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The sampling of a run-of-mine (ROM) ore with the objective of controlling the fundamental variance associated with the sampling step is a poorly understood subject. Finding the effective sampling constant by repetitive sampling to establish the variance between nominally identical subsamples of a given mass of the ore is a laborious, time-consuming and very expensive exercise. In this paper, the run-of-mine ore is modelled using three components: ore, waste, and relatively fine material which shows significant liberation of the mineral phase(s) carrying the target analyte. The expression for the sampling constant of the mixture is developed from first principles. The form of the equation provides insight into the factors that are important in controlling the magnitude of the sampling constant and hence the fundamental uncertainty associated with a given mass of sample. The controlling factors are shown to be the size distribution of the ore/waste mixture, the proportion of waste mixed with the ore and the extent of liberation and the size distribution of the liberated material in the finer fractions.

Jan 1, 2008

By H W. Scriba

The development and improvement of computer-based process simulation packages over the past 20 years has provided process engineers with a powerful tool to use in the design of complex metallurgical plants. The use of such modelling tools has enabled the design of process plants that minimise operating and capital costs whilst optimising plant efficiency and recovery. Almost every new project developed in the current market is underpinned by a simulation of the process. In line with engineering best practice this simulation should be based on laboratory/pilot plant test work results and sound assumptions. Any errors that are not identified in the development of the process simulation may have significant effects on the final design and operation of the processing plant. Developing a simulation of the process in a comprehensive, logical and auditable manner is thus essential in ensuring the simulation accurately represents the expected process plant behaviour. A methodology that ensures these requirements are met has been developed by SNC-Lavalin Australia and is described in this paper. The methodology includes the major review stages of data collection, model planning, model building and optimisation, model review, scenario testing and options development, and model reporting. All of these stages should incorporate comprehensive client interaction and review by a suitably qualified representative. In applying these methodologies SNC-Lavalin Australia ensures that the process simulation model developed can be confidently utilised in the design of the process plant, and in the estimation of operating and capital costs, whilst ensuring that engineering best practices are met.

Jan 1, 2008

During the last 20 years, more than 80 km (50 miles) of tunnels have been constructed in the Los Angeles, CA area. Recent projects include The East Central Interceptor Sewer (ECIS), completed in 2004. It spans more than 18 km (11 miles). The Northeast Interceptor Sewer (NEIS), completed in 2005, spans 11 km (7 miles). And the 2-km (1.3-mile) Metropolitan Transportation Authority?s Gold Line Eastside Extension (MCGLEE) was completed in 2006. All of the tunnel routes lay beneath heavily populated urban environments so minimizing ground surface settlement was critical to the success of the projects. Previous tunneling efforts in the Los Angeles area using open shield methods resulted in significant settlement that damaged roads, utilities, buildings and other structures. Earth pressure balance (EPB), or slurry machines, were specified for these projects to reduce subsidence risk. The contractors chose EPB tunnel boring machines (TBM) for the work. The closed and pressured face of the EPB TBM reduces loss of ground at the tunnel face and, when the machines are used in combination with gasketed pre-cast tunnel liners and backfill grout behind the installed segments, losses from over-cut of the excavated surface are also reduced.

Jan 1, 2008

By Baojun Zhao

Primary lead production using the lead blast furnace in conventional practice is carried out using sinter feed. At YMG, China, the sinter plant has been replaced with a lead ISASMELT furnace. The ISASMELT furnace produces lead bullion plus a high-lead slag, which is cast into lumps to provide a suitable feed for the blast furnace. In the present study the relative microstructures and reduction characteristics of industrial lead sinters and synthetic ISASMELT slag in CO/CO2 gas mixtures have been measured and compared. The microstructure and property changes, and the mechanisms of reduction in each case are examined and discussed. The results of the study are used to explain the successful implementation of cast slag feed in commercial ISASMELT- lead blast furnace practice. Key words: lead slag, lead sinter, lead blast furnace, reduction kinetics and mechanisms

Jan 1, 2008

The objective of this study is to classify ore and waste in a selected mine. The support vector machine, was used for the classification purpose, is applied to a zinc ore body in a skarn deposit located in the central region of the Peruvian Andes. The input parameters used for the model are spatial coordinates and the lithological information of the ore body. The input data was divided into training and testing data sets and the performance of the model was tested using the testing data set. The results show that more than 76% of the data could be properly classified by this method. The ore waste maps of the deposit was then developed using SVM model. From the result it was observed that a comparatively very few number of cells classified as ore. The ore is concentrated in small lodes at the middle of the volume of study, and not uniformly distributed throughout the study area. The lithological map of the deposit was also constructed as it was used as an input parameter for the SVM model. The indicator kriging was used for generation of lithological map of the ore body. Key word: Ore waste classification, Support vector machine, Indicator kriging, Confusion matrix.

