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By F. Nava-Alonso, O. Alonso-González, A. Uribe-Salas, R. Pérez-Garibay

"Cyanidation is the most used method to recover gold and silver from their ores. In this process, other metals besides gold and silver may sometimes dissolve and interfere with the efficiency of extraction. Copper is one of those metals, reaching concentrations as high as 1000 mg/L in some cyanidation plants, making difficult the extraction and purification processes, and increasing the operating costs.This preliminary work was intended to study the feasibility of using amines to form a precipitate and to eliminate copper from a synthetic solution containing high copper and cyanide concentrations, as is the case of some cyanidation effluents. The solid formed is removed from the solution using conventional filtration techniques. Seven amines were evaluated at different pH values and amine additions. Up to 90% of copper present may be removed at the natural pH of the effluent (alkaline). The remaining copper would permit to recycle the solution back to the cyanidation process. IntroductionCopper is generally considered the most problematic metal in gold leaching due to the rapid formation of copper cyanide complexes when some readily-soluble minerals are processed (e.g., azurite, malaquite, cuprite, chalcocite and bornite). The copper solubilization as cuprous cyanide complexes leads to a significant economic penalty in terms of excessive cyanide consumption and high cost for cyanide elimination. When activated carbon is used to recover gold and silver, the copper-cyanide complexes decrease the efficiency of the process because of the competition of the cuprocyanides with the aurocyanide for the adsorptive sites on the activated carbon (Rees and Deventer, 1999).Several techniques have been developed to attempt to overcome the problems caused by the copper presence in cyanidation solutions, notably: acidification-volatilization-regeneration (AVR), ion exchange-electrolysis or solvent extraction-electrowinning (Lu et al., 2002). In this work the use of some amines is proposed to remove the copper-cyanide complexes by precipitation of a copper-cyanide-amine solid. The process was evaluated for different amine additions and pH values, using copper-cyanide synthetic solutions of composition similar to that presented by some cyanidation plants with high copper."

Jan 1, 2008

By Waldemar Lindgren

No one would maintain that all ore deposits or all deposits of useful minerals have been formed by the same processes. Generally they have originated by special processes of concentration but these may be of many different kinds. Some deposits have their origin in chemical or biochemical processes of concentration in rivers, lakes or seas, others, developed on land by, means of chemical reactions of surface waters on various forms of rocks. Certain insoluble substances remained behind; others were dissolved and precipitated in favorable places. This action -proceeded in the realm of the oxidizing surface waters or in the deeper zones to which the waters from the surface could find their way. Examples of the latter kind may be found in the extensive copper and vanadium deposits of some sedimentary beds or in the lead and zinc deposits of certain broad limestone strata. In these instances the evidence for any other mode of origin would seem to be very weak indeed.1 Nor does it seem possible to deny that circulating waters may form deposits of the more common metals along fissures after having dissolved many constituents from paths traversed. Another very large class has been formed by magnetic processes of concentration. The last 40 years have been a period of intense activity in. the investigation and description of a vast number of deposits; all modern methods have been employed and the result is an accumulation of data, difficult or impossible to master. It has been a period similar to that in petrography. The generalizations, the able deductions have lagged behind. Evidently several geologists have become weary of this "infinite detail" and a mistrust of the microscope seems to have. arisen. Although this feeling of being swamped in microscopic detail is a painful experience, nevertheless only through the detail in combination with

