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By R-H Yoon

A turbulent flotation model has been developed by considering the subprocesses of collision, attachment, detachment, and froth recovery. AbrahamsonÆs model (1975) of infinite Stokes number is used to model collision, while the attachment and detachment subprocesses are modelled by considering the kinetic energies required to overcome the energy barriers and the work of adhesion, respectively. The energy barriers are determined by considering various surface forces, including electrostatic, dispersion and hydrophobic forces, while the kinetic energies are determined from the particle velocities at close separation distances from air bubbles. The latter has been determined by modifying the turbulent root-mean-square (RMS) velocities of Liepe and Moeckel (1976) and Schubert (1999) in view of a lubrication theory. In calculating the RMS velocities, it is assumed that a flotation cell is subdivided into low and high energy dissipation zones. The model predictions made by varying various hydrodynamic and surface chemistry parameters are consistent with flotation practice.

Jan 1, 2005

By Joseph Renk, David Akers, Glenn Shirey

Each year, US coal cleaning plants landfill or impound millions of tons of high-quality, fine-sized coal. This coal is not only difficult and expensive to capture during cleaning, but, if captured, can pose serious materials handling problems. The GranuFlow. Technology was developed and patented by the U.S. Department of Energy (DOE) to address these problems. GranuFlow involves the addition of a coal binding agent such as an asphalt or heavy oil emulsion to coal to reduce moisture, dusting, and freezing and to improve the flow properties of the coal in bins and chutes (1, 2, and 3). When the emulsion is added before mechanical dewatering, the binding agent causes the formation of fine-sized coal agglomerates that dewater better than untreated coal. In addition, the binding agent increases the capture of ultra-fine coal in screen-bowl centrifuges. Previous work by DOE has also demonstrated that such treatment results in a significant reduction in dustiness and a reduced potential to freeze. To address concerns about the handling and combustion characteristics of GranuFlow treated coal, DOE performed a pilot-scale pulverization and combustion test (4). No problems were encountered during pulverization or combustion, and use of this fuel in a p.c. boiler was found to be feasible from a technical perspective. CQ Inc. has an exclusive license from DOE to market this technology and is currently performing a series of commercial demonstrations to determine if GranuFlow is both technically and economically viable.

Jan 1, 2005

By Leon Maday, Robert Robinson, Judy Cochran, Don Davis

Over the past 20 years, several soft-ground tunnels have been successfully completed in the Seattle area. These tunnels were built using design-bid-build contracting methods, and have benefited from advancing technologies in exploration, design and construction methods. Owners have utilized various contractual means to share some of the risks that are inherent to tunneling projects. This has helped to foster a competitive bidding environment and to resolve issues related to unanticipated underground conditions in a fair manner. This paper presents case histories of tunnels constructed by King County and the Washington Dept. of Transportation that illustrate a common approach to design and construction issues. The common thread is successful project completion with minor cost changes under the design-bid-build contracting method. Lessons learned from these projects are being applied to the upcoming King County Brightwater Project tunnels, Sound Transit’s Light “Link” Rail tunnels and other tunnel projects.

Jan 1, 2005

By M. F. van der Merwe

Anglogold Ashanti?s Kopanang Gold Plant (previously No. 9 Gold Plant) treats ore from Kopanang and Tau Lekoa shafts. The plant is twin streamed and has dedicated treatment circuits, from milling to final product, for each shaft. Waste rock material is used to compensate for the mill gap on both streams. Each stream consists of three 4.85 m x9.15 m ROM mills in closed circuit with a single stage hydrocyclone, milling an average of 7 000 t per day. The liner configuration in each mill consists of six rows of 30 grid liners along with rectangular lifter bars. The topic of gold lock-up is not new and has been investigated and reported on many times, both within Anglogold Ashanti and the broader mining industry. Although the lock-up mechanism is understood, its measurement is neither practical nor precise. The initial lock-up in a new liner and the release as the liner wears down cannot be accurately quantified. Previous test work carried out on Kopanang Gold Plant (with a ?gold scanner?) measured the natural gamma radiation emitted by uranium. This radiation is in proportion to the mass of concentrate locked up in the grid liner pockets, as well as between the cast-on backing plate and the shell. The ratio of concentrate lock-up was estimated as 35% behind the liners and65% in the pockets. Mill gravity concentrates are recovered during routine relining operations from behind the grid liners at Kopanang Gold Plant. Prior to relining, the liners tend to release the concentrate from the pockets as the liners wear. Historical Kopanang data from actual ?mill gold? smelted indicates that an average of 29 kg gold is recovered from behind each row. This indicates a total lock-up of 250kg gold per mill. This locked-up gold should preferably be minimizedor eliminated for the following reasons: ?The cyclic build-up and release of gold in mills complicates accounting ?Gold concentrate arising from liners is a security risk and creates a major mechanism for gold theft ?Loss of interest on the value of 250 kg fine gold is significant and was a major driver for the project. These factors led to the need to develop techniques to eliminate or at least minimize the gold lock-up in the mills. Wave liners, with rubber inserts, have been successful in eliminating lock-up, and were tested at Kopanang Gold Plant in November 2000. However, due to increased load-slip and high wear rates associated with these liners, this option proved less economical in terms of liner wear. Grid liners, with rubber-filled pockets, demonstrated a very high wear life and eliminated pocket lock-up. This system was successfully trialed in January 2003, but unfortunately did not prevent lock-up behind the liners. Current developments have resulted in a system that eliminates both pocket and backing plate lock-up. The conventional grid liner design has been modified to remove its steel backing plate. Rubber inserts that are integrated onto a rubber backing plate, have been designed to be used with the newly modified grid. The backing plate and grid pockets are now completely occupied by rubber, thus completely eliminating concentrate build-up around the new grid liner system installed in November 2003. Results to date are promising and liner life is expected to exceed conventional performance.