Jan 1, 2008

By Gerald T. Homce

Data from the U.S. Bureau of Labor Statistics show that 89 water well drillers died on the job between 1992 and 2002, and 28 of these deaths were electrocutions (Figure 1). In fact, elec­trical accidents are the leading on-the-job killer of water well drillers. The use of electricity is such an integral part of our lives that we usually take it for granted, but if we don?t understand or choose to ignore the hazards associated with electricity, the results can be deadly. Why is electrical shock so dangerous? If the voltage (of a shock) is sufficient to drive electrical current through your body, just 10 milliamps of cur­rent (1000 milliamps = 1 amp) can cause muscles to contract and prevent you from releasing an energized wire or tool in your grip. As little as 30 milliamps of current can paralyze your breathing, and 75 milli­amps can cause your heart to stop pumping blood (ventricular fibrillation). As a comparison, a small bedroom night-light draws about 30 to 60 milliamps. Other factors influence how severely you?ll be shocked if you touch a live electrical circuit, such as the path electrical current takes through your body and how long it flows, as well as your body weight. How much voltage is needed to drive electrical cur­rent through your body? Not much! Generally, any power source at 50 volts AC or higher is considered dangerous.

Jan 1, 2008

By Daoxin Wu

In this paper, the rutile TiO2 were prepared under air, Ar and H2 calcination atmosphere by low temperature hydrolysis using Tetrabutyl titanate (C16H36O4Ti) as raw material. Powers were characterized by X-ray diffraction, UV-vis diffuse reflectance and X-ray photoelectron spectroscopy. The influence of the calcination atmosphere on the photocatalytic reactivity of rutile TiO2 for oxygen production was investigated. The photocatalytic reactivity of rutile TiO2 prepared under air, Ar and H2 atmosphere was compared under ultraviolet and visible light radiation with Fe3+ (c=8.0mmol.L-1) as electron acceptor. The results showed that rutile TiO2 prepared under Ar and H2 atmosphere had higher photocatalytic activity for oxygen production than that prepared under air atmosphere. The oxygen production rates under ultraviolet irradiation were 427.5, 378.2 and 357.0µmol.l-1h-1 respectively when rutile TiO2 was prepared under Ar, H2 and air atmosphere. The oxygen production rates under visible light irradiation were 78.2, 52.2 and 13.5µmol.l-1h-1 respectively when rutile TiO2 was prepared under Ar, H2 and air atmosphere.

Jan 1, 2008

By Vladimir G. Kochnev

Crushing and grinding account for the major portion (60 to 80 percent) of the overall expenses for ore processing. Autogenous (AG) and semiautogenous grinding (SAG) have been considered a step forward in comparison to conventional grinding circuits with several stages of crushing and using ball (and/or rod) grinding mills (Bassarear, 1982, MacPherson, 1989, Pithois, Casalis, 1983, Maripuu et al., 1983). However, there remains room for improvement to existing AG and SAG technologies and both technologies have immense economic benefit potential. Experience gained by the Technics & Technologies of Disintegration Ltd. (TTD) in the research of grinding processes shows that grinding in AG and SAG mills can be performed in a more effective way. The company's approach comprises the following elements: ? Novel mill design. ? New liners and lifters. ? Novel discharge grid design. ? Technique of treating material of critical particle size. Comparative tests that demonstrated the usefulness of these innovations are described in this article. Currently, there are hundreds of AG and SAG mills in operation throughout the world. Application of new internal elements of the mills and reconsideration of the circuit design of the existing grinding equipment using present technological solutions would significantly increase the throughput rate and diminish power requirement.

Jan 1, 2008

The Gordonsville Operation of Pasminco US Inc. along with the Center for Advanced Mineral and Metallurgical Processing (CAMP) at Montana Tech studied, developed and implemented a pilot scale hydrometallurgical facility for the industrial recovery of germanium and gallium. This paper describes the joint testing and engineering program that culminated in this successful process. 1. Introduction The Pasminco US Inc. (PAS), Gordonsville Operation, has been producing zinc concentrate continuously since 1975. Within the zinc concentrate, several byproduct elements were found to be significantly concentrated including gallium and germanium. The gallium and germanium replace zinc and other metals within the crystal lattice structure of the zinc mineral (sphalerite) and are concentrated in the same manner as the zinc mineral. This concentrate is then sent to the Pasminco Clarksville Zinc Refinery for further processing. Within the hydrometallurgical zinc-processing plant at Clarksville, a residue is formed that contains a majority of the impurities that would otherwise contaminate or hinder the zinc process. Approximately 5,000 tons of residue is formed annually containing approximately 0.80% gallium and 0.60% germanium along with significant quantities of iron, zinc, silica, and lead. Pasminco currently sells this residue for the germanium value. Until recently, no revenue for the gallium was obtained from the sale of the residue.

