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By G. van Aswegen

The geometry and morphology of a set of low-angle fractures around a stope in a deep Witwatersrand gold mine are explained in terms of extension fractures forming under variable conditions of stress. Primary extension fractures (E1) form some distance ahead of an advancing stope along the s1, s2 plane. With stope advance, a couple of these fractures end up in a stress regime conducive to transpressional shear and a secondary set of extension fractures(E2) is formed at a high angle to the primary fractures. i.e. at a low angle to the stope. As the E2 fractures are undermined, they migrate into a stress regime of transtensional shear and a third set of extension fractures (E3) may develop between E2 fractures. These have sigmoidal shapes, being parallel to the E2 fractures at the E2 discontinuity where s3 is negative, and curved through the unfractured rock between E2 fractures where s3 is positive at the instant of fracturing. The fractures all display fractographic features characteristic of dynamic extension failure with striae indicative of the direction of rupture propagation and the local, instantaneous orientation of s1.

Jan 1, 2012

By K. Koruyan

Although remote sensing technology has been available for many years, it has rarely been used for monitoring mining activity. Recent studies indicate that remote sensing is also a valuable tool for managing and planning certain aspects of the mining operation. In this paper, we examine areal expansion of marble quarries and the affected vegetation over a period of 10 years in the Mugla region in Turkey, using geographic information system (GIS) and remote sensing (RS) techniques. Images captured by ASTER Level 3A01 (3D Ortho Data Set), Landsat 5, and Landsat 7 satellites between 2001 and 2009 were used for the analysis. Changes in the natural vegetation as a function of the production level in the marble quarry were calculated using the normalized difference vegetation index. According to the study results, land cover and natural vegetation decreased by less than 3 per cent and 1 per cent respectively between 2001 and 2009, following an upsurge in mining activity in the region.

Jan 1, 2012

By P. P. Rosario

A research project was conducted at the University of British Columbia (UBC) resulting in the development and evaluation of a novel comminution circuit incorporating autogenous grinding and parallel trains of cone crushers and high-pressure grinding rolls (HPGR). A primary driver for the circuit was to treat ore from deposits with clay and variable hardness. This paper summarizes the unique pilot-plant test program that was developed as a basis for experimental simulation and lists the main findings of the research, including the circuit?s potential operational cost savings compared to a conventional SAG circuit.

Jan 1, 2012

By Jorge Alberto Soares Tenório, Flávia Paulucci Cianga Silvas, Bianca Medeiros, Denise Crocce Romano Espinosa, Ivo André Homrich Schneider, Daniella Cardoso Buzzi, José Roberto de Oliveira

"AMD is one of the main problems associated with mining activities and the techniques used in their treatment may be the biosorption. The aim of this work was to study the rice husk as a biosorbent for the AMD treatment keeping constant: pH (2.6), biomass concentration (1g.L-1), temperature (25°C) and agitation (175rpm). And varying the contact time of 5, 20, 60 and 240 minutes. Rice husk samples will be characterized before and after the biosorptives tests through analysis of SEM and IR. The micrographs indicate the occurrence of micro-precipitation and changes in biomass physical structure. Since the infrared spectra indicate changes in functional groups present in the biomass before and after the biosorptives tests. AMD synthetic solutions will be analyzed by ICP in order to quantify the metals concentration captured by biomassIntroductionThe preoccupation for the environment has led the industry in general, to treat their waste. As the only industrial activity is increasing, the pollutants generated must undergo treatment processes aimed at reducing pollution, and therefore, less aggression ecosystems.In mining there is waste water with accumulation of heavy metals, and these are harmful to health of living beings, thus being one of those industries responsible for some pollution of the environment. These wastewater in contact with oxygen to generate an acidic water is called acid mine drainage (AMD). This aqueous solution has a pH below 3 and varieties of dissolved metals. When this solution comes in contact with water, generates a series of environmental problems, so there is a need to recover the metals present in the DAM."

