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By A. Anderko, R. D. Springer, R. D. Young

A thermodynamic model has been developed for calculating phase equilibria and other properties of multicomponent electrolyte systems. The model has been designed to reproduce the properties of both aqueous and mixed-solvent electrolyte systems ranging from infinite dilution to solid saturation or pure solute limit. The model incorporates formulations for the excess Gibbs energy and standard-state properties coupled with an algorithm for detailed speciation calculations. The excess Gibbs energy model consists of a long-range interaction contribution represented by the Pitzer-Debye-Hiickel expression, a second virial coefficient-type term for specific ionic interactions and a short-range interaction term expressed by the UNIQUAC equation. The accuracy of the model has been demonstrated for common acids and bases and for multicomponent systems containing aluminum species in various environments.

Jan 1, 2005

By Eric M. Hill, Daniel E. Walsh, Hsing K. Lin, John T. Hollow

The Fort Knox Mine is located in Alaska’s interior where the average ambient air temperatures range from -24°C in January to 16°C in July. The mill processes a free milling gold ore utilizing both a gravity recovery circuit and conventional cyanide leach/carbon-in-pulp circuits. Plant slurry temperature cycles seasonally and allows for a unique opportunity to measure the impact temperature has on gold leach kinetics, carbon adsorption efficiency and cyanide destruction reactions. Mathematical models have been developed to accurately predict actual mill performance. This paper describes the development of the models and presents data that allow for a better understanding of the impact of circuit operating temperature on process efficiencies.

Jan 1, 2005

By Gregory A. Hope, Kym Watling, Matthew I. Jeffrey, Ronald Woods

Surface enhanced Raman Spectroscopy carried out in real time has been applied to identify surface species formed during gold leaching in chloride and thiosulfate media. Chloride ion is adsorbed prior to the gold dissolution potential, but its coverage is significantly diminished at the beginning of leaching. A gold chloride band is again observed when dissolution is rapid, together with bands characteristic of AuC14- ions in solution. With thiosulfate, a thin gold sulfide layer is formed slowly in the potential region where leaching occurs. At higher potentials, thiosulfate is oxidized to sulfur and sulfate, both products being identified by Raman spectroscopy.

Jan 1, 2005

By Michael Trevits

The NIOSH Lake Lynn Laboratory (LLL) is a unique research facility, located about 50 miles southeast of Pittsburgh, Pennsylvania, that is designed to provide a full-scale mining environment for testing and evaluation of mine health and safety technologies. The LLL occupies more than 400 acres and is composed of surface test and training areas and an underground mine. The Lake Lynn Experimental Mine (LLEM) was built at an abandoned commercial limestone quarry where surface mining ceased in the late 1960's. Later, new underground development was constructed to simulate modern-day coal mining scenarios; including room-and-pillar and longwall mining layouts. In January 1994, a sinkhole opened southeast of the No. 4 Portal of the LLEM and since then, the area of the underground failure and surface deformation has continued to expand and now includes several interconnected sinkholes. A concern developed that the overburden instability could expand and affect the structural integrity of the nearby highwall and the No. 4 Portal. It was unsafe to conduct a detailed underground survey of the mine in this area because the mine roof conditions near the No. 4 Portal had deteriorated significantly. It was decided to investigate the overburden conditions near the No. 4 Portal using ground penetrating radar (GPR). A GPR survey grid was located along an access road that passes over the top of the portal. To delineate the mine conditions near the portal, antennas whose frequency spectra produced pulses centered near 100- and 200-MHz were used. The results of the GPR survey suggests that the overburden rock units appear to be laterally consistent to a depth of about 15-ft. Below that point, the overburden appears to be significantly disturbed and it was hypothesized that this area contains a large roof fall. A follow-up ground truth survey of the mine roof conditions was conducted from the mouth of the portal. It is concluded that the observations and measurements made from the radar records appear to be correct as a large roof fall was observed and measured from the mine portal area.

