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Lime production is the largest single chemical use for limestone and dolomite. The term “lime” in this review refers to high-calcium and dolomitic quicklime, their hydroxide forms and dead-burned dolomite. This review is restricted to a discussion of the U.S. lime industry. Production and consumption In 2004, according to preliminary data, U.S. lime production was about 20.1 Mt (22.1 million st), an increase of 900 kt (990,000 st) compared with 2003. Production in2004 was valued at about $1.4 billion. Commercial sales of lime totaled 18.6 Mt (20.5 million st) and captive production was 1.5 Mt (1.65 million st). Total U.S. consumption was about 20.2 Mt (22.2 million st). The majority of U.S. lime trade was with Canada.

Jan 1, 2005

By R O. James

The usual focus of papers on fatty acid collector action in non-sulfide flotation is on the adsorption of the carboxylate and/or neutral molecule species at the mineral-solution interface. Little attention is paid as to whether or not the solution conditions correspond to true solutions, micellar and other self-assembly objects or precipitates. Our examination of the solution chemistry of the important fatty acid collector, oleic acid, has revealed that many, if not most investigators set their experimental conditions to be in micellar or precipitate domains while arguing, often by implication, that they have only solute species present. We have investigated the equilibrium solution domains usually encountered in studies of oleic acid flotation of such minerals as barite, calcite and fluorite. The alkaline earth-fatty acid and liquid oleic acid precipitate phases exert a strong influence on the solution chemistry, a fact not often appreciated in many studies.

Jan 1, 2005

By L D. Redden, M G. Nelson

Mechanical flotation machine design is typically based on hydrodynamic analysis, with scale-up calculated by geometric proportionality. End users often specify and purchase machines on the basis of retention time, characterised by the æ$/m3Æ approach; they may also consider the manufacturerÆs installed base. In some applications, end users also consider specific energy and the impact of energy consumption on operational costs. In other cases, a decision may be based on machine type (forced-air versus self-aspirating) and perceived metallurgical or operational advantages of one machine type over the other. With regard to metallurgical performance efficient bubble-particle contact is very important and is primarily influenced by two factors:the concentration and size distribution of bubbles in the machineÆs contact zone (the volume enclosed by the disperser); and the number of times that slurry is pumped through the contact zone. The second factor is a function of the machineÆs pumping rate and its retention time. Field data show that pumping efficiency is independent of aeration rate. In this paper, a new dimensionless number for the characterisation of flotation efficiency is presented. The contact frequency number (CFN) is defined as the number of times a given volume of slurry passes through a machineÆs active contact region, and is given by: CFN Qp/Qf, where:Qpis the pumping rate through the contact regionQfis the volumetric feed rate to the machine

Jan 1, 2005

By A. Iordanidis

Fly ash samples were collected from two large lignite-fired power plants of Ptolemais region, northern Greece. Environmental Scanning Electron Microscopy (ESEM) was applied for the characterisation of the samples. ESEM coupled with Energy Dispersive System (EDS) provided fast and accurate results on the morphology, mineralogy and chemical composition of the fly ash particles. Fly ash consists mainly of aluminosilicate glass, silicates, oxides-hydroxides, sulphates, carbonates and char. Various types of chars, spheres (e.g. ferrospheres, cenosphers, plerospheres etc.), spheroids, agglomerates and mineral crystalls were observed. The size distribution of the fly ash particles was correlated with their mineralogical and chemical composition. Possible environmental impacts and potential utilization is also discussed in this study.

Jan 1, 2005

By Harry Verakis

Electronic detonator systems are an advance in technology beyond conventional electric detonators for initiating explosives and blasting agents. Their use is widening into the mining operations of the U.S.A. Each electronic detonator system differs in design, construction, operation, and testing features and each system is different than “conventional” electric detonators. There are benefits of electronic detonator systems which serve to improve blasting safety. With the introduction of electronic detonator systems for mine blasting, issues were raised about the application of MSHA regulations for shunting and circuit testing. The MSHA regulations for surface and underground mine blasting operations address the use of “electric” detonators. Although electronic detonators are initiated by an electric pulse or current, their design is unlike “electric” detonators. To resolve the issues of shunting and circuit testing with respect to MSHA regulations, a technical and field evaluation of electronic detonators was made and the results are presented.