Jan 6, 1926

By D. L. Harris

Chemical upgrading testwork on Stillwater chomite concentrate shows that reduction roasting and leaching (sulfuric acid and/or ferric sulfate) can provide upgraded feed to ferrochromium furnaces for making upgraded ferrochromium. Two-stage reduction smelting in electric arc furnaces can make upgraded ferrochromium also. Sulfating roasts and leaching (acid and/or water) results using gaseous SO2—SO3 or solid ammonium sulfate were not satisfactory for upgrading chromite. Chemical upgrading of domestic Stillwater (Montana) chromite has been considered at various times1'2' to provide a material with higher chromium to iron ratio, more like foreign high grade ore, for the production of standard grade ferrochromium. Physical bene-ficiation of Stillwater chromite ore can provide a ratio, Cr/Fe, no higher than the ratio in the chromite mineral, which is approximately 1.7. For comparison the analyses of a foreign metallurgical grade chromite ore, a high grade electrostatic process Stillwater concentrate and a stockpile concentrate from the Stillwater ore are noted in Table I. Single stage smelting of the high grade foreign ore with a ratio, Cr/Fe, of 3.37 can provide a ferrochromium of over 65 pct chromium content. Similar smelting of the Stillwater concentrate with a ratio of 1.7 can provide a ferrochromium of 50 to 55 pct chromium content.' It has been demonstrated on a pilot plant scale that chemically upgraded Stillwater chromite having a ratio, Cr/Fe, of 3.0 also can be smelted to provide a ferrochromium containing over 65 pct chromium.5 Two major considerations for an upgrading process are the ratio, Cr/Fe, in the product and the chromium recovery. A minimum ratio, Cr/Fe, of 3.0 is required in the product but for economic reasons a higher ratio is desirable for blending purposes as long as the recovery is satisfactory. Data from different kinds of chemical upgrading testwork are presented in this report. Some of the testwork was conducted to make a product which was not intended to be feed for ferrochrome smelting, but the data are considered pertinent to chemical upgrading. Results reported by others are noted also for comparison. WORK REPORTED BY OTHERS The U. S. Bureau of Mines has contributed much to the literature on chemical upgrading of chromite and a summary is given in Table 11. Reduction roasting and acid leaching were reported by Boericke and Bangert,1 by Lloyd and Gorst, et a1,2 and by Boericke3 to demonstrate very good success on a laboratory scale and only fair success in pilot plant tests for Stillwater (Benbow) concentrates. This work included basic studies on thermodynamic properties to explain the reduction and leaching results. Canadian workers, Downes and Morgan,9 have reported experimental success in upgrading a low grade Bird River chromite, similar to Stillwater material by the same process. Russian workers1' have noted results on reduction tests of high grade chromite which may apply to low grade ores and which help in understanding the reduction process. The use of flux additives in the reduction process was an innovation of their work. The Canadian workers9 also reported other kinds of experiments, including autoclave leaching of the chromite in a limited amount of sulfuric acid. An insoluble basic chromium sulfate was formed and separated from soluble iron, magnesium, and aluminum sulfates to provide an upgraded material. U.S. Bureau of Mines workers, Lloyd, Rosenbzum, Home and Davis,' reported on autoclave leaching of Benbow concentrates as a means of obtaining chromium alum for electrolysis. This last work required selective crystallization of alum to separate iron from chromium. Chloridizing roasting of Benbow and Mouat concentrates has been reported by Hunter and Banning6 and others8 to show that the iron chloride could be volatilized from the chromite to provide upgraded residues.

Jan 1, 1964

By W. Bosmans

The European Commission published its Communication of the Thematic Strategy on the sustainable use of natural resources ("Resource Strategy") on 21 December 2005. The Resource Strategy aims at reducing environmental impacts associated with resource use - called decoupling - in a growing European economy and worldwide. The impacts of unsustainable resource use include e.g. climate change due to fossil fuel use, land use and environmental degradation due to mineral extraction and processing, or overexploitation of soil and fish stocks. To decouple environmental impacts from economic growth, a life-cycle approach is adopted. It means that the environmental impacts are taking into account at each stage of the life cycle of a resource, avoiding that negative impacts are shifted to other environmental media, to other stages of the life cycle, or to other countries. Key to achieving decoupling are three factors: - More value - creating more value while using fewer resources (?resource productivity?); - Less impact - reducing overall environmental impact per unit of resources used (through ?cleaner? technologies and consumption pat-terns); - Better alternatives - substituting currently used resources with better alternatives. The paper focuses on the implementation actions of the Resource Strategy in particular related to the minerals industry: 1. The Data Centre on natural resources; 2. Indicators to measure progress; 3. The involvement of economic sectors to take concrete actions; 4. EU Member States involvement, focusing on resource uses with the most significant impacts; 5. The International Panel on the sustainable use of natural resources, set up together with UNEP. With its 25 years time horizon and its wide approach the Resource Strategy will have a co-ordinating function to ensure enhanced coherence and efficiency. The challenge will be to integrate this approach into all policies and decision-making.

