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By E. Jannoulakis

This paper introduces a practical methodology for analyzing vi¬bration records in view of improv¬ing blast designs and preempting anomalous vibrations. This technique, which is based on empirical data, uses a blasting-efficiency determinator (BED) as an indicator of vibration-energy transmission. The method was tested using data from a blasting event at an open-cast coal mine in the province of New Brunswick, Canada. The results derived from the BED values showed that geology and delay timing were probably the principal factors that induced high-intensity vibration propagation.

Jan 1, 2000

By T. Innmi

The potential of the nickel matte anode was measured during the matte electrolysis in the commercial cell. The slime layer consists of elemental sulfur and was found to greatly influence the potential of anode. The measurements of porosity and permeability of the slime suggest that the voltage drop of the slime layer dominates the potential. Furthermore, the diffusion of the electrolyte through the slime layer is also one of the factors to determine the potential. In addition, the copper content of the nickel matte anode was found to affect the change in the anode potential during the electrolysis. The role of copper on the anodic dissolution of nickel matte is discussed in this work.

Jan 1, 1988

By R. E. Lindstrom

The mineral bastnasite is utilized to describe alternate processes for the extraction and separation of the rare-earth elements by solvent extraction. The rare earths can be acid-leached directly or fused with NaOH before acid leaching. Cerium, the major constituent, can be recovered by fractional precipitation, fractional leaching, or solvent extraction with tri-nbutyl phosphate. The latter process is capable of producing 99.5-percent pure CeO2 at 98+ percent recovery. Lanthanum is subsequently recovered by fractional precipitation or solvent extraction with a nitrogen-based extractant. A 20-stage mixer-settler operation with a primary amine extractant results in a 95-percent pure La203 fraction at 96 percent recovery. Europium is amenable to extraction from most of the remaining rare earths with an organophosphate extractant. Selective stripping of the europium, followed by reductive precipitation, produces high-purity Eu203. Another possibility for europium purification involves the differential extraction of europium with an amine followed by a sub- sequent reducing strip. Separation of the remaining elements is more difficult but can be accomplished with amine or quaternary ammonium extracts. Typical separation factors achieved are 3. 8 for praseodymium-neodymium and 10. 5 for neodymium-samarium.

Jan 1, 1967

By P. R. Beeley

Metal founding - a modern perspective The recent development of metal founding is reviewed in the context of basic requirements for the successful manufacture of cil;5ti,ngs.Progress has been related to the two interdependent fields of process technology and product characteristics. . After a brief review of the growth of the traditional industry. various features of the modern industry are discussed. Reference IS made to current trends in process technology and to the introduction of new techniques affecting production engineering, product quality. and the general nature of the industry. Metallurgical aspects of metal founding are considered, and modern techniques for the control of casting conditions are examined. These aspects are related to the structure and quality of cast metal and to the development of newer types of cast material and product.

Jan 9, 1976

By H. B. Menardi

The history, geology, ore deposits and current mining operations of the Huitzuco district have been described by C. W. Vaupelll and the current mill operations by David Segura.2 This paper completes the story of Huitzuco with a description of the reduction of the flotation concentrates. The predominant ore mineral in the Huitzuco deposit is livingstonite, a rare, mercury-antimony sulphide (HgS.2Sb2S3). Other associated minerals include cinnabar, stibnite and elemental sulphur. The gangue is largely limestone and gypsum. Former operators mined a selected grade of ore, from which the mercury was recovered by an expensive, inefficient operation. A considerable tonnage of rejects and fills, carrying mercury and antimony, was left in the mine. In order to recover both mercury and antimony from these fills and also from newly developed ore, a combination method has been developed, by means of which the livingstonite is concentrated by flotation and the flotation concentrates subsequently reduced to metallic mercury and antimony. An essential part of the flotation treatment, as developed by Segura, is the use of copper sulphate as an activating agent. A typical analysis of concentrates now being produced at the property is as follows: Hg, 7.73 per cent; Sb, 26.40; Fe, 1.20; S, 29.68; CaO, 11.50; MgO, 7.25; SiOz, 1.63; A1203, 0.65. PRocess foR Treatment op Concentrates In the development of a process for treatment of these concentrates, three different methods were investigated: (1) roasting in a Dwight-Lloyd sintering machine with an excess of air; (2) separation of mercury and antimony by distillation in a reducing atmosphere; (3) a third method, which ultimately developed into the present process. The third method involved a slow calcination at a closely regulated temperature with a limited admission of air, which separated the mercury and antimony, the raeroury passing out of the kiln with the furnace gases and the antimony remaining in the calcine or "sinter."

