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By X. Z. Yuan

Contamination introduced by the impurities from the feed stream can impact the PEM fuel cell performance dramatically. The presence of these unwanted trace species such as CO, H2S, NH3, can adversely affect the fuel cell functioning. It has been reported that the major impact of CO and H2S contamination on the fuel cell performance is kinetic while the effect of NH3 contamination is speculated as membrane conductivity reduction only. In this paper, a model regarding the NH3 contamination is described and the mechanism of the NH3 contamination is illuminated by the model calculations.

Jan 1, 2005

By R. P. Hackl, P. G. West-Sells

Carbonaceous gold ores are particularly attractive for leaching by ammonium thiosulfate as the gold thiosulfate complex is not significantly adsorbed by the organic carbon present in the ore. A technically and economically feasible process for treating these ores with ammonium thiosulfate has been developed. In this process, gold is extracted by leaching the ore with ammonium thiosulfate, the solution is separated from the ore by counter - current decantation, the gold is recovered by precipitation with ammonium sulfide, and finally the gold containing product is upgraded by reacting the elemental sulfur present in the precipitate with ammonium sulfite. The precipitation filtrate is recycled back to the grinding step to close the solution balance. Reagent consumption is not excessive. Besides precipitating gold, the precipitation step removes most deleterious solution impurities and converts a portion of the polythionates back to thiosulfate. This paper discusses the optimization of the leaching, precipitation, and upgrading steps. The results of a 10 kg/h pilot plant campaign are also discussed.

Jan 1, 2005

By S R. Grano, M Vera

This paper deals with two separate case studies investigating the froth phase performance and characterisation of two industrial rougher/ scavenger flotation circuits. Froth phase performance was quantified using a mass balance approach to estimate froth zone recovery. Measured characteristics of the froth phase included frother solution concentration determined by gas chromatography, and the time taken for an equilibrium froth sample to decay to one-half of its original froth height. The latter measurement is referred to as the æfroth half-lifeÆ and is strongly linked to froth stability. Special methods and techniques developed to preserve frother in solution and to measure froth half-life are briefly described. The frother type in the first case study was a mixture of straight and branched alcohols, whilst the frother type in the second case study was a mixture of alcohols, aldehydes and triethoxybutane. The first case study focussed on a flotation circuit treating a low-grade ore containing only a small fraction of floatable copper sulfide minerals, while the second case study focussed on a flotation circuit treating a higher grade complex sulfide ore containing significant quantities of chalcopyrite, galena, sphalerite and pyrite. It was found that froth zone recovery of valuable mineral generally decreased down-the-bank of the two industrial rougher/scavenger circuits. Moreover, decreases in froth zone recovery significantly limit the overall cell recovery of valuable mineral achievable from the plant scavenger cells. However, the decrease in froth zone recovery could not be linked to the removal of frother from the pulp solution to the concentrate product in the preceding rougher flotation stages. Measurements of residual frother in solution suggested that, approximately, only five to ten per cent of the added frother was removed into the rougher/scavenger concentrate, with the remainder appearing in the scavenger tailings. This finding suggested there was apparently adequate frother in solution in the scavenger stages.

Jan 1, 2005

By Gregory B. Poole

As part of a $3.5 billion program to improve the antiquated waste water system in the city of Atlanta, the Nancy Creek Tunnel is being constructed across the northwest portion of the city. This tunnel is over eight miles long and is being constructed using Tunnel Boring Machines (TBM) for the majority of the tunnel and conventional drilling and blasting for three shafts, starter and tail tunnels and four connecting tunnels, totaling 2400 feet in length. An extensive public relations program was developed for this project. A group effort by the owner, engineer and contractor produced a public relations program that both informed and educated the public of the anticipated perceptions and effects of the blasting and TBM activities.

Jan 1, 2005

By Phil Pennington, D. Jack Adams, G. Ward Wilson, Virginia T. McLemore, Luiza Aline F Gutierrez, Rodney Shields, Steven Lockwood, Samuel Tachie-Menson

Microorganisms are directly or indirectly involved in many chemical alterations and in the decomposition of minerals required for their growth. Microbial dissolution of sulfide minerals under acidic conditions can produce over 1,000 times more Acid Rock Drainage (ARD) than chemical action alone. Microbial actions can cause precipitation of minerals, adsorption or release of metals, and formation/destruction of organic-metallic complexes. Soluble minerals can serve as oxidizing substrates, electron donors/acceptors in redox reactions, and can be directly involved in cell metabolism. Microorganisms and microbial oxidation-reduction reactions and their contribution to mineral mobilization and stabilization will be discussed.

