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By K. Getsos

Western Greece is a favorable site for exploration and discovery of oil fields. The most important potential source rocks seem to be all the rocks deposited before middle Jurassic under special circumstances, such as reducing conditions, which allowed preservation and maturation of the organic material. In general all the rocks of middle Jurassic to Paleogene are not favorite source rocks. The porosity type was studied on fifty samples using scanning electron microscopy (SEM). Potential reservoir rocks are the porous Paleogene wackestones-packstones with boring, channel and vuggy porosity type. Finally seal rocks are the impermeable mud-stones and wackestones of Jurassic, Cretaceous and Paleogene age. These rocks consist of micrite and whole sells of foraminiferas and the porosity type is mainly intercrystal/interparticle. A Total Organic Carbon (TOC) analysis, conducted on seventy samples using a wet oxidation method, has revealed an extremely low TOC content (less than 0.05 %). This amount is by far less than the minimum organic content amount, required for source rock characterization and characterizes all the rocks of middle Jurassic to Paleogene age. Additionally, 18O and 13C stable isotope analysis was contacted and the results are given in d values. All the rocks within the studied time interval have much lower d values than petroleum source rocks. Clay mineral content was studied in almost seventy samples. As is indicated by the clay mineral content the studied rocks have reached up to the Middle Diagenesis and the temperature during diagenesis was rather low.

Jan 1, 2006

Coal has been mined in the central Appalachian coalfields of southern West Virginia, western Virginia, and eastern Kentucky for more than a century. The dwindling reserve base consists in large part of coal that would have been considered unmineable by earlier generations. Nearly every current operation is working on a property where coal has been extracted in the past, from seams either above, below, or both. NIOSH is conducting research aimed at helping mine planners prevent hazardous conditions due to multiple seam interactions. To-date, more than 300 case histories have been collected from underground mines, mainly from central Appalachia. This paper focuses on several of the more challenging situations that have been encountered, including: • Room-and-pillar development 20 ft (6 m) beneath full extraction workings at a depth of 1,000 ft (300m) of cover (Virginia) • Pillar recovery 45 ft above full extraction workings at 900 ft (270 m) of cover (Virginia) • Near-simultaneous room-and-pillar mining with pillar recovery with 40 ft (12 m) of interburden and 1,500-2,000 ft (450-600 m) of cover (Kentucky) • Longwall mining directly beneath main entries in overlying seams (West Virginia) • Some of these operations have been highly successful in overcoming the challenges, others less so. The lessons learned from their experience will help ensure that these and similar difficult reserves can be mined safely.

Jan 1, 2006

By Edwin W. Meyer

The augered cast-in-place piling technique was used to install deep foundations 20 feet into weathered sandstone. The project involved the upgrading of the Air Quality Control System (AQCS) for a 560 megawatt coal fired power plant located in Stillwater, Minnesota. The site subsurface consisted of 20 feet of overburden overlying weak sandstone. The overburden consisted of sands and gravels with cobbles and boulders, and variable thicknesses of peat. Ground-water at the site was approximately 8 feet deep. Two foot diameter piers were selected to facilitate installation through the cobbles and boulders in the over-burden and to penetrate the sandstone 22 feet. During installation of the first pier, the weak sandstone broke down to sand-sized material that could not be cleaned from the pier hole without the use of slurry to hold the material in suspension. However, the use of slurry would significantly impact both schedule and cost. Since the sandstone could be easily drilled with the pier equipment, it was believed that 2 foot diameter deep foundations could be installed as designed using augered cast-in-place piling techniques. A brief test drilling pro-gram was conducted to evaluate the viability of 2 foot diameter continuous flight augers penetrating 22 feet into the weak sandstone. The test drilling indicated that augered cast-in-place installation techniques should be successful. Following a short delay to mobilize the additional required equipment, construction commenced. Installation of the 2 foot diameter augered cast-in-place piling to a depth of 22 feet into the weak sandstone was successfully performed.