Jan 1, 2005

By V. I. Birss

Planar solid oxide fuel cells (SOFCs) offer great promise as stationary power generation devices, primarily due to their flexibility in terms of fuels, high energy conversion efficiency (when both electricity and heat are captured), and their relatively low fabrication costs. However, the anode performance can be compromised by such factors as exposure to certain sulfur-containing fuels and the deposition of coke when using hydrocarbon fuels. In terms of the cathode, its performance is limited primarily by the slow kinetics of the oxygen reduction reaction, while its lifetime can be negatively affected by factors related to the corrosion of currently used stainless steel interconnect materials. This talk will present an overview of these challenges and some possible solutions to these problems. The presentation will also focus on how electrochemical methods can be used to evaluate and improve the performance of SOFC anodes, cathodes, and interconnect materials. In addition, recent promising research efforts directed towards performance enhancement of SOFCs through the use of nanoscale electrocatalysts will be discussed.

Jan 1, 2005

By John B. Ackerman, John G. Mansanti

INTRODUCTION Placer Dome's Turquoise Ridge Joint Venture operation is located some 75 km northeast of Winnemucca, a community in north central Nevada. Formerly known as the Getchell Gold Corporation and First Miss Gold, the operation mines refractory ore from the Getchell and Turquoise Ridge gold deposits located on the east flank of the Osgood Mountain Range above the Kelly Creek Basin in the Potosi Mining District. Mining has been ongoing at Getchell since shortly after its discovery in 1934, and was the nation's second leading producer of gold after Homestake in the early 1940s. Over its history the Getchell property has been mined for gold, tungsten, molybdenum and arsenic; mining methods varied from open pit mining to underground mining; processing options included conventional milling, flotation, roasting, heap leaching, and most recently pressure oxidation followed by CIL (carbon-in-leach). As an historical note, the US Bureau of Mines developed the use of carbon for gold recovery at Getchell during the 1940s (Horton 1999). Placer Dome acquired the property in May 1999. The pressure oxidation plant was mothballed in July 1999 and the property was placed on care and maintenance in February 2002 pending further exploration results. The property is currently ramping up to full production status. A joint venture agreement (75% Placer Dome, 25% Newmont) was established with Newmont Mining in 2003 and ore is processed at their nearby Twin Creeks autoclave plant. Mine dewatering is a key element to success. Arsenic is a ubiquitous mineral in many of the mineralized areas of northern Nevada, necessitating treatment of water prior to re-infiltration.

Jan 1, 2005

By A. H. Swart

Rock engineering is concerned with the design of rock structures generated by mining activities. Therefore, rock engineering designs have major implications for the safe recovery of mineral deposits and operating costs. The paper deals with a few challenges facing rock mechanics engineers operating in the hard rock underground mining environment in South Africa. Finally, examples are included, which may assist rock mechanics engineers in providing better designs, which could ultimately lead to further improvement in safety and lower operating costs.

Jan 1, 2005

By T Weldon

In the last 15 years, it has become increasingly popular to win gold and silver from carbon strip solutions with electrolytic æsludgeÆ cells. The precious metal sludges produced in the cells are washed to the cell bottom and pumped into filters. Most new operations are specifying sludging cells, and many older operations are being retrofitted with up-to-date electrolytic sludge cells and filters. The new sludging cells are generally more energy efficient than older cells, but more importantly, the cell operations to remove product are much less labour intensive, cleaner, and the operator need not have physical contact with the electrolytically produced metal. A case study of a major North American gold producer (50 000 kg/yr) that removed old style stainless steel wool cathode cells and installed new sludging cells and sludge filters is presented. The effect of various impurities is discussed.

Jan 1, 2005

By T C. Westerfield, G, M J. Mankosa

An innovative separator known as the HydroFloat cell has been developed specifically for the upgrading of coarse particles that are difficult to recover using conventional flotation cells. The novel characteristic of this separator is the formation of a hindered teeter-bed of fluidised solids into which small air bubbles are injected. The air bubbles selectively attach to hydrophobic particles and form particle/bubble agglomerates that segregate atop the teeter-bed due to their lower apparent specific gravity. The low-density agglomerates are eventually carried into the product overflow launder by the rising current of teeter water. Hydrophilic particles remain in the teeter-bed and are discharged to underflow as a high solids content tailing. Benefits of this hybrid flotation-density separator include enhanced bubble-particle contacting, increased particle residence time, and very low air demand. Test data indicate that significant improvements in the recovery of coarse particles can be achieved using this innovative technology. This article describes the theoretical basis for the development of the HydroFloat cell and provides an overview of recent pilot-scale tests conducted for the phosphate industry.

