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By M. Fafard, M. Dupuis, P. Goulet, J. Bédard

Start-up of a Hall-Heroult cell is a delicate task that can affect pot performance and pot life. Modem practices for high amperage cells involve preheating the lining before the molten electrolyte is poured in. Different preheating methods and heat-up schedules are used throughout the industry, and the optimum between a short start-up and damage minimization to the cell is elusive. Direct electrical coke-bed preheating is one of the most common techniques. This practice typically results in a non-uniform surface temperature distribution and can generate detrimental thermal gradients in the cathode blocks. Numerical modeling is an invaluable tool to study this complex problem and can help improve the preheating procedures. The modeling of the mechanical response of the lining is critical to detect risks of cathode block cracking or the development of gaps where liquids could leak into. Taking into account the baking of ramming paste, the quasi-brittle nature of carbon and the contact interfaces between different materials are examples of key elements to consider. A finite element slice model of a cell was built and simulations of different electrical preheating scenarios were performed using the inhouse code FESh++ to demonstrate what can be learned through thermo-chemomechanical modeling. The potential industrial application of the model is discussed.

Jan 1, 2006

By M Lund

Due to operational and regulatory practicalities, pit lakes will continue to be legacies of many open cut mining lease relinquishments. Unplanned or inappropriate management of these significant geographical features may lead to a short-term liability to all stakeholders during mining operations, or to ongoing liability to the local community and environment following lease relinquishment. However, the potential for pit lakes to provide benefit to companies, communities and the environment is frequently unrecognised and yet may be a vital contribution to the sustainability of the open cut mining industry. Improved remediation technologies are offering more avenues for pit lake end use than ever before, at the same time mining companies, local communities and regulatory authorities are also becoming more aware of the benefit these water resources have to offer. Sustainable pit lake management aims to better minimise short- and long-term pit lake liabilities, and yet also to maximise short- and long-term pit lake opportunities as well.

Jan 1, 2006

By H. Utsunomiya

Most magnesium alloy sheets show low deformability in rolling. Edge cracks and transverse fractures are common difficulties. In addition, rolled sheets show well-developed basal texture <0001>//ND. The texture causes high anisotropy in mechanical properties and low formability in subsequent metal forming. Differential-speed rolling, where the upper and the lower rolls rotate at different speeds, introduces shear deformation through the thickness. Not rolling texture but shear texture evolves in the sheet so that the asymmetric rolling can be a method of texture control. However the primary slip system of the hcp alloy, is basal, the shear texture should be also basal. Differences between the two basal textures, i.e., the rolling texture and the shear texture, have not been understood completely. In this study, conventional (same-speed) rolling and differential-speed rolling have been applied to commercial AZ31B sheets at 623K. Microstructures, textures and mechanical properties of the rolled sheets before/after annealing are compared. It is found that the basal texture is more pronounced by the asymmetric rolling. On the other hand, the asymmetric rolling is effective to decrease the grain size and the planar anisotropy.

Jan 1, 2006

By Kliment Y. Hakobyan

A new technology for treating molybdenum sulfide concentrates has been developed. It includes roasting the concentrate in a special regime with water vapor, cooling and neutralizing exit gas, oxidation roasting of rhenium containing MoO2, and the extraction of rhenium from exit gases. This technology allows economically efficient and environmentally safe processing of molybdenum concentrates: The degree of molybdenum extraction is 98.8%, rhenium-90%, sulphur-98.4%. The technology also ensures high extents of extraction of selenium and tellurium as well as the fixation of sulfur in the form of sodium sulfide or elemental sulfur.

Jan 1, 2006

By F. Habashi

Siberia, a vast country rich in mineral resources and a large number of different ethnic groups. To the east of Lake Baikal is Buryatia with capital Ulan Ude. The Buryat are closely related to the Mongolians. Ulan Ude is connected to Ulaan Baatar (Ulan Bator) the capital of Mongolia by train – a 26 hours trip. Getting a visa to Russia is not a simple case. Visits to metallurgical research laboratories, Lake Baikal, and historical museums are enriching experience.

