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By Katsukiyo Marukawa, Mashamichi Sano, Shigeta Hara

"Various subject of studies are discussed to develop ·innovative refining processes in the 21st century for cost reduction, production of high quality steel and environmental conservation. The future refining reactor should have abilities of highly efficient mixing and separation of different phases. It is stressed ·that applications of electromagnetic and ultrasound energies, and control of flow fields rate required to create the highly efficient mixing I separation reactor.IntroductionIn recent years, it seems that the research and development in the field of steelmaking has shifted its emphasis to the solidification I ingot-making process in which continuous casting plays the leading role. From a long-range point of view, however, the need for continual development of the refining process will probably increase but is very unlikely to decrease. In order to meet such demands, it is required that problems and issues of the present process should be clearly grasped and that there must be rapid progress in process elements, such as highly efficient mixing and separation of different phases.Applications of electromagnetic and ultrasound energies and flow field control will become important options for resolving the above-mentioned problems. By efficiently and skillfully incorporating these new technologies into high-efficiency mixing/separation reactors, the innovative refining process will be established in the early 21st century."

Jan 1, 2000

By I. J. Wu

China’s land area, comparable in size to United States or Canada, contains diverse geological environments and mineral resource potential. The diversity in geological environments is such that the potential for developing many world-class mineral deposits in China is good. However, China’s mining sector was not open to foreign investment until the1990s. The long-term prospect for Chinese resource development is attractive because of China’s enormous population and cumulative demand for minerals. Approximately 33 foreign mineral companies, including 11 major internationals, are to various degrees active in China. Chinese mining laws and regulations pertaining to joint ventures with foreign companies are, from the international investment prospective, evolving slowly, but positively. This positive trend is continuing under the current government reform process, which is moving China towards a freer market economy. Although improving the enforcement of relevant laws and regulations is an ongoing process, the environment for mineral investment and joint ventures is increasingly more accommodating to foreign companies.

Jan 1, 2000

By R. R. Klimpel

This paper is a summary of the author's industrial experiences on the selection and optimization of flotation reagent schemes for the recovery of gold species. The trends given are a composite of data and experiences gained on 24 different gold ores from around the globe. The primary emphasis is on the benefits of matching the associated gold mineralogy to a reagent scheme most appropriate for that mineralogy. Two general categories are discussed: the flotation of free or native gold species and the flotation of gold associated with a variety of sulfide minerals. Important plant operating factors influencing each of these two categories are presented with supporting examples. Carefully matching reagent chemistry and appropriate operating conditions to any given gold-bearing ore will not only lower the total reagent cost but, more importantly, can lead to measurable increases in gold recovery.

Jan 1, 2000

Distinguished guests ladies and Gentlemen. As many of you know, before I became a Labour Member of Parliament, I had an unusual career path for a politician, in that I spent quite a few years working in the business community. In other words, I was mainstreamed before I was institutionalised. Given that some of this time was spent working for the then Macraes Mining Company Limited, now Gold and Resource Developments NL, I feel that I may have a perspective on how things are seen, on both sides of the fence. In terms of public perception and esteem I am not sure which career option was the step up and which was the step down. So far what I have found very familiar, is that in both roles there is a gulf between the reality and the perception of that reality - a gulf that is both huge and hard to bridge. I think it is a point worth making here amongst another busy industry cluster, that we can all too easily get so embroiled in the day to day activities, that we lose sight of how this might look to those running on a different treadmill. I can still remember scratching my head at the beginning of some days, as I worked to get new mining projects started that I knew were going to bring real jobs and economic benefit to New Zealand, but ending the day feeling like I may instead have been proposing bringing back both strip mining and slavery. If I learnt one valuable lesson out of that time it was this: .... mining has become so publicly demonised on the road to ecological nirvana, that even attempting a lucid dialogue on mining issues, with some, is incredibly difficult.

