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By He De-wen

The influence of coal desulphurization by fungus was experimentally studied. The present results suggest that fungus can effectively remove inorganic and organic sulfur in coal. The main factors that influence the desulphurization by fungus such as pH value, temperature, coal slurry concentration and coal granularity are studied by orthodox experiment and the optimal experimental conditions are as follows: pH value 6, temperature 45 C, coal slurry concentration 10% and coal granularity 100 m. Under the above conditions, fungus can remove up to 44.96 total sulfur and 54.87 inorganic sulfur within two days and their desulphurization rates will increase along with time. Compared to sulfolobas, desulphurization by fungus is steady and more effective and has the advantage of high speed.

Jan 1, 2006

By Linda Duncan, Trevor Yeomans, Chris Potorieko, Michael Fullam

"NVI Mining’s Myra Falls Operation is a 4,000 mtpd copper/zinc flotation circuit with by product gold of ~28,000 ounces per year. Gold recovery has historically averaged 40-55%, however, a portion of this was recovered in the zinc concentrate and received poor payment. Two Knelson CD-30 Concentrators have been operating in the grinding circuit since 1992, with gravity recovery averaging about 2-5% over that time period.The Myra Falls gravity circuit was one of the very first hard rock mining installations operating in the world with automated Knelsons. The mine has employed a unique and unusual upgrading method for the Knelson concentrate that had never been evaluated as to its efficiency. Recent Gravity Recoverable Gold Testing by McGill University, and mathematical modelling of the Gravity Circuit by Knelson Gravity Solutions indicated the gravity circuit was not living up to its potential. Myra Falls Personnel changed the upgrade system-operating regime, and a complete gravity audit of the grinding circuit was carried out, with the results confirming the initial suspicions. Gravity recovery increased from 5% to 15%, with overall gold recovery improving by 5%.INTRODUCTIONNVI Mining operates a 4000 tpd mine and mill complex on Vancouver Island. The milling circuit consists of open circuit rod milling, closed circuit ball milling, gravity recovery, copper flotation, zinc flotation, and tails disposal. There are two milling circuits, “A” circuit, and “B” circuit."

Jan 1, 2006

By Jelke Dijkstra

This paper presents the results of model pile load tests in a photoelastic material. The soil in this test is represented by an assembly of photoelastically sensitive glass particles, which allows for optical measurements of stresses. In the same test setup, displacements around the pile are measured using digital image correlation (DIC). During the pile installation stresses and strains are recorded. Tests were performed in loose and medium dense particle assemblies. The development of stresses and strains around the pile tip and pile shaft are quantified and presented in this paper. For the loose conditions the results show a small influence on the stress state. For the medium dense conditions a clear stress change is observed.

Jan 1, 2006

By Nikolay Boykov

Subsurface imaging technologies are part of the electromagnetic (EM) geophysical methods. EM technologies such as radio imaging method (RIM), ground penetrating radar (GPR), and drill string radar (DSR) have great application potentials in the mining industry. However, the success for applying the EM methods to subsurface observations is largely dependant on the correct evaluation of the electrical properties (i.e., resistivity and dielectric constant) of the rocks in the domain of interest. The depth of penetration of the EM signal in coal, as well as the electrical contrast between coal and subsurface boundary rocks or anomalies, are critical parameters for any successful radar system. Based on the measured electrical properties of the coal seam, the proper operating frequency of the radar system must be chosen in order to successfully detect features such as the coal-roof rock boundary, dykes, and voids ahead of mining. The electrical properties of the rocks in a coal seam are frequency dependent. Even though there has been a great advancement in the hardware and data processing software in the past twenty years, there have not been many examinations of the high-frequency properties of coal measure rocks. In this paper, the laboratory setups, the testing procedure, and case studies will be presented for a wide spectrum of frequencies for coal measure rock samples collected from various US coal fields. Tests have been conducted to study the different conditions, including moisture content, that affect the EM properties.

