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By Norman F. Patton

The subject assigned is so broad that thorough discussion is well-nigh impossible within the space allotted, and further, few specific data are available upon which to predicate conclusions concerning the efficiency of present methods of distributing anthracite. This paper treats briefly the various agencies through which both primary and secondary distribution are effected, the methods of transportation and the general interrelation of production, demand, inventories and price. Avenues of Distribution Three distinct types of primary distribution are common in the marketing of anthracite. First, though not most important, is the sale by the producer, or operator, direct to the consumer. These sales, other than to employees and the local trade, are generally confined to steam sizes for industrial uses, and are consigned to the sidings or docks of the consumer. Sales of this type often are so closely priced to compete with oil and bituminous that the addition of even a small dealer's margin is sufficient to increase the cost to the point where the business might be lost. Second, the operator sells to a wholesaler or broker for subsequent resale, either to a retail dealer for clearance through his yard or direct to large consumers. Usually this method of distribution is employed by the smaller operators, who do not find it economically feasible to maintain extensive sales organizations. In most instances, the wholesaler retains some 5 per cent for his services, paid, of course, by the producing company whose anthracite he handles. He may, and frequently does, handle the output of several different companies, suited to the varying needs of the different communities he serves. His business includes all sizes of anthracite. The third, and by far the most general method, consists in selling to retail dealers, shipments being made direct from the breakers to the yards of the dealers. In large consuming areas, such as the metropolitan districts of New York or Philadelphia, one operator may sell to several

Jan 1, 1936

The depletion of favourably located and higher-grade mineral deposits, combined with more favourable metal prices and higher capital costs, has stimulated research into heap leaching of lower grade ores and wastes. This has resulted in renewed interest in heap leaching of uranium ores, and in the development of processes for the bacterial heap leaching of low-grade chalcopyrite ores and the acid heap leaching of nickel laterites. A complete programme of heap leach testwork typically involves a sequence of bottle roll tests and column tests, followed by piloting on test heaps. The initial testwork is aimed at determining the amenability of the ore to heap leaching, which depends on the characteristic of the ore with respect to porosity and permeability to leach liquor, acid consumption, metal recovery and percolation. Subsequent phases of the testwork focus on the development of the process design criteria for the treatment of the ore. Basic techno-economic models have also been developed as a tool for the initial estimation of heap leach viability. Mintek has also developed in-heap monitoring probes, coupled to an operator guidance system, in order to assist the operator in achieving optimal conditions for bacterial growth and heat preservation during pilot-plant operation.

Jan 1, 2009

By H. C. Cooke

Those who have followed the geological developments in connection with the copper deposits of Quebec will recall that on many properties the sulphide bodies occur as replacements of fault breccias or tuff breccias, and exhibit a pronounced distaste for the more massive lavas. At the same time the rocks around the ore-bodies are profundly altered, first by addition of silica and sericite, later by conversion of these minerals into chlorite. It has been known for some years that at the Amulet and Waite-Ackerman Montgomery mines these conditions do not prevail. At both mines the ore-bodies are replacements of massive lavas, and at the Amulet they are associated with a very peculiar rock christened ?spotted dog', or 'dalmatianite'. Accordingly, when in 1929 the writer had the opportunity to make a further examination of these properties, two problems presented themselves for solution. The first was to determine, if possible, the conditions under which massive lava, rather than breccia, is replaced by the sulphide masses; the second, to find out the exact nature of dalmatianite and its relations to the sulphide bodies. The first of these problems is believed to have been solved; the second has been found very complex, and will require further work before it is satisfactorily settled.