Jan 1, 2005

By D. McSwain-Santos

Soda ash is the trade name for sodium carbonate, a chemical refined from the mineral trona or naturally occurring sodium carbonate-bearing brines (both referred to as natural soda ash) or manufactured from one of several chemical processes (referred to as synthetic soda ash). It is an essential raw material in glass, chemicals, detergents and other important industrial products. Production U.S. soda ash production during 2004 increased to10.9 million Mt (12 million st). Five companies comprised the domestic soda ash industry. Four were in Wyoming operating five plants. One was in California with one plant.

Jan 1, 2005

By J H. Sullivan

Contents Background information Locality of Kumba?s Iron Ore Mines Sishen?s Product Specifications Geological Description of boreholes Sample Preperation Block delineations Production Geology Process Laboratory information Turnover times reached Inter Laboratory Comparisons Quality control activities in lab Purpose of laboratory Results attained Standard samples Monitoring of processes with QA/QC standards Mean paired difference of duplicates Duplicate samples Conclusion

Jan 1, 2005

By D Moss, P Ganza

There are continuing developments in underground narrow vein mining, from innovative mining methods using low-profile equipment to adaptations of current mining methods using equipment such as road-headers. The development of new mining methods and mining equipment has one purpose in mind û to extract narrow reef orebodies keeping dilution to a minimum, whilst maximising mining recovery. Achieving this will increase the head grade of the ore mined and reduce the tonnes delivered to the mill. Narrow vein mining in Australia has been limited to traditional hand held or mechanised drill and blast methods using existing æoff the shelfÆ equipment. Numerous trials have been undertaken using rock cutting technology and lower profile equipment, but these mining trials have not resulted in the full implementation of any new mining method or the adoption of low profile equipment in narrow vein mines as an accepted mining methodology. Mine operators in Canada and South Africa have teamed up with a number of equipment manufacturers and have taken steps to further mechanise and automate the mining of narrow vein orebodies, in particular to increase safety and productivity. The challenge to Australian narrow vein mining projects is to capitalise on work undertaken by overseas mining companies and equipment suppliers and to investigate the adaptation of low profile coal mining machinery to specialised metalliferous mining. With the inevitable fall in metal prices, it is necessary for Australian mine owners and mining contractors to apply these specialised methods and equipment to make narrow vein mining profitable.

Jan 1, 2005

By C. O. Aksoy, H. Kose, K. Ozfirat, T. Malli, A. Gonen, S. Gurgen

In selecting mobile mining equipment, factors including availability, useful economic life, maintenance and operating costs, and spare parts availability are considered. Given these factors, trucks and shovels with different capacities are selected. Optimizing equipment for pit and hillside quarry cases, where 8% and 10% ramps are commonly in use, were examined; the effect of other mining activities such as drilling and blasting on unit cost were considered. In principle, 20 m to 25 m high benches should be economical for downhill haulage, and 7 m to 10 m low benches economical for uphill haulage. However, practice of both mining styles favours 10 m to 15 m bench heights. Hence, the analysis here was carried out with the field experience bench height range. In the study, a truck-shovel optimization was based on the movement of 5 to 20 million cubic metres (in 2.5 million cubic metre increments) of overburden stripping at the Eynez open pit mine in the Soma region of Turkey. The outcome showed that low-capacity shovels were unfavourable due to high production expectations. High-capacity shovels were also unfavourable due to health and safety issues causing high instances of impact vibration on trucks during the loading cycle and a decrease in foreseeable unit lifetimes. The number of shovel passes required to load a truck ranged from three to six. Trucks with high-capacity bodies were deemed uneconomical due to high investment and operating costs.