Jan 1, 2006

By K. G. Tshilombo

It should be possible to use an oxygen probe to follow iron removal during converting, if local equilibrium is established between iron in the matte and the iron oxides in the fayalitic slag. The oxygen activity is expected to increase strongly as the iron content of the matte decreases (and the iron activity in the matte drops) while the iron oxide activity in the slag remains constant. To test this idea, oxygen activities were measured in synthetic mattes (made up of mixture of Cu2S, FeS and Ni3S2) when in contact with silica saturated SiO2-FeO slags, and silica and (initially) magnetite saturated SiO2-FeO-Fe3O4slags. The measurements were performed on laboratory scale at 1250°C, using an oxygen probe consisting of a stabilized zirconia electrolyte and Fe/FeO reference, and containing the sample in a silica crucible. Electrical contact to the matte was by means of a platinum wire. The measured oxygen activity was sensitive to the iron content of the matte, and insensitive to the composition of the gas atmosphere over the melt. The measured oxygen activity was generally close to that predicted by Fact Sage calculations. This indicates that such oxygen activity measurements could be useful to monitor iron removal during converting of nickel-copper-iron mattes.

Jan 1, 2006

By Raffaella Granata

The paper deals with the remediation of two areas formerly utilized for the disposal of hazardous wastes in a petrochemical plant. The works, designed on the basis of the criteria of maximum safety and minimum environmental impact, consisted in the confinement of the contaminated soil and groundwater within surface caps and perimetrical cut-off walls embedded in the underlying clay layer. The cut-off wall is 0.8 m thick and has a maximum depth of 33 m: it was designed to guarantee, as a minimum, the level of safety for a landfill for hazardous wastes, in accordance with the applicable National Standards. It was constructed with self-hardening mud and with the installation of an HDPE geomembrane. The HDPE liner of the cut-off wall was then sealed to that of the capping to obtain the complete encapsulation of the contaminated soil. A system of piezometers allows the monitoring of the cut-off efficiency measuring the fluctuations of the groundwater table and testing the chemical contents. Some wells installed within the contaminated areas will contribute to guarantee the full efficiency of the system in case of state of emergency, controlling the water-table level inside the confined areas.

Jan 1, 2006

By R. Debkowski

The current underground infrastructure of an old monumental salt mine along with using it as a tourist, museum, nature, resort, conference and cultural events place is presented in the paper. At present, mainly in the monumental part of mine, only a small part of the historical chambers, which together with galleries form a tourist route available to visitors. Moreover, the essential activities aimed to make the tourist route more attractive and to change the decor of the underground sites are discussed.

Jan 1, 2006

By E Widijanto, A Srikant

PT Freeport Indonesia operates a copper-gold mine located in the remote highlands of Papua, Indonesia, about 3500 km east of Jakarta. Currently, the district produces about 240 000 tonnes per day (tpd) of which about 45 000 tpd come from the DOZ Block Cave and the rest is mined from the Grasberg Open Pit. Over the next ten years, ore production from large block caves in the area is expected to reach about 200 000 tpd, replacing a large part of the production from the Grasberg Pit. Block cave mining alters the hydrological characteristics of the area being mined and when the cave expresses itself at the surface in the form of subsidence, it increases the entrapment area for surface water. Operating a large block cave mine in a region with an average annual rainfall of 5500 mm in steep mountainous terrain and complex geological and hydrological features presents a challenging scenario for dewatering or depressurisation of the area. The high rainfall infiltration and entrapment in stacked mines operating within an essentially single orebody, coupled with the presence of fine-grained and clayey material within the draw points of the block cave, creates mud rushes or wet muck spills, which can endanger the personnel and interrupt production. This paper outlines the problems caused by high water inflow into the DOZ Block Cave and the efforts undertaken to ensure the safety of the miners and continued achievement of desired production rates from underground mining in the district.

Jan 1, 2006

By Kirk Nobis

Develop a Risk Management Plan for Your Mine ? Why? ? Measuring ? Managing ? Conclusion

Jan 1, 2006

By John O. Marsden

The past fifteen years have seen a number of important developments in copper hydrometallurgy, including the commercial application of biological heap leaching of secondary (chalcocite-dominant) copper ores, the commercial demonstration of chalcopyrite concentrate leaching technology using pressure leaching and biological processes, and the application of novel configurations of solution extraction circuits. Significant emphasis is now being placed on the development of effective stockpile leaching practices for primary ores (chalcopyrite and bornite-dominant mineralization). Some of these developments have been highly successful, and will pave the way for further development and commercialization. Others have been less successful. These developments are reviewed in the context of the metal price cycle and trends for the future are identified.