Jan 1, 1930

By Francis Crockard

DURING the past five years we have probably witnessed greater technological advances than in any similar period. Industry and science have steadily marched ahead. The makers of iron and steel products have watched with great interest the development of stream-lined trains, faster and safer airplanes, the entirely new science of air-conditioning and the widespread use of stainless steels. Since 1930, we have witnessed the erection of the world's largest suspension bridge, the largest and fastest ocean liner and the spectacular Boulder Dam, while even greater things are planned in these particular fields. Other indus-tries, too, have been moving ahead rapidly. This advance in a few years has been caused primarily by the fierce competition of the depression. Now, more than ever, is the emphasis placed upon quality and service. Makers of southern merchant pig iron have been no exception and have been confronted with increasingly strict chemical specifications and with much greater stress on physical characteristics than ever before. For example, sulfur in the iron must be held very low, competition demanding that it be in the 0.020's and low 0.030's; silicon content must be held within a very narrow range, and definite requirements of phos-phorus and manganese are an essential part of the specifications. Physical characteristics are becoming of increasingly greater impor-tance. The introduction of triple-skimmed, slow-cooled iron several years ago was the first step in this direction. Now there are a few customers who buy iron by chemical analysis and physical appear-ance, having found that the analysis alone is an insufficient guide to their requirements.

Jan 1, 1936

By E. V. Konopleva, H. J. McQueen

"The isothermal bainite transformation kinetics of low- and medium-carbon alloy steels after hot deformation and the rmocycling treatment (TC) has been studied by the magneto - metric method. Deformation was produced by rolling at 800°C-1000°C. TC included three cycles of rapid (30°C/s) electro-heating up to 900°C-1000°C followed by quenching.Hot deformation retards bainite transformation in the lower part of bainite range (<400°C) and accelerates it in the upper part (>400°C). The effect is greater for higher strain and lower deformation temperature. Deformation also diminishes the overall bainite fraction below 400°C and increases the completeness of reaction above 400°C.Thermocycling provides more uniform ultrafine austenite grains with average size of 3 µm -4 µm compared to 12 µm -14 µm after conventional heating. The transformation rate after TC was almost the same as after conventional heating in low-carbon steel but was faster in medium-carbon with no change in the completeness of reaction. The degree of acceleration increased with rise of transformation temperature.There are a number of factors which are responsible for a change in bainite transformation kinetics in austenite deformed at high temperatures or subjected to TC. One of the most important factors is the refinement of structure, another one is structural and chemical inhomogenity of austenite due to deformation or to rapid heating. To estimate the contribution of these factors, ?-transformation was studied after different austenitizing conditions (low-temperature heating at 850°C- 950°C; high-temperature heating at 1100°C; step treatment – austenitizing at 1100°C, then cooling to 950°C-850°C). The results obtained make it possible to conclude that the structural and chemical inhomogeneity of austenite activate the bainite reaction while the grain refinement retards it. Intensity of the effect produced by each factor depends strongly on the steel composition."

Jan 1, 1997

By J. H. Fulton

Summary Considerable test work has been done with the detachable type of carbide bit. In general, these bits improved drilling operations, but at a bit cost .greater than was compensated for by the reduction in man-hours of labour. Too few bits continued in service for the possible drilling life of the carbide inserts, and technical improvements or lowered first cost, preferably .both, are indicated ?in order that the bits can be generally acceptable as an economical drilling tool. In ?preliminary test work, the drill rods .with ?one insert of the chisel-bit type appear to be more trouble-free, to have a longer life, and to give a somewhat lower bit cost per foot drilled, than other types. INTRODUCTION The object of this paper is to outline briefly the &apos;methods used and the results obtained in test work with tungsten carbide bits used in combination with the smaller bore, lighter weight rock drills. As various articles have appeared in the past few years giving the historical background ?and early development of carbide ?bits, this information will not be repeated. Table I lists the equipment used in the test work. The stopers weigh about 95 pounds and the jackhammers with airleg from 97 to 110pounds. The smaller rock drills are stated to deliver about 2,200 blows per minute at 1 to 30 rotation and to require 85 to 95 cubic feet of air at around 100 pounds pressure.