Jan 1, 2005

By T J. Sheer

Water vapour refrigeration (systems using water as the refrigerant) could potentially be used to provide chilled water at underground locations in mines, as an alternative to conventional refrigerators using refrigerants such as R-134a. The use of water as both the primary and secondary refrigerants is attractive in concept since direct-contact heat exchangers could be used, yielding higher coefficients of performance. The disadvantage of water is the very high specific volume of the vapour at low pressures, which leads to great challenges in compressor design, as has been reported previously in the context of slurry-ice plants for mine applications (Ophir and Koren, 1999). Steam ejectors have long been known as alternative compression devices for refrigerators, but no work has been done previously on the possibility of using ejectors powered by high-pressure water, which is readily available in mines from long pipe columns in vertical shafts. This paper presents the results of a laboratory investigation into the use of high-pressure water as the motive fluid in an ejector refrigerator. No previously reported liquid ejector system has achieved subcooling of the process fluid, ie a reduction in fluid temperature within the evaporator to a level below that of the motive fluid. In contrast, the present work demonstrated that subcooling could occur at motive water pressures above 5 MPa. Mine cooling applications were considered and it was concluded that while this concept would not be feasible as a mine-wide cooling source, there could be specialised applications where it would be beneficial. One application would be to cool backfill and thereby reduce the heat load at the working face. In this case the best performance would be achieved by using the ejector in combination with an energy recovery system such as a Pelton turbine or a three-chamber pipe feeder.

Jan 1, 2005

Jan 1, 2005

By G. A. Achilleos

The insufficiency of Boolean Logic and ?hard? decision making to represent and manage spatial data in set with their spatial errors comprises a remarkable difficulty for widely accepted estimation procedures, in realistic planning of space geometric problems and management through a GIS. Fuzzy logic as well as other theories such as the theory of Probabilities, Bayesian theory etc., contribute substantially towards this direction. Data are accompanied by their accuracy and are managed through the applications and modules of Spatial Analysis, aiming to access a decision with known accuracy and fuzziness. As it concerns the cases of waste sanitary landfill sites designing, which are based on the construction of a bank, the problem shown by this paper, seems to be quite serious. The determination of the theoretical waste disposals body in the landfill is based on an uncertain Digital Elevation Model (DEM). As this model is a result of a procedure enclosing errors and inaccuracies, it is for certain a non - error free model. Thus, the geometric computation of the excavation quantities and the waste disposals solid body volume, misquotes the expected standard theoretical computation and imports the need to decide and set a risk level for the project.

Jan 1, 2005

By A. W. Bester

Paper written on project work carried out in partial fulfilment of B. Eng. (Mining Eng.) Cullinan Diamond Mine currently handles 3.2 million tons of run of ore per annum. This is done by means of an underground train system, which is located at 763 metre level. Four trains, one in each quarter of the pipe, collect ore from passes and transport it to centrally located tips in the north and south of the pipe. The ore is then split into coarse and fine fractions. The coarse fraction proceeds to the primary crushers in the north and south. Historically, mining has been performed in such a manner that an equal amount of ore has reported to each quarter of the pipe. However, the tonnage profile of the mine will change such that the ore will no longer be split equally. For approximately five years the majority of ore will report to the east and thereafter most of the ore will report to the western portion of the mine. This will continue for the remainder of the current infrastructure level?s operational life. Coupled with this is the fact that the mine is aiming to increase its annual production to 3.8 million tons. The result is that the current ground handling system cannot accommodate the additional tons and therefore alternative ground handling options have been investigated. The continued existence of Cullinan Diamond Mine relies on finding a system that can economically handle the additional tonnage. Three options were investigated. Firstly, a train option, which would be an upgrade of the current system, was investigated. Two truck options were also investigated, the first of which was a conventional truck option. The second truck option was more interesting and involved an unfamiliar Combi truck system. The truck options were investigated primarily due to the fact that the block height of the BA West (a new production block) can be increased by 15 meters if a truck option is decided upon. This would create a significant increase in revenue for the BA West project. Each of the options was assessed in terms of its physical and financial feasibility. In terms of the physical constraints, it was found that all three systems could work. Detailed financial analysis indicated that either of the two truck options would be a suitable solution. However, due to the limited information regarding the Combi truck option, it should be further investigated. This applies particularly to the actual running and maintenance costs for the equipment.