Jan 1, 2006

By M. E. Reed

Clyde Materials Handling (CMH) and WorleyParsons have developed a concept for a flash furnace feed system using the specialist pneumatic conveying equipment expertise of CMH and the flash furnace process experience of WorleyParsons. CMH has developed a proprietary volumetric feeder (called a Rotofeed) which is extremely accurate and overcomes many of the problems inherent with loss-in-weight screw feeders and drag chain conveyors, previously regarded as state-of-the-art. Initial indications are that the Clyde-WorleyParsons Feed System could deliver the following benefits to Flash Furnace operation: ? Accurate pulse-less delivery of feed material to the head of the burner leading to improved combustion performance and process stability; ? Highly accurate split to the individual quadrants of a conventional burner tube, or provision of a smooth hollow curtain to a burner without guide vanes; ? Decreased pressure pulsation in the furnace due to improved combustion control and performance; ? Decreased temperature fluctuations in the furnace due to improved combustion characteristics and hence reductions in refractory thermal stress and wear; Plant measurements have indicated a correlation between the discharge of concentrate from the drag chain conveyor and high speed pressure fluctuations in the flash furnace settler. Pilot scale test have been conducted to illustrate that the system delivers pulse-less feed to the burner with even feed distribution axially.

Jan 1, 2006

By P J. Fourie, J R. Walklate

Gravity separation techniques have been in use in the mineral sands industry for decades; from the Reichert cone to Wilfley tables, Wright sluices and the Kelsey Jig, all attempting that elusive perfect gravity separation. Just as the gravity separation industry evolved, Richards Bay Minerals also evolved in their use and approach to gravity separation. This paper discusses the history of gravity separation at Richards Bay Minerals and briefly comments on future developments. History Primary Concentration Richards Bay Mineral?s (RBM) first mining concentrator and mineral separation plant commenced operation in 1977 to process ilmenite, rutile and zircon bearing dunal deposits along the northern Natal coast. The orebody contained a greater proportion of non-valuable magnetic heavy mineral in the SG range of 3 to 4 compared to West Australian and Florida USA deposits, making mineral separation more difficult(1). The deposit was mined using two dredges feeding a floating 2000 tph concentrator. Concentrator feed was screened and fed to two four-stage circuits consisting of primary, scavenger, cleaner and recleaner Reichert cones [see Figure 1]. The primary units were fed at a rate of 80 tph and a density of 60% solids by weight.

Jan 1, 2006

By W. Gan

The interactions between bitumen and quartz sands in aqueous solutions were studied with the objective of recovering residual bitumen from Athabasca oil sands froth treatment tailings. It was observed that the presence of various multivalent metal cation (Fe3-, Fe2+, Mg2+,Ca2+, etc.) increased the mutual coagulation between quartz particles and oil or bitumen droplets within certain pH ranges. While the increased coagulation was detrimental to the recovery of the bitumen since it lowered the degree of bitumen liberation from sands, this effect could be reduced or eliminated by the addition of organic chemicals such as citric acid, oxalic acid and EDTA. Among these organic chemicals, citric acid was found particularly effective even at very low concentration.

Jan 1, 2006

By Roberto Parada

In a long term program for the optimization of the Outokumpu Flash Smelting Furnace at Chagres Smelter many different subprograms are being developed. One of them is the design and application of a sampling method that can allow the direct diagnostic of the quality of the copper concentrates combustion. We present in this paper the evolution of the sampling devices used in a ten months of continuous sampling campaigns and an example for the sulfur elimination and magnetite formation in the flame from 60 cm to 100 cm under the burner. These type of information combined with the appropriate mathematical modeling of the combustion must propose some considerations to correct the classic criteria in the preparation of the charge for the smelting of copper concentrates based only on the mass and energy balance from the chemical and mineralogy composition of the concentrates.

Jan 1, 2006

By Marek Dworzanowski

Dense medium separation (DMS) is critical to the operation of coal and diamond beneficiation plants. It is also utilised in iron ore, manganese, chromite and andalusite beneficiation as well as pre-concentration for platinum-bearing UG2 ore. Gravity concentration plays an important role in the processing of diamonds, coal, gold, platinum, titanium minerals, zircon, chromite, iron ore and manganese. The DMS and Gravity Concentration operations and technology in South Africa conference will focus on the operation of DMS and Gravity Concentration circuits in the South African Mining Industry. The current status of the technologies and equipment employed will be presented as well as future developments. The conference was set up to showcase South African DMS and Gravity Concentration operations and provide a forum where operators, technology and equipment suppliers can engage in knowledge sharing. The papers cover a wide spectrum of topics, including descriptions of operations, optimisation projects, new capital projects, equipment applications, process monitoring and process selection. Most commodities and unit processes associated with DMS and Gravity Concentration are covered. The conference venue was selected to be the CSIR Convention Centre in Pretoria. The CSIR has contributed to DMS research in South Africa and it is located not far from many coal, diamond, gold, platinum and chrome mines that extensively utilise DMS and Gravity Concentration in their beneficiation plants. I believe that the papers and presentations submitted for this conference will provide a valuable future reference for DMS and Gravity Concentration, thus making the work of all the contributors to this conference highly rewarding and worthwhile.

