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By Colquhoun L

Flooding velocities were measured in a laboratory column (96 mm 4) provided with both bottom and side air entry Packings used were 6 mm glass rings and spheres and -16 +8 mm coke. Results showed that when air was introduced through side nozzles flooding velocities were much higher than those obtained when air was introduced at the bottom of the column. Significance of the results and application to blast furnace flooding is discussed from the viewpoint of assymmetric gas flow.

Jan 1, 1975

By Liu Wei

In order to make clear the dissolving characteristic of the chrysocolla (CuSiO3?H2O) in the ammonia-ammonium chloride solution, a thermodynamic model of the chrysocolla (CuSiO3?H2O)-ammonia- ammonium chloride-water system is established using the exponential computation method based on both mass balance and charge balance equations. The equation group of the thermodynamic model is solved by the MATLAB Soft on PC. The condition which is favorable for dissolving high concentration of copper in solution is making out. The stable area of chrysocolla (CuSiO3?H2O) and the condition of chrysocolla (CuSiO3?H2O) converting to atacamite (Cu(OH)1.5Cl0.5) is also studied. A group of experiments are designed to validate the veracity of the results of the thermodynamic calculation.

Jan 1, 2010

By Courtney A. Young

All cyanide species are considered toxic and can be found predominantly in industrial effluents generated by metallurgical operations. For example, cyanide's strong affinity for metals makes it favorable as an agent for metal finishing and treatment and as a lixivant for metal leaching, particularly gold. These technologies are environmentally sound but require safeguards to prevent water contamination. Various methods of cyanide remediation by separation and destruction are available, but certain methods are more effective than others depending on the cyanide species being remediated. Photolytic destruction is regarded as the one technique that is independent of the cyanide species involved. The destruction of various cyanide species by several photolytic techniques has been investigated for the past few years. A literature survey suggests heterogeneous photocatalysis with anatase (TiO,) should behave similarly to homogeneous photolysis with hydrogen peroxide (H,O,) since proposed reaction mechanisms for both processes involve hydroxyl radicals. However, experimental evidence on a suite of cyanide species suggests otherwise. A new mechanism for the photocatalytic destruction of cyanides, especially SAD species, is therefore proposed.

Jan 1, 1998

By J. E. Lawver, W. D. Carrier

During the past 20 years, millions of dollars in research effort have been spent to improve methods of phosphate clay dewatering and disposal. Although to date no proven large-scale system has been developed that will result in ultimate below ground storage without the use of at least temporary dams, considerable progress has been made and a variety of techniques are being tested, some on a large scale. This paper summarizes the use of mathematical and centrifuge (physical) models that can analyze and evaluate various systems for the consolidation of phosphatic clays. These provide a powerful tool for engineers responsible for land management and mining waste disposal.

Jan 1, 1985

By N. A. Gjostein

The self-diffusion coefficient D, for a surface near the (100) plane in copper was determined by means of the Mullins theory of thermal grooving, and was found to obey the Arrhenius relationship, and Do = 6.5 x 10' sq cm per sec. Suppression of surface diffusion by chemisorbed impurities encounters difliculties as a satisfactory explanation for the large Q, and Do. Instead, a model is presented which indicates that Q,, as determined by a mass-transport technique, may involve both the energy needed to form an adsorbed atom from a ledge in the surface as well as that for the movement of the adsorbed atom.; LITERATURE reviews1-3 indicate that the mechanism of self-diffusion on metal surfaces is not clearly understood. The lack of experimental data on the temperature variation of the surface self-diffusion coefficient DJ has contributed greatly to this situation. Radioactive tracer techniques4-rn have been used to measure Ds, but for many years only Nicker-son and Parker8 had determined (for polycrystalline silver) an activation energy B, and a frequency factor Do for the surface self-diffusion process. Even in this case, a mechanism could not be clearly inferred because it was suspeted7 that a contribution from volume diffusion was not taken into account by the investigators. Some later work by Li and parkere on polycrystalline gold, in which they obtained essentially the same results as for silver and in which volume diffusion could be accounted for, seems to invalidate this criticism. In 1957, Mullins10'11 developed the theory for the thermal grooving process. This advance has opened a new and promising technique for measuring the surface self-diffusion coefficient Ds. Recognizing that a thermal groove may form by several different mass transport processes, Mullins first consideredlo the cases where a) the groove forms by evaporation and condensation or b) by diffusion along the groove surface, in either case, in a system where a metal surface is in contact with only its dilute vapor phase. In a later paper," he extended the treatment to cases where the groove forms by volume diffusion into c) the solid phase or d) by mass transport through a passive gaseous phase at 1 atm pressure. The time dependence of the groove dimensions and the shape of the groove profiles predicted by Mullins' treat-