Jan 1, 2000

By Du Sichen, S. Seetharaman, Wei Liu

"The viscosities of two-phase mixtures are of great importance in the modelling of the fluid flow in metallurgical processes. For example, in steel making and refining, the intimate mixing of metal droplets in the slag phase requires a consideration of the effective viscosities for the mixture. The present work was aimed at an understanding the phenomena underlying the viscous flow in a two-phase mixture with widely differing viscosities.Emulsions of silicone oils of known viscosities (345mPa.S and 1010mPa.S at 293K) with small amounts of water evenly distributed in the same were prepared by subjecting the mixture to uniform stirring using a magnetic stirrer. The viscosities of these emulsions were measured at constant temperature by rotating cylinder method using Brookfield Digital Rheometer. The uniformity of the preparation of the emulsions was confirmed by the reproducibility of the results. Th7 measured viscosities were generally found to be independent of the torque under the experimental conditions so that the two-phase mixture could be considered as a Newtonian liquid. The variation of viscosities with temperature and the effect of addition of a surface-active substance were also studied in this work.The measured viscosities were found to be· higher than those of both pure water and silicone oil. The experimental viscosities were found to increase with increasing concentration of water. The influence of surface tension on the viscosities was examined by adding surfaceactive agent to the mixtures. The result is discussed and compared with theoretical models developed by Einstein, Taylor and Oldroyd."

Jan 1, 2000

By Tsembel Darjaa, Toru H. Okabe, Yoshiaki Umetsu

"With the purpose of extracting molybdenum and rhenium from molybdenum sulfide concentrate; .electrolysis of slurry, solvent extraction and ·precipitation operations were carried out. The slurry of the concentrate in 10 mass% NaCl aqueous solution was continuously circulated into a vertical type 10 stack bipolar electrolytic cell consisted of carbon electrode disks, and, the concentrate was dissolved by electrochemically generated oxidizers at 313 K. The current efficiency for molybdenum dissolution was 73 % after 10 hours electrolysis, and the leach solution was found to contain 0.2 mol/l of molybdenum and 4x10-5 mol/l rhenium. This result shows the dissolution is more than 8 times faster than that obtained using a single cell. The leach solution from electro-oxidation was then subjected to a solvent extraction for rhenium which is then recovered as sulfides. After rhenium separation, molybdenum was precipitated by pH adjustment, and solid MoO3 (H2O)x crystals, free of sulfate, were obtained from the leach solution containing large amount of so42-.IntroductionIn the past, electro-oxidation using a bipolar cell was applied for leaching molybdenite concentrate and ores at U. S. Bureau of Mines [1-3] and also at Bhabha Atomic Research Center [4]. In· these previous studies, Moebious type bipolar cells, in which electrode plates were vertically inserted into the free surface of the electrolyte, were employed and its effectiveness was demonstrated.Recently, the present authors studied on leaching of Mongolian molybdenite concentrate, and the effectiveness of leaching of the concentrate by electro-oxidation in alkaline and acidic NaCl solutions was demonstrated [5]. The leaching reaction during the process can be explained by the 18 electron transfer reaction of molybdenite (MoS2) with the oxidizers produced in-situ by electrolysis of NaCl aqueous solution. Further investigation was made with respect to various process parameters for electrooxidation such as pH, pulp density and temperature of the slurry, and the dissolution behavior of minor elements such as iron, copper, and rhenium [6]. Solubilities of molybdenum in the leach solution at, various temperatures and pH .was · studied, and feasibility of molybdenum recovery by hydrolysis of molybdenum species was demonstrated. By adjusting the pH of the leach solution, molybdenum oxides or hydroxides free from sulfate were successfully obtained from the solution containing large amount of sulfate ion. Rhenium present in the concentrate at a level of several tens of mass ppm was found to dissolve into the leach solution, and co-precipitate with the molybdenum compounds. Rhenium in the leach solutions, therefore, has to be recovered before precipitation of molybdenum, otherwise it is lost in the precipitate."