Jan 1, 2006

By P Papanastasiou, J Hadjigeorgiou, E Kyriakou

The south west area of Cyprus has a long history of slope instability problems. The location and extent of these landslides has been influenced by ground morphology, geological structure and the presence of weak rocks and cohesive soils. The main triggering mechanisms have been precipitation and/or seismic events. Landslides have contributed to the decision to relocate villages and considerable efforts have been put into maintaining the integrity of the local transportation network. This paper uses a recent case study of road embankment failure near Pentalia in southwest Cyprus to review the available tools for the analysis of slope instability. It further demonstrates how the shear strength reduction technique can be used in a finite element analysis to better visualise the slope instability mechanism of a road embankment and provide a reliable tool in selecting appropriate remedial measures.

Jan 1, 2006

By F. Ajersch, A. R. Hekmat

Apparent viscosities of hypo-eutectic (Al-7% Al) and hyper-eutectic (Al-35% Si) binary alloys were measured in the semi-solid state using a Couette type viscometer at variable shear rates. Analysis of the microstructural evolution demonstrates the differences in the rate and degree of attrition of the primary phase particles which are characteristic of the thixotropic nature of the semi-solid alloy. It was observed that the Si primary phase in the hyper-eutectic alloy is much more difficult to fragment than the dendritic a-Al phase in the hypo-eutectic alloy. For the case of the a-Al, the dendritic structure is broken down by attrition and fracture of the dendrite arms whereas the fracture of the Si hexagonal crystals in the hypereutectic alloy occurs along the {100} and {110} cleavage planes. Results are presented for fixed solid fractions of the primary phase at isotherm condition for each type of alloy.

Jan 1, 2006

By Lifeng Zhang

The transport of fluid, heat and particles (bubbles and solid inclusions) in flowing molten steel is investigated in steel refining ladles, the continuous casting tundish, continuous casting mold and strand, and steel ingot casting processes. Inclusion removal from the molten steel by flow transport and bubble flotation, and inclusion growth by collision and diffusion are discussed. Removal of impurity elements such as [C] and [O] during steel refining are reported.

Jan 1, 2006

By Sergio N. Monteiro

Wastes generated by our society and the question on how to dispose them is, nowadays, a relevant matter of concern. The objective of the present work was to characterize the technical properties of composites made of discarded jute sackcloth with its coarse wove fabric, serving as reinforcement phase, and polyethylene wastes collected from city dumps, as continuous matrix. Different amounts, up to 30 wt.% of jute plain weave, fabric were press molded at 160°Ctogether with sieved polyethylene particles. The resulting composites displayed mechanical properties that could compete with those of low-density wooden board. Both by presenting a solution to, otherwise, disposed wastes and by helping to prevent deforestation, the investigated composite may be regarded as an environmentally correct material.

Jan 1, 2006

By Hideyuki Itou

Municipal wastes are mainly incinerated in Japan. Both bottom ash and fly ash from the incineration treatment are smelted recently to decrease the volume. Direct smelting of municipal wastes is also becoming popular. The smelting treatment generates fly ash which contains concentrated heavy metals such as Zn, Pb and Cu, and the harmfulness is causing concern. The smelter fly ash is mainly landfilled after stabilization. An effective treatment process of the smelter fly ash is required to recover the metals. For the treatment process, an application of chloridizing volatilization technique is considered. Chloridizing volatilization experiments were carried out to determine the effects of various factors on the volatilization behaviors in this study. A pretreated ash was mixed with a main raw material which mainly consists of hematite. Calcium chloride water solution was added into the mixture. The mixture was pelletized, dried and used as samples for the volatilization experiments. The sample was placed in the reaction tube heated in an electric resistance furnace. 5%02-95%N2 gas with controlled humidity was introduced into the reaction tube. Effects of humidity in the carrier gas, addition of calcium chloride and mixed ratio of the ash to the main raw material were investigated on the volatilization of Zn, Cu and Pb. To determine the volatilization behavior, samples were taken from the furnace at specified temperatures on the heating stage. In addition, experiments at specified holding temperatures for 15 minutes with shortened heating time were conducted. The two series of experiments revealed the effect of heating temperature on the volatilization behavior of Zn, Cu, Pb and Cl.