Jan 1, 2005

By H. Antrekowitsch

The decreasing quality of the input materials in copper recycling leads to a higher content of impurities in the anode copper. An improvement of the pyrometallurgical refining process is therefore necessary to produce high quality anodes for the copper refining electrolysis. The behaviour of the most important accompanying elements (e.g. nickel, tin, lead, zinc etc.) at different reaction conditions has to be investigated in order to improve the metal/slag reactions as well as the vaporisation by selective oxidation in the anode furnace. Therefore the thermodynamic conditions like reaction order and the activity coefficients at the copper refining process have to be known for the optimisation of this technique. Additionally the interaction between different elements has been investigated as a function of the temperature, the content of the elements and the slag composition especially for nickel. These investigations were done at the Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals.

Jan 1, 2005

By Luis Magallanes-Hernández

"Industrias Peñoles, S.A. de C.V. (Peñoles) in Mexico, is a major silver producer. The Peñoles Mining Division has eight Mining Operations and in seven of them, flotation is used to concentrate the metal and mineral values. Common metals and minerals values are: metallic gold and silver, gold-silver alloys, silver sulphide minerals (acantite, pyrargirite, argentite, proustite); lead sulphide mineral, galena; zinc sulphide mineral, sphalerite; and copper sulphide minerals (chalcopyrite and bornite).In the last years, a special emphasis has been given to using modal analysis to identify ore mineralogical limitations, in order to direct efforts into key areas where opportunities exist to improve the metallurgical results.This work aims to share Peñoles mineralogical and metallurgical results, through presenting, discussing and drawing conclusions on these results; as well as pointing out areas where more work is needed to improve the Concentrator´ performance.PEÑOLES BACKGROUNDPeñoles´s mission is to add value to non-renewable natural resources on a sustainable manner. It was established in 1887, and it is a mining group with integrated operations in smelting and refining non-ferrous metals, and producing chemicals. Peñoles is the world’s top producer of refined silver, metallic bismuth, and sodium sulphate, the leading Latin American producer of refined gold, lead, and zinc.Peñoles Mining Division is integrated into eight mining business, located on five different states in Mexico. Metal productions for the Mining Division during 2003 were: 343 thousand gold ounces, 48.4 million silver ounces, 81.3 thousand tons of lead, 235.1 thousand tons of zinc, and 10.6 thousand tons of copper."

Jan 1, 2005

By Shuangsuo Yang

Coal ribs can roughly be divided into three types: (1) roof and floor rocks are similar to ribs, (2) roof and floor rocks are stronger than ribs, and (3) roof and floor rocks are weaker than ribs. Different types of roof/floor and ribs will exhibit different types of ground pressure around an entry. Most coal mines belong to the 2" type with ribs fractured or even broken. In this case the mine ground pressure depends on the occurrence and development of deformation and fracture of the ribs. If it's not properly controlled, the following deteriorating process will follow: the roof bent downward > the ribs squeezed and broken > rib sloughing and collapse > rib support to the roof reduced > the roof bent downward further > the ribs broken further. In this paper rib instability is divided into four types: compression/shear sliding rib fall, gravity sliding rib fall, cross arch rib fall, and cleavage rib fall. Since failure in thin walls is largely of tension type whereas that of thick walls by compression or shear, a concept is proposed here to utilize a thick bolted rib to stabilize entry ribs, i.e. the thickness to height ratio of the thick bolted ribs