Jan 1, 2008

By H. F. Fuls

The quality of Pregnant Leach Solution (PLS) at Skorpion Zinc is of utmost importance for efficient operation of the Solvent Extraction (SX) Plant. Suspended solids in the PLS forms CRUD in the settlers, resulting in reduced zinc transfer capacity and increased impurity carry over to Electrowinning. The Ishigaki Fibre-Wakishimizu filter (fibre media rapid filtration equipment) has been identified as polishing filter that potentially could remove solids from the PLS of Skorpion Zinc. A pilot unit with 20m³/h capacity was tested on site over a period of 9 months under plant operating conditions in the refinery. The FW filter produces a clear filtrate, acceptable for the Solvent Extraction. Turbidity is improved by 72%. Gravimetric analysis indicates a 47% removal of solids. However, the gravimetric method is biased by a co-precipitation of saturated salts during the analysis. Filter media is blinded by the Skorpion Zinc PLS solution, as result of suspended solids and process chemistry. The media could not be regenerated to acceptable conditions. Further testwork to investigate the impact of process solution chemistry modification on blinding is undertaken. Based on the outcome of this investigation a final decision on the FW filter can be taken.

Jan 1, 2008

By Alicia Esther Ares

This study was conducted to investigate the directional solidification of Zn-20%A1 and Zn20% A1-1O%Si-3o/oCu alloys under different conditions of heat transfer at the metal/mould interface. The type of structure obtained in both cases was analyzed and related to the solidification thermal parameters such as cooling rate, growth rate, thermal gradient and recalescence which were determined from the temperature versus time curves. These parameters were correlated with the structure-like length of columnar grains and size of equiaxed grains. The metallographic analyses were done performing quantitative metallography and composition analysis of the different alloying elements along the cast samples by SEM (Scanning Electron Microscopy) and EDXA (Energy Dispersive X-Ray Analysis). Correlations between properties, structures and thermal parameters were found.

Jan 1, 2008

By Michael Drozd

"The operation of an activated charcoal system has five separate unit operations. These unit operations have common points for CIP, CIL and CIS system, which vary widely in application.The unit operations are:a. Absorptionb. Desorption (Stripping)c. Acid Washingd. Reactivatione. Carbon Handling (carbon transportation, sizing, dewatering, etc.)Cost optimization starts with the basic operating parameters (design philosophy) set down at the time of engineering design. These parameters undergo almost immediate change due to site specific ore requirements, throughput changes, operator requirements or reagent availability.Activated charcoal is sometimes viewed as simple, uncomplicated reagent that requires not optimization. To some extent, this statement is true, but under most circumstances, if the time necessary to optimize the use of activated charcoal is available, the effort is rewarded with significant savings. CPL-Carbon Link has embarked upon a program of supplying technical support with its activated charcoal. Several operations in the United States have undertaken to have CPL-Carbon Link do an operational survey to determine if potential savings are possible. CPL-Carbon Link has offered to do these surveys for projects that are clients or simply would like to have CPL-Carbon Link review their operation. The information accumulated by CPLCarbon Link is being used to attempt to fashion industry standards so that a common reference point can be established for activated charcoal usage."

Jan 1, 2008

By Selvin Yesilay, Guray Kaya, Bekir Karasu, Asli Cakir

"In this investigation, the wastes of Eti Maden Kirka Boron Company of Turkiye were evaluated in the production of diopside and anorthite-based glass-ceramic glazes suitable for porcelain tiles fast and single-fired under industrial conditions. First of all, high wear resistant frits were produced with the use of concentrator and derivative borax wastes. Second of all, pre-engobed porcelain tile bodies were coated with the standard and newly produced frit-based glazes and industrial fast single-firing was employed. Final products were undergone to the certain standard tests to determine their Vickers hardness, wear resistance, thermal expansion coefficient values, gloss and coloring parameters. The micro-structures and phase formations of the fired glazes were also studied. Consequently, it was confirmed that the utilization of borax solid wastes in fast single-fired porcelain tile glass-ceramic glazes is possible. Introduction Porcelain tiles were introduced at the end of 1980s by Friandre, one of the leading Italian porcelain manufacturers. The American National Standard Specifications for Ceramic Tile defines porcelain tiles as: dense, smooth, impervious (with water absorption value less than 0.5 %) and stain resistant [1]. The excellent technical performances for ceramic tiles, such as mechanical, wear, frost and chemical resistance that make their use possible in indoor and outdoor building applications [2-3]. In the last decade, the growth rate of the global production of porcelain tiles increased more than those of other ceramic products; in fact, the technical properties of porcelain tile, coupled with even more improved aesthetic appearance, gave it a prominent role on the tile market [2]. Glass-ceramics are composed materials of one or more crystalline phases immersed in a residual glassy phase [4-5]. Glass-ceramic technology is based on controlled nucleation and crystallization of bulk glass [6]. The concepts of controlled crystallization of glass designate the separation of a crystalline phase from the parent glass in the form of tiny crystals. Their growth rate and final size are controlled by a suitable heat treatment [7]."