Jan 1, 1944

By H. E. Bartlett

In the operation of some flotation plants treating platinum ores it was found that there were imbalances between the inputs and outputs. The inputs and outputs were sampled as slurries and it was determined that the imbalances arose from biases in the sampling, despite the samplers having been designed according to well-established rules. The launders feeding the sample cutters, and the sample cutters themselves were redesigned using finite element analysis to model the flows. A new set of design rules were formulated. The application of a Components of Variance Analysis, to determine the variance of primary and secondary sampling and of analysis in the lab for a concentrate is presented to illustrate the need for frequent sampling of process streams.

Jan 1, 2002

By Barry J. Hansen, Ruston A. Ford

Production of mine backfill from the tailings produced in a proposed Crandon concentrator is described. A process has been developed capable of producing suitable fill for the mining method selected for the Crandon orebody. It maximizes the placement of pyrite underground as fill and segregates tailings into pyrite and nonsulfide fractions. To determine the suitability and engineering characteristics of the backfill product for use underground, laboratory and physical stope simulation model testing was conducted. The results of the testing and the application of those results to the design of the backfill system ultimately affecting mine geometry and subsequent mine production will be presented.

Jan 1, 1981

By J. Bouchard, R. del Villar, A. Vazirizadeh

"Industrial flotation is a continuous and often multistage process, where particles of a given mineral species (usually the targeted one), present in different sizes, encounter a large amount of gas bubbles (normally air) to produce mineral–bubble aggregates, which are removed from the flotation device (cell or column) as a valuable product (concentrate). The bubble content inside the cell is characterized by the prevailing hydrodynamic conditions (known as gas dispersion variables), which in turn are known to influence the flotation performance. Although most researchers and practitioners agree that the relationship between the hydrodynamic variables and flotation performance exists, the lack of an adequate method foronline measuring the average bubble diameter has prevented such studies.The aim of this study is to apply appropriate hydrodynamic variables for flotation kinetic modeling (as a key feature of flotation performance) for a given introduced particle size distribution (PSD). In this regard, experiments were conducted in a laboratory flotation column (5.6 cm internal diameter for a total height of 650 cm), and mixtures of quartz (hydrophilic gangue) and talc (naturally hydrophobic mineral), classified in four different size fractions. The correlation between the flotation rate constant and given hydrodynamic variables were analyzed. Results suggest that the relative importance of hydrodynamic variables for flotation rate modeling depends on the PSD. Finally the suggested hydrodynamic variables for each of the various particle size-classes considered were used to produce single variable models for the flotation rate constant. INTRODUCTIONIndependently of the prevailing flotation conditions, the mechanisms for bubble-particle aggregation and the residence time of the phases inside the device must also be considered. In this regard, one of the most used approaches to represent the overall flotation process is as a pseudo-chemical reaction between a particle and a bubble, whose rate (at a given time) is proportional to the amount of remaining floatable species. The proportionating constant is called the kinetic constant or the flotation rate constant."