Jan 1, 2005

By C F. Prins, C LantuTjoul

Mineralisation in alluvial diamond or vein gold deposits is often hosted in trapping mechanisms. For instance, diamonds are nested in bedrock depressions such as gullies and potholes which were carved out by the sea long before the diamond deposition took place. Similarly, gold mineralisation can precipitate in the necks of a boudinage structure. In such deposits, the spatial distribution of the mineralisation is governed by the mutual arrangement of the trapsites and by the grade variations within each trapsite. Reliable estimates can be obtained only if they rest on a proper knowledge of both degrees of variability. This creates a challenging sampling problem, as during the exploration phase it is important to have a good global mean estimate to enable decision making towards the future. A similar problem occurs for local estimates at a later stage of development. To understand and manage the sampling for global means, specific sampling procedures are required based on an appropriate choice of sample support size and spacing. Estimates from such sampling campaigns should be unbiased, and the less variability they display, the better the sampling parameters. The performance and impact of sampling parameters are tested and compared on different simulated deposits.

Jan 1, 2005

By Rimas Pakalnis, Lyndon Clark, Tom Brady

A major focus of ground control research presently being conducted by the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) is to incorporate data on weak rock masses into existing design relationships, with an emphasis on updating the span design curve for manned entries and the overbreak curve for longhole entries. Both curves were originally developed at the University of British Columbia, Vancouver, BC. The original database has been augmented by information from mines throughout the United States, Canada, Australia, and Europe. The common factor in all these mines is the presence of a weak back and/or walls. In most cases, the ore zone is the weakest rock unit and must be stabilized so that the mineral-bearing rock can be extracted safety. The current NIOSH research attempts to provide rock mechanics tools to assist a mine operator in making economic decisions that will also ensure a safe working environment. This paper documents the Nevada database with a special emphasis on Nevada underground gold mines.

Jan 1, 2005

By Zhan Jing

Keywords: thermodynamic, Ni-Co alloy powders, composition, fibrous The mathematics model of Ni(II)-Co(II)-C2O42?-NH3?H2O-H2O of thermodynamic equilibrium system has been developed theoretically according to the law of conservation of mass and the law of simultaneous equilibrium, and the logarithm concentration-pH (log[Me2+]T-pH) diagrams of this system have been made. The effect of ligand and pH value was studied. Two issues in coprecipitation route to synthesize fibrous nickel-cobalt alloy precursor powder, com-position and morphology which are a first priority, are addressed based on thermodynamic analysis and experiments. The results show that suitable pH value range of coprecipitation of nickel ions and cobalt ions in theory can be obtained to maintain fibrous, excellent compositonal homogeneity and stoichiometry in coprecipitation products. Experimental demonstration is also carried out.

Jan 1, 2005

During 1995 a catastrophic accident took place at the No 2 Vaal Reefs shaft in South Africa, when a locomotive fell onto a cage, causing the death of 104 people. The subsequent Commission of Enquiry found that the safety detaching hook had opened when hit by parts of the falling locomotive, detaching the cage from the rope and allowing the cage to drop 400 m down the shaft. It was believed that had the hook not detached, the rope would have been sufficiently elastic not to have failed, implying that many fatalities may have been avoided. In addition, the risk of accidental opening of hooks due to impact with smaller falling objects in shafts became a concern. This paper deals with a comprehensive statistical investigation that was performed to quantify this risk, establish acceptable levels of such risks and to derive criteria for the resistance of detachment hooks against accidental opening caused by impacts. The investigation involved a survey, dynamic finite element analyses and Monte Carlo simulations.

Jan 1, 2005

By Numan Elmas

Barite deposits located in Dinek and surrounding region have important economic features with their large reserve capacity for Turkey. The objective of this study is to elucidate geological and depositional characteristics in terms of. site investigation and chemical analysis. In order to do this, geological area of about 300 km2 was examined and detailed geological map was constructed. It was observed that Barite mineralization in these deposits was occurred in carbonate and pelitic rocks of Lower Cambrian-Lower Ordovician. Deposits were exposed to advanced diagenesis regional metamorphism and tectonics that rotated and deformed the barites; therefore, barites shows secondary veins, brecciate and fracturing structure. Even though, a few light isotope values of barites may suggest hydrothermal and exhalative sedimentary characteristics or possible mixing with magmatic fluids, generally heavy isotope values indicate that the sulfate ions were supplied from coeval seawater and, many of sedimentary features and petrological, geochemical characters support dominantly sedimentary origin.