Jan 1, 2007

By Lloyd Williams

1. Reserves have been estimated for three coal beds in Bledsoe County, Tenn.: Morgan Springs, Lantana, and Sewanee. The Richland and Nelson beds occur in Bledsoe County also, but there was not enough information on them for making an estimate of reserves. 2. Known measured and indicated reserves for all beds, based on a minimum thickness of 14 inches and on 1,800 short tons per acre-foot of coal in place, are estimated at 43 million tons as of January 1, 1954. Of this total, 22 million tons represents coal 28 inches and more thick. Areas in the beds were omitted from the estimate because available data relative to the bed characteristics were insufficient for making an estimate conforming with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves deter-mined by this investigation.

Jan 1, 1956

By C. St. J. Lowe

Weir Minerals ? Linatex has developed a new approach to the dewatering of fine solids, particularly mine and process plant tailings and wastes. The Weir process, patented in 2009, uses standard process equipment in a standard flow sheet, but applies this approach to materials previously thought to be too fine to be dewatered with this type of equipment. The process can be applied to a wide range of materials, making lower moisture products that can be re-used elsewhere or sent to disposal. It has already been tested successfully on a small scale in Australia on coal fines, zinc mine tailings, red mud, iron ore tails, and copper/gold tailings. The principal factors affecting the solids recovery have been established as: 1. The % solids in the slurry feed to the process ? a higher % solids provides a higher recovery. 2. The particle size of the feed solids ? coarser feeds provide higher recoveries. The key factors affecting the % solids in the dewatered product have been determined to be: 1. The particle size of the dewatered product - coarser materials produce a higher % solids in the dewatered product. 2. The height of the discharge weir on the dewatering screen - a higher discharge weir on the dewatering screen also yields a higher % solids. 3. The angle of the dewatering screen. Setting the screen horizontal increases the travel rate, reduces the bed depth and reduces the % solids in the dewatered product. Back-sloping the screen up to 5° reduces the travel rate and increases the % solids in product. Eight plants ranging in size from 3 t/h to 40 t/h have been sold to a range of customers in China, for coal and iron ore tailings treatment. Australia has one plant, a small unit rated at 30 t/h of sand fines, and has recently completed test work on iron ore tailings for a dewatering plant rated at 135 t/h. Additional tests are under way with clients around Australia, to demonstrate the capabilities of this process on specific applications and to provide confirmation that materials can be processed successfully, before moving on to larger scale tests or full size plants. The advantages of the Weir process include - lower moisture in products, uses proven equipment, lower capital and operating costs, lower maintenance costs, reduced power consumption, compact footprint, can be used in parallel or in series with existing equipment, modular design to facilitate redundancy or expansion, efficient water recovery and simpler water management, reduced cement in backfill mixes, smaller tailings disposal footprint, reduced earthworks requirements, much lower seepage losses, more stable tailings mass, progressive site rehabilitation, reduced impact on local wildlife, reduced risk of dam wall failure, and reduced environmental monitoring and compliance costs.