Jan 1, 2006

By Ulrich Kerney

In 1996, bath smelting technology for lead recovery from concentrates and secondary materials was introduced in Nordenham to replace the common sinter plant/shaft furnace operation. Since start-up, a continuous improvement of equipment and operation lead to a steady increase of capacity and plant availability. The decision to skip the reduction stage for slag treatment now allows the treatment of 200000 t/a feed materials with a secondary fraction of up to 70 %. The main feed source for the furnace is automotive battery recycling, which offers oxide paste and metallics to be molten under oxidizing conditions in the lance fired furnace. The lead bullion is transferred to the refinery, where copper, silver and other impurities are removed. Silver is recovered as doré quality. All loopings are recycled to the BSF. Inert feed material is collected in a so-called lead concentrate of metallurgical origin, the primary slag, which is sold. It is rather a valuable feed material for further processing than a slag The off-gas is cooled in a flux-flow system, entering then an electrostatic dust precipitator. Having passed a further washing and cooling system, SO2 is oxidized and collected and sold as concentrated sulphuric acid. The presentation will cover a review of the start-up phase, the development of significant production parameters over the last years and actual production routes and figures. A comparison of environmental data between new and old applied technology is made.

Jan 1, 2006

By Peter J. Koros

The current wave of interest in this topic is the result of increased use of titaniferous ores or ilmenite in blast furnace burdens for the purpose of repairing hearth damage. The titanium compounds that promote deposition of ?patching? materials in blast furnaces are the cause of downstream problems in the steelmaking shops. Steelmakers historically have objected to significant amounts of titanium in hot metal (>0.10 % Ti) for several reasons: 1) accretions caused by the TiC.TiN needles that float out of the iron as it cools in transit and in transfers make the accompanying slag sticky and crusty, causing problems in desulfurization and increasing time and Fe yield loss at the subsequent raking, 2) defensive measures have been taken in treatment, such as use of argon for carrier gas, but without technical rationale for this approach, 3) difficulty in removal of the ladle slag by the raker, with subsequent sulfur addition to the vessel charge, and 4) transfer into the BOF and/or formation of a very corrosive TiO2 containing acid slag during the early part of the BOF blow which, in addition to causing lining damage, results in loss of sulfur removal capability by the vessel slag. Based on a conceptual analysis of the metal-slag-atmosphere interactions during transfer ladle desulfurization treatment, a mechanism is postulated for the apparent effectiveness of the use of argon in reducing the deleterious effect of titanium and an alternate technique, possibly more effective, is proposed. As probably the use of argon causes increased exposure to atmospheric oxidation of the titanium carbonitrides contained in the ladle slag, the same benefit can be obtained by use of either oxygen or an air blast to oxidize the noxious reaction compounds. Validity of the concept has been demonstrated in a pilot plant setting. These issues, and related effects on testing the hot metal, are examined in detail with reference to the literature and plant and laboratory experience.

Jan 1, 2006

A survey has been undertaken of the petrography of North Island greywackes with a particular focus on the occurrence in them of smectite (swelling clay) and chlorite, two minerals that are closely associated, chemically similar, and commonly interlayered with each other. Smectite is the mineral which is a major cause of greywacke aggregatesÆ poor performance. Smectite occurs in post-metamorphic shear zones and in surface weathering profiles over greywackes. This study focuses on the petrography of fresh greywacke rocks.   The occurrence and abundance of smectite and chlorite and their relationship in greywackes is largely a function of the chemistry of the sediment and the maximum temperature that the sediment has been subjected to during diagenesis and/or very low grade (anchizone) metamorphism. Rock chemistry, particularly total iron and MgO, determines the smectite and/or chlorite content in fine-grained greywackes (argillites and siltstones) but chemistry is less influential in sandstones, where at low grades of metamorphism much of the Fe and Mg of the rock is held in unreacted detrital minerals and the mineral constituents of lithic grains.   Four zones which represent different levels of diagenesis and very low grade metamorphism, based on the crystallinity of illite and chlorite in the greywackes, and the proportion of smectite interlayered with chlorite, have been mapped in the North Island. In the anchizone smectite does not appear as a discrete mineral, it is always interlayered with chlorite. In the upper anchizone chlorite contains approximately ten per cent of smectite interlayered with chlorite. In the lower anchizone about 30 per cent smectite can occur in chlorite.   In addition to the smectite and chlorite inherent in the greywackes as the result of the thermal overprint, smectite as a discrete mineral and smectite-chlorite interlayered minerals with high levels of smectite, occur in abundance on shear zone surfaces and in alteration zones adjacent to shear zones; these are the main contributers to the high levels of smectite recorded in many greywacke aggregates.