Jan 1, 2016

By F. J. Sotillo

"Scrubbing both horizontal (drum) and vertical (attrition) are considered simple unit operations in the beneficiation of phosphate ores. In general, the operating conditions are fixed at high solids content based on the experience of the engineering or equipment manufacturing company responsible of designing this beneficiation step. Nevertheless, scrubbing is a complex unit operation designed to clean the surfaces of phosphate mineral particles of slimes, break loose weak inclusions or attached particles of impurities, and break aggregates of clayish material. Therefore, it is considered that as high solids content as possible should be used to enhance particle-particle interactions (impact and rubbing) without taking into consideration the rheology of the system. However, scrubbing unit operations design requires studying the balance between the increase of particle-particle interactions with the cushion effect that may occur when slimes, clays and fines decrease the availability of free water increasing the apparent viscosity of the phosphate slurry up to that of a paste consistency. This paper presents data from laboratory tests to determine the best operating conditions for the design of these unit operations based on the highest P2O5 grade obtained with the lowest impurities for different size fractions. INTRODUCTION In the beneficiation of phosphate ores, unit operations such as horizontal scrubbing (drum) and vertical scrubbing (attrition) are considered simple unit operations. Therefore, little attention is given to the design of horizontal and vertical scrubbing during the basic engineering studies, and the detail engineering stage, the manufacturers recommending “standard” units and operating conditions based on their experience. Due diligence of several beneficiation phosphate plants at industrial scale indicates that a deficient scrubbing of the phosphate ore results in significant problems in downstream unit operations, such as classification, clarification, gravity separation, magnetic separation, flotation, dewatering, and filtration. Scrubbing is in fact a complex unit operation designed to clean the surfaces of phosphate mineral particles of slimes (clays and fines), break loose weak inclusions or attached particles of impurities, and break aggregates of clayish material. Two phenomena occur, the particle-particle interaction (impact and rubbing), and the rheological effects of releasing significant amount of fines into the slurry. Therefore, high solids contents are recommended to enhance the particle-particle interactions, which may result in a change in the rheological regime of the system due to the slimes, clays, and fines decreasing the availability of free water. This increases the apparent viscosity of the system up to that of paste consistency resulting in a cushion effect that suppresses scrubbing. Under these conditions, not all fines are release and rejected (deslimed), downstream unit operations being affected by the release of clays, resulting in P2O5 losses."

Jan 1, 2017

By C. A. Rawlins, P. Rostami

"Ventilation systems are not only an integral part of any underground mine design but are a significant contributor to the mine’s capital and operating costs. The ventilation and cooling design systems presented in this paper were part of the prefeasibility evaluation of an underground platinum mine in South Africa. The mine would ultimately operate at the depth of 1,200 m below surface with a proposed 4 Mtpa production rate. The proposed mining operation is a highly mechanized operation using diesel equipment. Significant daily production rate, large amount of equipment and expansive nature of the operation, contributed to a challenging while flexible ventilation design requirements. This paper presents how to safely and efficiently optimize capital expenditure and operating costs associated with the mine air cooling and refrigeration system through practical ventilation design practices. Successful capital and operational savings by modulating installation and commissioning of refrigeration facilities can influence the economic realization of such systems. The adapted planning and design approach provided a cost-effective advantage while complying with design safety and regulations. INTRODUCTION This paper outlines a prefeasibility evaluation of the heat loads and related cooling system to be employed at the proposed platinum mine. The paper also provides appropriate details for a comprehensive understanding of the applied methodology. The proposed mine will be a trackless underground operation using a combination of mining methods. Initially, ore zones with vertical thicknesses greater than or equal to 18 m will be mined using the long-hole stoping (LHS) method, while thinner ore zones will be mined using mechanized drift-and-fill or drift-and-bench methods; hence, a highly mechanized operation with LHDs, trucks, drill rigs, personnel carriers, etc. is envisioned. Broken rock (ore and waste) will be transported by the means of trucks to the main passes (ore and waste) and collection points. Mining zones identified in the project occur at depths ranging between approximately 700 m to 1,600 m below surface. Primary access to the mine will be via a 1,100 m deep, 10 m diameter production shaft (named Shaft No. 2), three additional shafts will be sunk to provide future ventilation and production support. Three main access levels are established as primary haulage levels and include a series of interconnecting ramps. Additional mining sublevels will be developed as necessary. Figure 1 shows the proposed shaft locations and main access levels in a 3-D elevated view. Mining is performed using highly productive mechanized methods. For this reason, an annual ventilation estimate is based on requirements for mobile equipment (i.e., 0.06 m3/s/kW). The air requirements imposed on the underground operation is further influenced by equipment heat loads, auto compression, and virgin rock temperature, as the main sources of in-mine heat."