Jan 1, 1962

By Dave Bulled

"This paper describes the design of an SABC grinding circuit using CEET technology applied to grindability data produced from testing 100 samples and distributed across the blocks of a mine plan using a geostatistical approach. The data distribution required the identification of the location of the sample points and a geological plan of the 130 million ton Ruby Creek orebody together with a mine plan of about 11000 blocks to be mined during the proposed 18 year life of the mine. The mill design was then made with consideration for the estimated hardness of each block in terms of both SAG and Ball milling with allowance for annual periods when the ore is harder to grind. Operating specifications were selected to achieve an optimum of capital and operating costs through use of the CEET program. The geostatistics assigned the statistical error that arises from having a limited amount of sample testing data to the hardness estimate of each block of ore in the mine plan. The final design could then include a quantification of risk and determination of safety factors based on the accuracy of block hardness estimates and CEET model fitting.INTRODUCTIONThe traditional approach to plant design involves the extensive testing of a single large composite sample or a small number of composite samples that are reputed to represent the ore body. It is accepted that the tests used can accurately measure in the laboratory the grindability of the sample by a process representing that to be used in the plant. The size of equipment required to achieve a specified throughput and product size is then calculated from one of a variety of models that have been developed by metallurgists over years of trial and error. Since these tests and models are tried and tested, they are accepted as reasonably precise; however during the operation of the resulting plant the design is sometimes found to be inadequate. It is then suspected that the flaw in the design process lies in the samples not being sufficiently representative of the ore body, since using only a single or small number of composite samples does not recognize the variability of the hardness of the ore, nor does it allow for the lack of precision in the hardness value used in the design.This paper outlines a design procedure suited to an orebody that is described by a geostatistical analysis of a reasonably large number of small samples of drill core. The analysis required the identification of the location of the sample points and a geological plan of the orebody, together with a mine plan of the blocks to be mined during the proposed life of the mine. The mill design was then made using the estimated hardness of each individual block with an allowance for annual fluctuations in the grindability of the ore. The geostatistical analysis assigned a statistical error to the hardness estimates of blocks and of each production year such that the final design included risk estimates and safety factors based on the possible errors that arise from having a limited amount of sample data (Kosick et al. 2002)."

Jan 1, 2007

By D. A. Belforti, M. P. Lepie

Spectroscopically pure copper was melted on sapphire plaques in a zydrogen atmosphere. The surface tension of the liquid metal was determined using the sessile drop technique. Measurements were made by direct observation with the aid of a specially const,mcted telescope. The value obtained, 1268 dynes per cm, is compared to that found in the literature. THERE is at this time considerable interest in the use of ceramics for vacuum tubes. The crystalline material is superior to the more conventional glass in mechanical strength, chemical inertness, dielectric properties, ability to withstand high temperatures, and so forth. However, ceramics are much more difficult to seal hermetically with metals than are the glasses. For this reason an investigation was undertaken to determine the wetting and adhesion of metals to ceramics. The sessile drop technique offers a convenient means at elevated temperatures for measuring liquid surface tension, wetting angle, density, spread- ing coefficient, and work of adhesion. Thus, from the contour of a drop of liquid at rest on a solid surface one can obtain a quantitative evaluation of the degree to which the two substances will bond. To this end a special apparatus was constructed so that various molten metals could be observed. Standardization of the apparatus was done initially by measuring the surface tension of copper since this is well documented in the metallurgy literature. Although there are many methods available for the measurement of surface energy,'+ the sessile drop technique has been used most extensively for molten metals and ceramics.5"' Fig. 1 illustrates the dimensions to be measured. From these values, the surface tension of the liquid can be obtained using the Bashforth and bdams' equation and tables.

Jan 1, 1963

By E. P. Jennings

(Read at the Amenia Meeting, October, 1877.) THE abundance and value of the tellurium minerals of Colorado is well known, but, as yet, few analyses have been made of them, and I offer these as a small contribution to the chemistry of these valuable ores. 1. Native Tellurium.-The specimens from which the analyses of this mineral were made are from the "John Jay" Mine, Boulder County, Colorado, where it occurs in quite large masses, though mixed with more or less silica and iron pyrites. It is usually a fine¬grained, tin-white mineral, but sometimes occurs in distorted, hexag¬onal prisms in cavities in the quartz. Before the blowpipe it gives the reactions for tellurium, sulphur and iron; by cupellation, it yields a small amount of gold. An analysis of a coarsely crystallized speci¬men gave the following results

