the neighbourhood of 10.5. Acid addition may act as a means of lowering the pH to the optimal operational value. Laboratory test work showed that acid addition brought nickel recoveries closer to the baseline."

Jan 1, 2000

By Jim Galvin

4 and 6 point timber chock constructions are used extensively on both a systematic and spot basis by Australian longwall operators to support tailgate roadways. In 1996, the School of Mining Engineering at UNSW published design and performance criteria for timber chocks constructed from Australian hardwoods. The research was funded by the Australian Coal Association Research Program (ACARP). In 1997, ACARP awarded funding for a stage 2 testing program. This testing focussed on examining the effect of using thinner timber elements in chock constructions to improve OH&S and comparing the full-scale performance of traditional 4 point chocks to Link-n-Lock constructions. It was established that chocks constructed from thinner elements have failure loads much less than thicker elements. However up to the failure loads of the thinner elements there was no significant difference in the response to convergence of chocks constructed from 25, 50 or 100mm thick elements. Chocks constructed from 150mm thick elements have a similar ultimate strength to the 100mm thick elements. However, they have a significantly lower resistance to load, thereby permitting more convergence to occur. There is more potential for chocks comprised of thin elements to be constructed 'out of plumb' and so suffer eccentric loading. The full scale testing program established that at any given level of convergence up to 10% strain, the timber in a Link-n-Lock chock generates twice the support resistance of the same quantity of the same timber in an equivalent size 4 pointer chock. On the basis of support resistance per cubic metre of timber, there is only a marginal difference in the performance of 1.0m Link-n-Lock chocks and 1.2m Link-n-Lock chocks constructed from select Blue Gum. The cost per tonne of support provided by a Link-n-Lock chock is effectively half of that provided by a 4 pointer chock of equivalent dimension and timber. Up to a strain level of 4%. Link-n-Lock chocks constructed from 1.2m long elements are slightly more cost effective than the same chocks constructed from 1.0m long elements. Thereafter, there is no significant difference in cost per tonne of support resistance. Beyond a strain level of about 4%, Link-n¬Lock chocks constructed from landscape grade Blue Gum are just as cost effective as Link-n-Lock chocks constructed from structural grade 4 Blue Gum.

Jan 1, 2000

By J. A. Rodgers, K. C. Whitaker

The time domain during which an explosive detonates and causes rock to fragment and displace is on the order of tens of milliseconds. Because of this, the dynamic processes that occur during this time frame often become a source of confusion when trying to analyze the performance of explosive products in decked blast designs. As an illustration, the authors have experimentally examined explosives malfunction in decked blasts through state-of-the-art measurement techniques. The interaction of explosive products and blast geometry was examined in detail using the analysis of a series of decked blastholes. Explosive and initiator malfunction in decked blasts is often considered to be entirely the result of insufficient inert decking material, however, it is shown that rock properties and dynamic burden conditions may have a significant impact on decking performance. The successful application of deck-blasting technique for control of ground vibration amplitude relies on an understanding of the true dynamic performance of the blasthole.

Jan 1, 2000

By J. Smolensky, M. Paul

The Nordhalde is a waste rock pile resulting from uranium mining near Ronneburg, Germany. The pile contains over 27 million m3 of waste rock. Typical seepage water has a pH of 2.7 and a sulfate concentration of 10,000 mg/L. Geochemical investigations of the Nordhalde from 1993 to 1996 included drillholes, test pits, ABA and metals analyses, column tests, and a detailed review of the construction history of the pile. In 1996, eight drillholes were instrumented for monitoring oxygen and temperature. Monitoring continued for a fill year. Hourly temperature and pressure readings were taken by automated data recorder. Oxygen concentrations were measured three times per week, and periodic gas samples were obtained for complete analysis. The resulting data set is believed to be one of the most comprehensive of its kind. Effects noted elsewhere, such as thermal convection, are evident. However, unlike other data in the literature, the NordhaIde data shows a strong seasonal effect, with convection dominating oxygen transport only in the winter months. Analysis of the data allowed the amount of contaminants associated with ongoing and historical oxidation to be compared, and results were used to assess the potential effectiveness of proposed remediation measures.

