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By Takashi Ikeda, Masafumi Maeda

"Demand for solar cells is increasing linearly throughout the world. Last year production totaled 3000 tons worldwide. The market size of solar silicon is expected to increase further because of international ""political"" demand to reduce carbonaceous emission from energy consumed. Most elemental silicon is produced by the carbon reduction of Silica in an electric arc furnace. Purity of silicon at this stage is 90-99%. Major impurities are Fe, Ti, Ca· and Al, and minor ones are P, B and carbon. The oxidizing metallurgical process is no longer effective to remove transitfon metals because those are less noble to silicon. Nonmetallic impurities such as phosphorus and boron must be reduced to 0.001ppm for semiconductor use. The most common process for high purity silicon is the Siemens C process, which is basically distillation of hydro-chlorinated silicon followed by CVD of SiHCl3. The cost of such silicon is expensive to allow its popular use in solar cells. Currently scrap silicon -of semiconductors is used for this; however, the supply-of that scrap is limited to just a portion of semiconductor production.In this paper world demand for silicon will be reviewed and some of the processes proposed summarized.IntroductionSilicon is element 14 in atomic number and has an atomic weight of 28.0855. Little elemental silicon is found in the earth, and it is mostly found as oxides or silicate. The Clark number of silicon is very large and the second in its number. If we were discussing the volatility of silicon element on the globe, we would never worry about it. However, it is very difficult to obtain pure elemental silicon because a high purity silicon compound is very rare. In most cases these are silica (silicon oxide SiO2). As shown in Table 1, there are many grades of silica ore classified mainly by their content of iron and alumina."

Jan 1, 2000

By Kikuo Okuyama, I. Wuled Lenggoro, Manabu Shimada

"Aerosol processing of materials such as (i) gas-to-particle conversion process (e.g., Chemical Vapor Deposition (CVD) method) and (ii) liquid (or droplet)-to-particle conversion process (e.g., spray pyrolysis) has become of major interest to produce novel submicron- or nanometer-sized particulate material used in electronic and chemical industries. After reviewing recent theoretical and experimental researches on the evaluation of properties and morphology of fine particles by the CVD and spray pyrolysis methods, the importance of the process engineering approach· for aerosol processing of materials and the use of advanced aerosol measurement technology have been pointed out.IntroductionMaterial synthesis via aerosol processing offers a route to producing nanometer-sized and submicrometer-sized particles of high purity with specifically tailored chemical and physical properties. Especially, single nanometer-sized particles (nanoparticle materials) are considered to play an important role in the synthesis of nanostructured materials as well as in nanotechnology in 21st century due to their quantum effect and so on.However, the transformation of gaseous or liquid precursors to the final functional particulate matters consists of various complex chemical and physical processes. In order to control the size distribution and morphology of produced particles, it is important to analyze and model various phenomena, such as gas-phase or liquid-phase chemical reaction, nucleation, condensation, agglomeration and sintering that occur simultaneously in aerosol material processing. By introducing the Aerosol Science and Materials Science, the authors have been trying to model the changes in particle properties and morphology by gas-to-particle conversion and droplet-to-particle conversion processes. The authors have also been trying to obtain the experimental data on the particles properties as accurate as possible."