Jan 1, 1878

By F. Vagnon, A. M. Ferrero, M. Pirulli, A. Segalini

"The topic of this study is the design of flexible fences to mitigate the risk due to debris flow phenomena by means of theoretical and experimental studies analysed in framework of the Rock Engineering System (RES).The study of the interaction between debris flows and flexible barriers is a major challenge since many different aspects concerning both the slope characteristics and the structure features are involved. Debris flows are often triggered by the mobilization of debris deposits that are generated by rock fall of adjacent rock walls. The rock debris deposits are difficult to be characterized by the physical and mechanical point of view due to their large variability in volume distribution and, moreover, when dealing with high mountains environment, they are also strongly affected by the presence of water at different phases (solid or liquid) depending on the temperature. The debris deposit turns unstable in relation with the geotechnical and environmental features of the areas and the instability evolution in high mountain steep valley is often a debris flow. Debris flow destructive potential is very high and protections are often needed to reduce the debris flow risk.This complexity determines the needs of comprehensive study able to include the global basin dynamic and the environmental conditions. An a-priori analysis of the influence of the different aspects can be useful to focus on the real driving aspects of the problem. Due to the complexity of the system the application of the RES methodology is recommended in order to clearly define the different assumptions needed, their influence on the simulations and a comparison among them.RES allows investigating triggering criteria, flow and depositional processes and interaction of flows with protection fences in a rational way. For this purpose, an interaction matrix is created: it summarizes the key geotechnical parameters that influence debris flows, their interactions and debris/engineering protection opera behaviour. The goal is to quantify the diagonal-off terms to assess the residual risk after barrier construction, using back analysis from real debris flow event and data collection from literature.This methodology is applied to analyze a debris flow event in the Italian Western Alps where numerical analyses are carried on to assess flow characteristics to be used for fence design through the application of an analytical and numerical model developed by the authors (Brighenti et al, 2013). In particular, the velocity and deposition heights have been estimated using the numerical code RASH3D (Pirulli, 2010), which is a single-phase model based on depth-averaged Saint Venant equations. Pathways of different lengths are studied to assess the input data necessary to design the protection barrier and to determine the associated risk. Simulation of the barrier at different places along the valley will also allow to determine optimal barrier location in terms of minimum residual risks by comparing the velocity, the volume and the energy of the debris after the barrier impact.The work will produce a possible design scheme to be adopted in this environment."

Jan 1, 2015

By Oliver Bowles

[In an endeavor to promote greater efficiency in the lime industry, the United States Bureau of Mines is preparing a series of preliminary reports dealing with particular problems of the industry. Through the circulation of these reports, it is hoped that sufficient interest may develop among lime-plant operators to prompt them to discuss with the bureau their our experiences with these problems. By such an interchange of ideas, it is believed that conclusion may be reached which will be of practical benefit to try entire industry. The first report, "Stripping problems it Limestone quarries of the Shenondoah Valley", Serial No. 2401, was issued during October, 1922. This report t is the second of the series. It is hoped that may operators will contribute additions to the information now at hand.]

Jan 1, 1922

By R. P. H. Willis

Uranium is back on the radar. Uranium has always been a controversial metal, from its role in the arms race to its claim to be the only viable alternative to fossil fuel. This paper will cover its properties and use, its occurrence and production in South Africa, the current market drivers and its future role as a primary energy fuel. It will highlight the difference between uranium used to make a bomb and uranium used in a power station. The recent significant uranium price rise will be put into context of the market drivers including geopolitical issues. Planned expansions in nuclear power station capacity will be reviewed, as will new mine production. Future demand will also be speculated on.

Jan 1, 2006

By Serkan Saydam, Ercument Yalcin

This paper presents the results of Caldagi Nickel-Cobalt Ore Deposit's, located in Turkey, reserve and ultimate pit limit design analysis. Reserve analysis of any deposit requires two steps. First one is to constitute of block model of the deposit and second step is to generate ultimate pit limit. The block model of the Caldagi ore deposit has been created by means of geostatistics. The reserves of nickel and cobalt in this block model are defined as resource, approximately 12 million tons of nickel and 1 million tons of cobalt with average grades of 0.9% Ni and 0.03% Co, respectively. Ultimate pit limit analysis has been performed by considering economic, technical and legal factors. In this paper, the ultimate pit limits are generated by Lerchs & Grossmann (L&G) algorithm. As a consequence of ultimate pit limit design, total amount of tonnage to be excavated is 1.4 billions of tons, 700 million of which contains ore and 747 million of which is the tonnage of waste.