Jan 1, 1950

By P. L. Raffo, T. E. Mitchell

Single crystals of Ta-Re alloys have been deformed in tension and compression as a function of solute concentration and temperature. The temperature dependence of the yield stress is decreased by alloying. At low temperatures there is a minimum in the yield stress (at about 2 at. pct) as a function of concentration. Three-stage hardening was not observed in the alloys. Linear hardening rates, where observed, were characteristic of stage II in pure tantalum. At low temperatures and high concentrations, work softening was often prominent at high strains. Electron microscopy revealed that dislocations are mostly of screw orientation, although heavily jogged and cusped, and often occurring in dipole pairs. The alloys become more prone to cleavage with increasing rhenium content, due mostly to an increasing yield stress rather than a change in cleavage strength. Alloying apparently decreases the Peierls stress of bcc metals at low temperatures by facilitating kink nucleation at solule atoms on screw dislocations. Higher solute concentrations further increase the yield stress. Quantitative calculations and comparisons with other bcc alloy systems are made to show that the predominant hardening mechanism is due to the interaction of dislocations with misfitting solute atoms close to their slip planes. The interaction is so localized that the core dilatation of dislocations could be important. CONSIDERABLE interest has arisen in recent years concerning the mechanical properties of unalloyed bcc metal single crystals.&apos;-7 These and similar studies on polycrystalline materials have resulted in a considerable understanding of the macroscopic yielding characteristics8, 9 and the process of work hardening.&apos;&apos; This latter advance is due in a large part to the increased use of transmission electron microscopy in P I RAFFO junior Membar AlMF is Metallyureist Iewis such studies and the general observance of three stages of work hardening in the shear stress-shear strain curves. The properties of substitutional alloy single crystals of bcc metals have not been determined in as much detail as in the pure metals. Insufficient systematic studies have been made on the effect of alloying on the magnitude and temperature dependence of the yield stress or the stress-strain curves. The alloy systems which have been studied to some extent have been Ta-W,11, 12 Ta-Mo," Ta-Nb,12&apos;14 Mo-Re,15 W-Re,16 and alloys of iron with nickel,17 platinum,17 vanadium,18 and aluminum.18 A large body of data exists on Fe-Si alloys, but these have mainly been a result of the experimental convenience of using this material in place of unalloyed iron, rather than a comprehensive study of the mechanical properties of the alloy system per se. The present authors have previously reported additional data on the properties of Ta-Re, Ta-W, and Ta-Mo alloy single crystals.1g Some of the data on Ta-Re alloys will be described later in this paper. Briefly, single crystals of Ta-Re (1.2 to 10.6 pct), Ta-W (6.2 and 10.2 pct), and Ta-Mo (2.9 and 9.0 pct) were grown by the floating zone method in vacuum. Compression tests were performed in the temperature range 77" to 623°K. Slip was found to occur in Ta-Re alloys at 77&apos; and 298°K on the (~ll)[lil] system and slip lines were coarser and straighter than in unalloyed tantalum. No three-stage hardening was observed in any of the alloy systems and the curves were nearly parabolic. At temperatures above 175°K the yield stress* increased monotonically with in- creasing composition while at 77" and 175°K the yield stress initially passed through a minimum after which it began to increase again for concentrations greater than about 2 pct Re. Similar minima were observed in Ta-Mo alloys and to a lesser extent in Ta-W alloys. The minimum was interpreted as being a result of a