Jan 1, 2006

By X. Shi

Magnesium, the lightest structural metal, has not yet been considered as a serious contestant for automotive use due to its weaknesses in corrosion. Electroless nickel-boron alloys are well known for their corrosion resistance and hardness. An electroless nickel-boron layer was successfully deposited first on the chemical conversion pre-treated AZ31 alloy and also on the Ni-P coating which was deposited on the conversion coating. The electroless bath contained nickel sulphate and dimethylamine borane (DMAB) as main salts and the samples were activated by a 5 g/L AgNO3 solution before the electroless plating process. The presence of the conversion coating between the nickel coating and the AZ31 substrate acted as a barrier and prevented corrosion of the alloy. The morphology of the nickel-boron layer was studied using SEM. The crystal structure and the composition were examined by EDS and the hardness was measured. The corrosion behaviour of the nickel-boron layer deposited on the conversion coating and on the Ni-P coating was studied using potentiodynamic polarization in a 0.5M NaC1 solution. A saturated standard calomel electrode was used as a reference electrode. The results show that the nickel-boron coatings had a significantly better corrosion resistance than the AZ31.

Jan 1, 2006

By Kurt R. P Petersen

This paper discusses the current approaches to modelling the DMS cyclone within the De Beers group. Current efforts are split into short term value-adding process understanding and longer term semi-fundamental analysis of separation mechanisms. To date, the basic applied approach has yielded significant value to the group, enabling operators to focus on simple diagnostic measures to control their process. The more involved modelling approach has given rise to a new understanding of the separation field, in particular that the high density gradients within a cyclone are highly localised, indicating that separation of medium to heavy density material takes place low in the cone. The model has proven to be conceptually robust, but still requires further development and validation to become a complete modelling and simulation tool for De Beers.

Jan 1, 2006

The feasibility of exploiting a mineral deposit by developing a surface mine is closely related to the environmental protection and land reclamation costs. This issue has utmost importance for West Macedonia Lignite Centre (WMLC) of Greece, where there is still a lot of interest for opening of new mines and for further development of the existing open-pits. The decision-making process in these cases can be based on a decision tree that takes into consideration the various cost components of environmental management, the alternative solutions, the environmental permits and the cost reports of environmental management actions carried out so far. Moreover, the mine planning procedure is affected indirectly by numerous uncertain environmental and socioeconomic parameters, such as the delays caused by the bureaucratic procedures and the settlement of arguments in the Court.

Jan 1, 2006

By John E. Leitch

The cost of corrosion as measured by such cost components as the renovation or replacement of coated steel, or the use of expensive coating systems on steel, is considerable. Extrapolating from figures for the USA would place the overall cost of corrosion for South Africa as a figure of the order of magnitude of something over 1% of the GNP. This is a sizeable amount, of which costs associated with atmospheric corrosion would be a significant proportion. The corrosivity of an atmosphere can be defined as the ability of the atmosphere to cause corrosion in a given metal or alloy (International Standards Organization [1]). The ISO Standard 9223 specifies the key factors in the atmospheric corrosion of metals and alloys, and defines categories of corrosivity on the basis of these factors. Prior to the publication of that ISO standard, Callaghan published the results of his twenty-year exposure programme and his excellent corrosivity map of Southern Africa [2]. The present author published updates of the corrosivity map in 1999 [3] and again in 2003 [4]. The summary of the individual areas of corrosivity around Southern Africa was published in the latter paper, and is reproduced here as the following TABLE 1. Of significance in TABLE 1 are the numerous regions of very high corrosivity (C5 or beyond), particularly the rural West Coast shoreline, the North East Coast (KZN) shoreline, and the coastal cities Cape Town, Durban and Richards Bay. The corrosivity map as published is obviously based on much extrapolation as only a small number of points have been measured. During the past three years further measurements have been made, mostly however at the same sites in order to give greater reliability and to monitor long-term trends with changes in pollution. These two aspects are incorporated in this update. There has become available a greater amount of air pollution data for centres in South Africa than was the case some years ago. In this present paper the pollution data are used to extrapolate the corrosivity over areas where little or no direct corrosivity measurement has been made. This methodology is described in ISO 9223.