Jan 1, 2005

By Li Chen

A new process, i.e. Ball milling--Neural leaching--Oxidation calcinations--Chloridizing distillation--Hydrolysis, was designed to recover germanium from the vacuum furnace slag produced in Shaoguan smelter. The suitable process and operational parameters were determined for the practical production.

Jan 1, 2005

By Gungor Tuncer, Ali Kahriman, Abdulkadir Karadogan, Mehmet Aksoy, Kagan Ozdemire

With increasing environmental constraints on the levels of disturbance induced by blasting operations upon nearby residents, there is an increasing need to be able to design cautious blasting with greater precision. Therefore, determination of maximum amount of explosive per delay for a certain distance especially in large blasts is of great importance for the elimination of these environmental problems. Although too many research studies had been carried out in the past in order to eliminate environmental issues produced from blasting unfortunately a general approach or formula has not been established yet because of the complexity of the matter. In addition to the wave and ground motion characteristics, the complexity of blasting parameters and site factors restrict the developing a general criterion. So experimental site-specific studies should be still done in order to predict and control blasting effects. This paper presents the results of ground vibration measurements carried out in Espey Open-Pit Boron (Colemanite) Mine located on the west side of the central Anatolia near Kütahya province in Turkey. Within the scope of this study, ground vibration components were measured for 13 shots during bench blast optimisation studies in order to predict peak particle velocity level for this site. In blasting operations; ANFO and Powergel Magnum 600 (blasting agent), Powergel Magnum (priming) and delay electric detonators (firing) were used as explosives. Parameters of scaled distance (charge quantity per delay and the distance between the source and the station) were recorded carefully and the ground vibration components were measured for all blast events using 4 different types vibration monitors (3 White Mini-Seis and 1 Instantel Minimate Plus Models). Then, the data pairs of scaled distance and particle velocity obtained from the 38 record events were analysed statistically. At the end of statistical evaluation of the data pairs, an empirical relation which gives average line at 95% confidence level and upper bound 95% prediction line with a reasonable correlation coefficient was established between peak particle velocity and scaled distance.

Jan 1, 2005

By D K, S Freij, A Rossiter, X Han, B Feng

In mining operations, the removal of overburden to expose the ores is achieved by rock blasting using ammonium nitrate based explosives, eg ammonium nitrate-fuel oil mixtures, commonly known as ANFO. However, ammonium nitrate can react with pyritic shales that are often found in many mines, leading to premature detonation or spontaneous explosion. In order to minimise the occurrence of spontaneous explosion, the reactivity of the shale in a mine must be assessed. This will provide a better understanding of blasting risks and thus will improve the safety and the cost efficiency of blasting through the selection of appropriate explosives. In this study, shale samples were collected from different locations in Western AustraliaÆs Mt Whaleback iron ore mine and geochemically characterised. The reactivity of the shale samples towards ammonium nitrate and ANFO was investigated using a combination of large-scale firing range tests and laboratory isothermal reactor tests. Results of the firing range tests show that the reactive ingredients of the shale are the limiting factor for the reactions between shale and ANFO. Based on the firing range test results, further isothermal reactor tests were conducted to investigate the reactivity of shale samples towards ammonium nitrate under controlled conditions. Analysis of the results from the firing range tests and the isothermal reactor tests shows that there are correlations between the reactivity of shale samples and several geochemical characteristics such as sulfate, sulfur, ferrous and zinc content.

Jan 1, 2005

Structure is the most important control on the location of hematite deposits in the Hamersley Province in the Pilbara region of Western Australia. Unravelling the structural history of mineralised areas, however, is complex because the Province underwent three orogenic events, and three regional extension events followed the main episodes of compression. Steeply E to ENE dipping normal faults immediately predated deposition of the Beasley Quartzite of the lower Wyloo Group after the Ophthalmian Orogeny. Steeply NE and SW-S dipping normal faults predated deposition of the McGrath formation of the middle Wyloo Group, following the Panhandle Orogeny. The resulting interpreted rift was subsequently reactivated and tilted during the Capricorn Orogeny. Late NE trending normal faults are confined to the eastern half of the Province. High-grade hematite deposits occur in rocks that range from intensely folded (Mt Whaleback, Giles Mini) to rocks with less, or only little deformation (Paraburdoo, Channar), suggesting that folding had at best limited influence on ore genesis. In contrast, extensional normal faults are always associated with high-grade hematite deposits, and in particular faults that link the underlying dolomites of the Wittenoom Formation with the overlying iron formation, thus providing a pathway for mineralising alkaline fluids.