Feb 23, 2014

By E. Tarshizi

Research was conducted to develop a simulation and animation model for an aggregate (sand and gravel) mine operation. This model can assist the mine engineers to investigate and consider the various options of haulage systems which are critical for the mine operation productivity. Discrete-event system simulation studies can be used for the typical haulage issues that mining engineers are often faced with: using truck fleet haulage, conveyor belts, or a combination of both. The simulation has identified some strengths and weaknesses in the current loading and hauling fleet of the mine, and has resulted in some suggestions for improving the system. The simulation includes animation of the operation. Animation is needed to enhance the benefit of any mine simulation model. By combining the visual power of animation with a mine simulation, a complete picture of the mine system is obtained and displayed. The mine is modeled and animated using GPSS/H® and PROOF Professional®, both of which have shown great applicability in discrete mining simulation projects.

Feb 23, 2014

By Robert Hopler

RBH Note: in 1913 black powder was still dominant as a coal-mining explosive, but permissible explosives were making some slight headway. For example, in 1902 there were only 11,300 pounds of permissibles used in coal mining, but in 1913 the quantity was 21,801,285 pounds. However, there were 187,551,653 pounds of black powder used that year. It took many years before the use of black powder ended in coal mining. From the picture of the miner reparing his explosives it’s hard to tell what he’s using, but the fact that a wooden Du Pont powder box is shown, he’s probably not using black powder. That doesn’t mean he’s using a permissible, either, since that was not yet a requirement. It’s interesting that the miners have open flame cap lamps, and the miner is actually smoking a pipe while preparing his explosives.

Jan 1, 2014

Stressed steel cables, similar to those used in pre-stressed concrete, have been used for rock mass reinforcement, in civil engineering, for many years. This type of reinforcement has been attempted for open pit wall support, on several occasions, but has never gained wide acceptance as a practical approach because of high cost and complexity of installation in a mining environment. On the other hand, untensioned, fully grouted cable dowels (cable bolts) have gained wide acceptance for ground support in underground mining and it is perhaps surprising that this technique has not been used to a greater degree in open pit mining. The first systematic application of this technique in Australia was at the Mary Kathleen uranium mine in 1976, where it was spectacularly successful in maintaining steep stable walls in a jointed rock mass with unfavourably dipping structures. Cable bolting, and other techniques, are now being used to an increasing degree for wall support in both small and large open pits, for two basic applications: 1. stabilisation of potentially unstable sections of a wall, or 2. to allow steeper walls and reduce waste stripping volumes. In virtually every situation, wall rein- forcement has significant economic as well as technical advantages. The paper describes the development of the techniques, the mechanisms of wall support, the methods used, and discusses several case histories of its application to Australian open pit mines.

Jan 1, 1986

By . Menad Gaballah I

Three samples of solid wastes generated by the non ferrous metallurgy were characterized. These residues contain up to 42 % of valuable metal compounds ( Cu, Pb and Zn ) and 23 %of toxic compounds t As, Hg, Cd and Se ). These sample were subjected to thermal treatments between 200 DC and 800 °C in controlled oxidizing. reducing and chlorinating atmospheres. Up to 99 % of As, Cd, Hg and Se were eliminated from these industrial wastes. Cu, Pb, and Zn compounds were concentrated in the treatments' residues of these samples. A Global Decontamination Factor' GDF ' was defined to measure the efficiency of the elimination of toxic elements and the recovery of valuable elements for a specific sample submitted to a given treatment. It seems that the thermal treatment in a reducing atmosphere was the most efficient in decontaminating these solids and the concentration of valuable elements. a.

Jan 1, 1995

By Robert B. Parsons

"This article addresses the relationship between mine evaluation, the tax system, and economic risk. It is based on a paper presented by the author at recent seminars in Moscow and Tashkent on the subject of mine evaluation.IntroductionTaxation can have a strong influence on the feasibility of a mining project. For the most part, because metal prices are determined on a global basis, the mining concern is not able to pass on to its customers any portion of taxes which the concern has to pay. Taxes are a direct charge against the project. The purpose of the article is to highlight the various ways whereby different taxes can affect the financial viability of a mining operation.The first part of the paper identifies different forms of taxation, and the second part of the paper addresses the different forms of taxation in terms of risk analysis and impacts on the mining project. Finally, the third part of the paper makes brief mention of using the taxation system to provide incentives with respect to investment in mining activities."