Jan 1, 2012

By W. G. Huang

To recover the coal resources of high-sulphur anthracite in Jincheng Mining Area, underground coal gasification (UCG) of No. 15 seam in Fenghuangshan Coal Mine was proposed. The feasibility of the project was confirmed by investigations of occurrence conditions, coal properties, and roof conditions, as well as experimental studies and theoretical analysis. It was found that UCG technology is appropriate to be adopted in the mining of the No. 15 seam, due to the stable rock conditions, simple geological structure and hydrogeology, the high carbon content of the coal, non-cohesiveness, medium-thermal stability, high ash fusion temperature, and weak reactivity with CO2. Further factors are the characteristics of the immediate roof, which consists of 9.11 m of limestone and mudstone with a compact structure and low permeability, and 4.27 m of dominantly mudstone with low permeability.

Jan 1, 2012

By Fiseha Tesfaye, Pekka Taskinen

"A thermodynamic study of the equilibrium phase assemblage AgBi3S5-Bi2S3-S was made by an EMF-technique, using the RbAg4l5 solid electrolyte. The ternary phase was synthesized from the pure Ag2S and Bi2S3 in an evacuated silica ampoule and grinded into powder and mixed with appropriate compositions of B12S3 and S, in a series of experiments, for pressing in to pellets. The pellets were assembled to form the galvanic cells Pt (-) | Ag ] RbAg4ls | AgBi3S5+ Bi2S3 + S + (C) I Pt (+). The EMF-measurements were made in the temperature range 299 - 460 K.In this paper, thermodynamic functions of the ternary phase AgBi3S5 (pavonite) have been determined. The agreement between the obtained results and the literature values were established.IntroductionThe complex group of ore minerals constitutes from trace amounts to a major proportions of sulfosalts. Although the sulfosalts rarely form massive ore bodies, they are commonly associated with rich sulfide ore minerals for the base and precious metals and widely distributed in a metal poor sulfide minerals [1]. For instance, Ag-bearing sulfosalts are encountered in ore minerals for the production of the base metals and are common sources of silver. Nevertheless, thermodynamic properties of the sulfosalts are poorly known.Reliable thermochemical data are essential for quantitative modeling of the chemical behavior of the sulfosalts in equilibrium with sulfides, which in turn would promote the optimization of complex minerals treatment and extractive metallurgy of the valuable metals."

Jan 1, 2012

By Hideyuki Takahashi, Taro Aichi, Kazuyuki Tohji, Makoto Muramatsu, Rie Sato

"There are several ways to condition lead-based alloy anodes for zinc electrowinning: electrochemical treatment, chemical treatment and physical treatment. Two advantages of physical treatments are their productivity and variety. In this report, physical treatments, including blasting with silica, alumina, steel grit and cut zinc wire, were tested. The laboratory tests confirmed there were differences in the formation of anode scales during electrowinning and in the suppression of lead dissolution from the anodes. With an increase in the surface roughness, the misfit between the PbC""2 and the MnC>2 was mitigated and the anchor effect was promoted; these effects resulted in dense Mn oxide scales on the anode.IntroductionZinc is widely used for hot-dip zinc plating and for die casting alloys. As a supplier of materials, we have endeavored to produce zinc that is economical and contains as little impurity as possible. As a result of our efforts, a technology for consistently providing special high-grade (SHG) zinc has been established. However, as seen in the issuance of the Restriction of Hazardous Substances (RoHS) Directive, public awareness of the industrial impact of heavy metals on the environment has been heightened. Increasing efforts to control environmentally sensitive substances will be necessary for our production processes.Electrolytic SHG zinc is produced by electrodeposition in an acidic solution with a Pb-Ag or Pb-Ag-Ca alloy for the anode and an Al alloy for the cathode. Pb alloy anodes are widely used because of their excellent durability; however, they are a source of Pb, which is the main impurity of the product."

