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By M. L. Cunha

The lack of control of As and Sb compounds from copper smelters and converters has rendered some chalcopyrite containing arsenopyrite, stibnite and tetrahedrite minerals unusable for metal extraction. In the present investigation, we have studied the carbothennic reduction of Portuguese chalcopyrite mineral concentrate in the presence of lime/CaS04 and CaS04/Si02. Thermodynamic equilibrium calculations were performed to study the distribution of As and Sb between metal and the CaO-Si02-FeO slag phase. The phase equilibrium calculations also show the effect of oxygen partial pressure on the increase in the volume of the slag phase, which helps in lowering the copper metal formation temperature and facilitates a better separation between metal, matte and slag. The reduction reaction kinetics was studied between 850°C and 1100 °C, and the phases formed were identified by X-ray powder diffraction and scanning electron microscopy techniques. The importance of this research for using recycled matte, lean and rich minerals with As and Sb is also explained.

Jan 1, 2001

Portman Mining Pty Ltd very successfully operated the Ferro GullyNorth Mine in the Hamersley Province of Western Australia to satisfy a contract for the delivery of six million tonnes of iron ore in less than two years to the Mount Newman Mining Co Pty Ltd. The high-grade ore extracted from Ferro Gully North Mine was unusual in that, not only was it within the Joffre Member of the Brockman Formation, but it was rich in red ochreous hematite and martite and very low in phosphorus.

Jan 1, 2001

By R. J. McGregor

The Internet has revolutionized worldwide communications. Any real or perceived mining incident or environmental spill, no matter how small or remote, can become a disaster of "biblical proportions" through the judicious use of the Internet by environmental and anti-mining groups. In addition, mining companies' own Web sites and unofficial message boards can provide plenty of additional ammunition to the anti-mining forces. This paper explores how the Internet and readily available information are used by anti-mining groups active on the Web.

Jan 1, 2001

By Tanya Arsh, Thomas P. Kwiatkowski, Heather Marsh, Barry Doyle

The Big Walnut Sanitary Trunk Sewer Extension Project consists of two segments, the first a 10' excavated diameter tunnel in rock through the gas producing Ohio Shale formation and the second will be microtunneled through unconsolidated water-bearing deposits. Relatively large quantities of methane gas have been encountered in the Ohio Shale. In the softground segment, the sands and gravels contain large water storage capacity and contain shallow residential wells. This paper will present an evaluation of potential gas inflows in the rock tunnel, design considerations for contract documents preparation to inform bidders as to the volumes of gases which may been countered and design options for construction of an impermeable shaft excavation support system to insure residential wells remain in service.

Jan 1, 2001

By Ross Seedsman

Discussion on the design of roof support in tailgates has often been conducted without a clear statement of the stress and failure conditions acting. There is general agreement that in the tailgate the vertical stresses above the chain pillar increase. Within the stress 'bulb' associated with this vertical stress increase there will be an increase in horizontal stress. This does not mean that the horizontal stresses acting across the roof line increase. In retreat longwalling, the proximity of the tailgate to the adjacent goof results in a substantial reduction in the horizontal stress field acting in the immediate roof. Furthermore, at the face/tailgate corner the onset of significant compression of the chain pillar. if it is designed to yield, will result in a further reduction in the horizontal stresses in the immediate roof. It is suggested that this latter mechanism can cause the horizontal stresses in the immediate roof to go to zero. Whatever, the horizontal stress acting across the roof in the face/tailgate corner will be significantly lower than in the face/maingate corner. The implication of the model is that support design in tailgates should be based on the assumption of zero horizontal (in fact tensile) stresses. How the roof behaves in a tensile stress environment is a function of joint spacing and orientation compared to excavation width and direction. It is speculated that the empirical relationship between support density and roof rating results from the relationship between joint spacing and bedding spacing. The onset of stress reductions has major implications to the design of cable and bolt anchorages in the tailgate environment.