Jan 1, 2006

By M. R. Saharan

A brief overview of rockburst control measures is presented. The paper then elaborates on one key rockburst control measure, which is known as destress blasting. A historical background of the technique is presented in order to understand different aspects of its field application. The publication enumerates key aspects of the technique as being used in practice in South Africa and North America. The paper also presents an analysis of three case studies in order to demonstrate difficulties associated with the field application of distress blasting in hard rock mines.

Jan 1, 2006

By Ray. K. Filip

The concept of installing a steel sheet pile retaining wall into the ground by "pressing" has resulted in the development of various equipment solutions over the last thirty years e.g. Taylor Woodrow ?Pile Master', Giken 'Silent Piler" & Tosa 'Still Worker?. Dawson Construction Plant Ltd (DCP), have recently advanced the pile pressing concept with the introduction of their 'Push-Pull' system. This advancement offers significant improvements in the quality of installation compared with traditional pressing solutions but also greater versatility, higher productivity and, most importantly, generates new opportunities through a wider range of applications for "silent piling'. This paper will focus primarily on the use of the Push-Pull concept in the construction of a unique "integral" bridge in Milton Keynes, England. Finally, the paper touches on the development of quiet, vibration-less pile extraction equipment, which allows steel to be considered the foundation material of choice for truly sustainable construction. It is no longer acceptable to leave unwanted piles in the ground.

Jan 1, 2006

By D J. Fray

In this work, a fused salt electrochemical process was investigated experimentally for production of metals and alloys directly from respective solid oxides by electro-deoxidation. Direct electrochemical reduction of the oxides was carried out in molten CaCl2-based chlorides in an electrolytic cell, incorporating an oxygen-evolving inert anode, over the temperature range of 850 - 950¦C. The technical viability of the process was demonstrated by the electro-deoxidation of pure oxides and oxide mixtures including NiO, Nb2O5, Nb2O5/TiO2 and Nb2O5/SnO2 to produce nickel metal, niobium metal, NbTi alloys and the intermetallic compound, Nb3Sn. Compared to the conventional metallurgical processes for producing these metals and alloys, this new electrochemical process appears to be much less energy intensive, with lower costs and no direct greenhouse gas emissions from the electrolytic reduction process. The present electrolytic reduction process has the potential to be scaled up for the green extraction of a number of non-ferrous base metals and processing of many advanced alloys.

Jan 1, 2006

By David J. Baxter

Use of bored displacement piles has experienced significant growth in the UK piling market sector, largely due to their environmental advantages over other piling methods and through cost benefits. Bored displacement piles are a cast-in-situ construction which can be formed with minimal production of spoil and offer low noise and vibration compared to driven displacement piles. A large variety of bored displacement piles have been developed. This paper describes a standard system for their classification. The development of the different types is described along with the factors which have led to their increased use. Consideration is given to processes undergone by the soil during pile installation and design approaches for bored displacement piles are compared. Comparisons are made between the different classifications of bored displacement pile. Comments are also made on the installation of such piles. It is concluded that complex changes occur in the stress states of the surrounding soils. Such effect of the pile installation on the soil should be accounted for and there is a need, therefore, to further refine the design process for these piles.

Jan 1, 2006