Jan 1, 2002

The inquiry into the explosion at the Moura No. 2 Mine in August 1994 recommended -?Emergency procedures should be exercised at each mine on a systematic basis, the minimum requirement being on an annual basis for each mine.? (Windridge et al. 1996). In December 1996 the ?Approved Standard for the Conduct of Emergency Procedures Exercises? was published and has been subsequently revised (Queensland Department of Mines and Energy Safety and Health Division 1999). This document provided guidelines for conducting mine site emergency exercises as well as the requirement for a test of state-wide emergency response by holding a Level 1 Mine Emergency Exercise at one mine on an annual basis. From 1998 to date (January 2008) ten Level 1 Mine Emergency Exercises have been held in Queensland, Australia. This paper discusses each of the exercises conducted to date as well as the logistics, scenario preparation, planning and organising required to conduct emergency exercises at this level.

Jan 1, 2009

By R. Bruno

The problem of testing different production strategies has been studied in relation to reserves selection and a computer programme for ore production management has been developed. The case study presented concerns an underground rock salt mine in Sicily with different product lines and variable ore characteristics. A geostatistical block model of the deposit was constructed on the basis of the physical and chemical parameters that ultimately determine the type of end-product in operations according to different selection strategies were simulated using the model and taking account of both technical and 'commercial constraints. The structure of an ore production management programme running on a PC to select both the mining unit and the end-use of the ore is described.

Jan 1, 1989

By Thomas M. Barczak

Advancements in support technology have occurred to a large extent because of the demands of the mine operators. Shield supports are no exception. The most notable changes in shield technology in the past decade have been increases in shield capacity and life expectancy, which have increased by a factor of 4 and 7 respectively since the inception of the shield support 25 years ago. The purpose of this paper is to set goals for the future generations of longwall shields. These goals include: (1) 100,000 cycle life expectancy, (2) improved hydraulic diagnostic capability, (3) smart load control with adjustable setting pressure algorithms, (4) composite material design to reduce weight and increase shield width, (5) constant set leg cylinder design, (6) improved joint design to reduce wear and stress, (7) advancements in leg cylinder socket design, and (8) an instrumented shield to measure in-service structural component loading. These design issues will continue to push the envelope in longwall shield technology that has provided the safest and most productive mining system employed in the history of mining. In preparation for this, a historical examination of shield failures is made and recent trends in shield design are evaluated. Design practices to improve structural margins of current designs are also addressed.

By H. Yin, T. Emi

"Advantages of gas/flux injection technology as materialized in the main stay unit processes for steelmaking are depicted covering hot metal pretreatment through secondary refining. Current status of micro-kinetic issues involved in the injection technology are reviewed including gas-in- metal, gas-in-slag, flux-in-metal, metal-in-flux and three-phase dispersion systems with reference to macro-kinetics. Key problems are briefly addressed to further develop injection technology for steelmaking processes.1. FROM PAST TO PRESENTApplication of gas injection to steel industry started in early 1950's when inert gas bubbling via stopper rod, lance, or porous refractory plug was practiced to make the temperature of steel melt in ladle uniform The gas bubbling in ladle was then extended to slightly removing hydrogen ti'om the steel melt tapped from Electric Arc Furnace (EAF) and Basic Open Hearth Furnace (BOH) when vacuum processing facilities were not popular. Later, oxygen gas injection via calorized steel pipe into molten steel bath in BOH Furnace was also put into operation to promote the decarburization to increase the productivity of the process. This line of development has been made in parallel with more profound processes, i.e, top blowing Basic Oxygen Furnace (BOF) for primary steelmaking and side blowing Argon Oxygen Oecarburization (AOD) vessel for decarburizing stainless steels.On the other hand, injection of fluxes into steel bath was first industrialized in Germany in 1960's, Primary objective was to desulfurize steel melt in ladle by injecting CaC2 or CaCrCaO mixture via lance under neutral slag cover with good success. Difficulties in injecting fluxes without clogging and rippling at a desired flux/gas ratio, and durability of injection lance were resolved in due time to bring forth many injection facilities to flourish for versatile refining operation. Top injection of fluxes from main oxygen lance to BOF was also industrialized as LDAC to promote early slag formation. A new process then emerged which injects oxygen gas and fluxes together through concentric annular tuyere, installed at the bottom of the BOE into steel melt. This process, developed in Germany [Oxygen Bottom Maxhutte (OBM)] and brought into maturity in USA (Q-BOP) and Japan in a large scale operation, became the predecessor of the combined blowing (top and bottom blown) BOF which dominates modern steelmaking."