Jan 1, 2000

By James M. Fragomeni

"The mechanical behavior of an Al-Li alloy was studied and related to the extrusion processing parameters, the plastic metal flow during defonnation, the anisotropy, and the microstructure. The extrusion temperatures, strain rates, extrusion ratios, billet temperatures, and extrusion geometries were varied during processing and correlated with the microstructure and properties. The extrusion processing variables were related to the mechariicar behavior, anisotropy, and microstructure through the ZenerHollomon parameter i.e., the temperature compensated strain rate. Based on optical and electron microscopy studies it was found that regardless of the extrusion conditions, the various microstructures for the most part were unrecrystallized for both the as-extruded and the solution heat-treated conditions. Smaller grain sizes were correlated to larger Zener-Hollomon parameters. The extrusion temperature and ratio did not significantly affect the strength or ductility as did the section geometry, which had a large affect on these mechanical properties. The anisotropy of the properties varied substantially when comparing the extruded longitudinal versus transverse grain orientations.IntroductionThe extrusion process also has a substantial influence on: the microsfructure and mechanical properties of a material that is Athens, Ohio, 45701 fonned The plastic defonnation that occurs during the extrusion process alters the grain size, crystallographic texture, anisotropy, subgrain size, dislocation density and various other microstructural features. Often the material being extruded is not homogeneous, therefore variations in the microstructure and properties occur across the cross-section of the final extruded product. The mechanical properties and microstructure can also vary with length since it is hard to maintain a constant temperature throughout the extrusion process. The extrusion temperature often varies from the heat generated during the extrusion process. The demonstration material that was extruded for this .study was an aluminum alloy containing 2.6wt, % lithium and 0.09wt.% zirconium. This alloy was strengthened by heat treatment causing nucleation, growth, and coarsening of coherent metastable o' (Al3Li) precipitates in the microstructure. The ? precipitates which are a consequence 9f artificially aging the AlLi alloy, are spherical, ordered, and coherent with the aluminum matrix and impede the dislocation glide inotion during plastic defonnation. Theo particles grow homogeneously in the matrix, and have the Cu3Au (L 12)"" superlattice crystal structure. Aluminum-lithium alloys are used primarily for aerospace structural applications since they have attractive properties such as a lower density and higher elastic modulus than conventional 2XXX and 7XXX alloys."

Jan 1, 2000

By Charles L. Morgan

In June 1996, the United Nations International Seabed Authority opened shop in Kingston, Jamaica as an autonomous international organization charged with the administration of seabed mineral developments in all areas beyond national jurisdictions. The Authority is a consequence of the 16 November, 1994 entry into force of the 1982 United Nations Convention on the Law of the Sea (UNCLOS) and the 1994 Agreement relating to the Implementation of Part XI of UNCLOS. The total seabed area included within the Authority?s purview has yet to be assessed accurately, but clearly constitutes the largest single jurisdiction on the planet. The Authority is governed by legislative bodies called the Assembly and the Council and an administration called the Secretariat. The Assembly includes representatives of the 132 member states which are currently parties both to UNCLOS and to the 1994 Agreement. These member states directly fund the operations of the Secretariat. They include most of the world?s developed nations, island nations, and others among the 188 independent countries which are members of the United Nations. Notably absent are the United States and Canada, which are the only developed coastal states not represented. The Council is a 36-member subset of the Assembly representatives selected through a somewhat involved process designed to achieve a balanced representation of the specific interests of the members. Ultimate responsibility for the Authority?s actions resides in the Assembly, but most initiatives originate in the Council. Also included in the Authority are two subsidiary advisory bodies, the Finance Committee, which reviews the Secretariat?s budget, and the Legal and Technical Commission, which evaluates claims and drafts technical regulations. The Secretariat itself includes a staff of about 30, including 15 highly qualified and competent attorneys, accountants, engineers, and scientists. Details describing the composition and activities of these bodies can be found at the Authority?s website (http://www.isa.org.jm).

Jan 1, 2000

By M. Kobashi, T. Choh, N. Kanetake

"A new processing route, which enables the cost-effective and energy- saving fabrication of metal matrix composites, have been proposed. The pressureless infiltration of the reactive powder blend with molten aluminum was investigated in this work. The molten aluminum infiltrated into the [Ti + C] powder blend spontaneously, whereas the spontaneous infiltration into the TIC powder phase did not occur under the same experimental condition. The processing time was shortened and· the processing temperature was .lowered by adding the aluminum powder in the [Ti + C] powder. The differential thermal analysis revealed that the aluminum powder in the powder blend melted at 933K and then ignited the reaction between titanium and ·carbon. However there was an .optimum additional amount of aluminum in the powder blend. The TiC formed in situ had three-dimensionally continuous morphologyIntroductionThe squeeze casting process has been used as one of the processing routes for aluminum matrix composites. [1, 2]. Non-reactive metal-ceramic systems have been, generally, used in this technique in order to prevent the degradation of the ceramic phase. Materials obtained by this process basically consist of a continuous metal matrix and discontinuously dispersed ceramic particles. Reactive systems have begun to be introduced into the infiltration process· recently [3A]. Since the ceramics are synthesized in-situ, this process can provide a continuous ceramic matrix [5]. This is one of the outstanding features of this technique in that a bulk ceramic-can be synthesized at relatively lower temperatures in a short time. Another advantage is that the highly reactive combination of a ceramic with a molten metal is in many cases wettable [6], which enables a spontaneous infiltration."