Jan 1, 2005

By V. Schwinn, P. Fluess, N. Cauderlier, J. Bauer

From a strategic and economic point of view, the development of fine grain high strength steels for long distance pipelines is intensified world wide to satisfy the demand for natural gas in the future.The project related property profiles based on strength, toughness, crack arrest and sometimes resistance against HIC at defined design temperatures require an effective structural refinement using advanced steelmaking and processing in the rolling mill. The microstructure of modern line pipe steels ranges from ferritic pearlitic to ferritic-bainitic and structures where bainite is the dominant component, possibly upgraded by secondary phases. This paper illustrates microstructures and properties of recent orders on line pipe steels both for onshore and offshore application using different processing routes in the plate mill. Examples will be given for SAWL 485 offshore grades, X65 HIC and X70 HIC onshore grades, respectively. Finally, production results of a recent X80 order will be presented.

Jan 1, 2005

By T. P. R. de Jong, H. Harbeck

"This contribution reports recent mineral sorting experience and lists the opportunities of the newest generation of automatic sorters with a special focus on electromagnetic detection and Xray transmission. With the available sensor resolutions and actuator systems that are available today sorting of minerals down to 2 mm size and up to 250 mm lump size is technically feasible. In industry, ore as well as coal is still hand-picked and current automation potential only utilised in a handful of specific applications. Recently a number of technological developments took place that may increase sorting potential, save mill costs and lead to lower overall tonnage costs.They are:??High speed and high resolution sorting systems based on X-ray transmission imaging??High speed on-line image processing and further development of advanced data processing??Modular multi-sensor automatic sorting units (using one or more sensors such as colour, electromagnetic and X-ray in a single device)??Sensitive electromagnetic sensors for sorting based on differences in magnetic susceptibility and electric conductivityThe above enables compact dry separation, insensitive for moisture fluctuations and at high separation sharpness, as well as “electronic” high gradient magnetic separation for larger particles. Besides conventional X-ray transmission (XRT), dual-energy XRT (DE-XRT) is now being redesigned to meet the requirements of the mining industry. The mentioned technologies provide automatic dry separation of minerals and rock as alternative for conventional processing."

Jan 1, 2005

By K. Feindel

The distribution of water in operating fuel cells must be carefully managed to optimize the performance, durability, and functionality of the system. For example, the ionic conductivity of polymer electrolyte membranes decreases as membrane hydration is reduced. Flooding at the cathode inhibits mass transport, and it can lead to failure of materials. Build up of liquid water in the gas flow channels of a fuel cell stack will create a non-uniform distribution of pressure drops across the individual cells. We will discuss the application of 1H NMR microscopy to investigate in situ the production and distribution of water throughout an operating H2/O2 polymer electrolyte membrane fuel cell. Polymer electrolyte direct methanol fuel cells posses high theoretical storage capacities as power systems for portable electronic devices. There are, however, two long-standing hurdles to development of practical methanol fuel cell systems. First, the electro oxidation of methanol at the anode of the fuel cell is poisoned by absorbed carbon monoxide, an intermediate in methanol electro oxidation. Second, methanol readily crosses over from the anode to the cathode of the fuel cell. This methanol crossover wastes fuel, and it poisons the electro reduction of oxygen at the cathode. We are investigating use of 2-propanol as an alternative to methanol as a fuel. 2-Propanol is less toxic than methanol, and it is less prone to crossover from the anode to the cathode. More significant, however, is that the electro oxidation of 2-propanol to acetone is faster than the electro oxidation of methanol because it avoids formation of adsorbed carbon monoxide. We will present active catalyst systems for the electro oxidation of 2¬propanol to acetone in fuel cells. We will also present methods to convert the resulting acetone back into 2-propanol, possibly leading towards rechargeable portable fuel cell systems.