Jan 1, 2005

In the human body, the balance between heat production and heat loss is continuously being disturbed, either by changes in metabolic rate (work being the most influential) or by changes in the external environment (heat stress), which alters heat loss. These changes in body temperature can adversely affect the function of body systems and organs. As a result, heat production or heat loss processes are triggered in order to restore normal body temperature (36 - 37¦C). If the heat generating systems of the body are excessive or the environment hostile then the capacity of the body to maintain thermal homeostasis is exceeded and can lead to a serious threat to health, or even death. This health deficit can severely affect an individualÆs capacity to work optimally; the end result is both poor productivity and health. Strategies to minimise or eliminate this effort will benefit both the health of workers and the productivity of companies. The principal strategies to reduce the effects of the environment on workers are: engineering interventions: to improve environmental conditions and reduce heat stress; and a comprehensive working in heat protocol: with provisions to identify risk situations and procedures to be adopted in relation to these. The above points will be discussed in detail with practical and simple strategies proposed to combat the deleterious effects of heat in mining.

Jan 1, 2005

By B. Anameric, S. K. Kawatra, K. B. Rundman

The iron nugget process is an economical, environmentally friendly, cokeless, single-step pig iron making process. Residence time dependent process requirements for production of pig iron nuggets at a fixed furnace temperature (1425 C) were investigated. Three chemically and physically different products were produced after complete reduction to iron, depending on the residence time in the furnace. These products were direct reduced iron (DRI), transition direct reduced iron (TDRI), and pig iron nuggets (PIN). The increase in the carbon content of the system as a function of residence time was detected by optical microscopy and Microhardness measurements. Sufficient carbon dissolution for the production of pig iron nuggets was obtained after 40 minutes residence time. The pig iron nuggets produced had chemical and physical properties similar to blast furnace pig iron. They were liquid state products and slag was completely separated from the metal.

Jan 1, 2005

By Bruce Hebblewhite

This paper focuses on the recent achievements and practices developed through the Minerals Tertiary Education Council (MTEC) initiative of the Minerals Council of Australia (MCA), in conjunction with the three partner universities involved in mining engineering education – University of New South Wales (UNSW), West Australian School of Mines, Curtin University (WASM), and University of Queensland (UQ). The collaboration between these partner universities and industry has led to the development of shared course material, cross-institutional teaching arrangements, and development of a number of flexible, distance-based delivery programs. The paper will then move on to future initiatives. Importantly, the exciting challenge is the future initiative planned to cement this collaboration by the formation of a “virtual” national school of mining engineering – Mining Education Australia (MEA). This will provide a common 3rd and 4th year program to all three universities from 2007, involving innovative teaching and learning arrangements, greater student exchange potential and a more significant input by industry into the education process. Such an initiative is not without its challenges, and has a long way to go, before becoming a reality. However, it offers greater attractiveness and marketing potential to prospective students, as well as economic efficiencies, whilst delivering a better quality, and hopefully greater quantity of graduates to industry. It can also form a launching platform for a much greater level of international collaboration, through a proposed International Mining Education Network (IMEN) which is currently being floated amongst a number of international educators.

Jan 1, 2005

By C. S. Kucukkaragoz

An ilmenite concentrate was reduced in the solid state with carbon under argon atmosphere at temperatures between 1000oC and 1400oC. The ilmenite concentrate and 50% excess carbon were reacted to achieve the highest attainable degree of reduction at each temperature and the reaction products were subjected to a series of analytical work by optical microscopy, X-ray diffraction analysis and SEM ( EDS) analysis. The ilmenite remained unaltered at 1000oC and had a slight change in its composition at 1050oC. A secondary oxide phase containing metallic nuclei was detectable at 12% reduction at 1100oC. The reduction of TixOy took place in a sequence changing the y/x ratio from 2.0 to a value less than 1.0 at 84% reduction at 1400oC. Metallic phase consisted of Fe and C initially and started to include Ti at the later stages. Complete reduction of TixOy to metallic Ti was not possible at these temperatures.

Jan 1, 2005

By Randall M. Wheeler, Kenneth K. Eltschlager

Blasting Seismographs use microphones to measure air overpressure from blasting. The microphone height above the ground has been the object of some controversy. The current ISEE “Field Practice Guidelines for Blasting Seismographs” specify microphone placement within 1.2 inches of the ground or over 3 feet above the ground. In this study, air overpressure measurements were taken at different height intervals and compared. Blasting seismographs constructed to the ISEE “Performance Standards for Blasting Seismographs” were used to monitor construction, quarry, and coal mine blasting. Near and far field measurements were taken to obtain representative spectral and amplitude ranges. The comparative analysis shows that microphone height has negligible impact on air overpressure measurements.1