Jan 1, 2000

By Alfred W. Hefferan

A longwall face conveyor system serves the primary function as all material handling systems; i.e., to transport material between the source and its destination. However, the conveyor system must provide many other functions as opposed to the traditional belt conveyor system. In this paper, we will attempt to contrast the longwall face conveyor system with a belt conveyor system. In addition, the unique problems encountered along with the solutions to these problems will be covered. Table 1 lists the characteristics required of each conveyor system. The table demonstrates the contrast in the two systems. Both must be designed specifically to encounter its unique problems. The balance of this paper will explain how the longwall face conveyor is designed to address its requirements.

Jan 1, 2000

By G. Taylor

A 21st Century worker is one who works less with his physical power and more with mental ability. Such a worker is more skilled than a labourer and is consequently rewarded accordingly. A21st Century supervisor is one who ensures that workers are constantly supported so that they can maximize safety and productivity. A 21st Century manager is one who constantly searches for ways to maximize returns for the various stakeholders. Given the well-known constraints in narrow reef mining, all of the above is meaningless unless a mining method is found which provides conditions which support the 21st Century initiatives. [ ] The identified mining method is a continuous non-explosive stope breaking system using rocksplitter technology. Rocksplitting is defined as: The fragmentation of rock through high energy pulse wave transmission in a fluid-filled hole or hydro fracturing. Shotholes are effectively filled with a water-based geland 30 grams of explosive after which the hole is closed off with a ?rocksplitting gun?.

Jan 1, 2000

By Denis Murphy, James Gusek, Carl Mann, Thomas Wilderman

An active underground lead mine produces water having a pH of 8.0 with 0.4 to 0.6 mg/L of Pb and 0.36 mg/L. of Zn. This water is pumped at the rate of 1.200 gpm into a five-cell, bioreactor system covering about 5 acres. The gravity flow system is composed of a settling basin followed by two anaerobic bioreactors arranged in parallel which discharge into a rock filter polishing cell that is followed by a final aeration polishing pond. The primary lead removal mechanism is sulfate reduction/sulfide precipitation. The discharge has met stringent in-stream water quality requirements since its commissioning in 19%. However, there have been startup and operational difficulties. The system was designed to last about 12 years, but estimates suggest a much longer life based on anticipated carbon consumption in the anaerobic cells.

Jan 1, 2000

By J. W. Slatter

Cast in situ screw piling techniques (both displacement and non displacement) have seen considerable growth in recent years due to competitive production rates, low noise and vibration free installation. However the discussion on the mechanics of auger installation, which has implications on the installation effects and installation forces of screw piling augers, has been almost exclusively targeted towards non displacement techniques and in particular continuous flight augers (CFA). This paper discusses the historical development of the understanding of screw piling auger mechanics in sands and presents a new theoretical model to predict the soil transport and displacement characteristics of both displacement and non displacement augers with variable geometry.

Jan 1, 2000

By M. E. Rossi, V. Camacho

Reconciliation of production information is critical to evaluating the effectiveness of predictive models that would allow for the optimization of mining operations. Whether mining open pit or underground, mine-to-mill reconciliations can be one of management's better tools for the performance of proper accounting. Such reconciliations can also be a very useful tool in evaluation and optimization. This paper proposes a set of criteria and objectives for a typical reconciliation program. This paper also presents a stepwise, logical approach to performing reconciliations and discusses the benefits associated maintaining good information. It also highlights some of the potential pitfalls involved and the methods used to avoid collecting misleading information. These issues are illustrated with an example of a model-to-mine-to-mill reconciliation program that is being implemented at an operating mine. The program involves multiple predictive models (long-term and short-term block models), feed from three open pits and one underground mine, in addition to intermediate stockpiling, for a total of 23 mill streams. This paper presents a summarized version of this reconciliation program and its initial results as implemented at Minera Michilla S.A.