Jan 1, 2005

By K. B. Hodgins, P. Ouellette

"The North American mining industry faces challenging emissions regulations in the coming years with the introduction of new standards for off-road diesel engines. In order to remain competitive, industry stakeholders must invest in new technologies that are economically and environmentally sustainable.Westport Innovations Inc., Vancouver,British Columbia, has developed high-pressure direct injection (HPDI) technology that allows diesel engines to run primarily on natural gas with no intrusive engine modifications while reducing emissions of nitrous oxides (NOx), particulate matter (PM), and CO2 with no loss in performance. This is accomplished through late-cycle, high-pressure direct injection of natural gas into a diesel engine combustion chamber at the end of the compression stroke. A small amount of diesel fuel is injected first to initiate combustion, followed by the natural gas fuel main injection. The diesel cycle and its operating characteristics are fully retained including high combustion efficiency, lowspeed torque, high-power output, no engine knock, and fast response to load changes. Natural gas has not been an attractive fuel alternative in mining operations due to the reduced performance associated with spark ignition engines and the added weight and space required for compressed natural gas tanks. However, liquefied natural gas (LNG) can be stored with less impact on weight and space than compressed natural gas (CNG) by virtue of its increased energy density over CNG.Westport has applied HPDI technology to the Cummins QSK series engines for high horsepower applications such as power generation and mine haul trucking. HPDI can also be applied to other engine manufacturer platforms and market applications. Westport is interested in demonstrating the unique characteristics of HPDI in mine haul trucks to show diesel performance with low emissions levels using low-cost LNG fuel.Retrofitting a Tier 1 engine with HPDI would provide emissions reductions below the EPA 2006 Tier 2 standards while maintaining the performance and efficiency of the Tier 1 platform. The longer-term target is the Blue Sky voluntary standards of 3.8 g/kW-hr (2.8 g/bhphr) of NOx + non-methane hydrocarbons (NMHC), and 0.12 g/kW-hr (0.09 g/bhp-hr) of particulate matter (PM) and future standards. Typically, an HPDI engine is capable of reducing NOx emissions by 40% over diesel operation at the same efficiency. On a mining truck meeting Tier 2 standards, this NOx reduction would translate into NOx emissions approximately 14 t per year lower than under diesel operation. PM emissions are typically reduced by some 60% with HPDI fueling, which would translate into a yearly reduction of 650 kg. Similarly, engine-out greenhouse gas (GHG) emissions are reduced by 21%, resulting in a yearly reduction of approximately 950 t per vehicle.Above those of emissions reduction, efficient natural gas usage in mine haul operations would offer significant benefits in terms of fuel cost savings, which may be further combined with monetary emission credits. HPDI technology would enable operators to exercise environmental stewardship while gaining a competitive advantage in advance of new Tier 2 and Tier 3 emissions regulations. The advantages of natural gas use among mine haul truck operations can be replicated across a broad range of engines and applications."

Jan 1, 2005

By J. Brent Hiskey

INTRODUCTION Metal electrodeposition processes are of fundamental technological importance to a number of fields. Electrorefining, electrowinning, electroplating, and electrogalvanizing have all been the subject of intense study for over a century. More recently, electrochem- ical deposition has played a critical role in advances in microelectronics and lately has been an enabling technology for the production of certain nanostructured materials. Electrometallurgists have most frequently been concerned with the structure and morphology of massive deposits. For example, in metal recovery steps such as electrorefining and electrowinning, deposits demonstrating adherent coarse-grained characteristics are most desirable. In the case of electroplating, a bright fine-grained, tenacious and strongly adherent deposit is required. The fabrication of microelectronic devices and the production of nanoscale structures such as nanoparticles, nanowires, and nanorods requires a keen understanding of early stage deposition effects. The initial stages of metal deposition, usually referred to as electroclystallization, are fundamentally linked to nucleation and growth phenomena. Early stage deposits are typically very ordered. Whereas, bulk metal deposition structures are much more ran- dom. In both cases, the discharge of a metal ion at an electrified interface is represented by simple cathodic reduction as follows: [ ] Me(H2O)xn[ ] is a hydrated metal ion residing in the bulk solution and Me is the metal atom occupying a crystallographic lattice position. A similar reduction reaction can be

