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By Yury Kapelyushin

Formation of cementite in the reduction of hematite by CO–CO2 gas was studied in situ using high temperature XRD (HT XRD) analysis. Reduction of hematite was examined in the temperature range 873–1173 K by CO–CO2 gas mixture with high carbon activity. When carbon activity in the system was 1.5, cementite was formed only at 1023 K; it was not observed in experiments at 973, 1073 and 1123 K. Formation of cementite was observed at 923–1073 K when carbon activity increased to 3–5; and at 873 K when carbon activity was 10. Formation of cementite at 973–1073 K proceeded through metallic iron; however, in the reduction of hematite at 873 and 923 K, iron was not observed; cementite apparently was formed directly from wüstite. XRD spectra were used to estimate concentration of carbon in austenite in the process of cementite fromation.

By J. W. Harden

APART from the merits of the respective systems of mining under conditions alike, there is much in the nature of the coal and the measures with which it is associated, to make that system which is successfully practiced in one locality ill adapted to that of another ; the structure of the coal itself, the roof, the floor, the depth and character of the overlying strata, each exercising more or less controlling influence. Again, in the highly bituminous districts, and with such as have caking coals, where the size of the coal as it comes off the face does not affect its value, as the very smallest of it may be utilized, and in the hard, the open and free-burning coals, in some of which the round only (large coal) is merchantable,

Design of underground extraction layouts to protect surface improvements is an important area of subsidence research in the Coal Mining Engineering Branch of the Department of Mineral Resources, New South Wales, Australia. Some conventional partial extraction layout are important with reference to coal recovery and surface subsidence. The analysis ofsubsidence data collected from field surveys over longwall panels in the Southern Coalfield of New South Wales allows assessment of the effect of pillars left unmined between the longwall panels in reducing surface subsidence. The availability ofa wide variety of layouts with ranging degrees of surface movements affords considerable flexibility in designing layouts to suit a particular situation.Total extraction of coal should be the aim as far as possible. Partial extraction layouts should only be considered when surface subsidence movements caused by total extraction are not acceptable to the surface improvements.

Jan 1, 1985

By D. M. Carris

Since the Buffalo Creek incident in February, 1972, Federal and state environmental agencies have had the pressure on the coal industry in the Appalachian area to close the coal processing plant water circuits. In an attempt to comply with this requirement, Eastern .Associated Coal Corp. decided to install a vacuum disc filter system at its Kopperston plant to eliminate the tailings pond and reduce the amount of plant make-up water. It was recognized at the time that the plant static thickener tailings would be a very difficult slurry to dewater because of its unusually high clay content. The following is a case history of the Kopperston installation and the refinements Eastern has made in its vacuum disc filter operation to increase efficiency.

Jan 1, 1979

By Richard O. Kneisley

Microseismic activity observed in both the laboratory and underground indicates that a quiet period, associated with the closure of existing fractures and strongly influenced by coal seam microstructure, occurs prior to coal bumps. Field studies conclude that coal mine bumps occur against a background of this so-called microseismic calm. This Bureau of Mines report summarizes microseismic activity associated with face bumps and floor bursts in a deep, western U.S. coal mine. Results conclude that while bumps are often accompanied by panel-wide increases in microseismic activity, bumps are not only preceded by a localized decrease in activity, but occur within these quiet zones. The results of this study concluded that microseismic activity may be applicable to the global detection of potential bump-prone zones, but that future studies are necessary to confirm these findings and to improve the techniques for evaluating stress control effectiveness.