Jan 1, 1993

The following is a 'partial list of members and guests who called at Institute headquarters during the period Oct. 10, 1917, to Nov. 10, 1917. Edwin T. Blake, Berkeley, Cal. Alfred C. Lane, Tufts College, Mass. H. M. Boylston, Cambridge, Mass. W. G. Matteson, Houston, Texas. W. B. Cogswell, Syracuse, N. Y. E. Francis M'Crossin, Birmingham, Ala. Paul R. Cook, Zaruma, Ecuador. R. E. Murray, Butte, Mont. F. W. DeWolf, Washington, D. C. Edmund Newton, Minneapolis, Minn. A. Faison Dixon, Venezuela. J. J. Ormsbee, El Paso, Texas. W. H. Dufur,, Oil City, Pa. Pablo Ortega, Havana, Cuba. Maxwell E. Erdofy, Lieut. Engr. Officers'. W. E. Pomeroy, El Paso, Texas Reserve Corps, New York. J. C. Ralston, Spokane, Wash. Evan Fraser-Campbell, Scotland. W. L. Remick, Chrome, N. J. David B. Gemmill, Crown King, Ariz. Howard D. Smith, San Francisco, Cal. F. Lynwood Garrison, Philadelphia, Pa. Harold C. E. Spence, Steeple Rock, N. M. C. J. Hall, Spassky, Siberia. R. K. Stockwell, Salt Lake City, Utah. H. Hamada, Tokyo, Japan. Maurice W. Summerhayes, Timmins, Rush M. Hess, Bouse, Ariz. Ont., Canada. A. Howard Higgin, London, England Malcolm M. Thompson, Morsemere; N. J. A. O. Ihlseng, Joplin, Mo. Nicholas Truschkoff, Petrograd, Russia. T. Ishikawa, Japan. H. J. Wendler, Los Angeles, Cal. C. H. James, Tucson, Ariz. Ira T. Wright, Hurley, N. M. R. R. Landon, Philippine Islands. C. Yabe, Japan. Robert W. Bissell has now become associated with Gunn, Richards & Co., of New York, N. Y. Major Reginald W. Brock is giving a course in a school for commanding officers in England.

Jan 12, 1917

By G Kennewell

At 11 am Monday 8 September 1997, the successful detonation of the 5/9 Mass Blast at Pasminco - Elura was signified by the subsiding of æMt KevinÆ (a 15 m high earth fill mound). The blast was in response to earlier mine subsidence, which holed through to the surface affecting future stability of underground workings. The blast was a first for Elura which fires small tonnages regularly to avoid rapid oxidation of the ore. This paper discusses the strategy and the considerable planning that went into EluraÆs first blast of this magnitude in order to succeed first time round.

Jan 1, 1999

By G. Rehder, C. Hensen, P. Linke, J. Bialas, M. Haeckel, W. Weinrebe, K. Wallmann

Research on marine gas hydrate and the methane cycle has a tradition at IFM-GEOMAR. In summer 1996 during a cruise with RV SONNE offshore Oregon (USA) scientists of the former GEOMAR recovered the largest amount of gas hydrate from the seafloor. This discovery stimulated research on marine gas hydrates in Germany and induced funding of scientific programs such as LOTUS and OMEGA with numerous innovative technologies within the special program GEOTECHNOLOGIEN of BMBF and DFG. The primary objectives of ongoing and future research are to achieve a comprehensive knowledge of: • gas hydrate distribution and quantity; • variation and regulation of gas hydrate formation and dissociation as well as of the related fluid flow; • functioning of chemosynthetic communities in methane oxidation, carbonate precipitation and methanotrophy as biological barrier against methane emission and • delineating the escape routes of methane to the hydrosphere and atmosphere.