Jan 1, 2005

By Mikko Ruonala, Pertti Lamberg, Olli Hyvärinen

The smelting of copper sulphide concentrate is the dominant route in copper production (Figure 1). Heap leaching of oxidized copper ores with weak sulphuric acid together with copper solvent extraction and electrowinning has gained popularity during recent decades, and it accounts for close to 20 % of primary copper production. Heap leaching offers advantages such as lower costs and consequently the construction of a production plant at a mine site is made possible. Limited resources of oxidized copper ores, the long leaching time of chalcopyrite and inability to recover gold inhibit this growth. The HydroCopperTM process developed by Outokumpu Technology at the laboratories of Outokumpu Research, Pori, Finland, is a new chloride leaching technology /1,2/, which offers an alternative to smelting and heap leaching (Figure 1). In the HydroCopperTM process sulphidic concentrates with various mineralogy and grade can be treated at the mine site to produce high-quality copper. Instead of copper cathodes the HydroCopperTM end products are copper wire rod, copper bars or copper billets. One of the advantages of HydroCopperTM technology is that gold can also be recovered in the process simultaneously /3/. To confirm the functioning of the new process and to dimension equipment Outokumpu Technology built the HydroCopperTM demonstration plant in Pori, Finland /4/. It has a capacity of 1 metric ton of copper per day. After testing with Pyhäsalmi copper concentrate in 2003, the first commercial demonstration run with Erdenet copper concentrate took place in 2004.

Jan 1, 2005

By Y Peng, D Wannas

In the fine particle flotation technologies being developed today the fine hydrophilic (gangue) particles are usually well dispersed. These highly dispersed fine particles can be recovered into the flotation froth product by mechanical entrainment. Flocculation of hydrophilic particles caused by polymer depressants could potentially reduce the mechanical entrainment of these particles. This paper reports testwork completed on fine particles of several solids, iron oxide, hydroxylapatite, galena and sphalerite, as well as on a relatively coarse quartz sample (-75+38 ¦m). Dodecylamine was used as a collector for the quartz, and several dispersants and polymer depressants, including sodium silicate, sodium metaphosphate, zinc sulfate, potassium dichromate, corn starch, corn dextrin and carboxymethyl celluloses (with molecular weights of both 700 000 and 80 000) were used as flotation modifiers. The major part of the testwork involved flotation tests in a 200 ml flotation column. Both water and solid recoveries were recorded. The degree of flocculation and dispersion was determined by settling tests in 250 ml graduated cylinders. It was observed that flocculation of the fine hydrophilic particles significantly reduced their mechanical entrainment, while dispersion severely aggravated it. Thus, in the flotation separation of artificial mixtures of the -75+38 ¦m quartz and fine iron oxide or hydroxylapatite, polymer depressants that caused flocculation were found to perform better than the ones that did not cause flocculation.

Jan 1, 2005

By Yannick Beaudoin

The source of base metals in modern seafloor hydrothermal systems can be attributed to leaching of host rocks by hydrothermal fluids and/or potentially by direct degassing of magma. From an economic perspective, metal grade is the most important consideration for seafloor deposits. Tectonic setting appears to be a key factor influencing the development of high grade seafloor base metal sulfide deposits. Back-arcs have a clear advantage over other settings in producing large and rich polymetallic sulfide ores. Microinclusions of magma or so-called melt inclusions trapped in phenocrysts of lavas have contributed to our understanding of the ore-forming process. n this study, we present data from 103 melt inclusions mainly in plagioclase crystals hosted in basaltic to rhyolitic lavas from 9 modern seafloor tectonic settings: oceanic back-arcs (Manus Basin including an ODP Leg 193 drill hole, Bransfield Straits), continental back-arc (Okinawa Trough), mid-ocean ridges (Explorer, MAR), seamounts (Foundation, Axial, Pito), and a transform (Garrett). Most sites host active hydrothermal systems that are producing polymetallic sulfides.

Jan 1, 2005