Jan 1, 1989

By J-S Zhang

In this paper, the author briefly introduces the resource characteristics of Chinese iron ore, as well as the present increasing market demand for iron concentrate. The SHP-3200 wet high-intensity magnetic separator (HIMS) is used to separate complicated weak-magnetic iron ores being composed of specularite, limonite and siderite in Jiuquan Iron and Steel (Group) Co Ltd. Some technologies have been used to improve SHP-3200 HIMS, including modifying the angle of magnetic polar from 90¦ to 83¦, cooling the exciting coils by oil instead of air, adding reverse-washing equipment to wash off magnetic particles and adjusting the tooth-space of the matrix from 5.0 mm to 3.5 mm or 2.5 mm to enhance the recovery of fine particles. It is still difficult to meet the requirement for recovering more difficultly separated iron and the demands for high-grade concentrate of iron. In order to improve the recovery of difficult-separated iron, the film-magnetic separation technique is applied into the HIMS and a new LY matrix is designed to form magnetic gradient vertically. A flowing-film feeder is also added and the feed mouth is modified to make a slurry flow formed in the form of film along the wall of matrix. The microstructure and dissemination character of the mineral particles is studied, and the specific susceptibility of the primary minerals is measured. Then the distributive characteristics of a magnetic field for the separator with film-magnetic technique and the motion of particles in the process of separation are all analysed. By introducing the film-magnetic separation technique to SHP-Φ700 HIMS, the recovery of iron can be raised from 69.45 per cent to 76.07 - 78.96 per cent with the similar grade of concentrates of iron. Such an increase of 9.51 per cent in the recovery also shows that it is feasible for such film-magnetic separation technique to be applied into HIMS.

Jan 1, 2005

By Charles H. Jacoby

During the past three decades an ever increasing number of uses for underground storage space has been developed. In some instances, the value of the space created has been so great that the host rock has been wasted. The preferential use of salt to host underground cavities is based on numerous factors, the primary two being low extraction costs and low permeability. Both dry and solution mined cavities have been created for the storage of a variety of materials. As the demand for underground storage and disposal grows, so must our selectivity of the materials to be stored.

Jan 1, 1985

By Robert L. Braun, Arthur E. Lewis

A contained nuclear explosion is proposed to produce a chimney of broken ore well below the water table. After the chimney is filled with water and reaches hydrostatic equilibrium, oxygen, under pressure, is introduced near the bottom of the mass of broken rock. The increase in solubility of oxygen at high hydrostatic pressure is sufficient to initiate the oxidation of the primary sulfides, chalcopyrite and pyrite. The oxidation and dissolution of these sulfides produces enough heat to increase the temperature of the ore and water in the chimney as much as 100° to 150°C. The rate of dissolution of chalcopyrite exposed to oxygen-saturated solutions becomes so rapid under these conditions that the rate of copper extraction becomes limited by the accessibility of chalcopyrite to the solutions. Means of solution control and distribution of oxygen in the chimney have been examined in some detail. A calculational model utilizing experimentally determined solubility rates is utilized to estimate the temperature rise in the chimney and the rate of copper recovery as a function of initial temperature, sulfide content of ore, and size of ore particles. It is concluded that the high pressure and high temperature obtainable in a large ore mass broken by nuclear explosives promise the rapid and economic recovery of minerals not considered soluble by conventional in-situ leaching methods. The method should be broadly applicable to the kinds of deep deposits that must be depended on for future production and with minimum disruption of the environment.

Jan 1, 1974

By John Dean Smith

"In many operations the two most overlooked aspects in the drilling and blasting process is theblast optimization and explosive selection. Often times we find a blast design that seems to work andproduce acceptable results and will use this cut afier cut, even years. When in reality one should never become complacent and should be constantly looking for ways to improve the drilling and blasting operation."

Jan 1, 1995

By C. Cunningham

The process of initiating opencast blasts through long cables is onerous. An obvious alternative is to replace these with radio controlled firing apparatus. Such devices appear from time to time and with the advance of telecommunications, more are likely to appear. However, there are two crucial and seemingly intractable obstacles to overcome: firstly, the problem of malfunction of the system, which can either fire prematurely or go into a state of suspense in which it is unknown whether firing might unexpectedly occur, and secondly, the problem of terrorism, as such a system could provide the capability for an off the shelf remote bomb. The issues of accessibility and electronic reliability when linked to explosives in a mining environment have to be demonstrated to be adequately covered before serious consideration should be given to these systems, up to now largely confined to military applications.

Jan 1, 2003

By Thomas A. Simpson

Hydrogeological techniques were used to solve problems of slope stability in open-pit mines of the Eufaula bauxite district, Alabama. Geologic and hydrologic data were evaluated and used to design a system of dewatering wells to enable the operators to mine bauxite more efficiently and economically. Walls of open-pit mines in the district were subsequently stabilized by the operation of the dewatering system. Three open-pit mines, each at varying stages of the mining process, of the A. P. Green Refractories Company, were used to develop a sequential series of guidelines that indicate how to effectively remove ground water from the formations surrounding the ore bodies in the district. The use of sound engineering principles in well design, in combination with the correct interpretation of the pit hydrology provided the basis for solutions of the slope- stabilization problem aided in the economical removal of bauxite from mines of the district.