Aug 24, 2006

By A. H. Hand

When considering the question of future demand for crude petroleum in California, one must first decide whether it is to be approached in the light of the definition of "demand" when used in economics; i.e., "The quantity of any commodity required or sought in the market," or in the light of markets developed to dispose of total supply. Therefore, is the California demand of future years to be predicated on a continuation of supplying markets developed following the surplus production commencing in 1922, or predicated on supplying what would be termed economic markets ? If the latter, what are economic markets ? Obviously, the Pacific Coast States and Canada, Alaska, Hawaii and probably the Pacific side of Central and South America, can be considered as normal markets for California petroleum products. While there have been small quantities of gasoline shipped into the PacSc Coast from East Texas, transportation costs, plus import taxes in the case of foreign oil, are a sufficient barrier to justify considering that these markets will be retained. But how about our participation in Atlantic and Pacific foreign and intercoastal markets? During the five years preceding 1931 California shipped substantial quantities of gasoline to the United Kingdom and to France, Germany and Italy. During recent years our business in European markets has been restricted to occasional shipments of gasoline and Kettleman crude. This loss of business is occasioned by the development of production in the Mid-Continent, principally East Texas, and in Iraq, Rumania, Venezuela and other closer producing areas, which makes it impossible at the prevailing crude-oil prices for California to be competitive in supplying any substantial portion of these markets. It is therefore apparent that under a stabilized price structure that will return the California producer a reasonable price for his oil, future Atlantic foreign -business will be restricted to occasional spot cargo sales. As to Pacific foreign shipments which, in addition to Central and South America, consist principally of shipments to Japan, China, Australia and New Zealand: A considerable portion of the business we had with Australia and New Zealand until four or five years ago is now being

Jan 1, 1937

By Z B. Rakisheva

By explosion rock mass behaviour is conditioned by preset complex of rocks natural characteristics. Very important role of blockness, which is percent (share) content at examining massif of natural separatenesses of different dimensions and configurations, separated each from other by the cracks of geological and technogene origin. Besides natural properties of massif the power, detonational characteristics of applied explosives, parameters of explosives charges disposition at massif and technology of explosion influence vastly at lumpiness (granulometric structure) of exploded rocks. The mathematical model of rock mass destruction by explosion had been elaborated and substantiated. It ties mutually the initial data (rocks properties, parameters of the charges disposition) and final results of explosion (granulometric structure of exploded rocks). The program of this complicated problem solving had been compiled. Analysing the received results of the problem solving, one can reveal contribution of each group of influence factors for lumpiness of exploded rocks. This fact creates preconditions for elimination or diminution of negative role of some controlled initial data.

Jan 1, 2003

By R. M. Oliver

THE Falconbridge property is almost completely covered with over-burden to a depth varying from 60 to over 200 feet. This overburden consists of grave], sand, and boulder, with bands of very fine silt, and there is usually a layer of water-bearing quicksand adjoining the r:ock surface. In previous shafts sunk at Falconbridge, this water-bearing quicksand had given considerable trouble, and further difficulties were expected in sinking No. 5 shaft, due to its greater size. The method described in this paper is the one adopted in sinking this shaft, after the matter had been carefully considered. No. 5 shaft is located 2,400 feet east of the old main No. l shaft, and is sunk in norite in the hanging-wall of the ore-body, which is, however, ? practically vertical to the deepest known intersection. The greatest depths of overburden prevail on the south side, or footwall, of the ore-body, and this, together.. with the fact that the footwall is wet and more badly fractured, swayed the final decision to sink in the hanging-wall. After the shaft site had been chosen and cleared, a diamond drill was set up a few feet away and a hole bored to a depth of 405 feet to test the over-burden and character of the norite bedrock. The depth of overbudren indicated by the hole was Ill feet, with the last 10 feet water-bearing. The norite was rusted and broken up for only a few feet below bedrock. A steel sinking shield (Figure l) was assembled at the shaft location, and consisted of 5/8-inch plate, 5 feet deep, built around a frame of 6 inch by 6 inch angle-iron, and braced at the corners with the same material. Twelve-inch I-beams held the shield as rigid as possible. In order to reduce binding against pebbles to a minimum, the shield was constructed with a 1-inch batter on all sides.