Jan 1, 2001

By Gabriel Riveros

The stags from the Teniente Converter (TC) have high copper and magnetite contents. The reduction and copper impoverishment of these slags in an electric furnace was simulated in the laboratory, as part of a conceptual study for the Ventanas smelter of ENAMI. The effect of power input, electrode immersion, temperature of the slag, coke and solid revert additions on the rate of magnetite reduction and copper recovery was investigated. It was found that the addition of solid reverts, containing copper matte, enhanced the recovery of copper. Magnetite stratification and a corresponding gradient of the copper content occurred in the slag. Microscopic examination of slag samples showed the presence of copper in the form of matte and metallic copper inclusions. The results of the experimental work combined with an analysis of the phenomena that take place in an electric furnace led to a better understanding of the slag cleaning mechanism. The successful start-up of the slag cleaning electric furnace at the Ventanas smelter resulted in good copper recovery and confirmed the beneficial effect of solid reverts addition. Electrode consumption is lower than anticipated. No bottom build-up problems have been experienced. Keywords: copper, slag, magnetite.

Jan 1, 2001

By Alan DonaldsoN

Plasma Quench production of titanium is the thermal dissociation of titanium tetrachloride into gaseous titanium and chlorine followed by rapid quenching to prevent back reactions. Titanium tetrachloride dissociates into titanium and chlorine atoms at 5000 K. Expansion through a Delaval nozzle accelerates the gas to supersonic speed cooling it very rapidly. Cooling rates are as high as 7exp 1 0 Kelvins per second. Injected hydrogen reacts with condensed titanium particles to form titanium hydride and with the chlorine to form hydrogen chloride. We have produced titanium powder at 20 kglh in a continuous reactor. Costs are projected to be lower than the Kroll Process at large enough scale. Most of the cost reduction would result from elimination of magnesium as a reducing agent and much lower capital costs.

Jan 1, 2001

By John Vynne

Too often, a mine’s operations, including drilling, blasting, loading, hauling, crushing, processing, etc., are considered independent steps, rather then a continuous process. In fact, these are interdependent operations with each step in the process having an impact on subsequent operations. If the effectiveness of the drilling and blasting operations can be improved, they will impact the entire mining process. Some of the resulting improvements include: level benches on grade; fragmentation and diggability with the result being reduced loading times; haul cycles improvements; and the crushing and milling operations will be more efficient and less energy consumed. Thunderbird refers to this as “Drill to Mill” information cycle or process. This paper focuses on two of the technological enhancements Thunderbird has added to its drill monitors that allow the mines to impact the “Drill to Mill” concept. These enhancements are: incorporating global positioning satellites into drill monitors; and radio off-loading of data.

Jan 1, 2001

By M P. Simpson

Forty one whole rock samples from the Gold Cross low-sulfidation epithermal Au-Ag deposit have d18O values that range from 4.4 to 9.3 per mil, with an average value of 7.0 per mil. Unaltered and weakly altered rocks have d18O values greater than eight per mil, and the orebody is surrounded by samples that are depleted in 18O. A strongly silicified sample adjacent to the Empire Vein System has a d18O value of 9.0 per mil, similar to previously reported analyses of vein quartz (7.0 to 11.7ë, average 9.4ë). This suggests that, in detail, Golden Cross may have a zone of 18O-enriched wall rocks in the core of the deposit, adjacent to the main underground veins. Although some workers have suggested that stable isotope geochemistry may provide useful information for epithermal mineral deposit exploration, at Golden Cross this is not the case. Alteration minerals, major elements and trace elements all define larger, less ambiguous halos than the zone of 18O-depleted wall rocks.

Jan 1, 2001

By Mark Cross, Andrew P. Campbell, Koulis A. Pericleous

"Computational Fluid Dynamics (CFD) modelling is being used to simulate the freeze layers formed within direct smelting processes. There has been some concern whether water-cooled elements can withstand the p~ocess conditions and in particular abnormal cases where they may be splashed in molten metal.To validate the models being developed, two cases from literature have been modelled for solidification and stress analysis. The solidification case is presented in detail and is for hot molten metal flowing through a cylindrical pipe. The walls are at a temperature below the melting point for the metal. The resulting solid (or freeze) layer is within 3% of the value calculated by Sampson & Gibson9 •Preliminary modelling of the refractory-slag interactions is presented. Although three basic mechanisms: Penetration; Corrosion; and Erosion will eventually be modelled, only the penetration is considered here. The corrosion mechanism is to be modelled by tracking the time that the penetrated refractory is at the required temperature.Future work, after adding all the required physics, will focus on the modelling of a water-cooled element placed lower in the smelter. Process perturbations will be simulated to examine what these elements will withstand."