Jan 1, 1975

By Renato G. Bautista, Theodore D. Tiemann

A kinetic study of the hydrogen reduction of taconite from the Wisconsin Gogebic range was made over the temperature range from 500° to 1000°C on eleven size fractions from 4 to 150 mesh. Two stages of reduction were observed, a rapid initial reaction followed by a slower reaction presumably taking place at an internal receding FexO-Fe interface. Calculated mean activation energies for the two reactions were 7800 and 14,600 cal per mole respectively. In recent years there has been an increased interest in the direct reduction of iron oxide ores to metallic iron by means of gaseous reducing agents such as hydrogen and carbon monoxide.1,2 These investigations have been motivated by the desire to develop a process that will by-pass the blast furnace in the production of steel. The majority of these processes have been developed to produce metallic iron by direct reduction from high-grade iron oxide ores.3"5 Very little work has been done on the low-grade siliceous iron oxide ores.6"8 The work reported here is directed principally towards the fundamental aspect of the reduction reactions of siliceous iron oxide ores, since the practical aspects of the gaseous reductant process were discussed previously. The ore used in the investigation was obtained originally from the United States Bureau of Mines10 trench sample of the Yale member of the Wisconsin Gogebic range iron formation. The Yale taconite has an average analysis of 28.2 pct Fe and approximately 50 pct SiO2. Chemically, these nonmagnetic taconites contain on the average about 53 pct silica and 30 pct Fe. An average analysis calculated fron the USBM10 figures for a composite of the five members (Norrie, Plymouth, Pence, Pabst, and ale) of the iron formation is given in Table I. Mineralogically, based on previous X-ray diffraction and other studies, the principal minerals are hematite (Fe2O3), geothite (Fe2O3.H2O), and quartz (SiO2). Minor amounts of iron containing silicates, siderite (FeCO3) and magnetite (FeO. Fe2O3) are present.10,11 The iron minerals and the quartz are finely disseminated requiring extremely fine grinding for liberation. For the experimental work, the ore sample was screened into a number of size fractions, the analyses and densities of which are given in Table II. EXPERIMENTAL PROCEDURE The reduction experiments were carried out in a 24 in. by 2 in. ID nichrome-wound vertical-tube furnace mounted on a stand. A 1 1/2 in. OD zirconium-oxide combustion tube was used inside the furnace to contain the atmosphere. To the top of this combustion tube was joined a pyrex ground-glass joint to which was attached a glass bulb with a small (1.0 mm) opening at the center, and with two outlets controlled with a stopcock on each side. A pyrex-glass joint with connections to three stopcock joints for introducing hydrogen, nitrogen, and mixtures of hydrogen and nitrogen gas was joined to the tapered bottom of the combustion tube. The sized ore fractions were contained in a 1 in. diameter by 1 1/2 in. 150-mesh nickel screen basket. The basket was suspended in the furnace from a balance by means of a supporting nickel wire which hung freely inside the combustion tube. The furnace temperature was controlled by a Leeds and Northrup Speedomax Type G controller, connected to a chromel-alumel thermocouple placed

Jan 1, 1962

By Q. Lin, D. Z. Wang

Molecular design plays an important role in development of new flotation reagents. Group electronegativity calculation is a main method of molecular design. It is commonly used in calculating the hydrophilic-hydrophobic balance of reagents, particularly in designing chain length of flotation reagents for located minerals. But there is a limit to group electronegativity method. The method can only apply to those of [Ø]known straight-chain compounds ([Ø] is the hydrophobic energy of each -CH2- , determined by experiment). In this Paper, we propose another new calculation method: fragment method of flotation reagent. The method could be used as a supplement of group electronegativity method to design and calculate flotation reagents without any limitation. With the fragment method, we can calculate the hydrophilic-hydrophobic performance of any known or unknown reagents including those complicate structure compounds such as cyclic, branch, heterocyclic and so on by summing the appropriate structural elements (fragment). The principle, calculation stages and some results of designing new-type flotation reagents by fragment method are presented in this paper.