Jan 1, 2006

By F. Vallianatos

The main objective of the present investigation is to demonstrate the potential of ERT (Electrical Resistivity Tomography) and HVSR (Horizontal to Vertical Spectral Ratio) methods as geophysical tools for the monitoring of subsurface cavities. The survey sites are located in Akrotirion Peninsula, almost 7 km east of Hania town in Crete Island, Greece. At this site, the surface expression of a known cavity with a diameter of about 25 m is visible. The true geometrical characteristics of the cavity were unknown since there are no boreholes in the area. The focus of this survey was primarily of a qualitative nature and the objective was to determine if ERT and HVSR could be used to identify and map near surface cavities (less than 30 meter in depth) in a limestones kartsic area such as Akrotirion Peninsula. A 2D/3D model of the resistivity distribution is given for the area under investigation. Furthermore, analysis of microtremors data provides a profile of the seismic response of the tectono-karstic voids.

Jan 1, 2006

By H. W. Read

The South African platinum industry finds itself in the midst of a rapidly evolving society that is no longer characterized by the apparent stability of the previous decades. The features of this society include increasing global competition, rapid technological innovation, a declining skills pool, major political transformation, a more challenging working environment as the mines reach deeper into the earth?s crust and a greater concern for human welfare. It is therefore axiomatic that new ways will have to be found to engage the all-pervasive change in the mining environment. Although in general terms project management is a universal endeavour for managing change, it takes place in a specific socio-techno-economic environment and geographical setting that gives it a particular context. The argument of this paper explores, analyses and synthesizes the impact of these changes on the emerging project management methodology. In essence, the management of change will inevitably contribute to the emergence of new dilemmas, issues and challenges. The change management process and procedures will also be affected by this change and in response, drive internal change of its own structures and organization. And, therefore, a new paradigm of project management will become apparent. A new project management model will then be proposed to the industry.

Jan 1, 2006

By R. Latifovic

Assessment of the possible impact of existing and future mining projects located in remote areas may be difficult and costly. This may have an adverse effect on the process of issuing mine permits and development of new mines. A remote sensing based land cover change assessment methodology presented in this paper is a promising avenue to render this process more meaningful, precise and affordable. It has been applied to a case study of the Oil Sands Mining Development in the north-east of the Canadian province of Alberta. Recently, the Athabasca Oil Sands Region (AOSR) is a place of unprecedented growth of open-pit mining operations. This study was focused on the primary impact onto the landscape and vegetation resulting from exploration and, mining development. This impact was assessed using an information extraction method applied to two LANDSAT scenes. The analysis based on derived land cover maps shows a 8.64% decrease of natural vegetation in the study area (715,094 ha) in 2001 relative to 1992. It is demonstrated that the methodology presented here provides reliable results and is fully applicable for the assessment of the environmental impact of large scale mining operations.

Jan 1, 2006

By K. Law

"The Hatch Product Transport (HPT) system is a highly flexible and configurable route selection and sequencing system for controlling large bulk material handling facilities. The system has a generic control algorithm that can be configured to suit any material handling facility. It can also be easily reconfigured to cater to plant expansion or modifications without incurring significant disruption to the existing production, costs in testing, and re-commissioning, thus achieving cost savings throughout a facility’s lifecycle.This new material handling control system has been installed at BHP Billiton’s Port Hedland iron ore terminal to facilitate its expansion to beyond 100 Mt output capacity."

Jan 1, 2006

By Kang-In Rhee

Nonferrous metal recycling not only provides energy saving and environmental benefits but also is a significant factor in the supply of various types of metals used in our society. Recycling plays an important role in establishing the sustainability of materials. The total amount of recycled nonferrous metals by weight accounts for less than 5% but their value is larger than 50% compared to ferrous metal recycling which consists of about half of the total metal recycling in weight. This paper describes trends and typical achievements in nonferrous metal recycling and overviews the present and future of nonferrous metal recycling technology and business in Korea.