Jan 1, 2008

By Akira Usui

Ferromanganese crusts on topographic highs in the western Pacific Ocean are believed to be potential resources of cobalt, nickel and platinum. Earlier shipboard geological and geophysical studies by Japanese organizations have focused on mapping of distribution of thickness and metal contents of the deposits when estimating the total reserves. This paper summarizes our attempt to obtain more feasible data of distribution patterns and configuration of the deposits which are important parameters for resource evaluation at some seamounts in the South Pacific Ocean. Morphology of the seamounts and micro-topography of the sea floors are described using shipboard acoustic remote sensing, deep-tow sonar images, and TV/camera. [ ]

Jan 1, 2008

By David Hill

The Australian underground coal mining industry is increasingly operating in an environment that challenges traditional concepts of coal pillar design, against a background of heightened expectations and demands from other stakeholders with regard to the protection of both natural surface features and burgeoning civil infrastructure. The result is greater possibility of conflict between mine operators, developers and regulatory bodies, with potential for unnecessary sterilisation of Australia?s coal resources and/or escalating surface development / infrastructure protection costs. On the positive side some significant advances have occurred in the general level of understanding of pillar behaviour and stability, both in Australia and overseas. This paper examines some current issues in coal pillar design, focussing particularly on the application and limitations of analytical models of pillar loading. Established methodologies are reviewed and alternative approaches explored, including examples of key geometrical, geological and probabilistic concepts. Practical experiences from the Southern Coalfield of New South Wales (NSW) are examined for the purpose of highlighting critical variables. Finally, some suggestions are made with regard to the direction and opportunities for future research, with particular regard to coal pillar loading, in the interests of all stakeholders.

Jan 1, 2008

By Karsten Zimmermann

Surface deformation monitoring is required all over the mining industry. For example oil and gas companies need this information to support exploration and production activities and to detect impacts from surface subsidence of existing hydrocarbon fields. Also opencast mines require large area information of subsidence due to dewatering of the overburden. Because of this, a lot of surface deformations measurements with GPS or traditional geodetic measurement techniques have been conduced during the last decades. This paper presents the actual capabilities to analyze GPS data using the state of the art Bernese GPS Software for GPS post processing. A new way of monitoring subsidence is a combination of GPS and satellite InSAR data. Considering this it is hoped that a combined strategy will permit receiving overall more information by integrating high point density of InSAR and accuracy of GPS. DMT is one of the leading actors on GPS services especially for monitoring surface movements from underground activities e.g. mining, water pumping or oil and gas exploitation. The paper will discuss preferences and problems of this approach on results of a current project of DMT.

Jan 1, 2008

By H Catchpole, L FontbotT, J PTrez, M Ageneau, A Bendez·

In the world-class mining district of Morococha, epithermal polymetallic replacement bodies and veins overprint porphyry mineralisation and skarns related to subvolcanic intrusions of Miocene age, thus indicating ore formation in two different environments, separated in time or forming a continuum. The district covers an area of about 70 km2 in the north-western part of the Domo de Yauli complex in theWestern Cordillera of central Peru and is part of the Miocene polymetallic belt, also hosting the deposits of Colquijirca (Bendez· et al, 2008b) and Cerro de Pasco (Baumgartner, FontbotT and Vennemann, 2008). Multiple late-Miocene porphyry stocks intruded Permian, Triassic-Jurassic and late-Cretaceous sedimentary carbonate and volcano-sedimentary formations, as well as large mid-Miocene barren intrusions. Extensive field work and detailedmapping of different styles of orebodies suggest that ore formation in the area was related to the late-Miocene magmatism. Good outcrop conditions and superimposing of different mineralisation styles make Morococha an ideal location for studying ore-forming processes in a complex porphyry-related magmatic-hydrothermal system in which porphyry-to-epithermal transition occurred. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By P Hollings, J Holliday