Jan 1, 1969

By Alexander N. Mitinsky

Up to a certain limit, the increase of pressure on the diamond-drill increases the rate of progress in drilling. That limit is set by the resistance of the diamonds to compression; and beyond it, the destruction of the stones will involve an economic loss, both in time and in money. It is, therefore, important to all diamond-drillers to know what is the resistance mentioned. In Europe, operators usually follow an empirical rule, which directs the maintenance of a pressure, on the area of the bottom of the drilling-tool, of 12 kg. per sq. em. For the tools in ordinary use, this is equivalent to 1 kg. per sq. mm. of the diamonds set in the tool. So far as I know, American drillers are using pressures as high as 50 to 60 kg. per sq. em. of the total area of the drill, and the consumption of diamonds (on Denny&apos;s authority, 0.2 carat per meter bored) is greater in America than in Europe. But the reason for this diffrence may be the comparatively larger size of the diamonds commonly used by American drillers. With the assistance of my friend, the late S. Woisslaw, who was the pioneer of diamond-drilling in Russia, I selected from his stock a number of black diamonds, which I subjected in my laboratory to compression-tests, To prepare regular cubes for such tests, as is generally done with other stones, would have been not only costly, but, what is more important, practically useless. I therefore determined, in order to assimilate as nearly as possible the conditions of actual use, to place each sample between a hard plate (corresponding to the rock) and a softer plate (corresponding to the bottom of the tool), into which it would be pressed during the test.

Jan 1, 1907

This paper presents a theoretical investigation on the ionic equilibrium of Fe(III)?Ni(II)?H2SO4?H2O system. A non-ideal speciation model is developed to calculate the concentration distribution of iron and nickel species in a mixed ferric and nickel sulphate aqueous solution over the pH range from 0 to 4 and temperature from 25 to 100°C. A series of speciation diagrams for iron and nickel species is plotted with the effects of ionic strength and temperature on the equilibrium constants being taken into account. The ionic strength-dependent equilibrium constant is treated through a semi-empirical Vasil&apos;eV equation, which is based on an extended Debye?Hückel theory. A Helgeson model is applied to extrapolate the equilibrium constant to elevated temperature. The ionic equilibrium reactions are described by a group of numerical equations containing the temperature and ionic strength-dependent equilibrium constants, which are solved by the Newton-Raphson method. The speciation model is also applied to estimate the hydrogen ion activities and corresponding pH values. The calculated pH values are in agreement with the experimentally measured pH, and are compared to literature data and pH values produced by the Visual MINTEQ® program (a computer code for the calculation of chemical equilibrium in natural aqueous system). This investigation provides a deep insight into the ionic equilibrium behavior of a mixed metal sulphate aqueous system which commonly occurs in hydrometallurgical processing. Keywords: speciation, chemical modelling, thermodynamics, iron, nickel

Sep 1, 2012

By Gerald H. Luttrell, Mohammad Rezaee, Roe-Hoan Yoon, Rick Q. Honaker, Aaron Noble, Abhijit Bhagavatula, Michael J. Kiser

A field study was undertaken to experimentally measure the concentrations of rare earth elements (REEs) contained in the process streams generated by a group of 20 coal preparation plants located in the eastern USA. For each site, representative samples of clean coal product, coarse refuse, and fine refuse were collected. Each sample was then partitioned into preselected size and density classes by wet screening/sieving and float-sink testing. The resultant products were dried and subjected to laboratory analyses to determine ash contents and rare earth element concentrations including Yttrium and Scandium. A detailed analysis of the database generated by this exercise showed that coal-based products from these preparation plants contained significant quantities of rare earth elements. In particular, the coarse refuse streams currently discarded by the 20 plants examined were found to contain a sufficient tonnage of REEs to satisfy the current domestic demand for these important elements. The data also showed a strong positive correlation between ash content and REE concentration, which suggested that the primary association of REEs in eastern USA bituminous coal sources is likely within fractions containing inorganic impurities. This association was well described using a simple power equation relating ash content and REE concentration. The ratio of heavy-to-light rare earth elements was discovered to be significantly higher in organically rich fractions of clean coal, suggesting that mineral impurities intimately associated with carbonaceous matter have elevated concentrations of heavy rare earth elements. A similar trend was observed for a grouping of rare earth elements (Y, Nd, Eu, Tb, and Dy) that are likely subject to near-term supply shortages. Finally, the database showed that a linear correlation existed between La for many REEs of interest, although there were several notable exceptions for some high-value REEs (Lu, Pr, and Tb).