Jan 1, 2000

By A Coulson, J Hussey

Noranda Inc is a Canadian mining and metallurgical company with its activities managed through businesses in copper and recycling, zinc, aluminum, magnesium and various metals through its interest in Falconbridge Ltd. Noranda operates three base metal mines, three copper smelters, one copper refinery, one zinc refinery, one lead smelter and refinery, three copper recycling and sampling facilities seven aluminum producing facilities and one magnesium production facility in the construction stage. The mining side of Noranda has a strong history of open stope, cut and fill and shrinkage mining. The 1999 Noranda Annual Report lists a 206 million tonne resource located at Porphyry Mountain in GaspT, QuTbec. Mont Porphyre is a large tonnage, low-grade porphyry style Cu-Mo deposit that was discovered in 1994. It is located at a depth between 1.0 and 1.7 km below surface and characterised by a very competent rock mass. The Mont Porphyre resource is located adjacent to the town of Murdochville, close to NorandaÆs Mines GaspT operations. Mines GaspT closed its open pit and underground operations in 1999 after approximately 45 years of mining, but still operates a copper smelter near Murdochville. The low-grade and great depth of the Mont Porphyre resource suggested that mine design could not be based on the conventional Noranda open stoping mining practice. This paper will review NorandaÆs approach to evaluating the Mont Porphyre deposit. The approach included two definition diamond drilling campaigns, a review of current caving practice, an in-house scope study, a geotechnical logging program for diamond drill core and participation in an international study on cave mining. One interesting component of NorandaÆs approach was the scope study that involved a team of multi-disciplinary personnel drawn together for a short period of time. The objective of the scope study was to determine what conditions would be necessary to mine the deposit and to assess the merits of continuing with further exploration work. A review of current worldwide underground bulk mining practices, and in particular an evaluation of the applicability of caving mining methods, were key components of the scope study. The scope study team concluded that derivatives of caving could be applied to the mining of Mont Porphyre, but additional diamond drilling was recommended to further define the deposit and improve the level of geotechnical information. Following the recommendations of the scope study team, a diamond drilling campaign was completed during the summer and fall of 1997. The 1997 drilling campaign had two secondary objectives, in addition to the primary objective of defining the limits of the orebody. The first objective was to improve the level of geotechnical information available for the characterisation of primary block cave fragmentation. The second objective was to improve the delineation of a lower grade intrusive core. A geomechanical investigation was conducted and included particular emphasis on geotechnical data collection and analysis. A review of the actual data collection process, including several trials of different core orientation techniques, will be included in the discussion.

Jan 1, 2000

By Kevin Tallent

The use of military-type energetic materials in commercial explosive products is not a new concept. In the United States, the techniques for utilizing significant quantities of surplus military explosive materials by commercial explosive manufacturers dates back to the 1950’s. At times, explosive companies have found surplus military high explosives and propellant materials to be suitable ingredients for their commercial explosive products. The availability of these military-type energetic materials has varied over the past 50 years, as a function of the military’s strategic defense needs and the advances in modern weapon technology. For the most part, the commercial explosives industry has been able to implement methods for safely incorporating military-type high explosives and propellant materials, whenever these surplus materials become available. During the past 5-6 year period, a large amount of military-type energetic materials have once again become available for recycling into commercial explosives. This situation can be attributed to a number of factors, such as the political changes in Europe, the development of more sophisticated weapons systems, and the increased EPA pressures on the U.S. Department of Defense for disposing of surplus energetic materials. As in the past, U.S. commercial explosive manufacturers have made efforts to recycle these surplus materials into their explosive products. This paper describes some of the commercial explosive products that are currently on the U.S. market, which contain rocket and gun propellants as energetic ingredients. Some U.S. explosive companies, such as DYNO NOBEL, ORICA and Slurry Explosive Corporation, have been able to recycle significant quantities of surplus smokeless powder and composite propellants as energetic ingredients into their commercial Blasting Agents. The successes enjoyed by these companies have once again shown recycling into commercial explosive products to be an economically and environmentally sound method for disposing of surplus military-type energetic materials.