Jan 1, 2000

By Bruce Vandenberg, R. Frank Chiappetta, John Foley

Recent advances in solid-state, field portable, fast framing compact video camera systems and PC based frame capture hardware now allow blast imaging up to 1000 frames per second. Up to 4.1 seconds of data can be captured directly into the unit, downloaded to a PC or archived to a standard VCR without data compression. Since no film processing is involved, motion analysis can be performed instantly and on-site within a few minutes. This paper will describe the design features and applications of the MotionMeter system and compare these with the analogous aspects of film-based cameras and other systems. Of all blast monitoring systems and techniques available today, high-speed motion picture photography and videography still remain as the most valuable, stand alone, diagnostic techniques for troubleshooting and evaluating full scale blasts in the mining and explosives industries. High-speed image data, coupled with information obtained from other instrumentation systems, such as continuous velocity of detonation recorders, laser surveying systems, refraction and ground vibration recording seismographs, etc., can eliminate many assumptions about what actually took place in a blast. Thus, diagnostic confidence in evaluating both excellent and poorly designed blasts is increased, and optimum blast results, (which are application dependent), are achieved considerably faster when compared to the trial and error approach of relying on strictly the experience factor. Applications include developing site-specific blast designs, decay equations relating burden, burden velocity and explosive energy, determining ground response times, reducing coal damage, quantifying backbreak, evaluating the effectiveness of sternming, checking delay detonator firing times, evaluating air decks and for studying general dynamics. Motion analysis is performed with a 2D and 3D software package developed specifically for video analysis, but is also directly applicable to film analysis when using a digitizer. Dimensional controls, lens aberration, field set-ups and camera orientation are all automatically corrected for with matrix analysis.

Jan 1, 2000

By David J. White

The decreasing availability of land in urban areas, and the increasing demand for urban development is leading to the construction of taller and heavier buildings at increasingly marginal sites. Such structures usually require founding at depth and modern construction methods are making the economics of piled foundations ever more attractive (Salgado, 1995). However, the urban environment is not suited to pile driving. Conventional dynamic installation techniques (i.e. drop hammer or vibro-piling) induce vibrations and settlement in a zone close to the pile, and cause noise and dust pollution. Damage to existing structures resulting from pile driving vibrations is not uncommon (Tomlinson, 1986).

Jan 1, 2000

By Grigori Abramov

As we enter into the 21st Century, miners are looking more attentively at new mining technologies allowing decrease environment damage along with operational cost. This technic would allow developing of poor and difficult mineral deposits, including the World Ocean offshore zone. Borehole Mining is an underground/underwater remote method of mining carried out from floating platforms or vessels. Definition of Borehole Mining (BHM), working schematic, main technical data and its advantages are given. The method is currently in use in mining of different type of raw materials, such as: uranium, iron ore, quartz sand, coal, polymetallic ores, phosphate, gold, diamonds, rare earths, amber and more. It is also in use in oil and gas stimulation, salt domes storages building and environmental problems solution. Recently recorded data of Borehole Mining productivity (80-100 t/hour/hole) and a depth of mining (over 1 km) has been achieved in a last couple years. Remoteness of method not only secures complete safety of operations but also allows wide sector of underwater applications. The World leaders in Borehole Mining are Russia and the United States. Based on previous experience the Universal Tool for Seabed Borehole Mining has been developed for wide sector of usage: from exploration and mining - through oil & gas stimulation to souterrain storages construction and lake's bottom cleaning.

Jan 1, 2000

By M. Nienoord, O. S. L. Bruinsma, J. A. F. M. Schade Van Westrum, W. H. Sillekens, B. Mehmetaj

Recycling of aluminium is an effective way of enhancing the efficient use of energy and limiting the burden on the environment. Where cascade recycling is an established way of using reclaimed aluminium, closing the recycling chain is currently hampered by the unavailability of suitable techniques for refining contaminated scrap on an industrial scale. To overcome this problem, purification based on fractional crystallisation appears to be a promising option. This implies that the material is to be processed in the semi-solid state; that is, at a temperature where a solid and a liquid phase co-exist. In the current paper, it is shown that zone melting can serve as an indi.cative test for assessing the refining potential of fractional crystallisation processes, since they are both based on the same thermodynamic principle. Next, the results of zone-melting experiments are presented for some representative aluminium model alloys. The BPS-model (developed by Burton, Prim and Stichter) is used to interpret these results, from which it is concluded that the model needs extension to obtain a predictive tool for fractional crystallisation processes.