Jan 1, 2005

By Fumito Tanaka

The Mitsubishi Process is the sole pyrometallurgical process for the continuous production of blister copper from copper concentrates. Continuous converting originates from the application of the proven technology of a lime-ferrite slag (CaO-FeOX-Cu2O) on the Converting Furnace (C-furnace). Recent improvements on the C-furnace operation have included increasing the processing of recycled materials and the investigation of alternative fluxing agents. However, some minor oxides adversely affect C-furnace operation, with respect to magnetite behavior of the slag, with the most significant impact having been observed with the silica content of the slag. This paper will quantify the impact of silica on the lime-based slag, and discusses the controls that have been identified to sustain continuous converting operation.

Jan 1, 2005

By A. Glover

As the demand for natural gas as a prime global energy source continues to grow, the search for new sources of the fuel spreads into geographical areas that are more remote from the marketplace. Along with this comes the need for longer and ever more efficient pipelines. This requirement for higher value in natural gas transportation is satisfied to a large extent through the application of high strength technology and innovative design approaches that support increased design and operating pressures. This paper reviews the latest accomplishments and successes in these technologies for use in gas transmission. It also explores some of the technologies which are targeted for the future to allow the industry to achieve even higher benchmarks in reliability and cost-effectiveness. The central element in the theme of high strength technology for gas pipelines is that of high strength steel. From tensile strengths of Grade 359 a few decades ago, more and more operators are now specifying Grade 550 linepipe for their large diameter projects. As well, Grade 690 steel is operating successfully in limited transmission applications and Grade 825 has recently been installed. With the introduction of the latest high strength pipe comes the need for high strength fittings. The industry's first Grade 550 fittings were recently specified and installed on a project with Grade 825 line pipe. High strength materials can only be implemented successfully if compatible design and construction processes are in place. The latest developments in strain- and reliability based design will be described as well as the corresponding advancements in welding and inspection technology.

Jan 1, 2005

By E. Snyders

The upgrading process of an inferior grade of zircon to a superior opacifier for ceramic applications was investigated. A calcining process in the presence of mineralizers was used to produce the product in a conventional muffle furnace. A pre-milled inferior grade zircon concentrate, with a relatively high iron and alumina content generally not suitable for high quality ceramic applications, was used in this study. The influence of the upgrading process on the opacifying properties of the zircon material was compared to that of commercially available prime grade zircon opacifier products currently being produced in South Africa. The influence of a calcining step in the presence of mineralizers with regard to the milling characteristics of the treated zircon material was also evaluated in this study. The morphology of the treated and untreated zircon opacifier samples were investigated by SEM micrographs and the colours of zircon samples were characterized on the grounds of the Commission Internationale de l`Eclairage (CIE) standard procedure (CIE L* a* b* measurements) after application on a bisque ceramic tile. It was found that the treatment improved both the milling as well as the opacifying properties of the treated inferior grade zircon concentrate and renders it equivalent to or better than prime grade zircon opacacifiers currently produced. Keywords: ZrSiO4; opacifier; colour; milling; calcining.

Jan 1, 2005

There is an increasing demand for refrigeration as mines progress deeper. Mine refrigeration plants have special requirements in terms of their duty and application. There are no national or international standards applicable for the testing of these plants. There have been numerous examples of plants failing to meet their required nominal capacity, but with the plant owner being unable to enforce the design duty on the manufacturer, due to a failure to unambiguously specify testing or accepting criteria. This paper discusses some of the reasons for performance shortcomings and describes a methodology for developing and specifying performance criteria, when inviting design and/or construction tenders, and a method of performance and acceptance testing once the plant has been built and commissioned. These guidelines encompass the full range of performance duties expected from a mine plant, including stable operation at maximum and minimum plant capacity, and under the various combinations of extremes of high and low condensing and evaporating pressures. A description of a methodology for developing a computer-based mine refrigeration plant model is also presented as part of the performance testing criteria. The methodology is illustrated with reference to the actual performance and acceptance testing process used on the worldÆs largest bulk air cooler (R67) at the Enterprise mine at Mount Isa, Australia.