Jan 1, 2000

By Osamu Takai, Yoshiki Sato, Nobuhiro Tajima, Hiroyuki Sugimura

"Amorphous carbon thin films doped with nitrogen ( a-C:N) have been synthesized by means of shielded arc ion plating (SAIP). Their electron field emission properties, that is, threshold field strengths for electron emission and maximum emission current densities, were evaluated and compared with those of pure amorphous carbon (a-C) films prepared by the same SAIP apparatus. Among all of the fabricated a-C:N films, the a-C:N films with a N concentration of 23 %, which prepared using Nz arc plasm at a pressure of 1 Pa with applying a sample bias voltage of -100 V, showed the lowest threshold filed of 13.4 V/µm and the highest emission current density of 1.87 µAfcm2 at a field of20 V/µm. These field emission properties of the a-C:N film were much better than those of the a-C films. The best results obtained on the a-C film in this study were the lowest threshold filed of 15.5 V/µm and the highest emission current density of 0.052 µA/cm2 at a field of 20 V /µm. Nitrogen doping to aC was found to be effective for lowering threshold voltage for field emission and for increasing emission current density. The electron field emission characteristics of the a-C:N films depended not only on N concentration but also on chemical bonding state of nitrogen in the a-C:N films. The presence of the ~-C3N4-like phase, which contributes to improve wear resistance of a-C:N as well, distinguished by the NlsXPS peak at 400.5 eV is proved to be crucial in order to enhance field emission properties of a-C:N.IntroductionThere has been much interest in electron field emission from a cold cathode due to its potential applications in vacuum microelectronic devices including field emission displays which are expected as flat panel displays in next generation [l]. It is well known that efficient emission can be rather readily realized using tip-like shape cathodes, e.g., microfabricated three-dimensional electrodes [2], carbon nanotubes [3-5], etc. However, electron emission from planar surfaces is of particular importance since such a type of cathode is· simply fabricated and assembled into microelectronic circuits. Currently, amorphous carbon thin films doped with nitrogen (a-C:N) prepared by plasma processes have attracted attention because their threshold voltages of field emission are relatively low [6]. Among various methods for preparing a-C:N films, the process using arc plasma is of special interest since, in arc plasma, nitrogen is highly activated and new types of carbon nitride phase are expected to be synthesized. However, field emission properties of a-C:N prepared by arc plasma have been studied in less detail compared with that prepared by the other methods such as sputtering."

Jan 1, 2000

By Gong-yi Guo, Yu-li Chen

"A partially-stabilized zirconia powder was prepared by metalorganic precipitation process from technical-grade zirconium oxychloride and the effluent of an acrylic acid plant. The effluent contained low molecular weight carboxylic acids, i. e., acrylic acid and acetic acid. The· developed process is based on the selective precipitation of acrylic acid at suitable pH values by the addition of zirconium oxychloride to the effluent. The resulting precipitate is a precursor that can yield a pure, ultrafine, and partially-stabilized zirconia powder. The evolution of formation of the partially-stabilized zirconia in the present process was investigated using thermal analysis, infrared spectroscopy, and X-ray diffraction technique. Environmental, technological and cost advantages will make the present process feasible for manufacturing advanced zirconia ceramics.IntroductionIn recent years the superior mechanical, thermal, electrical and chemical properties of stabilized zirconia have become the focus of growing scientific and technological interest, and hence resulted in various structural and functional applications. The great potential of the material has given rise to numerous preparation approaches to obtain the material with the excellent properties; nevertheless, an extensive number of programmes are underway worldwide aimed at understanding and improving both the preparation and behavior of stabilized zirconia ultrafine powders. (1 – 8)."