By Shulan Wang, Xuan Liu, Li Li

"Electrochemistry of Fe(III) in 69CaCl2-12CaF2-19KF and 81CaCl2-19KF (mole percentage, %) was investigated at 827 oC on molybdenum electrode by cyclic voltammetry, chronoamperometry and galvanostatic electrolysis using Fe2O3 as the Fe(III) source. The reduction of Fe(III) to Fe was conducted in one step and controlled by diffusion process. Fe(III) shown greater reduction rate and diffusion coefficient in molten 81CaCl2-19KF than in 69CaCl2- 12CaF2-19KF. Galvanostic electrolysis of Fe was performed in both molten salts with a cylindrical cathode rotating at 200 r/min and dendritic iron deposit was obtained.Keywords: iron; electrolysis; electrochemistry; molten saltIntroductionThe production of iron and steel causes huge emissions of CO2. Iron electrowinning in molten salts with dissolved Fe2O3 using an inert oxygen evolving anode is an alternative process to reduce or eliminate the formation of CO2. Research on novel process of producing metal has been reported recently [1-2] by using CaCl2 as the main electrolyte and dissolving CaO in CaCl2 due to the high solubility of CaO in the melt. This process has been used in preparing many active metals and alloys [3-14]. In the present work, the electrochemical behavior of iron in CaCl2-KF was studied and transport property of iron ion in the melt was discussed.ExperimentalCaCl2,CaF2 and KF (in analytical purity) were dried in air for 48 h. Mixed salts used in experiments were placed in a graphite crucible (??58 mm inner diameter). The graphite crucible together with the salts was heated at 473 K for 12 h in a furnace with flowing Ar (99.99%) before further heating. Temperature inside the furnace was measured by an S type thermocouple. Electrochemical measurements, such as cyclic voltammetry and chronocoulometry, were performed in a three electrode cell by EG&G PAR273A potentiostat/galvanostatand. Galvanostatic electrodepositon of iron was conducted in a two electrode cell. Molybdenum (??2 mm) and iron (??5 mm) were used as the working electrode (WE) and the reference electrode, respectively. A graphite crucible and a magnetite rod (??25 mm ) consisted of 100% magnetite and sintered at 950 oC in argon atmosphere for 2 h with electrical conductivity of 366 O-1m-1 at room temperature were used as the counter electrodes in the galvanostatic electrolysis experiment. Carbon (??10 mm) was used as the counter electrode in electrochemical measurement. The deposits were washed in distilled water bubbled with argon and dried in air before being characterized by X-ray diffraction (PW3040/60 diffractometer) and scanning electron microscope (SEM, SSX-550)."

Jan 1, 2014

By R. S. Olson

An analysis of the wash thickener-two stage filtration circuit was undertaken to quantitatively describe the circuit performance. On the basis of information developed in this study, the factors of major importance in reducing soluble loss are: filter wash, wash zone size, filter capacity, filter feed pulp dilution, blow back, filter cloth, water to repulp, water to primary wash, water to feed pulp and thickener underflow. The wash thickener-two stage filtration circuit has been used in many hydrometallurgical plants to separate solute from leach solids. As many as 20 to 30 plant operating variables determine the performance of the wash circuit and hence the soluble loss. The complex relationships of these variables, with each other and with soluble loss, make the evaluation of their effect on mill performance difficult. An analysis of this type of circuit was undertaken to quantitatively describe the circuit performance. THE CIRCUIT The diagram in Fig. 1 represents the operation of the wash thickener-two stage filter circuit. This circuit provides for counter current, cross current or for a combination of countercurrent-cross current operation. The feed pulp stream, J, is intended to include any solution or water, other than primary and secondary filtrate, which enters the wash thickener. Except for filter washing, the operations in the circuit are simple mixing operations which can be described by material balance. The concentration of solute in the filtrate and cake solution after application of wash liquor cannot be described by simple material balance. The displacement washing equation, derived by Rhodes1 and extended by Choundhury and Dahlstrom,2 appears to best describe this case of miscible displacement in porous media. In a useful form, it is