Jan 1, 2005

By B Delaney

For worker safety, mining companies are required to stop production and inspect hoist ropes. Visual inspection is generally done daily and EM inspection occurs every three to four months. During visual inspection, rope speed is generally reduced so an inspector can look for problems. In EM testing the LMA and LF traces are printed on a paper strip chart and a skilled operator interprets these traces. Mining companies only find large defects during visual inspection and are sometimes concerned about the content of EM trace information. This paper will present research outcomes that show how muck can be hoisted while performing a complete visual rope inspection at full speed. Other research results will show that digital signal processing can increase the amount of information available to the EM rope inspector. The research was funded by Inco, C-CORE, three AMIRA International sponsors and six sponsors from the Canadian Deep Mining Research Consortium (DMRC). The research will be commercialised in 2005.

Jan 1, 2005

By G. Baldermann, Hüttenrauch

Occupational health and safety are an important tool to increase a company’s economic efficiency. The integration of safety-related tasks into the overall structure of entrepreneurial tasks is an inalienable requirement for the sustainable achievement of positive effects. Investments into technical and personnel occupational safety that are tied in a streamlined organizational structure guarantee the improvement of defined indicators. The labor force is of central importance. Its added value ought to be ensured. It is necessary to move away from the employees‘ hazard awareness towards a safety awareness including many other aspects in order to save costs in the long run.

Jan 1, 2005

By Kokichi Iizasa

Two major Kuroko-type deposits and minor sulfide deposits have been found in the middle Izu-Ogasawara (Bonin) Arc, Japan (Fig. 1). The Hakurei deposit, one of the major Kuroko-type deposits, was recently found in Bayonnaise knoll caldera in the nascent rift zone, which lies 20 km westward of the Sunrise deposit in Myojin knoll caldera on the Izu-Ogasawara volcanic front. The Hakurei deposit is a huge hydrothermal field measuring 500 m by 700 m in plan view. The Bayonnaise knoll caldera is mainly composed of dacite lavas and fragmental material on the caldera wall and rim, and its floor contains sediment composed of pumice, volcanic fragments, and hydrothermal clay. It is associated with a post-caldera dome and has a slightly ellipsoidal caldera rim that measures 3 km by 2.5 km, with about 200 m relief. The water depths of the caldera floor range from about 840 m to 920 m. The Kuroko-type deposit in the Bayonnaise knoll caldera occurs on the southeastern caldera floor where the caldera boundary faults intersect with a N-S-trending normal fault of the rift zone. In the deposit, many sulfide chimneys are generally less than 10 m high, and sulfide mounds are distributed around the caldera floor and on the sloping talus at the foot of the caldera wall. The deposit is buried in part by talus composed of pumice and volcanic fragments. Sulfide chimneys are still active, and inactive ones and their fragments are partly oxidized to reddish material. Chimney sulfides are mainly composed of sphalerite associated with chalcopyrite, galena, pyrite, and barite, and chemically enriched in Au up to 14 ppm and Ag up to 1400 ppm with major Zn, moderate Ba, and minor Pb, Hg, Cu, and Fe.

Jan 1, 2005

By Alaina B. Hanlon

Keywords: Undercooling, Convection, Dendrites, Stainless Steel, Levitation Certain Fe-Cr-Ni stainless steel alloys solidify from an undercooled melt by a two-step process in which the metastable ferrite phase forms first followed by the stable austenite phase. Recent experiments have shown that the lifetime of the metastable phase is strongly influenced by flow within the molten sample. The current research will provide insight to why flow affects the metastable phase. This new understanding will lead to the use of convection to control microstructural evolution in spray-forming of stainless steels. Simulations using a commercial computational fluid dynamics package, FIDAP, yield a range of convective flow velocities that cause mechanical damage to the dendrites which is compared to experimental results. If the convective velocities are great enough that the dendrites bend, then low angle boundaries form at the points of collision. These result in high energy sites that could serve as nuclei for the stable phase.

Jan 1, 2005

By Pengfu Tan

A program ?SlagVis? has been developed to simulate the liquidus temperature, phase compositions and viscosities of ZnO-CaO-SiO2-Al2O3-?FeO? slag, such as Imperial Smelting Furnace (ISF) slag and lead blast furnace slag, combined with F*A*C*T slag database and the mathematical model of slag viscosities based on a modified Urbain formalism. The modeling results have been validated by a number of measurements. The effects of slag compositions on viscosities of ISF slag and lead blast furnace slag have been simulated and discussed.