Jan 1, 2000

By Kenneth Faroni, Catherine Aimone-Martin, Thomas Gelormino

A blasting improvement program began in 1985 at two traprock quarries in Connecticut to reduce the levels of ground motions and airblast measured at residential structures surrounding the operations. The quarries are situated within town limits, adjacent to a number of historical and other structures. Although blasting vibration amplitudes were found to be far below those that could produce cosmetic defects in structures, they were perceived to be the cause of structural defects observed by homeowners. Based on a comprehensive * review of blasting practices in place during1985, an extensive vibration monitoring program was implemented. The initial study included the instrumentation of selected residential structures to record and analyze strains imposed within structures from quarry blasting, environmental changes, and from daily household activities. A comparison of the results was made with the results reported by the U.S. Bureau of Mines in 1980. The highest strain imposed in drywall from blasting (13 J_I strain) was 12% and 1% of the highest strain levels recorded for normal household activities and temperature changes, respectively. The present philosophy in production blasting is to attempt to keep vibration amplitudes as low as practical by implementing state-of-art blasting control techniques. Currently, blasting seismographs are placed in a circular manner around each quarry, providing production blast vibration records for 360 degrees of coverage at distances of 2500 to 4000 ft. from blasting operations. Seismograph and production blast records are analyzed each year and become part of a Blasting Improvement Plan submitted to the local zoning commission as part of the annual operating permit process. This paper summarizes the results of previous vibration monitoring programs and outlines the modifications made to blasting practices to minimize the levels of ground motions and airblasts. The public relations efforts and standard corporate procedures used by company personnel to address all blast related complaints and alleged damage claims since 1985 are also discussed.

Jan 1, 2000

By Uchil Jayagopal, M. Krishna, P .. V. Krilpakara, S. Manjunath

"There have been a pioneering efforts over the last forty years in the development of metal matrix composites (MMCs) as a new engineering materials, having improved properties, light weight characteristics and competitive costs compared to traditional materials. Following recent advancements in casting technology and the use of melt stirring device by foundries, discontinuously reinforced MMCs where prominent alloys are reinforced with particulates or short fibres and the being employed ·in the production of castings targeted for automotive and aerospace application.The ZA-27 alloy has a high strength compared to zinc or alluminium alloys with a lower melting temperature. The main objective of the present research is to study the effect of quartz particles on the mechanical behaviour of ZA-27 alloy composites. The results showed that the ultimate tensile strength, hardness, Young's modulus of the composite gradually increased with increase in the weight percentage of the quartz reinforcement. However overall ductility decreased with an increase in quartz reinforcementIntroductionMetal matrix composite (MMCs) offer outstanding benefits as they combine metallic properties with ceramic properties there by yielding improved physical and mechanical properties.1Among the various type of MMCs particulate reinforced composite are the most versatile and economical2. By suitable choice of metal matrix and particulate system a wide range of properties combination can be obtained such as strength, modulus, fiiction.al resistance, tribological performance and machinability. These composites are capable of replacing conventional alloys in a considerable range of applications. They also offer significant saving in energy and resources"

Jan 1, 2000

Ok Tedi Mining Limited has recently completed the first phase of a trial to compare the performance of D26B Krebs cyclones in different configurations to the new Warman 650 mm CAVEX cyclones. From 1992, rougher flotation feed size has increased from the target d80 grind size of 150 ¦m with increasing SAG mill throughput. At high SAG mill throughput, operators have difficulty maintaining the target cyclone feed pressure and must increase the cyclone feed density, thus resulting in a coarsening of the cyclone split. Warman International have developed the CAVEX high capacity cyclone. The new CAVEX cyclones, when compared to the Krebs units appear to:produce a measurable increase in volumetric flow for the same pressure drop; maintain or decrease the proportion of coarse particles reporting to overflow; and lower the overflow density. In all plant trials to-date, the CAVEX cyclones appear to be superior to the standard Ok Tedi Krebs cyclones. Further testwork is planned to evaluate modified Krebs cyclones (with recent design improvements) against the CAVEX cyclones.