Jan 1, 1995

Response of a mineral to anionic and cationic flotation reagentsvaries with the nature of the mineral and the particle size. A ruleis deduced for the selection of the correct type of reagent, which leads to a simple method of testing ores to determine the possibility of separating the constituents by flotation.

Jan 1, 1963

Jan 1, 1931

By S. K. Kawatra, R. A. Seitz

Nonpolar hydrocarbon oils are commonly used in the flotation of minerals to fulfill a number of roles. These roles include reducing overall reagent costs by replacing part of the collector addition, improving coarse particle recovery without reducing selectivity, as well as several others. This paper will cover the types of oils which are available, their physical and chemical characteristics, and the effect of these characteristics on the function of hydrocarbon oils in flotation. In addition, techniques for improving the behavior of oils will be discussed.

Jan 1, 1986

By D. E. Parson, W. A. Morgan

This paper offers a brief review of current literature pertaining to vacuum degassing or vacuum casting of steel as practiced in the U.S.A., Germany and the U.S.S.R. The advantages of vacuum degassing of large forging ingots, heavy section casting, for the conversion of rimming bessemer steels to killed steel and for the production of transformer steels are discussed. Operating pressures, reduction in gas contents and improvements in hydrogen segregation, steel cleanliness and mechanical properties, obtained with the various techniques, are described. The paper includes a description of an experimental vacuum stream-droplet degassing unit and some preliminary results obtained at the Physical Metallurgy Division Research Laboratories Department of Mines and Technical Surveys, Ottawa on laboratory steel melts. Experimental 500 lb direct arc, basic melts have been spray cast into either ingot moulds or dry sand moulds, held inside a vacuum tank. Also 500 lb melts have been

Jan 1, 1961

By F. H. Samuel, J. E. Gruzleski, S. Valtierra, H. W. Doty, F. J. Tavitas-Medrano

319-type cast Al-Si-Cu-Mg alloys are commercially important due to their popular use in automotive applications. Artificial aging heat treatments are commonly performed in these alloys to achieve precipitation hardening and, therefore, improve their mechanical properties. The present work was carried out to investigate the effect of conventional (at a constant temperature, as specified by the standard T6 heat treatment regime), and non-conventional multi-temperature and interrupted aging cycles on the hardness, tensile and impact properties of two 319-type alloys (with and without Sr+ Mg additions). The results show that certain multi-temperature aging cycles have a more favourable effect in improving some mechanical properties than conventional cycles.

Jan 1, 2006

By Muhammad Tawalbeh

The calculated temperature history of a single particle of MgCl2 hydrates when it came in contact with fused salt electrolyte at 650 °C was determined using the measured heat transfer coefficient for the molten salt bath at 650 °C. The calculations revealed that the entire interior of the particle reached the temperature required for the formation of MgOHCI from hydrated MgCl2 in less than 2 seconds. This was much less than the time required for dissolution of the prills as observed in experiments. It is very likely that the formation of MgOHCI during prill dehydration and dissolution is a result of hydrolysis in the interior of the prills.

Jan 1, 2004

By R. H. Johnson

The Manual of the Oil and Gas Industry, under the Revenue Act of 1918, published by the Treasury Department for the guidance of oil companies in preparing their estimates of future recoverable oil for the purpose of calculating depletion, gives the first large public collection of comparative decline curves for the whole country. It is a matter of both scientific and practical interest to so arrange these data that the pools can be readily compared. There are certain difficulties in such a comparison, however: (1) The economic limit varies from 50 to 2000 bbl. a year in different pools taken. (2) Because of this variation in economic limit, the range of data shown makes comparison possible only for wells of intermediate size. In order to be as inclusive as possible, I have taken as an expression of the rate of decline the amount of oil produced in the period during which a well drops from 3000 to 2000 bbl. a year. No period of smaller production could be used because of the high economic limit in California; and no period of larger production and yet include the small well areas of the Appalachian. As it is, the Lima-Indiana wells are excluded. In a few instances, curves were extrapolated to obtain the reading, where the curve seemed regular enough to warrant it. In general, the amount of oil, in barrels, produced while a well declined from 3000 bbl. to 2000 bbl. a year is shown in Table 1.

Jan 1, 1921