Jan 1, 2000

By Carol Cox Russell

More than two thousand abandoned mines within the Animas watershed in Southwestern Colorado are being prioritized for remediation by the Animas River Stakeholders Group (ARSG). Phased collection and assessment of information progressed from large scale to site specific. Prioritization was based on existing or potential environmental impact and technical feasibility of remediation as measured by dissolved Cd, Cu, and/or Zn in the discharge; indicators of habitat degradation; aquatic life in streams; cumulative impacts at the point of compliance; cost effectiveness; treatiblity/feasibility; and cultural and historic preservation.

Jan 1, 2000

By R G. Jeffrey

The Northparkes, Endeavour 26 orebody is a porphyry copperûgold deposit and comprises a moderately to well jointed rock mass characterised by gypsum veining, the intensity of which decreases with depth. The top 480 metres of the orebody is currently being mined by block caving, the undercut dimensions measuring 196 metres in length by 180 metres in width. Continuous caving was never achieved after the completion of the undercut thus cave inducement techniques were sought to maintain caving so as to safely sustain production. The use of hydraulic fracturing as a cave inducement tool was successfully trialled in December 1997 using existing exploration boreholes located midway up the current lift. Subsequent fracturing campaigns have enjoyed various degrees of success and have yielded in excess of seven million tonnes of ore at a significantly lower cost than conventional cave inducement techniques. Monitoring of both the hydraulic fracture system and the rock mass response has provided considerable insight into the geometry, growth and influence of hydraulic fracture networks above the Northparkes block cave, and has initiated additional research into the use of hydraulic fracturing in other mining methods.

Jan 1, 2000

By M. C. Roberts

To assess the future markets for a mineral from a producing district, the following three aspects must be considered: the future growth of the markets, the competitiveness of the district in terms of production costs and reserve adequacy, and the competition from alternative sources of supply. This paper focuses on the first issue by developing a method for predicting the demand for phosphate from trends in the major market for phosphate products, the fertilizer and agricultural market. The paper shows how broad changes in this end-use market for phosphate has evolved over time. These trends are then projected into the future to make an assessment of future phosphate requirements.

Jan 1, 2000

By R. K. Mehta, U. Cetin

The Nevada Test Site is located approximately 100 km (65 miles) northwest of Las Vegas, NV. The site was primarily used by the Department of Energy for the field testing of nuclear weapons and has been contaminated by several million cubic feet of low-level radioactive wastes, heavy metals, explosive materials, and volatile and nonvolatile organics. The transportation and leaching of these contaminants are creating serious environmental problems. The purpose of this study is to examine pozzolan, a natural alumina-silicate mineral, as a possible replacement for the existing impermeable clay barriers. In the first phase of this study, radionuclide sorption characteristics of pozzolan were investigated. This paper presents the results of the adsorption tests for the target radionuclides.

Jan 1, 2000

By Tobias Hansson

The quality of Lime Cement (L/C) columns is to a great extent dependent on the installation procedure. At a site in the south of Sweden, the client reported problems with the installed columns. To evaluate the operator and equipment dependent part of the installation, Hercules Grundläggning AB was appointed as a competitor to the site contractor. The purpose was to install a number of L/C columns with equal installation parameters for both contractors. A total of 65 test columns were installed in June 1999. The geology is a typical Swedish organic soil profile with a top layer of peat overlying gyttja and clay. Two different binders were used in the comparison; blast furnace slag with cement and lime with cement. After installation, the quality of the columns was monitored by penetration tests and a column sampler for extracting whole columns. The column penetration test were performed 28 and 134 days after installation and extraction 134 days after installation. Inspection and tests of the extracted columns showed that by using a fully computer controlled procedure, the contractor produces columns of superior quality and homogeneity.