Jan 1, 2000

By Suguru Kohno, Yoshihiro Momose, Masakazu Honma, Tokirou Kamosawa

Copper metal surfaces have been examined by an extremely sensitive surface analysis technique called temperature programmed photoelectron emission (TPPE). The surfaces were ultrasonically cleaned and subsequently abraded by a screw in organic solvents and water. The TPPE apparatus is composed of a Geiger counter with Q gas (He+ iso-C4H10). The curve of photoelectron emission (PE) intensity vs. wavelength from 300 to 170 nm, termed PE spectrum, was repeatedly measured at different temperatures in the temperature- increase process from 25 to 350°C. The number of emitted electrons in a PE spectrum (PE total count) increased, reached a maximum at-250°C, and decreased with increasing temperature. With the surfaces cleaned alone in the liquids the maximum PE total count decreased in the order C3H70H > (CH3) 2CHOH > C2HpH > CHPH > H2O. With the mechanically abraded surfaces in the liquids the maximum PE total count changed as a function of the abrasion period and the maximum tended to appear at higher temperature with increasing abrasion period; the maximum value at 10-min abrasion decreased in the order H2O > CHpH > C2HPH > (CH3) 2CHOH > n-C3HpH. It was suggested that the TPPE behavior can be related to the acid-base interaction between the alcohols and the abraded metal surfaces and the presence of a contaminant over layer on the surface. From the XPS analysis of the 01 s spectra it was suggested that the chemical change of the adsorbed oxygen to oxide oxygen with temperature plays a substantial role in the appearance of the maximum PE total count.

Jan 1, 2000

By Toshiaki Tsuru, Takeshi Ohgai, Hisaaki Fukushima, Shigeo Kobayashi, Tetsuya Akiyama

"Electrodeposition behavior of Zn-Cr alloys from the methanol baths was investigated. In the methanol baths of low Cr3+ concentration, Cr (III) compound was incorporated in the deposits and no lusfrous Zn-Cr alloys was deposited. However, Cr was existed as metallic state in the deposits obtained from the baths of higher Cr3+ concentration. With an increase in water content in the baths, the chemical state of Cr in the deposits changed from metallic to trivalent state. Under the condition that metallic Cr can be electrodeposited, Zn deposition was significantly polarized to the potential of Cr deposition.INTRODUCTIONAn attention has been paid to Zn-Cr alloy plated steel sheet because of its excellent properties for body panels of automobile and electrical appliances [1]-[4]. This plating process can be operated using the sulfate solutions containing Cr3+ ion [1] - [6].In decorative single Cr plating, on the other hand, many attempts have been made to electroplate Cr from trivalent electrolytes, which is motived by environmental deficiencies of the presently used hexavalent process [7]. [8]. However, it has been reported that in the aqueous solutions the behavior of the electroreduction of 0 3+ is atypical due to the complicated nature of the chemistry and electrochemistry of cr3+ species [9]-[11]. Even in Zn-Cr alloy plating, it is difficult to codeposit metallic Cr with Zn in simple sulfate electrolytes [l]-[4], [12]. Therefore, it can be expected that the electrodeposition behaviors of Zn-Cr alloys as well as Cr are significantly changed when the electrodeposition is conducted in non-aqueous plating solutions.In this study, the electrodeposition of Zn-Cr alloy was conducted from methanol solutions to clarify the electroreduction mechanism of Cr3·-Cr0 in the alloy deposition process."

Jan 1, 2000

By S. K. Kawatra, T. C. Rao, J. P. Barnwal, Durga D. Patil

Coal macerals differ widely in their surface properties and in their hydrophobicities. Therefore, it is necessary to study the flotation time dependence of coal macerals using varying concentrations of various frothers and collectors. In the present study, froth flotation is used to explore the possibility of segregating coal macerals based on their relative rates of flotation. Petrographic analysis of the various macerals in the concentrate were carried out, and the results are expressed in terms of the recoveries of various maceral groups and mineral matter. Results show that it is possible to recover a good volume of the reactive macerals without mach loss of calorific value.