Jan 1, 2012

By A. Bascetin

Waste materials caused by mining activities are an important environmental problem. Paste technology is a good alternative for waste management because it has many benefits in the aspects of environment, cost and safety. Disposal of process wastes in paste form is an attractive option for waste management, as it eliminates or reduces the risks associated with conventional methods. Due to the geotechnical characteristics of the paste, it is very similar to soil materials. So determining the geotechnical properties of the paste material is essential to durability of the paste. The some important geotechnical properties are compressive strength, porosity, shear strength, hydraulic conductivity, water content, consolidation, etc. In this study, the important parameters and the relation between them were investigated and obtained some results which will affect for optimum design of waste management.

Jan 1, 2012

By M. M. Makhofane

Anhydrous zirconium tetrafluoride can be used as a precursor for the manufacturing of nuclear-grade zirconium metal. This can be done by fluorinating plasma-dissociated zircon with ammonium bifluoride in a batch reactor. This paper describes the batch process. It was proved that anhydrous zirconium tetrafluoride can be manufactured by this route as confirmed by X-ray diffraction. The process shows potential for scaling up to the kilogram scale and possibly the tonnage scale.

Jan 1, 2012

By Greg Beckstrom

On Oct. 1-3, SME?s Twin Cities chapter (SME TC), in cooperation with the University of Minnesota ? Duluth?s Precambrian Research Center (UMD-PRC), cohosted a symposium on silica sand mining and processing. The conference was held at the Earle Brown Heritage Center near Minneapolis. The symposium was followed by a day-long field trip to operating mines, processing plants and loading facilities located in southwestern Wisconsin. Speakers and attendees at the symposium included university professors, industry experts, regulators, mining company representatives, equipment suppliers, consulting engineers and service companies. Approximately 320 people attended the conference. In addition, about 50 people who oppose mine development and the oil and gas industry showed up to voice their displeasure with the event and those companies that operate in this space.

Jan 1, 2012

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By Xie Zhang, Jiang Diao, Xiaojun Li, Bing Xie

"Vanadium is widely utilized as an important element to improve the quality of alloyed steels in iron and steel industry. Moreover, the crystallization process of V-containing spinels plays a significant role due to the aim of achieving a fairly larger size of spinel crystals in vanadium extraction. Thus, a comprehensive exploration and discussion on the competitive precipitation and growth of vanadium, chromium and titanium spinel crystals in vanadium slag during a cooling process were carried out in the present study on the basis of a crystallization kinetic model. To be more specific, the abilities of forming crystal, precipitation order and suitable temperature range for crystallization of the three kinds of spinels were discussed with both theoretical and experimental methods.IntroductionVanadium is an important element which is used almost exclusively in ferrous and non-ferrous alloys due to its excellent physical properties such as high tensile strength, hardness, and fatigue resistance [1]. Various kinds of processes of vanadium extraction from V-containing hot metal are available at present. However, only four processes which are the Highveld process (South Africa), the Pan-steel process (China), the NTMK duplex process (Russia) and the New Zealand steel process (New Zealand) take the dominant positions [2, 3]. Although the type of reactor and the initial vanadium content in hot metal are different in these techniques, they share the same principle that vanadium is oxidized by oxygen into vanadium slag."