Jan 1, 2015

By Per Kofstad, Hallstein Kjöllesdal

The oxidation behavior of niobium (columbium) has been studied in the temperature range 500° to 1200°C and at oxygen pressures of 760,100, 10, 1, and 0.1 mm of Hg. The work comprises kinetic studies of the oxidation as well as structural investigations of the oxidized specimens by means of X-ray diffraction, electron diffraclion, electron microscopy, and metal1ographic techniques. The oxidation reaction has a highly irregular temperature dependence and is unusually sensitive to changes in the oxygen pressure. The complex oxidation behavior is suggested to be due to formation of different Nb2O5 modifications in different temperature regions. During oxidation oxygen is also dissolved in the metal. Formation of oxide whiskers take place on the oxide surface at temperatures above approximately 800°C. VARIOUS aspects of the oxidation of niobium have been studied.l-12 The investigations show that niobium has a complex oxidation behavior, and the oxidation

Jan 1, 1962

By D. W. H. Su

Following a roof fall in the B12 headgate of a CONSOL Pennsylvania Coal Company (CCPC) underground coal mine in February 1998, CONSOL R&D and Exploration initiated an underground roof geology reconnaissance program along the B13 and B14 developments to define potential roof instability areas and to recommend appropriate supplemental headgate support. This reconnaissance program revealed the presence of a thick, massive Pittsburgh sandstone channel overlying the B13 and B14 panels. Surface and underground core holes confirmed the close proximity and the very massive, nonlaminated nature of the sandstone. To mitigate anticipated adverse conditions at the B 13 and B 14 longwall faces due to delayed caving of the massive sandstone behind the shields, a task force consisting of Operations, Exploration, and R&D personnel was formed in May 1998. Several operational adjustments were made by mine management, including repairing damaged lemniscate links, maintaining immediate forward shield support, and implementing measures recommended by the task force intended to boost the shield set load density at the face. After reviewing available geotcchnical information, the task force also recommended fracing of the massive sandstone over the B13 and B14 panels to enhance caving characteristics and further reduce the bending-induced stresses in the sandstone near the face. Horizontal fracs were created at a horizon about 25 feet above the Pittsburgh seam main bench over the two panels in June and November 1998, respectively. To evaluate the effect of sandstone fracing and operational adjustments on the bending-induced stresses in the sandstone, three finite element models were constructed and analyzed. Results from the finite element analyses indicate that one horizontal frac, 25 feet above the Pittsburgh seam, would reduce the bending-induced stresses in the sandstone by approximately 50 percent, maintaining them at a level below the ultimate strength of the sandstone. Operational adjustments to increase the support set load density and support stiffness could reduce the bending-induced stresses in the sandstone by a maximum of an additional 10 percent. Shield pressure monitoring at the B14 midface confirmed the presence of a lower roof pressure zone inby and outby the 1314 frac holes. This lower face pressure significantly contributed to improving the B13 and B14 longwall productivity and safety. The total production downtime due to bad top at the B 12 face within the interval of channel influence was 30,600 minutes compared to about 3,500 minutes each for the B13 and B14 faces. The average longwall advance per machine shift for the B13 and B14 faces within the channel was about 70 percent higher than that for the B 12 face.

Jan 1, 2001

By Rossiter W. Raymond

The substance known as carbonite, or natural coke, has been several times the subject of comment before the Institute. The most important contribution hitherto made to the discussion is that of Dr. Henry Wurtz, of Hoboken,* who states, upon the strength of a chemical analysis, that carbonite is not a coke, but contains 14.08 per cent. of volatile combustible matter. In 1882 a mine was opened upon a carbonite seam, near Midlothian, Chesterfield County, Va., by Messrs. Jewett & Brother, of that place. The seam, which dips westerly at an angle of about 30 degrees, was struck at the depth of 137 feet with a vertical shaft, and followed on the dip 325 feet, at which depth gangways were opened north and sooth. For these statements (having made no personal examination of the locality), I am indebted to Mr. Albert Blair, of Richmond, and for the following section, to Mr. John Bladon, engineer at the mine. The section was taken in the face of the gangway, February 17th, 1883. It shows an aggregate thickness of 15 feet of "coke," of which about 5 feet were extracted by the system employed last winter. It is reported that under the "coke" seam there is a thick seam of highly bituminous coal, which has been extensively worked on a neighboring property, a little south of the Jewett colliery, the coal being sold for gas-waking. The carbonite is used for domestic purposes, and is said to burn