Jan 1, 2005

By Thomas Barczak

Longwall mines typically use some form of standing support for secondary roof support in longwall tailgate entries. Although there have been several new support products developed for this application, there remains no universal design criteria to optimize the application of these support technologies. The requirement for optimization and proper support selection is to understand the degree of control that the support has on the ground behavior. The ground reaction curve and numerical modeling was used to evaluate the impact of standing support on ground behavior. LaModel was used to evaluate the impact of standing support on main roof and floor behavior and pillar yielding. The conclusion drawn from this study was that standing supports do not have sufficient capacity to control main roof or floor loading or prevent the resulting convergence of the tailgate entry. However, it is imperative that this "uncontrollable convergence" be considered in the support design to prevent premature failure of the support. A FLAC model was used to evaluate the near-seam roof and floor behavior in conjunction with the global vertical and horizontal stresses. The model suggests that standing roof supports can have some impact on the ground behavior as the elastic response of the rock is exceeded and rock structure deteriorates from the stress concentrations that develop around the tailgate opening. During this phase, the capacity and stiffhess of the standing support can be critical to the stability of the opening, as eventually the rock mass will be transformed into a partially detached structure whose weight must be supported by the standing support. This work is part of a ground control program of research at the National Institute for Occupational Safety and Health (NIOSH) aimed at improving mine safety by reducing roof fall injuries and fatalities.

Jan 1, 2005

By D Cotnoir, Q Liu, D Richard, M Ourriban

The difficulty in fine particle flotation has been attributed, among other things, to a low bubble-particle collision efficiency. Many technologies have been developed which aim at increasing bubble-particle collision efficiency, either by generating micro bubbles or by enlarging particle sizes. However, commercial applications of these technologies are limited. Over the last five years COREM has been actively testing fine particle froth flotation technologies with the objective of commercialisation. Several fine particle flotation technologies, such as dissolved air flotation, electro-flotation, floc flotation, selective flocculation-flotation and carrier flotation, were tested on both single minerals and ore samples in order to identify the reasons that prevented these technologies from being used on a commercial scale. It was found that the two most noticeable factors that prevented the successful application of these technologies were: Mechanical entrainment of fine gangue minerals. This was a general problem in fine particle flotation, but was aggravated by these technologies that either generated micro bubbles or enlarged the sizes of hydrophobic particles. Oxidation of (sulfide) minerals that resulted in hydrophilic oxidation product coatings. The oxidised fine particles could not be recovered by these fine particle flotation technologies effectively. Solutions to the two problems, ie gangue entrainment and fine particle oxidation, were proposed and tested. It seems that polymeric depressants with both depression and flocculation functions could significantly reduce gangue entrainment, and hydrophilic surfaces of oxidised fine particles could be modified by high intensity conditioning or controlled sulfidisation, thus increasing the recoveries of fine valuable minerals. The improved fine valuable particle flotation and reduced fine gangue entrainment along with fine particle flotation technologies resulted in much improved flotation separation of fine particles.

Jan 1, 2005

By J. Gunaselvam

This article deals with an investigation into the specification and use of appropriate seating systems to reduce whole-body vibration (WBV) exposure in typical vehicles used in the SA mining industry. The EU Directive EU/44/2002 to be legislated in 2005 in European countries, provides legal and economic motivation for this project. The criteria for seat selection can be condensed to the requirements in the directive, which mandates an action level of 0.5 m/s2and a vibration exposure limit of 1.15 m/s2 for an equivalent 8-hour daily exposure period. As part of this study six suspension seats, which the manufacturers claim satisfy the requirements in ISO 70966, were tested to determine the most suitable seat for an articulated dump truck. Six test subjects, three ?light? and three ?heavy? as specified in ISO 70966, were used to estimate the seat transmissibility functions in the vertical direction of the six different suspension seats. Transmissibility functions were measured in the laboratory with two excitation levels of 1 m/s2 and 2 m/s2 r.m.s. in the 0.5?30 Hz frequency range, as well as one spectrum approximating the EM5 spectral class. SEAT values were calculated for road vibration data measured on a typical articulated dump truck. A set of seat selection guidelines that can be followed by vehicle manufacturers and suppliers, procurement officers and and the technical staff on a mine is proposed in this article. It is recommended that additional studies of the use and operating conditions of seating systems in the SA industry, as well as an epidemiological survey be commissioned to gather additional information on this subject. Nomenclature ADT Articulated dump truck DSTF Dynamic seat testing facility EM1 Frequency spectra associated with earth moving equipment (?articulated or rigid frame dumper?) according to ISO 7096 EU European Union ISO International Standards Organisation PSD Power spectral density r.m.s .Root mean square SEAT Seat effective amplitude transmissibility WBV Whole-body vibration