Jan 1, 2005

INTRODUCTION This paper was originally presented at the Platinum Adding Value Conference, held at Sun City from the 4th to 6th October 2004. Narrow reef mining may not be applicable to the base metal operations in Zambia, however, it is considered that the methodology used is equally appropriate to the development of technology and mining methods in mining environments other than narrow reef mining. The purpose of this paper is to explore the integration of technology and stoping systems. For the last hundred years the South African narrow reef mining industry has battled to control working costs in a labour intensive industry. It is only through the application of appropriate technology that change will occur. Stoping systems, because it is the stoping method and methodology that is at the heart of the mining system. Introduce a different technology that results in a more efficient stoping system and the mining system will look after itself. The technology applied to stoping in narrow reef mining, over the last 100 years, can be categorised as follows: ? The introduction of pneumatic rockdrills early this century. The cumbersome rig mounted units being replaced by smaller, lighter, hand held units that were then made easier to use with the addition of an air leg. (The so called Swedish method of mining.) As late as the early 1970s some drilling was still being carried out without the assistance of an air leg. ? Scraper winches to replace gravity and shovels to move rock both in the face and the gullies were first introduced in the late 1920s. ? Hydraulic props installed close to the face and capable of applying force against the hangingwall as well as yielding in a controlled manner under dynamic load arrived in the 1960s. In many instances these have now been replaced by yielding elongates fitted with water hydraulic tensioning devices. ? Some people argue that the introduction of tungsten carbide inserts, to improve drilling, was equally important.

Jan 1, 2005

By R. Y. Wan, J. D. Miller

Thiohydrometallurgical systems including thiosulfate, thiocyanate and thiourea have been stud- ied as alternative liriviants for the leaching of gold. Research and development of thiohydrometallurgical technology has been prompted by environmental concerns with the use of cyanide and problems associated with the processing of difficult-to-treat ores. These thiosystems have some chemical similarities, enabling gold to be leached in a practical oxidizing environment. However, the solution chemistry of the thiosystems is complicated due to instability of the thioreagents and many other reactions which occur during the gold leaching reaction. In this paper, interference reactions of selected metal ions and sulfide minerals are examined in order to understand important aspects of solution chemistry which control the stability of the thioleaching reactions. Applications using thioreagents as lixiviants for oxide and refractory gold ores are presented.

Jan 1, 2005

By G B. Arehart

The Midas epithermal system is one of the larger low-sulfidation epithermal vein systems discovered in the western US in recent years, containing in excess of 3 Moz of gold (premining). The deposit is spatially and temporally related to bimodal volcanism in the Northern Nevada Rift; dates on igneous rocks (16 - 14.7 Ma) bracket the age of high grade veins (15.3 Ma). Hydrothermal alteration at Midas is typical of epithermal systems, comprising proximal potassic through distal propylitic assemblages; in contrast to many epithermal systems, Midas has minimal development of wallrock illite/sericite. Mineral assemblages are clearly zoned on the vein structures that acted as focal planes for fluid upflow. Geochemical zoning patterns also show this zoning. Metals were deposited in open-space veins as the result of boiling of hydrothermal fluids; multiple episodes of crustiform mineral deposition are documented in the vein textures. The major vein minerals include quartz, adularia, calcite, selenides and sulfides, with electrum as the primary ore mineral. REE patterns for vein material are similar to patterns for coeval rhyolites, but distinctly different from patterns of the host rocks. Stable isotope data are consistent with meteoric water as the dominant ore fluid. Combined REE and stable isotope data suggest that fluid from which the main ore-bearing stage of the veins was deposited was slightly lower pH than other stages.

Jan 1, 2005

By Shu Yan

The high resolution resistivity method (HRRM) is developed specifically for detecting underground cavities and tunnels. HRRM has a special feature in that it can recognize and cancel static shift, which makes it different &om the high density resistivity method (HDRM). In searching for various means for detecting underground cavities, we found that the detecting depth of the transient electromagnetic field method (EM) depends mainly on the measurement duration, not the loop area. In addition, TEM can also be used to locate the high-resistivity bodies. In order to use them for local working site conditions, we combine HRRM with TEM to become a combined electromagnetic method. Since the late 1980's this method has been used to locate abandoned mines and air passages and burning centers of mine fires with great success. This paper cites case studies for which this technique was successfully used.

Jan 1, 2005