Jan 1, 2000

Good morning and thanks for the chance to talk to you. It's really pleasing to see so many industry representatives here I want to spend a few minutes talking about issues relating to your industry. At the end of today I would like to leave you with three strong messages from government. The first is that this government supports environmentally responsible mining and the endeavours of the mining industry. The second is that explorers and developers are wanted and welcomed in New Zealand. And the last is that it is up to the industry to keep the public properly informed about how your industry and to constantly work on improving your public image. The mining industry is a high-tech industry which fits snugly with our concept of a growing knowledge-based economy. It has particular value for regional development, the gold mining industry alone provides more than 4,000 jobs û mostly outside of the main cities. The industrial minerals industry is twice as large as that. As well as those people directly employed by the industry there are greater downstream effects for the community. One example from the broader extraction industry of this is of the local pie shop down the road from one of Taranaki's petroleum industry locations. The shop sells over $4,000 worth of pies a week to workers in the industry. That's just one example of the positive benefits the industry brings to its local community and is the sort of real positive benefit you need to be telling people about  

Jan 1, 2000

By Tom Treleaven

The success of any blast is dependent on the accuracy of the blast design and the field controls used on the shot. This point cannot be over emphasized because when the geometry is not measured and/or field controls are not properly implemented, it can often have devastating effects on the final blast results. Thus drilling accuracy, tiont row burden control, explosive confinement, energy distribution, explosive selection, timing and structural geology become critical parameters in the design of successful blasts. Understanding the actual dynamics of the blast and why certain results were achieved is the fast step in optimizing a blast design. As stated by R. Frank Chiappetta, “Of all the blast monitoring systems available today, high speed videography still remains as the best stand alone instrumentation system for blast diagnostics.” Over the past years I have analyzed hundreds of blasts using either high-speed lowcams (500 frames per second) cameras or standard digital (30 frames per second). These analyses confirm, without a doubt, that shot geometry, in combination with structural geology, is the most important factor in overall blast results. Drilling accuracy is the single most important component in efficient blasting. Having equal mass associated with an equivalent energy is the basis in which blasts are designed. When drilling inaccuracy or borehole deviation occurs, not only is the energy unevenly distributed, but the basis of all design calculations becomes invalid. Over the past several years, quarry and mining operations have employed the use of boretracking measuring devices to measure borehole deviation and hole toe locations. In cases of operations using top hammer drills, it was discovered that the amount of deviation was significant and far greater than they believed they had. Set up error, improper drilling techniques and bit wear were some of the contributing factors. Through video anaysis of boretracked blasts, blast results were directly linked to drilling ..accuracy. The comparisons here took into account blast design, energy factors and hole sequencing.

Jan 1, 2000

By T. R. A. Davey

It is often important in the study of a process to determine whether the limitations are governed by equilibrium or kinetic considerations. Sometimes it is possible to devise a design of the process or the equipment so that the apparent. limitations set by equilibrium considerations are overcome. In this paper, detailed consideration is given to the lead refining processes of sulfiir-decoppering and of vacuum dezincing to illustrate this, and possible implications for other refining processes are indicated.

Jan 1, 2000

Most statistical and geostatistical methods of re-source and reserve estimation work extremely well for Normal (Gaussian) well-behaved information. However, most interesting mineral deposits exhibit far from this idealistic distribution of values. It seems that the more valuable the mineral, the less likely the data are to have a Normal distribution. Values tend to be "positively skewed" with a long tail into the high values. Using averaging techniques, such as inverse distance or ordinary kriging may result in consider-able overestimation of grades and tonnages unless such values are cut or otherwise modified. This paper presents some real case studies where distributions are (a) highly skewed and (b) the product of multiple phases of mineralisation. Practical methods are presented for solving such problems including combinations of indicator and log normal kriging methods. The emphasis of the presentation is on developing operational methods which can be used on project evaluation or grade control in producing mines.

Jan 1, 2000

By Yannis Faitakis, Brenda M. Wright, Gail Powley, Mark Hamblin, Randy B. Paine

A major problem in the ore extraction process is the high degree of variation in the mix of materials that make up the mined ore. The mix of materials makes it extremely difficult to characterize and predict the behavior of the ore when it is processed. The Quality Production Database (QPD) tool was successfully used in order to predict and transfer information regarding the quality characteristics of the ore being delivered to the extraction and hydrotransport unit operators. This paper describes the use of QPD in the prediction of various ore characteristics at the Syncrude Canada Ltd. processing facility.

Jan 1, 2000