Jan 1, 2012

By G. Barr

"The Polymetallic Twin Metals Project deposits in Northern Minnesota are being developed by Twin Metals Minnesota. Amongst the flowsheet alternatives being examined at a prefeasibility study level is one involving flotation of a bulk concentrate followed by high temperature autoclaving of the concentrate using the PlatsolTM Process to solubilize all the valuable metals in the concentrate (Cu, Ni, Pt, Pd and Au). Autoclave operating conditions have been established in which recoveries of all the pay metals are in the 92 to 99% range, and the autoclave residence time has been reduced to an hour. The stability of the precious metals in solution after autoclaving has been assessed, as well as the impact of internally recycling process liquors to the feed to the autoclave.INTRODUCTIONPlatinum group metals (PGMs; platinum, palladium, rhodium, ruthenium, iridium and osmium) are traditionally recovered from their ores by production of a high-grade concentrate by flotation and/or gravity concentration followed by smelting of the concentrate. Concentrates are smelted to remove nonsulphide minerals and converted to remove iron and sulphur. The resulting high PGM grade matte is processed hydrometallurgically to leach the base metals, leaving a residue with a very high grade (20-40%) PGM concentrate for final refining to individual PGMs. Due to the complexity of this process and its high capital cost, this process can only be applied economically to high grade PGM ores. Lower grade PGM concentrates might be accepted as copper and nickel concentrates but may not yield attractive payment terms for the PGMs. The mineralized Duluth Gabbro region of Minnesota hosts several low grade base and PGM deposits and Twin Metals Minnesota is working to develop the Twin Metals Project deposits. Earlier studies at both pre-feasibility and feasibility level, by other mining companies, have failed to yield an economically viable project based on the traditional process. It is possible to produce a saleable copper concentrate from these ores, but economic recovery of nickel and PGMs into saleable concentrates proved elusive.In the late 1990’s and early 2000’s the Platsol™ process was developed at SGS in Lakefield, Ontario (at the time Lakefield Research Limited) for the NorthMet deposit (also within the Duluth Gabbro) owned by PolyMet Mining. The process developed was a high temperature chloride-assisted pressure oxidation process capable of dissolving simultaneously the base metals (Cu, Ni, Co, Zn), gold and the PGMs."

Jan 1, 2012

By S. B. Breyner, A. Ressler, D. Gregurek, A. Spanring

"The changes in process conditions that frequently decrease the service life of refractory products provided incentive for RHI AG to develop high performance bricks, especially for non-ferrous metal applications. Innovative product development was required to determine suitable refractory products for improving lining life. At the Technology Center in Leoben, Austria, practical corrosion testing methods and facilities, including an induction furnace and rotary kiln, enable detailed comparative analysis of brick wear on a pilot scale. In tests that were carried out using a fayalite type slag, the newly developed RADEX VFG magnesia-chromite grade showed very promising results compared to the standard grades. Based on the test results, optimal refractory solutions can be recommended for this challenging industrial application and field trials can be performed directly at the customer's site.IntroductionThe complexity of metallurgical processes in the non-ferrous metal industry, and especially changes to the process conditions in combination with the diversity of metal processing furnaces ''', requires a precise understanding of each individual system for appropriate refractory product selection l2'. In addition, particular importance is focused on the specific refractory consumption being as low as possible.Another important aspect results from the global shortage of resources, which forces companies to invest in recycling processes. In the base metal industry, recycling operations have resulted in significant changes; for example, operating with two slag chemistries and process temperatures will influence the performance of previously suitable linings. The raw material mix for primary smelters has also changed, including higher levels of secondary raw materials in the smelter feed."

Jan 1, 2012

By Thierry Bernard

Since the signature hole method principle has been described in the 80's, there has always been a lot of controversy about it. The theory is easy to understand but when it comes to apply it for predicting vibration level, optimizing timing to reduce PPV or shifting frequencies, it’s not always working as expected. Simulations show waveforms that don't make any sense or predictions that are far away from actual results.

Jan 1, 2012

By Dennis L. Murr, James E. Wennen

"The through-put and energy efficiency of an autogenous (AG) grinding mill are adversely affected by variability in rock size and rock competency. This applies to both fully autogenous and semi-autogenous (SAG) grinding circuits. In this paper we focus on an approach to overcome the problem of inconsistent mill through-put related to variability in mill feed size and rock competency. The focus is on ores containing hard, competent rock. This approach consists of preparing feed to an autogenous mill that contains 20% coarse media rock and 80% of material crushed to pass 37 mm. Results of pilot-scale testing for two iron-ores will be presented to show that a 10% to 12% reduction in unit energy consumption is possible with prepared feed, compared with feeding the mill with conventional primary crusher discharge.INTRODUCTIONIn the past 30 years or so, autogenous grinding and semi-autogenous grinding have been the comminution technologies of choice for most mining and mineral processing operations. These technologies saved both capital and operating expenses associated with the installation and operation of multi-stage crushing and screening plants required for conventional rod mill – ball mill circuits. However, SAG and AG are inherently inefficient in terms of energy consumption, especially for very hard ores. In cases of hard ore, changing characteristics of rock fed to the mills causes wide fluctuations in mill capacity, which contributes to the inefficiency. Rising electric power costs make this the most expensive unit operation used in the extraction of valuable minerals from an ore. The objective of the concept discussed here is to reduce the energy consumption in AG grinding for hard ore and eliminate the use of large-diameter steel grinding balls that are required for SAG grinding"