Jan 1, 1938

By C. B. Dudley

In a work published in 1838, De Morgan, the author of the article on " Probabilities," in the Encyclopedia Metropolltimn, says: " The method of least squares is not yet introduced iutb the affairs of common life,.....that many thi~gs which are denlonstrable only by the higher branches of mathematics are looked upon as useless." And he mentions an instance in which "a method was suggested for estimating the relative importance of boroughs, by considering their population and ~wntributions to the revenue con)-

Jan 1, 1881

By M. R. TECK, N. Rudd, L. K. Thomas, D. L. Katz

The authors are to be congratulated for presenting the first comprehensive paper on the theory and practice of threshold pressure determination in connection with underground gas storage. It is of particular value since most previous experimental work on this subject has been proprietary to the commercial laboratories engaged in such testing and to their clients. This dlscussion is presented in amplification of the subject paper, not in criticism, and is based upon our experience with approximately 5,000 threshold pressure determinations. Our comments are directed primarily to the experimental procedures as described by Thomas et al. It should be noted that, while clay mineral-rich lithologies are the most common caprock materials, the samples used (Table 1) include low permeability sandstones and carbonates, but do not include shales or other formations in which clav minerals exert a dominant effect. While our experience on samples analogous to those investigated by the authors generally confirms their findings, we have found that even more rigorous experimental conditions must be imposed where clay minerals are the controlling factor. These additional conditions result from the well-known molecular character of the clay minerals themselves in which water is interlaminated with, and bonded to, silicate sheets, thus becoming an essential component of the molecule. In many clay minerals the character of the intersheet bonding, and thus the dimension of the lattice, is strongly affected by variations in the identity and concentration of cations present in the intersilicate water. On a supermolecular scale, adsorbed water films on particle or "flakes" of shale provide much of the cohesive force necessary to maintain mechanical strength. The thickness of these films is variable and inversely proportional to intergranular pressure within the dimensional limits involved in caprock investigation. The thickness of the intersilicate water layers may also be subject to pressure under some conditions. These considerations are reflected in several necessary modifications of the experimental procedures described by the authors. Two of these are, in our judgment and experience, of such importance that they cast real doubt on the validity of data obtained on argillaceous materials without their application. The very careful resaturation procedures proposed by the authors should give good results in connection with the relatively "inert" lithologies used in their experiments. Our experience suggests, however, that they would create more problems than they would eliminate if applied to argillaceous materials. 1. Drying of the sample at the temperature and for the duration indicated by the authors not only will dessicate the sample with consequent shrinkage cracking, parting along bedding planes, and even total disassociation in the case of fissile shales, but it may also alter the character of the clay minerals themselves — in some cases irreversibly. 2. Prolonged evacuation to 2 microns Hg further dessicates the sample and is even more effective in reducing the intersilicate water content. 3. Resaturation with water differing in pH or chemical content from that existing originally in the sample also serves to alter the nature of the sample, particularly its structure and strength. 4. Our experience has been that, even with the thorough precautions proposed by the authors, complete resaturation of very fine grained materials is rarely obtained. Yet our experience confirms the

Jan 1, 1969

By J. Baicker

A two-inch diameter probe containing an intrinsic germanium detector, a canister-type solid cryogen cooling system, cooled FET preamplifier, linear amplifier, high voltage supply, analog-digital converter, microprocessor, buffer memory, bidirectional cable link, and all power supplies has been designed, assembled and tested. A surface support vehicle was designed, built and outfitted. A mini-computer system was constructed and preliminary software developed and tested. A special handling system for a Cf-252 neutron source was designed and has been ordered. The entire system (less the neutron source) is ready for its first field tests. Lab description of the system is presented.

Jan 1, 1978