Porphyry copper, gold and molybdenum deposits form in subduction-related settings in association with calc-alkalic or alkalic magmatism. Hydrothermal alteration assemblages are zoned, with potassic cores and propylitic haloes overlain by extensive domains of clay alteration and silicification (lithocaps). Copper sulfides, gold and molybdenite typically occur in veins or hydrothermal breccias, and less significantly as wall rock replacements. Epithermal deposits may form above or to the side of porphyry systems, and may be juxtaposed into the core of a porphyry deposit if rapid uplift and exhumation occur through the life of the magmatic-hydrothermal system. Volcanichydrothermal breccia pipes (ædiatremesÆ) commonly form late in the life of a porphyry system. They may contain clasts of porphyry-style mineralisation, and can host significant epithermal gold resources. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By T. A. Chepushtanova, B. Mishra, E. O. Kilibayev, V. A. Luganov

"The paper contains the results of studying about modification of pyrite and arsenopyrite specific surface and porosity at their thermal decomposition. The studying of specific surface was carry out by B.E.T. – adsorption of nitrogen at his boiling-point. In our work were using the electron-microscopical, X-ray structure analysis and chemical analysis. There was established that the decomposition of pyrite and arsenopyrite accompany by increasing of pores volume from 0.303 · 10-3 to 1.23 · 10-3 at increasing of pyrite degree of decomposition about 41 % and then decrease about 0.131 · 10-3 m3/g at degree of decomposition near 100 %. The surface area of pores increase from 0.31 to 1.085 m2/g with following lowering due to enlargement and confluence of minor, small pores. Increasing of porosity accompany with increasing of particles windage that appear the result of heightened dust-furnace partially decomposing pyrite and arsenopyrite particles by air flow from furnace reaction zone. This explains heightened contention of sulfide sulfur in roast dust of sulfide concentrate. 1. INTRODUCTION As a result of ore base exhaustion of ferrous and nonferrous metallurgy at metallurgical treatment are involving more complicated and less qualitative ores. Magnetiting ores content considerable quantity of pyrite complicative the technology of iron extraction. At the same time the pyrite concentrates wining at dressing content different nonferrous metals in industrial quantities. Extracting ores of nonferrous metals are contenting considerable quantity of arsenic at the present time. Extraction of base metals from complicated raw materials demands new technologies. Arsenic contenting in ores is necessary to utilize (waste burial) in more ecological compatible form. Arsenic on acting metallurgical and chemical enterprises from technological cycle is withdrawing in the form of arsenate – arsenite cakes, burial of their may lead to seriously ecological problems as times goes by. In Kazakh National Technical University is carry out the cycle of researching by pyrite, arsenopyrite and arsenate – arsenite cakes treatment with the object of arsenic withdrawal in sulfide form – in more ecological and safe form and with the object of preparation of initial ore raw materials to following pyro- and hydrometallurgical treatment. As a result of sulfidizing of arsenate – arsenite cakes by pyrite are forming the volatile arsenic forms and pyrrhotite of variable structure."

Jan 1, 2008

By A. A. El-Midany

Traditionally, the choice amongst different upgrading techniques or in finding the optimum operating conditions for a given upgrading technology depends on whether one is looking at the grade or the recovery of the valuable mineral in the concentrate. In fact, the conclusions are not usually the same. This is because the best technique or optimum operating conditions for the highest grade are not the same as the conditions to achieve the maxi-mum recovery. Therefore, a unique measure that takes into consideration both grade and recovery is urgently needed. Finding such a measure is the objective of this paper. A proposed measure provides a selectivity index in the range of 0 to 1, where 0 is no selectivity and 1 is ideal selectivity. The index can be obtained by plotting the so-called Fuerstenau upgrading curve, which relates the recoveries of the components in products of separation and a running regression applying a one-parameter equation. The measure was applied to assess the selectivity of selective flocculation under different operating conditions when used as a sensitive upgrading technique for ultrafine ground ores. After applying the proposed selectivity measure in the case of the selective flocculation of ultrafine Egyptian iron ore without the addition of cations, it was found that the optimum conditions are pH 11, 1 kg/t sodium silicate and 0.4 kg/t potato starch with a selectivity index of 0.55. With the addition of cations, the optimum conditions were found to be pH 11, 1 kg/t sodium silicate and 2 kg/t potato starch with a selectivity index of 0.65. It should be noted that determining these optimum conditions using the traditional grade or recovery measures was highly ambiguous.

Jan 1, 2008