Jan 1, 2006

By D P. Murphy, R F. Dewhirst

Traditionally closure has been seen by the Resource sector solely as a green or an environmental issue, focused primarily on the requirement to rehabilitate the site following cessation of production activities. In addition to operational, maintenance and production aspects of processing plant design, future design teams will need to take a more holistic view and consider an increasing number of sustainability issues including safety in design and cleaner production as well as closure itself. Sustainability principles being adopted by industry such as the Minerals Council of AustraliaÆs Enduring Value Framework are now broadening our understanding of closure. While issues around the closure of tailings dams and associated infrastructure have been widely studied, few investigations have looked closely at the implications of closure on the design of minerals processing plants. It is likely that design teams may be able to make a significant contribution to meeting industry objectives by adopting innovative designs which, in addition to meeting production objectives, deliver sustainable and cost effective plant closure outcomes. This presentation explores the opportunity for innovative design of mineral processing plants through the assessment of alternative closure objectives. This assessment specifically looks at current industry standards and statutory requirements, as well as potential risks and opportunities associated with each objective. Alternative design strategies to meet these objectives are discussed.

Jan 1, 2006

By M. I. Kalashnikova

The leaching of metal nickel in copper sulfate solutions is investigated. It is established, that irre-spective of presence or absence of chloride-ion and oxidizer (oxygen) in system process can be divided into three stages, characterizing by restoration and oxidation of metals with formation of metal copper and cuprite and differing in the speeds of sedimentation of copper and transition of nickel into solution. At the initial stage of process along with allocation of metal copper it is be-sieged cuprite, that results in excess of speed of sedimentation of copper in comparison with dis-solution of nickel. At the second stage speed of transition of nickel into solution falls practically to zero, and sedimentation of copper proceeds on reaction of interaction of metal copper with copper sulfate solutions with cuprite formation. During the final period speed of transition of nickel into solution exceeds speed of sedimentation of copper due to course of reaction of resto-ration of cuprite up to metal. Influence of an ion of chloride and oxidizer on formation of various phases is revealed. It is established, that presence of an oxidizer results in increase in a share of cuprite in a deposit. With increase of the maintenance of chloride-ion speed of metal copper allo-cation essentially grows even at presence of an oxidizer in system.

Jan 1, 2006

By Michael Alber

Resin grouted rock bolts are the major support measure in coal mining. They are rather easy and foolproof to install, take immediately load and are the least time consuming support measure for controlling gateroad deformation. The use of only resin grouted bolts allows fast gateroad development which is essential for economical resource exploitation. The design of reinforcement / support systems for coal mining typically bases on empirical methods, which work fine when encountering known or usual ground conditions. However, coal mining approaches depths where little experience exists and numerical modeling is often the only method to estimate ground behavior. This paper discusses the geotechnical properties relevant to numerical model and focuses particularly on input values for modeling resin grouted rock bolts for safe gate design.

Jan 1, 2006

By M. N. H. Khan

CSIRO has been experimenting with supersonic flows as a method of rapidly quenching metallic vapours. Cooling rates above 106 °C/s have been achieved. The supersonic flow conditions are achieved by adiabatic expansion of the vapour through a Laval nozzle into a vacuum chamber. This paper will describe the basic physics of the process, outlining computer fluid dynamic (CFD) modelling of flow in the nozzle, the effects of different flow conditions on the condensation process and discuss the practical design issues associated with operating supersonic nozzles. Results obtained from a CFD model of the nozzle, which compared two methods of incorporating condensation, showed that inclusion of condensation substantially changes the conditions in the nozzle. Most noticeably, the effect of condensation produces a region in the nozzle where the temperature remains almost constant.