Jan 1, 1883

By High Archbald

It is possible to construct a simple diagram of the earnings, or the production, of the men employed at a coal mine that will show not only if the conditions tend toward contentment among the men, but if the operating distribution of the work is correct. As earnings are the greatest cause of discontent, even exceeding all the other causes, if contentment exists in the matter of earnings, the likelihood of other discontents flaring up is greatly lessened. The basis of such a diagram would be the Gaussian curve of the normal variation in human ability. Such a curve has long been recognized. H. L. Moore,' in discussing the quantitative relation between wages and ability says: "It has been pointed out that industrial efficiency is dependent upon physical, mental, and moral qualities, and these qualities . . . there is good reason for regarding as being distributed according to the Gaussian law.

Jan 1, 1925

By Raphael Trousselle, William Reisz

The blasting industry is now well into its second decade of commercial use of electronic detonators. As an increasing number of blasters are introduced to the technology, the benefits are becoming more widely monitored and accepted in many surface blasting operations. However, their use in underground applications is not yet as widely established. This is primarily due to the distinct cost dynamics and processes associated with underground lasting.

Jan 1, 2012

Most analysts determining tungsten trioxide in low grade samples are aware that colorimetric procedures do not possess the inherent disadvantages of gravimetric methods operating on milligram quantities of tungsten trioxide. Apart from the inaccuracies associated with weighing four or five milligrams of ignited oxide in a platinum crucible of about 30 gm. weight with a large surface area to absorb moisture, using a 5 gm. charge on samples less than about 0·15 per cent tungsten trioxide, it is extremely difficult toget complete or pure precipitation of tungsten with cinchonine, cinchonine plus alpha benzoin oxime, rhodamine B or any other of the commonly used precipitants. Table 2', No. 8, illustrates the low results obtained by gravimetric as opposed to colorimetric procedures. In addition the colorimetric determination requires only a small portion of the time consumed by gravimetric practices and the increased accuracy obtainable in low ranges together with the saving in time made it highly desirable to develop a colorimetric method suitable for King Island ores.The most commonly used colorimetric method is that introduced by Feigl and Krumholz (1932), since modified by various investigators (Grimaldi and North, 1943; Sandell, 1946; Westwood and Mayer, 1947; Gentry and Sherrington, 1948; Freund, Wright and Brookshier, 1951; Grouthamel and Johnson, 1954; and others). Stannous chloride is used to reduce tungsten followed by colour development with a thiocyanate, usually sodium, potassium or ammonium.Other reducing agents have been proposed (Emery and Curtis, 1948), but only in recent years have the conditions governing maximum colour development been fully estab...

Jan 1, 1958

By G. L. Neumann

The Andover-Sulphur Hill iron mines in Sussex County, N. J., have a production record extending over 100 years. The last production recorded was about 1880. These mines produced high-grade ore of two types: Bed ore (hematite) and blue ore (magnetite. Some sulfides (lead, zinc, and copper) were found underlying the iron deposits. Data as to size and grade of these sulfide bodies are very sketchy, Toward. J. Hewitt of Elizabeth, N. J., lessee of the Sulphur Hill mines from 194045, prospected for lead, zinc, and copper. .His Only production was several hundred tons of low-grade iron ore, which was crushed and used as heavy aggregate to make concrete blocks for ship ballast. In October and November 1942 made a magnetic survey of this area and bored six-diamond-drill holes with the dual objective of prospecting for sulfides and testing for extensions of the iron-ore deposits indicated by the magnetic survey. In 1944, an iron-mining company examined this property and diamond-drilled seven holes Between December 1949 and March 1950, the Bureau Of Mines in search of sulfide deposits, bored three additional diamond-drill holes. Two of these were on the Sulphur Hill tract and one on the adjoining Tar Hill tract.