Jan 1, 2012

By Jilai Xue, Jun Zhu, Yongqiang Liu

"Up-grading silicon feedstock by removing B and metal impurities can improve process efficiency and lower production cost in metallurgical processing for solar cells production. Hydrometallurgical study has been carried out in laboratory through alternative treatments of the metallurgical grade (MG) silicon (-200 mesh) by using hydrogen peroxide, hydrofluoric acid (4 mol/L) and NH4Cl-NH4 F (30:5) solution. The experiments were usually performed under mechanical agitation at 70 ? for 5 h. ICP-AES analysis showed that B content in MG silicon after the hydrometallurgical treatment has reduced by 92.4 %, and Fe, Al, and Ca contents by 98.8 %, 98.0 % and 81 %, respectively. Kinetics of these processes was also studied for better understanding of the effects of silicon powder size, acid concentration, leaching and oxidizing time on the processing chemistry.IntroductionAs one of the most clean and promising new energy, solar energy is used more and more in many countries all over the world, especially in United States, Japan and European Union. Most of industrialized states have made their national photovoltaic plans, which have stimulated further increase in use of solar energy. Photovoltaic Industry is at a high growth rate about 30 % [1-2]. For silicon solar cells to remain the mainstay for the photovoltaic industry it is necessary to develop a low-cost solar grade silicon feedstock [3]. At the same time, the availability of the currently M-G silicon from the semiconductor industries becomes limited [4]. With the advantages of low cost and low energy consumption, metallurgical routes to product solar–grade silicon get more attention [5]. These routes mainly include pickling, slagging, vacuum processing and directional solidification, etc [6]. Among them the most important processing step is the directional solidification, but it still can not satisfy the industrial demand for removing B. Removing B from Si remains as one of the most difficult and important processes in making M-G silicon [7]."

Jan 1, 2012

By M. J. Latva-Kokko, T. J. Riihimäki

"Oxidation autoclaves are normally operated at elevated temperature and pressure. The improvement in kinetics is due to combined effect of temperature and partial pressure of oxygen. In this paper exclusive effect of pressure has been studied with a low grade sulphide ore at below 100 °C temperature. These studies are related to development of a novel tower-like reactor that utilizes hydrostatic pressure. Technology is designed to generate high amount of effective fluid volume for high solid content slurries with lower energy consumption and improved kinetics compared to normal atmospheric operation.INTRODUCTIONEconomical utilization of low-grade ores requires handling of enormous amount of material. This sets new requirements for process equipment in terms of size and energy efficiency. For example on the field of mineral processing this has lead to a six fold increase in the operating volume of mechanical flotation cells over the past two decades. Ore beneficiation methods like flotation greatly reduce amount of material that needs to be further processed in smelters or hydrometallurgical refineries. However with some ore types, such as nickel laterites and refractory gold ores, traditional concentration technologies cannot be utilized. Thus direct leaching of ground ore could be an attractive option. In many cases normal atmospheric tank leaching has traditionally been a non-feasible option mainly due to high capital and operational expenses induced by large amount of stirred reactors required. Main restriction for increasing reactor size to beyond 500 m3 has been mechanical load and power requirements set by mixing in cases when high dispersion efficiency of gas is required. THEORETICAL BACKGROUNDIn hydrometallurgical industry autoclaves are typically operated at elevated temperature and pressure. In many cases increase in operating temperature is the desired phenomena and improvements in kinetics are strongly related to that. Thus increase in pressure might be induced solely by water vapor pressure. However when gaseous feed is present, pressure itself has a strong effect on leaching kinetics for various reasons and its role should not be neglected."