Jan 1, 2006

By Takao Mori

Novel rare earth boron icosahedral compounds are investigated as potential high temperature thermoelectric materials. REB50-type compounds and REB22C2N compounds were synthesized and the thermoelectric properties measured. Seebeck coefficients in excess of 200 V/K are observed at temperatures above 1000 K for the REB50-type compounds. Strikingly, n-type behavior was observed for REB22C2N. Up to now, non-doped B12 icosahedral compounds have all been p-type. The discovery of an n-type compound is extremely important in terms of the potential development of this class of compounds as viable thermoelectric materials. Low thermal conductivities of < 0.03 W/cm/K at room temperature was observed for these rare earth boron cluster compounds.

Jan 1, 2006

By S. M. C. Santos

Preliminary bench-scale studies were carried out on the leaching of a zinc sulphide concentrate from Somincor, Portugal, and the purification of the resulting pregnant solution using solvent extraction techniques. The sulphide concentrate contained 36% Zn, 36% S, 2% Fe and 4% Cu. The leaching was carried out with sulphuric acid in the presence of ferric sulphate as the oxidant. Important leaching parameters, such as the effect of reaction time, the solid-liquid ratio, temperature and concentrations of acid and oxidant, were investigated. After leaching, the recovered solution was contacted with an organic phase containing Acorga 5640 to remove the copper. Subsequently, the removal of iron from the leaching solution was achieved with a mixture of Cyanex 272 and TBP. This solvent mixture was relatively selective for iron over zinc. The stripping of the loaded solvent was performed with 200 g/L H2SO4. Six countercurrent extraction stages achieved a separation of about 99% of the iron from the leaching solution. The iron-free leachate can be further treated to recover minor metals by cementation, and finally, zinc by liquid-liquid extraction. The advantages of the suggested process relative to the traditional jarosite process are discussed.

Jan 1, 2006

By John E. Feddock

Retreat mining plays an important role in the coal production within Kentucky and the Appalachian Coal Basin. In Kentucky, the majority of retreat mining is performed in the Eastern coal field. However, since September 2004, Kentucky has suffered four mining fatalities during retreat mining operations, and the coal industry has focused attention on the safety concerns associated with retreat mining practices. The Kentucky Department of Natural Resources (KYDNR) engaged Marshall Miller & Associates, Inc. (MM&A) to conduct a study to ensure that retreat mining is utilizing the best technology currently available and that the current available employee training programs afford maximum safety to miners. MM&A studied 34 coal mines that were conducting active retreat mining operations and represent about one third of all the mines with approved retreat mining plans in Kentucky. This paper summarizes the major research work conducted (Feddock and Ma, 2006) and recommends the practical methods for improving safety during retreat mining operations.

Jan 1, 2006

By Susumu Imashuku

A pseudoternary phase diagram of the BaO?ZrO2?ScO1.5 system is established and the conductivities of the scandium-doped barium zirconate are measured in wet conditions. According to the phase diagram, the molar fraction of scandia in the barium zirconate phase that equilibrates with the cubic zirconia (ZrO2) and scandia (Sc2O3) phase is 0.03. On the composition line, where the molar fraction of barium oxide (BaO) is 0.50, the solubility of scandia into barium zirconate is 0.27 as a molar fraction of scandia. At around 500 °C, the conductivities of scandium-doped barium zirconate are estimated to be almost same as that of yttrium-doped barium zirconateThe activation energies for bulk proton conduction in scandium-doped barium zirconate (0.57 eV for BaZr0.90Sc0.10O3-d) are higher than that of yttrium-doped barium zirconate (0.44 eV for BaZr0.90Y0.10O3-d). In addition, the bulk conductivity of scandium-doped barium zirconate in this study is 10 times higher than the reported conductivities in the temperature range of 75 °C to 300 °C.