Jan 1, 1963

By W. M. Johns

The geological mapping of Lincoln and Flathead Counties was a five-year project undertaken by the Montana Bureau of Mines and Geology. This paper, written by the Project Geologist of the survey, is primarily concerned with the stratigraphy of the Belt rocks encountered in mapping. Lincoln and Flathead Counties of northwestern Montana are underlain by sedimentary rocks of the Belt Series of Precambrian age. In only a very small part of the area, near Libby and Troy, have economic mineral deposits been worked with any success. Most of the area has been inadequately mapped as to geology. The region is crossed by the Great Northern Railway and served by the Pacific Power and Light Co.; officials of these two companies believed that with better geologic maps, prospecting might be stimulated and lead to the discovery of mineral resources that would contribute to new economic development within the area. A cooperative mapping agreement was proposed jointly by the two companies to the Montana Bureau of Mines and Geology in May 1958, and thus was born the Kootenai-Flathead five-year project. The dual objectives of this project are: 1) the possible location of mineral deposits of economic value, and 2) the &apos;&apos;stimulation of prospecting exploration" by others. This was to be achieved by geologic mapping of some 6800 sq miles and by establishing a field office in Kalispell where prospectors could come to have their rocks and minerals identified and receive geological advice on their problems. This writer has finished four field seasons as Project Geologist and thus became familiar with the Belt section in the Libby, Yaak River, Ural, Thompson Lakes, Pleasant Valley, and Stryker quadrangles (see Fig. 1). Progress on the project is given in annual reports issued by the Bureau.* This *Montana Bureau of Mines and Geology, Bulletins 12 (1959), 17 (1960), and 23 (1961). paper is concerned essentially with the stratigraphy of the Belt rocks so far encountered in mapping. PREVIOUS WORK IN THE AREA Willis28 made the first study of the stratigraphy and structure in the Lewis and Livingston Ranges of Glacier Park just east of the project area. In 1904, Daly made a study of the Belt rocks of the 49th parallel, using the names from bottom up, Creston, Kitchener, Moyie, and Gateway, for rocks ranging in age from that of Prichard to that of basal Missoula group. Walcott26 studied the Belt rocks exposed in the Mission Range (see Fig. 1) and other areas to the south of the area under discussion. Calkins and McDonald made a reconnaissance of northern Idaho and northwestern Montana in 1905. Calkins was the first to use Walcott&apos;s term &apos;Ravalli&apos; as a group name for the strata equivalent to the Burke, Revett, and St. Regis formations (see Table I). Clapp worked on the Belt of western Montana (including Lincoln and Flathead Counties) throughout his lifetime. The Fentons9 studied the Belt of Glacier Park and

Jan 1, 1962

What is a nugget effect? In the early development of geostatistics, the term ?nugget effect? was coined for the apparent discontinuity at the beginning of many semivariogram graphs. This name was chosen to reflect the large differences found between neighbouring samples in ?nuggety? mineralizations such as Wits gold reefs. Geostatistical theory assumes that the difference between a sampled value and a potential repeat sample at the same location is actually zero. Included in this ?nugget effect? would be true variation between contiguous samples due to the nature of the mineralization, micro-fracturing, nugget or crystal size, and so on. Also included in the nugget effect would be any ?random? sampling variation which might occur due to the method in which the sample was taken, the adequacy of the sample size, the assaying process, etc. Arguments were put forward that ?sampling errors? actually exist at zero distance. Some geostatistical schools actually maintain that the ?nugget effect? is all sampling error. This would imply that ?perfect? sampling would eliminate the nugget effect entirely. There is now a dichotomy both in the geostatistical world and in the software packages provided for geostatistical analyses. It may seem academic to argue over whether the semivariogram model should take a value of zero, a value equal to the nugget effect, or a partial value at distance zero. However, the decision can have a profound effect on both the estimated resource and in our confidence on that resource. Whereas most geostatistical texts define the semivariogram model as taking the value of zero at zero distance, others imply that the full nugget effect should be used at zero distance. For example: ?The nugget effect refers to the nonzero intercept of the variogram and is an overall estimate of error caused by measurement inaccuracy and environmental variability occurring at fine enough scales to be unresolved by the sampling interval3 ?Christensen4 has shown that the ?nugget effect?, or non-zero variance at the origin of the sernivariogram, can be reproduced by a measurement error model ?The nugget effect is considered random noise and may represent short-scale variability, measurement error, sample rate, etc.5. In many training texts and Web courses, the definition of the semivariogram is ambiguous as the formulae for semivariogram models is not actually specified at zero distance6,7,8.