Jan 1, 2005

By V Ser, I Smit, C Robertson

Anglo American has been researching the potential benefits of inter-particle comminution techniques for several years. Inter-particle comminution has additional benefits in terms of milling circuit performance such as energy consumption and stability. This paper focuses on the flotation benefits. Inter-particle comminution leads to selective breakage, mineralogical analysis has shown that this leads to improved liberation of the valuable minerals. In addition to selective breakage, the relatively short residence time experienced in typical inter-particle comminution machines allows more efficient classification which contributes to a æsharperÆ product size distribution. The effect of particle size in flotation has been well documented in literature. In general, it is has been shown that there is an optimal particle size range for flotation, and that both above and below this range, flotation recovery is adversely affected. Results show that the narrow size distribution which results from inter-particle comminution improves flotation recovery. Furthermore, the absence of excessive fine gangue material which typically results from conventional fine (-75 ¦m) milling of talcaceous ores, can lead to 100 per cent savings in depressant consumption when such ores are subjected to inter-particle comminution. To-date, this technology has been evaluated on more than ten ores. This paper will focus on one set of results which demonstrates a number of common differences that exist between material that has been milled conventionally and using inter-particle comminution technologies, with emphasis on what the impact of these differences is on flotation performance. A pilot scale (200 kg/h) vertical roller mill (VRM) was used to produce the material, and the results shown will describe conventional laboratory batch, locked cycle and pilot plant flotation testwork.

Jan 1, 2005

By B. T. Lu

The corrosion and wear properties of a series of chrome white iron (CWI) castings were study using electrochemical and low-stress sliding abrasion tests. The results confirm that the corrosion resistance of these materials is largely dependant on the quantity of chromium in the matrix, while the wear resistance is mainly controlled by the volume fraction of chromium carbides. A pseudo-wear/corrosion map is developed to identify alloy compositions that may be suited for erosion/corrosion conditions.

Jan 1, 2005

By O. Hyvärinen

Outokumpu has developed a new chloride leaching process called HydroCopper®. In this process copper sulfide concentrates are leached at atmospheric pressure in concentrated sodium chloride solution using cupric ions as the oxidant. Copper is recovered from the purified leach solution by precipitating cuprous oxide, which is then reduced to pure copper and further melted and cast directly into copper products. The key reactants: sodium hydroxide, hydrogen and chlorine are generated from the spent sodium chloride using chlor-alkali technology. An important feature in the HydroCopperTM process is that the gold contained in copper concentrates is leached as chloride complexes and recovered from solution by activated carbon. Conditions for the leaching of gold-bearing pyrite can also be achieved in the chloride system by optimizing the redox conditions. This paper deals with the basic factors affecting gold leaching from copper sulfide concentrates. Opportunities for the recovery of refractory gold associated with arsenopyrite and pyrite will also be discussed.

Jan 1, 2005

Away from past controversial presentations, a matter of fact, intuitive and simplified approach to the Theory of Sampling (TOS) sampling variance prediction formula is offered which gives an insight on the type of model required for the liberation factor, the practical limitations of such model and methodological principles for its calibration. This paper intends to see what happens in TOS when trying to go from the very simple towards the full level of real life complexity, and actually tries to answer the question: Is there such a thing as a æsimpleÆ TOS?

Jan 1, 2005

By Clyde Sitterud

Presentation Agenda ?Global Mining Tire Demand ?What is driving it? ?Latest Situation ?How long it will last? ?Michelin?s Response to Increase Supply ?New plant ?Additional presses ?Recommendations for Mining Users ?Treat tires as your major assets ?Areas of attention that will produce immediate results

Jan 1, 2005

By A. J. Romeo

The Old Hickory heavy mineral ore body, which lies within the Fall Zone of south central Virginia, has been mined since 1997. There are many differences in this deposit when compared to humate-laden mineral sands mines of southern Georgia and Florida. These differences include an abundance of kaolin-rich clayey sands, highly concentrated and iron-colored heavy mineral sand units, and a base of mineralization that is undulating. For these reasons, the selective approach of dry mining with track excavators is ideal. Grade control in this deposit uses traditional panning techniques and requires an intimate working knowledge of near-by drilling data. Mine geologists train equipment operators to recognize the base of mineralization by such characteristics as a stark color change, significant changes in grain size, and/or considerable, recognizable shifts in the concentration of heavy minerals. The regular pattern of mine site drilling does not always prepare the geologist and digging crews for occurrences of near-vertical contacts between the saprolite basement and the ore sands. These deformed areas, combined with undulating and pinching ore zones, require close monitoring and flexibility by the geologist and the mine operators.

Jan 1, 2005