Jan 1, 2000

By Takeo Fujino, Nobuaki Sato, Yarong Wang, Kohta Yamada

"Ternary mixed sulfides of some transition metals MTS3 (M=Ba, ·Pb, T=Ti, Zr) were synthesized by a relatively low temperature process using sulfur melt. The mixture of starting materials, such as, metals and/or binary sulfides and a large excess of sulfur was reacted in a vacuum-sealed Pyrex or quartz ampoule at 350- 600 °C for one to three weeks. After the reaction, the remaining sulfur was completely removed by a process composed of filtration of sulfur melt and followed dissolution in CS2• The binary sulfides impurities coexisted in the products were removed by rinsing the products in water and acetone. By using the above method, BaTiS3, PbTiS3 and BaZrS3 'Were obtained in pure form. The effect of addition of halides on the yields of these ternary sulfides were also discussed.IntroductionThere have been a vast number of studies on the preparation and physical and /or chemical properties of mixed metal oxides. As is well known, some of such compounds exhibit excellent materials properties, causing them for use in mechanical, electronic, magnetic and chemical devices. Not a few mixed metal sulfides show similar physico-chemical properties to those of the corresponding mixed metal oxides. However, the study of the mixed sulfide crystals is rather sparse mainly due to difficulties in preparing these compounds. In various methods which have been adopted for preparing mixed sulfides, the simplest method would be the solid-solid reaction of the component binary sulfides or elements. However, there are always diffusional constraints with regard to the reactions in solid phases causing it necessary to heat the reactants at sufficiently high temperatures, viz. 800-1200°C. On the other hand, some mixed sulfides are unstable at high temperatures or to change their materials properties due to sulfur nonstoichiometry and structural modification depending on temperature, i.e., synthesis of such compounds needs to be made at lower temperatures. Processing in alkali halide melts is hopeful to overcome the above problems but to obtain the halide melts the temperatures above ~ 600 °C is needed. Low temperature reaction has been carried out for the preparation of Hg1.24TiS4, which was formed by the ·combination of TiS2 and molten Hg metal at 320°C[l]. Reaction of WS2 with LiBH4 melt at 350°C yielded LixWS2[2]. These sophisticated methods, however, can be applied only to the vary special cases."

Jan 1, 2000

By D. L. Stewart

"Melt loss is usually one of the highest individual cost items in the operation of ah ingot casting facility. While melt loss and the resulting cost for the entire facility is usually well known (at least via standard cost accounting), dross generation and melt loss for individual unit operations within the plant are usually not known. Thus, the financial impact of various practices, alloys and scrap types is not known. Development of an accurate, relatively low-cost technique for measurement of melt loss at commercial scale would aid in understanding melt loss for existing units, as well as evaluation of the melt loss impact of alternate processes.This paper will describe a methodology developed at Alcoa for accurate and inexpensive measurement of melt loss at commercial scale. The methodology has been used to evaluate the impact of scrap type, melting practices, and dross treatment technology on melt loss."

Jan 1, 2000

By Khoo Khyou Pin, Yoshiyuki Funaki, Hirotsugu Takeuchi, Ryoichi Urao, Naotatsu Asahi

"Steel is used to be ion carburized with mixing gas of methane and hydrogen. In carburizing, carbon in the methane decomposes and deposits on the steel by plasma, so methane gas flow may influence on ion carburizing of the steel. An apparatus in which works can transfer preheating, ion-carburizing and diffusion treating zones continuously was made for effective carburizing of steel. The gases were flown into above three zones with three different gas inlets. The hardness and microstructure of the works were investigated after ion carburizing and quenching. The steel is carburized deeper near the carburizing gas flow nozzle of the inlet than far from the nozzle. Hard surface layer fom1ed by quenching of ion-carburized steel.IntroductionGas carburizing is used for a surface hardening treatment which decreases fatigue and wear of the industrial parts used in automobile, machines etc. Ion and vacuum carburizing have been developed recently and applied to some industrial parts of restrictive purposes. The ion carburizing treatment which uses hollow cathode discharge (HCD ion-carburizing) is superior in energy saving, resource saving, environmental cleanness to the other carburizing treatment. Specially, carburizing energy can be saved in HCD ion-carburizing, because highly heated zone can be restricted in the range between work and subsidiary cathode where hollow cathode discharge arises, and the work is carburized in shorter tin1e in HCD ion carburizing method than other carburizing methods. Three treatments of preheating, carburizing methods and carbon potential controlling by hollow cathode discharge tried to be carried out in one continuous transferring series to carburize works more effectively, so the HCD ion-carburizing apparatus with continuous transferring system was made and gears of works were HCD ion-carburized in continuous transferring. The works were rotated themselves to get homogeneous carburizing by continuous transferring in glow of hollow cathode discharge."