Jan 1, 2010

By K. D. Peaslee

Slag splashing is an important development that has dramatically improved BOF vessel campaign life and reduced operating costs. This paper highlights research from physical modeling work using a 1/8-scale room temperature model BOF and slag characterization studies from several plants in North America and China. In the model studies, gas flow rate during blow and viscosity of the liquid were found to be two of the most important factors to changing the overall rate of liquid splashed onto the vessel sidewalls. When the flow rate was increased or viscosity decreased, the lower regions of the walls were splashed at a much greater rate. It was also shown that by changing the lance height, more liquid was deposited in the upper regions of the vessel at the expense of lower regions. Reducing the number of nozzles was found to be the most effective method of selectively coating a particular vertical section of the wall. Studies of BOF&apos;s using slag splashing in North America and China showed a difference in the melting characteristics of the final slag. Generally, slag splashing is successful when the melting point of the slag is 220-270°C below the tap temperature to maintain a balance between fluidity and refractoriness.

Jan 1, 2004

By J. M. Cases

Study of the normal interaction between flotation collectors and the silicates through measurement of the electrokinetic potential carried out by the streaming potential and flotation recovery methods indicates that the interaction is wholly 07 partly of electrostatic origin. In some cases, it partly consists of the chemical affinity of the polar head of the collector for the active surface sites. Reagents composed of a polar head and a paraffinic chain and forming micelles in solution were used as flotation collectors. They are sodium dodecylsulfate (anionic collector) and dode-cylammonium chloride (cationic collector). The adsorption isotherms on biotite of alkylamine chloride having 10 to 18 carbon atoms in their chain all show a sharp change in slope relevant to the condensation of alkylammonium ions into bidimensional phase.1-1 Condensation is possible because of the relative homogeneity of the adsorbing surface and of the very strong lateral binding forces through Van der Waals type bonds in the adsorption layer. The different isotherms are seen to coincide when, instead of the equilibrium concentration, the under-saturation ?µ = kT In C/C, is plotted in abscissa, C representing the concentration of the solution with which the adsorbed layer is in equilibrium and C, the saturation concentration of micelles in solution or. critical micellar concentration. More particularly, the undersaturation ?,u1*, corresponding to a surface coverage 6 of 0.5, is equal to Since silicates immersed in aqueous solutions show a surface charge which is a function of pH, it is of primary importance to study the influence of this parameter on the adsorption of collector ions acting as Strong electrolytes in the pH range where they are utilized. The aim of this present paper is to determine by studying electrokinetic phenomena and recovery curves effectuated with a cationic collector and a anionic collector, the nature of the normal adsorbate-adsorbent interaction. Tables 1 and 2 sum up part of the results previously obtained&apos;H11 for the determination of the point of zero charge of the silicate studied by the streaming potential method. Throughout the remainder of this paper, the surface charge will be considered positive for all values of pH below the point

Jan 1, 1971

By Roy H. Grau

The National Institute for Occupational Safety and Health (NIOSH) has conducted research to improve the ventilation of large-opening mines whose entries are at least 93m2 (1,000 ft2). The ventilation of large-opening mines is unique compared to other types of mines because (1) it is challenging to keep airflow velocities high enough to effectively remove or dilute airborne contaminants because the entries are so large, (2) large air volumes can be moved through the mines with little static pressure drop, and (3) stoppings that are used to direct ventilation airflows are costly to construct and to maintain. The research results suggest that the ventilation of large-opening mines is improved significantly by incorporating ventilation planning into the mine planning process, using propeller fans to direct airflow, developing new stopping materials and construction methods, and using long pillars to eliminate crosscuts where possible.