Jan 1, 2005

By K B. Barnard, M D. Urbani

A synergistic solvent extraction (SX) system for nickel and cobalt recovery using Versatic 10 and decyl-4-pyridinecarboxylate was tested with BHP Billiton pilot plant leach solution. Another synergistic SX system for cobalt and zinc recovery was successfully tested using Baja MiningÆs pilot plant leach solutions. Synergistic SX systems have also been developed to separate iron, zinc and copper from nickel and cobalt for Minara Resources and to separate manganese from magnesium and calcium in waste stream for HiTec Energy. The gypsum precipitation problem at the former Bulong operation could have been alleviated using a Versatic 10 and CLX50 synergistic SX system. These synergistic systems have shown high selectivity for target metals over impurity metals and would largely improve SX plant operation. Maintaining a æhealthyÆ organic is very important for efficient plant operation. Careful analysis of plant organic at CSIRO has been used as a tool to pre-empt and/or solve problems in operating circuits. Work performed to assist operators has included assessing plant organic solutions to highlight impurity build-up with time, assessing reagent stability under prescribed operating conditions, correlating organic composition with impurity transfer and crud analysis. An independent estimate has determined that work in this area by CSIRO has provided over $50 M in benefits to the industry.

Jan 1, 2005

By G. Rehder

The release of methane as free gas from the seafloor into the water-column well within the hydrate stability field is a natural process observed today in various ocean settings, such as the Cascadia margin, the Black Sea, the Guayamas Basin, and the Gulf of Mexico. The subsequent dissolution of gas bubbles into the water-column determines the vertical distribution of aqueous methane in the water-column and the upwards methane flux. Understanding this process not only is essential to describing the impact of natural deep-sea gas seepage, but also to assessing the hazard potential from blowouts and offshore exploitation activities, which are steadily expanding to greater ocean depths. Furthermore, the fate of methane from seeps contributes to scenarios of global change in the past and future involving the large scale destabilization of gas hydrates on a. We recently reported on the extended lifetime of methane bubbles within the hydrate stability field due to the formation of a hydrate skin (Rehder et al., 2002), based on in situ measurements of methane and argon bubble dissolution in the depth range 400 to 800 m. More recently, these observations were extended to depths from 900 to 1500 m. Single bubbles were injected from the ROV Ventana into an attached, back-illuminated, flow-through imaging box. The ascent of individual bubbles within the imaging box was recorded with Ventana?s HDTV camera system by piloting the 3-ton ROV upward, at the bubble rise velocity, for up to 400 m of vertical transit. Observed rise velocities were approximately 30cm/sec for all depths. Post-dive analysis of the HDTV video allowed detailed measurements of the bubble shrinking rates. The results of the earlier and new experiments lead to the following conclusions: (A) Methane bubbles released below the hydrate stability field showed markedly enhanced lifetimes, attributed to hydrate skin formation. The change in radius with time, dr/dt, varied from -7.5 micrometer/s above the hydrate stability field to about -1 micrometer/s at the deepest release depth. (B) Bubble lifetime within the hydrate stability field increased with distance in P-T space from the hydrate phase boundary. (C) Before hydrate skin nucleation, dr/dt for CH4 bubbles was comparable to dr/dt above the hydrate stability field. Although variable, the onset time for the hydrate skin effect to occur generally decreased with distance from the hydrate phase boundary (super-pressurization and super-cooling with respect to hydrate formation). (D) Even before the onset of the hydrate skin effect, a slight decrease of dr/dt with increasing depth was observed.

Jan 1, 2005