Jan 1, 2000

By Ronald Klepper

In hydrometallurgy, pure gases like oxygen and hydrogen are used for oxidation and reduction. The gases are expensive and therefore should be used efficiently. Non reacted gas can be recycled into the liquid. Historically vortex gassing has been used; Le. a mixing impeller close to the liquid surface entrains gas from the headspace into the liquid through a gas vortex. Novel and more efficient methods are surface gassing with up pumping impellers and self- inducing gassing impellers. These alternative impeller systems are well established and common in the chemical industry, but have not been used until recently in hydrometallurgy. Gassing impellers act as internal compressors and increase the interfacial surface for a much higher mass transfer compared to alternate methods mentioned. In the paper results from lab and pilot tests and data from operated plants will be presented. The reactions with gases normally take place under moderate to high pressure, therefore a safe enclosure with mechanical seals and the safety "philosophy" is important. Experienced life and replacement cycles will be reported.

Jan 1, 2000

By Jingbo Liu, Zhimin Wang, Wenchao Li

"IntroductionThe advantages of non-stoichiometric perovskite material are highlighted in many papers[l]and many of this family of materials are well-suited to integration into microsensor devices. Among them, barium titanate is the most promising due to it's piezoelectric, pyroelectric, dielectric properties. Through modification, BaTiO3-based materials can be utilized in many kinds fields, such as surface wave probe; pholoconducting devices, field-effect transistor, permanent memory permanent storage, and ultrasonic transducerl2-3l. In this Paper, a series of BaTiO3-based polycrystals were synthesized by sol-gel processing which appears to be a very promising method for the manufacture of ceramic, because it offers significant advantages such as high purity, chemical homogeneity, controlled particle sizes of ceramics, and lower processing temperatures [4]. In a sol-gel process, alkoxides of the constituent elements show different reactivity toward water so that the preparation of multi-component homogenous system is difficult. In the experiment, inorganic salt was substituted for some of the alkoxides. Acetic acid which is employed for the solvent and catalyst, acts as donor ligand to titanium alkoxide and controls, the hydrolysis polycondensation reaction. Taking these aspects into consideration, we select the system Ba(OAc)2, , La(OAc)3, Ti(O11Bu)4 and acetic acid which is used as both solvent and homogeneous catalyst for the first time.ExperimentalA series of La3+-doped BaTiO3-based nano-crystals were prepared with sol-gel technology using various parameters. The precursor solution was prepared in the presence of barium acetate, lathanium acetate, and titanium tetrabutoxide monomer in butyl alcohol. According to the flow chart (fig. I.), Ba(OAc)2, La(OAch dissolved in the glacial acetic acid (0. lmol/40ml) in a three-neck flask were mixed with a solution of titanium tetrabutoxide monomer in butyl-alcohol(l 7ml/20ml) at room temperature and under constantly, vigorous stirring conditions. In most cases, the resultant solution was golden yellow and stable in the air. To this precursor solution, containing Ba, La, Ti in the desired ratio, water was added incrementally for hydrolysis under continuous stirring until sol was formed. After aging for more than 2 hours, sol was transformed to gel at room temperature. If heated during aging, the gel was formed in a shorter time. The wet gel was allowed to dry at 50°C for more than 10 hours. The dried gel was transparent or light yellow. In order to obtain BaTiO3-based nano-crystals, the amorphous dry gel was calcined at 600°C, 700°C, 800°C, 900°C, 1000°C respectively[5]. The ceramic humidity sensor was formed through the cold-pressed, aged, capsulated routes. The dried gels were crushed in an agate mortar and then pressed into discs of ? 1.5 X l.5mm (l.5mm diameter and l.5mm thickness), then held at about 16.5 MPa pressure for 3 min [6]. The disc was sintered at 1350°C and 1400°C for I hour respectively. During the processing, an Ag-Pt electrode was inserted in the sensor [7]. (See the flow chart.)"