Jan 1, 1952

By Burk, Hugh A.

AT THE inception of the cyanide process and its adaptation to the practice of gold and silver metallurgy much difficulty was experienced in applying it to auro-cupriferous ores, both in economy of treatment and recovery of the gold from solution. The presence of copper in the ore effected a high chemical consumption of cyanide during treatment, and in the solvent solution, it retarded the precipitation of the gold on zinc shavings. The coating of the copper on the zinc shavings presented even worse difficulties than the increased cyanide consumption as most ores contain a small amount of copper. This interference of copper led to the use of other precipitating methods and attempts to recover the cyanide which was consumed during ore treatment. Of the other methods used, electrolytic precipitation was the most practical until a better understanding of the application of zinc shavings and zinc dust developed. In September, 1905, a patent entitled, "Method for Recovering Precious Metals from Solution," was granted to Isaac Anderson and Michael Scanton. This method is adaptable to precious metal ores containing a small percentage of copper but has never been extensively used or perfected. The process has

Jan 1, 1925

By Rita Michael

"The Marmara Ironworks was not the earliest ironworks in Ontario, but it was distinguished from other early works in a number of ways. It was established on an ambitious scale as a self-sufficient and, for the time, sophisticated community. In effect it was an iron plantation on the scale and scope of those at Hopewell, Pennsylvania and Saugus, Massachusetts(1). It was, besides, the only one of the few early ironworks in Upper Canada which operated almost to the end of the nineteenth century, albeit in fits and starts, and which used magnetic ores rather than bog iron ores (limonite). Furthermore it is the only works which has produced archaeological interest over a number of years. The ironworks is on the east bank of the Crowe River near Highway 7, on Lots 7 and 8, Concession 4, Marmara Township, Hastings County, Ontario. It is the property of the Village of Marmara, and the extant remains encompass about 2. 5 acres of the original 2000 or so which made up the original grant. The mineral riches of the Canadian Shield had been known since the days of the Jesuit missionary-explorers. A consortium headed by Alexander Henry and the Duke of Gloucester planned to exploit the copper near Sault Ste. Marie during the last part of the eighteenth century, but nothing came of the venture(2). This attempt may have grown out of Lord Dorchester's suggestion that private enterprise be encouraged in order that the iron ore which ""abounds"" in Canada might be exploited(3). John Graves Simcoe, the first Lieutenant Governor of Upper Canada was also anxious to see iron working develop. Simcoe was eager to encourage many enterprises, among which ""the development of iron mines""(4) - Governor Gore had been approached by John Mason for help with his ironworks in Norfolk County (5). Three Americans had applied for permission and support to erect an ironworks on the Gananoque River at the falls to become known as Furnace Falls. They were granted 1000 acres of land in fee simple to encourage their endeavor(6). Sir Peregrine Maitland, only a few months after taking up his duties as Lieutenant Governor in 1818, intended to visit the ""bed of iron ore on the Crow River"" (7) - Maitland was to provide a good deal of support, both moral and substantive, to Charles Hayes when he came to Canada in 1820."

Jan 1, 1999

In this paper, the use of electrochemical AC impedance spectroscopy (EIS) for in-situ diagnosis of high temperature PEM fuel cells is described. EIS was performed on single cell hardware, built in-house, using a fuel cell test station modified to operate up to 120°C and 30 psig. Electrode kinetics, membrane resistance, porous-layer and mass transport impedance of MEAs, assembled in-house, were measured at various current densities for the purpose of validating the test station and cell hardware, and for optimizing MEA and flow-field designs. The effect of temperature and humidity on the various impedances was investigated. Impedances obtained at lower and higher temperatures were compared to obtain insight into the issue of water management in operating fuel cells.

Jan 1, 2005