Jan 1, 2012

By Liyuan Chai, Bing Peng, Ji Peng, Di Yu

"Electric arc furnace (EAF) stainless steel dust has been classified as a hazardous waste by various government regulatory agencies as it releases heavy metals to environment. The solidification of EAF dust is to stabilize the hazardous components to the amorphous silica-alumina-based clays. The process of solidification is investigated and the softening temperatures of dust and additive clay mixtures are measured for economical thermal treatment. The results indicate that the mixture of dust and local clay with the ratio of 1:1 has the lowest softening temperature 1100 °C and it could pass the toxicity characteristics leaching procedure (TCLP) test for the environmental regulatory limits after thermally treated at softening temperature for 15 min. Major phases of thermal solidification product clinker are CaAl2Si2O8, (Fe, Cr)2O3, (Fe, Mg)(Cr, Al)2O4 and Al6Si2O13.IntroductionThe yield of stainless steels in China arrived to 10 million tons in 2006 and more than 0.2 million tons of stainless steel dust are produced annually. Approximately 1-2 wt.% of scrap charged to an electric arc furnace (EAF) enters the off-gases and then is converted into the dust and reported to the bag-house. The disposal or landfill of the dust becomes a serious environmental problem in China due to the increased production of stainless steels in recent years. The dust contains elements such as chromium (Cr), nickel (Ni), lead (Pb), zinc (Zn), cadmium (Cd) and their solubility in leaching media exceeds the environmental regulatory limits [1]. Even though easily feasible for low-grade MgO, it is not appropriate to stabilize the heavy metals from the heavily contaminated soils after the dust landfill [2]. Several dust treatment technologies have been developed and they can be divided into two types. One is to recover the metals from the dust [3, 4] and another is to stabilize hazardous components present in the dust [5, 6]. Recycling of the dust generated in EAF is a remediation option for cleaner production. Direct recycling of EAF stainless steel dust was developed to recover the metal value from the dust and protect the environment [7], but it was only suitable for the dust with high contents of Ni, Cr and Fe. As for the dust with low valuable metal content, thermal solidification is an appropriate choice for the dust treatment."

Jan 1, 2012

By E. Krystad, G. Tranell

"The kinetics of boron removal from liquid silicon during slag refining, as a process step in the production of solar grade silicon, has been investigated by means of small scale mass transfer experimental series at 1600°C, using a graphite crucible. The slags were SiO2-CaO based, with or without addition of approx. 19 wt% MgO. Experiments were carried out at slag-metal ratios of 1 or 2, where the silicon initially contained approx. 250 ppm boron. The metal-slag mass transfer coefficients for boron were found to be in the order of 1-3 · 10-6 m/s and were largely influenced by slag composition. The mass transfer rate was higher for the MgO-containing slag than the slags without MgO. The final equilibrium distribution of boron between metal and slag, LB, was determined to be in the order of 2.3-3.3.I. INTRODUCTIONRecent years have seen a race in industry and research aimed at obtaining a reliable metallurgical route for production of silicon for solar cells (SoG-Si) from metallurgical grade (MG) silicon. Metallurgical routes can successfully challenge the traditional chemical routes for production of SoG-Si if they generate metal of sufficient purity while being less expensive in terms of production cost and energy consumption. Efficient removal of boron is one of the greatest obstacles in the refining of silicon by a metallurgical route, because the segregation coefficient of boron in silicon makes directional solidification unfeasible; in addition, the vapour pressure of boron is not high enough for removal by vacuum refining. However, the thermodynamic properties of boron makes removal from silicon by oxidation possible, and thus the process of slag refining of silicon has been receiving increasing attention as a method for boron removal."

Jan 1, 2012