Jan 1, 2000

By Matsufumi Takaya, Yukihiro Sakamoto

"Electric field emission properties from CVD diamond fabricated using pulse-modulated microwave plasma CVD were studied. Diamond was synthesized by microwave plasma CVD apparatus equipped with a pulse-modulated microwave power supply. Pulse conditions were varied from 1 to 10 seconds for pulse periods and from 0.1 to lHz for pulse frequency either. Surface morphologies of the deposits were differed by pulse frequency and duty cycle. As a result, FE properties prepared by different pulse duty cycle were different from continuous film which synthesized using continuous microwave significantly. Highest current density was obtained from the uneven morphology diamond film prepared at 17.5% pulse duty cycle.FE properties of the CVD diamond were depended on surface morphologies that related to the pulse conditions.1. IntroductionDiamond has excellent physical and chemical properties as an industrial material. Especially, hydrogen terminated diamond had the negative electron affinity (NEA) 1) and CVD diamond has this NEA property either as deposited 2). So the electron emission source to the FED is expected as one of this application of CVD diamond as cold cathode of electric devices. We studied on FE properties of various CVD diamond, pulse microwave plasma CVD diamond showed better property than those of other CVD diamond 3).This report studied on· the effect of the duty-cycle of pulse modulate microwave condition on FE properties of the diamond fabricated by pulse modulated microwave plasma CVD."

Jan 1, 2000

By A. L. Anderson, J. T. Rybock

KEECO has developed the Silica Micro Encapsulation (SME) technology for the treatment of acidic, metal-laden waters. Utilizing a silica-based chemical formulation that entails chemisorption and micro-encapsulation of heavy metals in a permanent silica matrix, encapsulated particles settle quickly and are effectively isolated from the surrounding environment, producing a stable sludge that is characteristically non-hazardous. In a number of independently-verified pilot and full-scale applications (including the Bunker Hill Mine, Leviathan Mine, Wheal Jane Mine, and Meldon Quarry), SME has been proven highly effective. The technology has been featured in a number of mining publications and selected for innovative technology awards.

Jan 1, 2000

By W J. Bruckard, M J. Vaisey

Ashton Mining Ltd (Ashton) and Lynas Corporation Ltd (Lynas) have established a joint venture partnership to develop and process rare earth oxides (REOÆs) from the Mt Weld deposit in Western Australia. The deposit is located in a deeply weathered volcanic carbonatite structure that contains approximately two million tonnes of rare earth oxides at an average grade of 20 per cent REO. As part of the 1999/2000 feasibility study currently being undertaken by Ashton and Lynas, an extensive laboratory beneficiation test program was undertaken by CSIRO Minerals on diamond drill core samples from the Mt Weld orebody. The aim was to develop a flowsheet, based primarily on flotation that could be confirmed at pilot plant scale. The target concentrate grade was 52 per cent REO with a REO recovery of at least 35 per cent. Two main ore types, nominated as CZ (limonitic siltstone) and LI (nodular limonitic ironstone) were identified for separate laboratory evaluation. The lower grade LI-type ore overlies the higher grade and more extensive CZ-type ore. The majority of the work was conducted on the CZ ore; only limited testing of the LI ore was undertaken. The latter contains a clay component that will present difficulties in processing due to its poor filtering and settling characteristics. Two processing options for treatment of CZ ore were presented for pilot plant consideration. One (Option 1) includes gravity concentration prior to flotation while the other (Option 2) includes finer grinding and four stages of open circuit cleaning. The benefits of each scheme are discussed in detail. Neither has been fully optimised and the definitive flowsheet is most likely to be a hybrid of the two schemes, incorporating the best features of each. Typical metallurgical results from each scheme were final concentrate grades of 49 per cent REO, 10-16 per cent Fe2O3 and 3.2-4.8 per cent CaO. REO recoveries were above 35 per cent in both cases. Features of the processes developed by CSIRO were the inclusion of a gravity concentration stage prior to flotation, a modified flotation reagent scheme, a change in the method of feed preparation, and incorporation of magnetic separation to upgrade final flotation concentrates. Metallurgical results obtained from flotation tests on LI ore were much poorer than those obtained for CZ ore. The best rougher/scavenger result, with the limited amount of testing so far completed, was an REO grade of 32 per cent with a recovery of 28 per cent. Further work is needed to develop a viable processing route for this ore type.