Jan 1, 2009

By R. Flatabø, K-E. Johansen, L. Hunsbedt, P. M. Cowx, J. A. Bustnes

Eramet and Tinfos are two producers of manganese alloys in Norway, which have worked hard for several decades to improve both the internal and external environment. Furnaces producing ferro- and silico- manganese alloys generate large amounts of off-gas that contains substantial amounts of dust, heavy metals and organic by-products. The dust is separated from the gas in venturi scrubbers by washing with water. The water is cleaned and recirculated, and the surplus water coming from moisture in the raw materials, is discharged to the adjacent fjords after further treatment. Emission figures show that the discharge of suspended solids, manganese, zinc and PAH (polycyclic aromatic hydrocarbons) have been reduced substantially over the last three decades as a result of process improvements and installation of state of the art environmental control measures. The two plants were the first world wide to install mercury cleaning of the off-gases from the furnaces. Mercury emission reduction has exceeded 90%. Concerning other environmental issues, such as utilisation of off-gases for energy recovery and chemical purposes, both plants have achieved good results. Major effort in the environmental work has come from the plants themselves, but other players like FFF, The Norwegian Ferroalloy Producers Research Association, and SFT, The Norwegian Pollution Control Authority, have contributed to the achieved results.

Jan 1, 2007

By M. Potesser

In the past, different furnace types have been developed for use within the copper industry, with two common anode furnace designs typically used in copper smelting plants worldwide: the tiltable reverberatory furnace (KPO) generally used for the secondary copper industry and the cylindrical or drum type anode furnace (TRO) for handling a liquid blister charge generated in primary copper production. The disadvantage of the KPO is its design related to the longer refining period, because of the low bath depth, however it provides good conditions in the melting period due to its large bath surface. On the other hand, small amounts of scrap charged into the TRO increase the melting and dissolution period, but it provides good conditions for the refining period. The newly-developed elliptical furnace concept (TRE) offers the advantages of each of these furnace types. The special design allows melting of the scrap more efficiently than in the KPO and refining the liquid copper more efficiently than the TRO. This paper shows a metallurgical comparison of the three furnace types in regard to the melting period by heat technological considerations (optimized arch design) and of the refining period done by CFD with concentration on current, recirculation and dwell time of the gas in the melt. The paper outlines the possibilities for a reduction of the tap-to-tap time and energy consumption as well as for an increase of the production capacity, which can be achieved by applying the TRE instead of the conventional furnace designs.

Jan 1, 2007

By Keith A. Heasley, Timotlly M. Barton

Historically, the surface subsidence over underground coal mines has been predicted using empirical profile or influence functions which have little or no connection to the actual mechanics of the subsidence- Without a mechanistic basis, establishing the exact site-specific parameters to use in these empirical methods has been problematic. A practical subsidence predictive method based on mechanics has the appealing capability of allowing the determination of site-specific parameters from fundamental properties of the overburden with minimal field calibration work. This paper presents a case study where a mechanics-based, boundary-element program is used to calculate the surface subsidence associated with several panels of a Northern Appalachian longwall coal mine. The program used in this case study is called LAMODEL, and it incorporates a frictionless, laminated overburden into a general purpose displacement-discontinuity code primarily designed for calculating the stresses and displacements in coal mines or other thin seam or vein type deposits. In this paper. the program is used to calculate both the underground convergence and the resulting surface subsidence at three longwalls. The subsidence results from the model are compared with field measurements and analyzed The results from the case study in this paper demonstrate that the laminated model with calibrated properties can easily provide fairly accurate subsidence predictions and is fairly flexible for fitting measured subsidence. However, additional subsidence predictive case studies are recommended in order to ultimately evaluate the potential of the laminated overburden model for practical subsidence prediction