Jan 1, 1996

By Ralph Dawson

The following additions to SLP-4 “ALWAYS AND NEVERS” have been approved by the Board of Governors since the last printing 6/97 and will be included in the next printing soon. They are also included in the Second Printing of the 17th Edition of the ISEE Blasters Handbook. Review them and apply those which might be applicable into your blasting program now.

Jan 1, 2001

One of the features of modern life has been the increasing speed of change. We see this in many facets of activity, but in few areas more clearly than in the financial sector. The speed of communication and the advent of screen trading have made world markets one.We have titled this presentation "Cycles". It has been the conventional wisdom that Economies, Metal Prices, Equity Markets, etc. move in cycles. The objective of our presentation is to examine these cycles, to comment on the interrelationships, and to postulate where we are in The Current Cycle". We will draw conclusions as to where one should direct effort in the Mineral Scene over the next decade or so.Throughout this discussion we will use various terms to describe Time. The "Short Term" is typically meant to refer to the next six months: the "Medium Term" is one to two years; and the "Long Term" is the three to five year horizon.

Jan 1, 1990

By Hal J. Kelly

A number of problems that developed in processing the halloysitic clays of eastern Washington and northern Idaho were investigated by the Bureau of Mines. The deflocculating effect of tetra sodium pyrophosphate is compared with several other compounds, and on the basis of current theory, the advantage of sodium pyrophosphate as a deflocculating agent is explained. The adsorption of the sodium ion by clay in a clay"-water system was established by a radioactive tracer technique, and the deflocculating action of sodium pyro- phosphate was postulated. The effective dispersion of the halloysitic clays was limited by the occurrence of tightly bound aggregates of small, individual crystals. Disaggregation of the agglomerates was investigated by liquid extrusion and ball milling of dilute slurries and by extrusion of the clay in a plastic state. The greatest increase in the production of small particles was by high? pressure liquid extrusion.

Jan 1, 1963

By F. Q. Su

Underground Coal Gasification (UCG) is a promising environmentally acceptable clean-coal technology. A typical UCG system has two wells drilled from the surface into a coal seam with some separation of injection from production. The wells are connected underground by various linking techniques. After creating a combustion reactor in an underground coal seam, air and oxygen flow through the injection well. Heat energy and gases are collected from the production well. As gasification progresses, the combustion reactor is moved along the linking hole. Using this process, the fracturing activity inside the coal seam serves an important role for enlargement of the gasification zone because the surface area oxidization increases continuously by coal cracking. For effective coal gasification, fracturing activity must be controlled. Moreover, excess fractures inside the coal seam and surrounding rock can induce gas leakage, underground water contamination, subsidence, etc. Therefore, monitoring and control of fracturing activity in underground areas constitute key technologies for efficient and safe UCG. To monitor fracturing activity, we conducted laboratory and small-scale field experiments of UCG using acoustic emission (AE) measurements. UCG model tests were conducted for linking and coaxial types UCG models. Coaxial UCG systems are compact and are anticipated for application in underground coal seams having a complex geological structure. The UCG model consists of a coal block molded in a steel canister (20 liter capacity) with heat-resistant mortar, with a linking hole or a coaxial-hole passing through the coal block. During coal combustion, coal temperatures, production gas contents, and AE activity were monitored under the control of injection-air and oxygen flow rates. Results show that the combustion propagated inside the specimen along the linking hole. Many AE events were generated during coal combustion. The AE activity was related closely to temperature changes inside the coal block. This AE generation apparently results from crack initiation and extension around the coal combustion area under the influence of thermal stress. However, comparing the results from UCG models of linking and coaxial types, the gasification of the linking type model showed an average calorific value as high as 11.3 MJ/m3. The coaxial type yielded an average calorific value of produced gas as only 5.79 MJ/m3. In the coaxial type of UCG model, the combustion region was limited to the area around the coaxial hole. The AE activity was lower than in the linking type model. For small-scale UCG field experiments, linking and coaxial types were tested at an open pit coal mine in Hokkaido, Japan. Using a linking type UCG, 58.2 kg coal was processed in 39 h, with the calorific value estimated as 11 MJ/m3. However, the coaxial type UCG processed 7.0 kg coal in 9 h, yielding an estimated calorific value of 6.0 MJ/m3. These tendencies resemble those of results of laboratory UCG experiments. Results of these experiments demonstrate that AE monitoring is a useful tool to evaluate combustion reactors for efficient and safe UCG systems. To develop a coaxial UCG system, results show that fracture control around combustion reactors is indispensable.

Aug 1, 2013