Jan 1, 2000

By R A. Medower

This paper provides a glimpse into the future of minerals processing with emphasis on æAutomation InnovationsÆ for the new millennium, particularly those involving advanced process control and innovative new applications of process control technology in 2007.

Jan 1, 2000

By Christof Brewka

Los Pelambres, 200 km north of Santiago, Chile, is the latest in a series of mega-projects developed in this part of the world. While most of its predecessors are spread over open desert, the Los Pelambres mine is nestled inside a narrow alpine valley high in the Andean Mountains. To handle the daunting task of transporting the mined copper ore more than 12 km and 1,400 vertical meters downhill to the concentrator plant, a gigantic belt conveyor system (capacity of 8700 mtph, 1800 mm wide ST 7800 steel cord belt, 2.5m diameter pulleys, an elaborate braking system including a mechanical failsafe and large reducers with a total installed drive power of 25,000 kW) has been employed. Many of these components have pushed the limits of conventional belt conveyor design.

Jan 1, 2000

The effect of microwave radiation on the processing of Palabora open pit ore has been investigated. Significant reductions in Bond work index are demonstrated for microwave treated samples. Reductions in work index were found to be sensitive to applied power level and method of application. After single stage magnetic separation tests, improvements in recovery of FeO were noted. However, these were curtailed by oxidation of the magnetite species as a result of continued heating. The effects of microwave radiation upon the recovery of copper after froth flotation were also quantified. Small initial increases in recovery of copper were note dafter microwave treatment. However, with prolonged exposure, recovery was found to decrease. Overall recovery of copper was not affected except for samples treated for extended duration. The influence of microwave treatment upon the conventional Palabora grinding circuit has been quantified with the use of USIMPAC software. Conclusions are made regarding the economics of microwave treatment for this ore. Keywords : Microwave; Grinding; Magnetic Separation; Flotation; Economic Analysis

Jan 1, 2000

By J Zhiming, X Qian

All high stopes and pillars in Anqing Copper Mine were extracted by use of large-diameter longhole mining method. The height of stopes was 120 m. The forced mining was the leading concept that the safe and efficient operation was carried out in this mine, while the mining production was faced with the major technical problems on the stability of both primary ore pillars produced in the first-step stoping of stopes and the cemented fillbody on two sides of stope in the second-step stopping of pillars. Starting with mining technology, the authors emphatically describe the test results obtained in Anqing Copper Mine and make an approach to the deployment prospects and development trend of large-diameter longhole mining technology in China underground metal mines.

Jan 1, 2000

By Jr. Pomykala, B. J. Jody, E. J. Daniels

Each year, about five (5) million ton of shredder residues are landfilled in the United States. ·Similar quantities are landfilled in Europe and the Pacific Rim. Landfilling of these residues results in a cost to the existing recycling industry and also represents a loss of material resources that are otherwise recyclable. In this paper, we outline the resources recoverable from typical shredder residues and describe technology that we have developed to recover these resources.

Jan 1, 2000

Sulphide minerals, such as pyrite and sphalerite, are leached by ferric sulphate. This reaction produces ferrous sulphate and other dissolved products. The ferrous sulphate is re-oxidized to ferric sulphate by bacteria. These reactions can be written as: [ ] However, in 1964 Silverman and Ehrlich proposed that this is not the only role that is played by bacteria. These researchers proposed that T. ferrooxidans enhances the rate of oxidation of pyrite above that achieved by chemical reaction with ferric sulphate at the same solution conditions. This enhancement in the rate of dissolution was proposed to occur by direct microbiological action, possibly by the extra cellular secretion of an enzymatic oxidant. Since the Silverman and Ehrlich proposal, different authors have made opposing claims concerning the action of T. ferrooxidanson pyrite. This ?direct mechanism? of bacterial dissolution of pyrite can be given by the following reaction: [ ]

Jan 1, 2000