Jan 1, 2001

By M. G. Basavaraj, S. Sarkar, G. S. Gupta, P. D. Patil

"Previous experimental study on raceway size hysteresis on two-dimensional cold model showed that the inter-particle and wall-particle friction had a very large effect on the raceway size. Existing literature correlations for raceway size ignore the frictional effects. It has also been shown in the present study that their applicability to the ironmaking blast furnace is questionable. To take into account the effect of friction on the raceway size a stress analysis has been done for the raceway region. Two-dimensional fluid flow equations under turbulent conditions have been developed and solved computationally in order to get the pressure forces. The frictional forces were obtained in terms of stresses. To predict the raceway size a force balance was done for the raceway zone considering the pressure force, the frictional force and the bed weight. The resulting equations from the force balance are able to describe the raceway hysteresis phenomena reasonably well along with the raceway size. A two dimensional experimental set up has been fabricated in order to validate the computer predictions. Predicted values agree well with the experimental values.IntroductionWhen a high velocity blast of air is introduced into a packed bed through a tuyere, a cavity is formed in front of the tuyere. This cavity, formed in the iron-making blast furnace, is called the raceway. Coke tumbles down and bums in this raceway, generating heat and reducing gases for the iron-making process. The raceway is responsible for producing most of the reducing gasses in the blast furnace. In addition, the size and shape of the raceway determines the movement of solids within the blast furnace, the distribution of gases and liquids (slag and metal), setting the location where the primary chemical reactions occur and the temperature profile in the lower part of the blast furnace.Due to the importance of the raceway, many investigators l - 6 have studied it and have predicted the raceway size using the empirical correlations based on experimental (hot & cold) and mathematical models. A number of correlations have been reported in the literature to predict the raceway size by various investigators3 - 6 which are different to each other. Each of the correlations shows a different dependence of raceway diameter (DR) on bed height, particle size, solid density, bed voidage and blast velocity. None of the correlations includes the effect of solid stresses on the raceway size and shape. The magnitude of these stresses will depend on the bulk solids properties (internal angle of friction, wall angle of friction) and the bed dimensions."

Jan 1, 2001

In November 1999 Waihi Gold Mining Company commissioned its new crushing and conveying plant used to transport both ore and waste from the Martha Mine to its ore processing plant and also its tailings dam construction area. To date, a record monthly throughput of 854 000 tonnes throughput has been achieved. This paper outlines the measures taken subsequent to the commissioning of the system to achieve greater than design throughput and to mitigate the environmental and safety issues associated with operating the system in the middle of a town.

Jan 1, 2001

By Mohammad T. Izadi

Piles are, often, used for transferring load from the super structure through soft consolidating strata onto relatively stiff uncompressible soils. Downward movement of the soft soil strata develops negative skin friction and dragload around the pile shaft, with time. Traditionally the induced dragload is considered in determining the pile bearing capacity. On the other hand, field measurements on instrumented piles show that negative skin friction is reduced by the magnitude of applied live load. A method for calculating the pile bearing capacity, driven through soft consolidating strata is presented. In this method, two allowable load-bearing capacities are calculated for each pile, live load plus dead load and dead load. The proposed method, substantially, increases the allowable load bearing capacity of piles compared to calculated values by the traditional methods.

Jan 1, 2001

A wide range of materials are used in hydraulic backfilling operations and the pipeline flow behaviour of these mixtures varies considerably. It is shown that despite the large differences in constituent materials and flow behaviour, a common approach can be applied to analysing the flow of all hydraulic backfills. This is extended to include a rational design approach for backfill distribution systems. The use and limitations of pipe loop tests as a design aid is discussed. Backfill quality control is identified as a key area where improvement needs to be made to enhance the reliability of backfill system operation.

Jan 1, 2001

By Peter B. Dowden, Robert A. Robinson

Boulders, frequently found in tunnels excavated through soils, can pose major problems for full face TBMs in terms of slowing or halting the tunnel advance, cutter damage, and abrasive wear. The paper aims to consider the problem as a whole, from the geological characteristics of boulder sites, to the appropriate physical design of theTBM, and its operation in boulder-laden soils. In addition, visualization of boulders and other subsurface obstructions by seismic methods and ground penetrating radar are reviewed. The paper will assist the construction planner in assessing the risks and preparing appropriate specifications.