Jan 1, 2006

By Ketan H. Trivedi

This paper describes the method of analyses used for the design of temporary and permanent Secant Pile Walls, describes various aspects of construction including, guide walls, sequence of pile installation, plan alignment and verticality tolerance, methods of drilling (auger, wash boring, cased and open holes), lateral bracing for secant piles, cutting of keys in secant pile walls for the connection of permanent floor slabs, sealing of water leaks and waterproofing. The paper concludes with a brief case history of a secant pile wall project recently constructed in New York City.

Jan 1, 2006

By Mike Fabius

The Lakehead Region Conservation Authority is responsible for slopes along the Kaministiquia River, one of the largest tributaries to Lake Superior in Canada. After arresting toe erosion for a mile of riverbank, the remainder of the slope required stabilization to stop further crest regression and to protect the houses, street and services at the top. Stabilization of the 100 ft. high slope was tendered as design-build with a target safety factor of 1.3 and a design life of 75 years. The successful bid was a system of 1.4 inch diameter soil nails up to 40 feet long, installed perpendicular to the slope on a 3 to 5 foot grid. The conventional shotcrete facing was replaced with a ?green? biotechnical facing and special transverse plate heads on the nails. The key to keeping costs low proved to be installation with light equipment working on the slope, and driving the nails without drilling or grouting. Rather than tension, the design was based on bending in the nails, similar to a laterally loaded flexible pile. The paper describes the design and installation of this innovative system. The design is discussed in terms of soil properties, nail resistance as it varies with depth, failure modes, corrosion protection, root design and nail head design. Construction challenges are discussed. The system is compared to an adjacent anchored soldier pile wall built along the same slope 20 years ago. Post construction monitoring results confirm predicted performance.

Jan 1, 2006

Current design guidelines for the surface catalysed oxidation of Fe(II) on Fe(OH)3 (Ochre) in passive mine water treatment systems are based largely on empirical data as the details of rates and mechanisms have not fully been revealed. Also the effects of elevated carbonate concentrations, typical of many UK minewaters, on the surface catalysed oxidation rate are unclear. In order to move away from empirical design and towards sound engineering that is based on geochemical and hydrological understanding it is necessary to quantify these reaction rates. In this study the effects of Fe(OH)3 and carbonate on the rate of Fe(II) oxidation by dissolved oxygen have been investigated with an aim to delineate the reaction mechanism. Experiments were conducted under well-controlled conditions. Preliminary results indicate that the surface catalysed reaction is an order of magnitude faster at pH ~6.4 with 200 mg/l Fe(OH)3 than the homogeneous rate and is dominated by an elevated rate of removal and oxidation of Fe(II) from the solution phase. It is also apparent that the oxidation rate of actual adsorbed Fe(II) is substantially retarded with respect to the homogeneous rate. Carbonates were not shown to affect the surface rate within the bounds of this preliminary study.

Jan 1, 2006

By Glen Mc Gavigan

The roof of the Sishen cave is being mined in order to exploit 6.8Mt of high grade ore. The cavity is filled with quartzite backfill in order to support the roof in the event of collapse. The cave dips at approximately 37o, is 260m along dip and 70m along strike and has a total volume of 261,391m3. GPS and optical monitoring techniques were attempted to detect subsidence but proved to be impractical. The GroundProbe Slope Stability Radar (SSR) uses differential interferometry to measure sub millimetre movement in a rock face. The SSR was applied in a non production situation and detected subsidences of 38mm/day before visual signs of instability were detected. The rate of deformation detected was slowing as a result of the roof coming to rest on underlying backfill. Monitoring during production drilling detected a sudden subsidence of 18.6mm/hour which resulted in the evacuation of personnel from the area. Further inspection of data showed that the rate of deformation was slowing and production was allowed to continue without further incident. The SSR has helped dispel the fears of workers and has proven that subsidence can be accurately measured and delineated with the SSR.

Jan 1, 2006