Jan 1, 2000

By H. E. (Buzz) Neal

"Abstract - The Labrador Trough contains world-class iron deposits which have been mined since 1954. The direct shipping of Knob Lake ores were mined at Schefferville from 1954 to 1982. Concentrate production began in 1961 in the southwest end of the Trough, with three mines currently producing concentrate and pellets at a rate of 35 Mt per year. West and north of Schefferville, several billion tonnes of taconite have been outlined in fine-grained, cherty magnetite iron formation. Several deposits of highly metamorphosed magnetite-specularite iron formation are located west of Ungava Bay. Numerous studies have shown that this medium- to fine-grained iron formation can be beneficated to 66% to 68% iron. In the area from Wabush Lake to Mont-Wright, a medium- to coarse-grained friable specularite-quartz iron formation is repeated by folding to form several large deposits. In this area, three mining operations are located with reserves and resources in the order of 5 billion tonnes.The iron deposits occur within iron formation in sediments in the extensive Proterozoic geosyncline called the Labrador Trough. Several facies of iron formation within the Sokoman Formation reflect variations in chemical composition and depositional conditions. The correlation between the mineralogy and textures is discussed to illustrate the development of different types of iron ores. This band extends for about 1100 km southeast of Ungava Bay through both Quebec and Labrador. Further south, it turns southwest past the Wabush and Mont-Wright areas to within 300 km of the St. Lawrence River. The iron formation is essentially folded and faulted along most of its length. The degree of metamorphism is variable, ranging from intense in the northern and southern portions to greenschist facies in the central portion.The stratigraphy, structure and mineralogy of the producing mines are described along with the history of discoveries. Geological input is required to achieve the strict specifications of the international iron ore market."

Jan 1, 2000

By Norimasa Yamasaki, Masao Kurosaki

"The effects of plating conditions on the crystal orientation of electrodeposited zinc were investigated by varying elecyrolyte flow rate and current density. Precipitation of the Zn (00 • 2) basal plane is promoted at lower current density and higher flow velocity. Effect of the flow velocity on the mass transport was evaluated based on the polarization measurement in which Cu was used as the tracer. As a result, it has been clarified that the crystal orientation of electrodeposited zinc can be uniquely arranged by the overvoltage (iU0.5) that can be simply calculated by considering -the current density and boundary layer thickness. At the same time, the electrode potential during electrodeposition that can be calculated by using a model based on the competitive reactions of hydrogen reduction 'and zinc reduction exhibits an extremely good correlation with the crystal orientation of electrodeposited zinc.Introduction Electrogalvanized steel sheet has better surface properties than hot-dip galvanized steel sheet, and is used in home electric appliance and automobile applications. Factors such as crystal morphology, crystal orientation and surface roughness have a large influence on its appliance, formability and corrosion resistance [1-3].Electrolysis, condition, bath composition and alloying elements are reported as factors that affect the crystal orientation of the electrogalvanized coating. Factors that can be controlled on time in the production site are electrolysis condition that-is current density and plating solution flow velocity.Some studies[4-6] report that the crystal- orientation of the Zn(00 • 2) plane is increased by promoting, the mass transfer of zinc ions in the plating solution or decreasing the concentration overvoltage, but did not investigate in detail the plating solution flow conditions in the plating cell nor quantitatively determine the effects of both current density and plating solution flow conditions on the crystal orientation of ' electrodeposited zinc."

Jan 1, 2000