Jan 1, 2001

By Charles L. Richman

The effect of the addition of Silver Sulfide on the rate of Chalcopyrite (CP) of Sulfuric acid (H2SD4 leaching is discussed, Although Ag2S in an expensive addition, a theoretical explanation of it's use will aid in the development of a economic substitution. We have used cyclic voltammography to show the presence reaction species at different potentials. Cyclic Voltammography maps the surface reaction current peaks on CP, to regions on the CP Phorbaix diagram. AC Electro-lmpedance spectroscopy (EIS) models the surface impedance properties, which control the rate of electron and ion transfer, and the surface kinetic reactions, with and with out light. EIS and other measurements show that AgCuS u Photo-reactive material- The EIS results are compared with the SEM and EDXA results to show the presence of diffusion pores, and diffusion controlled reactions during CP leaching without the addition of silver sulfate. We hypothesize that AgCuS is an ionic conductor like Ag2S. EIS shows an imposed negative leaching rate greatly. Our theory shows how the formation of Silver Copper (1) sulfide layer at open circuit potential gives an effect similar to negative potential, that is enhanced with illumination. We verify that AgCuAS is an N-type semiconductor that forms a diode type junction with the electrolyte with the Mott-Schoottly relation.

Jan 1, 2001

By S. P. Singh

"The geological features of a rock mass have a direct influence on its blasting characteristics. It has been observed that perimeter control techniques provide excellent results in massive crystalline formations but may give poor results in weak and or highly jointed formations.A field study was conducted with the objective of understanding the role played by the geological features of a rock mass in producing and controlling blast damage. The field work involved the assessment of blast damage at several operating mines and the blasting of drift rounds in a geologically dominant rock mass.The effect of rock strength, rock quality designation (RQD), joint parameters and hydrogeological conditions on blast damage is described below. The influence of number and thickness of weak layers on blast damage is also discussed below on the basis of quantitative data. In addition, critical particle velocity ranges for damage to different rock types have also been outlined in this paper."

Jan 1, 2001

By Emmanuel John M. Carranza, Martin Hale

Abstract- An application of logistic regression to mapping of gold potential in the Baguio district of the Philippines is described. Categorical map data such as lithologic units and proximity classes of curvi-linear features, based on spatial association analyses, are quantified systematically and used as independent variables in logistic regression to predict the probability for presence or absence of gold mineralization. Regression experiments to compare between using all independent variables that are associated spatially with the response variable and using only statistically significant independent variables are performed. The results of the regression experiments are similar; however, the use of all independent variables produces slightly optimistic results but better prediction rates for the known gold deposits in the test district. At least 68% of the ‘model’ large-scale gold deposits and at least 76% of the ‘validation’ small-scale gold deposits were predicted correctly. The predicted geologically favorable zones are also similar to delineated geochemically anomalous zones. The technique presented using logistic regression as a data integration tool is effective for geologically constrained technique of mapping mineral potential.

Jan 1, 2001

By Mike Boissonneault

It was three years ago when the “storm of the century” had taken a firm grip over the Pacific West Coast and inland areas. At the Big Sky ski resort in Montana on Christmas morning two ski patrollers set out to perform an explosives “hand charge” avalanche control mission that would see only one return. It has been difficult to determine exactly what happened. Investigators do know that there were three separate and consecutive attempts to light a safety fuse, when it had apparently been burning since the first attempt. Time ran out after the third attempt. Although this accident has had a profound impact on North American avalanche control programs, I am sure it pales in contrast to the shock and grief experienced by family members who lost a loved one.

Jan 1, 2001

By Richard B. Berg

Until its closure in 1999, the Antler was North America's only active chlorite mine. The mine is located 25 miles (40 km) southeast of Butte in the Silver Star district - an old Montana gold mining district. In 1975, two prospectors searching for talc re-examined a prospect showing a green, fine-grained mineral resembling talc. Following identification and testing of this magnesian chlorite (variety clinochlore), Cyprus Industrial Minerals began processing ore from this deposit in 1976. Chlorite veins ranging up to 30 feet (9 m) in thickness were formed by essentially complete replacement of Precambrian (Archean?) quartzofeldspathic gneiss. Chlorite replacement was controlled by near- vertical faults. These chlorite veins, typically surrounded by envelopes of sericitic alteration, were formed by the introduction of magnesium-rich hydrothermal fluids, probably related to the Proterozoic talc-forming event in southwestern Montana. Luzenac America, Inc. acquired Cyprus' talc operations in 1992, and continued to mine this deposit until the ore body was mined out in March 1999, and the mine was reclaimed. Total sorted ore production from this deposit is about 250,000 short tons (st) (227,000 metric tons [mt]). Chlorite from this deposit was primarily used in ceramic and paint applications.

Jan 1, 2001