Jan 1, 2006

By D. Quattrini

The aim of the present work is to present the gas chromatography (GC) as an alternative method of analysis in the thermal decomposition of calcium carbonate. Therefore, a furnace/GC on-line system was employed to study the kinetics of the reaction, measuring the CO2 produced in the decomposition. One of the advantages of the GC method is the possibility to perform an in-situ characterization and quantification of the gaseous products to obtain kinetic parameters, besides the method is simple and shows a good reproducibility. The decomposition of calcium carbonate was carried out in isothermal conditions at temperatures from 655 to 715°C with nitrogen as purge gas. Several gas velocities were used to determine the adequate flow that minimizes the effect of external mass diffusion as rate controlling step. It was made a preliminary analysis of the sample size influence on the reaction rate. The activation energy of the reaction was determined by Flynn method. The value obtained was in a good agreement with other authors. On the other hand, gravimetric measurements were employed for compare GC results.

Jan 1, 2006

By Thomas M. Barczak

The era of the shield-supported longwall face began in the United States a little over 25 years ago. The most fundamental development of the shield in the past 25 years has been an increase in size and capacity and a progression toward two-legged designs in favor over four-legged shields. Is the ?bigger-the-better? design philosophy justified? The advantage of the two-legged design is largely attributed to its active horizontal force caused by the forward orientation of the leg cylinders. How do we know this? You might be surprised to learn that shield loading data may suggest otherwise. In addition, what about setting pressures? Should they be set as high as possible? Some people have advocated that setting pressures should equal the yield pressure. Does this make any sense? Is yielding a good or bad thing? These are some questions still worthy of investigation that are addressed in this paper. The first major change in gateroad support was the use of cable bolts to replace conventional wood cribbing particularly in Western mines. Standing support changed very little until the mid-1990s, when Strata Products1 introduced the Hercules and Propsetter supports in Eastern mines and Burrell Mining Products introduced the Can support in Western mines. Since then, there has been a dramatic increase in new roof support technologies for longwall gateroad support. Historically, standing support, including shield supports, have been designed based on a simplistic model requiring the support to have sufficient capacity to support the gravity loading of a perceived detached rock mass. This approach ignores the stiffness of the support and the resulting ground deformation that is known to be critical to roof stability. Recently, a new approach based on the ground reaction concept has been promoted by the National Institute for Occupational Safety and Health (NIOSH) to account for the interaction of the support with the rock mass behavior in achieving ground stability. In addition to gateroad support design, this concept has ramifications for shield capacities, setting pressures, and recovery room support design that challenge current practices in these areas. Although longwall mining has matured into the safest and most productive underground mining method used today, traditional concepts of roof support design and practice should still be evaluated and challenged. Ultimately, advancements in the science of ground control are made by recognizing deficiencies in current theories and thinking outside the box.

Jan 1, 2006

By R. Cottam

The deformation and recrystallisation of magnesium yttrium alloys containing 0.23, 0.84 and 2.71wt% yttrium and commercially pure magnesium extrusion has been investigated at temperatures between 200 and 350°C. The alloys were produced as billets 7.5 cm diameter, solution treated at 525 °C for 8 h and extruded into 3 cm diameter bar at 390°C. Channel die compression was employed to deform the samples at a strain rate of 1x10-3s-1. For the 0.23 wt% yttrium alloy and the pure magnesium, dynamic recrystallization (DRX) occurred at all temperatures and the amount of DRX increased as the temperature was raised. In the alloys containing 0.84 and 2.71 wt% yttrium DRX was almost completely suppressed at all temperatures. The absence of DRX in the 0.84 and 2.71 wt% yttrium alloys was accompanied by a decrease in the ductility, except at 350°C the highest deformation temperature. It was observed that this increase in ductility was accompanied by a reduction in deformation twinning and the initiation of pyramidal slip. This work highlights the important role that DRX plays in enhancing the ductility of magnesium alloys.

Jan 1, 2006

When a company has an effective hearing loss prevention program, everyone wins-the employers, the employees, and the safety and health professionals who implement the program. This guidebook is not about minimal programs that meet only the letter of the law. It is concerned with programs that are effective as well as efficient: those optimizing program elements that succeed in preventing hearing loss in a practical and cost effective manner.

Jan 1, 2006